CN104845640B - The clay-based sand fixation material for function of being fixed the sand with water saving temperature adjustment - Google Patents
The clay-based sand fixation material for function of being fixed the sand with water saving temperature adjustment Download PDFInfo
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- CN104845640B CN104845640B CN201510238922.0A CN201510238922A CN104845640B CN 104845640 B CN104845640 B CN 104845640B CN 201510238922 A CN201510238922 A CN 201510238922A CN 104845640 B CN104845640 B CN 104845640B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2105/00—Erosion prevention
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Abstract
The invention discloses it is a kind of integrate water saving, temperature adjustment, function of fixing the sand multi-functional clay-based sand fixation material, belong to sand control and sand stabilization field.The sand fixation material of the present invention is prepared using clay, biomass castoff, animal bone, animal wastes, perlite, lactic acid, potassium hydroxide, phosphoric acid, naturally occurring emulsifying agent, cellulose as raw material by certain technique.Desert surface is directly sprayed on spray appliance during use, skinning thickness control is in 5 ~ 10mm.Experiment shows that product of the present invention integrates temperature adjustment, economizes on water, fixes the sand, and raw material is natural products, and cost is cheap, and preparation technology is simple, will not cause any secondary pollution after use to environment, has to desert area vegetation restoration and reconstruction and energetically acts on.
Description
Technical field
The present invention relates to a kind of clay-based sand fixation material, more particularly to a kind of there is water saving, temperature adjustment, the clay for function of fixing the sand
Base sand fixation material, belong to sand control and sand stabilization field.
Background technology
Desertification is a global ecological environment problem.Counted according to United Nations Environment Programme (UNEP), entirely
The area that ball has been subjected to and be expected to be influenceed by desertification accounts for the 35% of global land area.China is desertification in the world
One of serious country.National desert, gobi and sandy land are generally investigated and desertification finding shows, China's Desertification Soil
Area is 262.2 ten thousand square kilometres, accounts for the 27.4% of area, nearly 400,000,000 population is endangered by desertification, every year because of desert
For direct economic loss caused by changing harm up to 120,000,000,000 yuan, ecology, society and economy receive serious influence.
Solves the problems, such as desert area Ecological Restoration, matter of utmost importance is the mobile problem for solving the grains of sand.On different ground
Area, the control measures of shifting sand area are different, but mainly have engineering to fix the sand, sand consolidation with biologic, 3 kinds of chemical sand-fixing.Contrast actual effect hair
Existing, most of engineering is fixed the sand(Such as use nylon grid)And chemical sand-fixing(Such as use waterglass)It is failure, and can be to husky area
Environment brings serious secondary pollution.In recent years, with the improvement of people's environmental awareness, using based on vegetative sand control, engineering arranges
Apply and fix the sand(Use environment friendly materials)Supplemented by sand-fixation method by large-scale popularization.Secondly, revegetation is recovered.The life of vegetation
Deposit, be unable to do without nutrition and moisture, but drift sand does not provide this two classes material just, it is therefore, how permanent effective for plant of fixing the sand
Thing provides nutrition and moisture, is the essential condition of ecological restoration and ecological construction.In addition, desert day and night temperature is big, the temperature rapid drawdown that rises sharply shows
As the survival to husky area plant also has important influence.So a kind of green sand-consolidating agent of exploitation is particularly important.
At present, the research of sand-consolidating agent is relatively broad, reports that most is exactly chemical sand-fixing materialses, such as interior cross-linking type can biology
Degraded Waterborne polyurethane sand-fixing agent, Cornstarch Grafting Acrylic Acid/Vinyl Acetate Copolymer sand-consolidating agent, the organic sand-consolidating agent of macromolecule, biomass
Discarded object is combined the sand-consolidating agent, inorganic salts sand-consolidating agent etc. prepared with chemical reagent.The major advantage of chemical sand-fixing materialses is to prepare
It is convenient, good weatherability, but its shortcoming is also fatal, after most of chemical sand-fixing materialses spray on drift sand surface, causes Sha Shengzhi
Thing Large Scale Death, rainwater it is also bad by property, it is often more important that after Shamian Island is destroyed, the chemistry stayed in desert is consolidated
Husky agent can cause secondary pollution to environment, it is difficult to cleaning of degrading.
In numerous sand-consolidating agents, starch base sand-consolidating agent, biomass castoff base sand-consolidating agent and clay-based sand-consolidating agent have been
Loopful protecting degradable, the nutrition of growth can also be provided to psammophytes, but starch base sand-consolidating agent will use substantial amounts of starch,
The raising of cost can be caused, the also supply to grain causes potential danger.Biomass castoff and clay-based sand-consolidating agent from
Can fundamentally solve the two problems, be the study hotspot in sand-consolidating agent field in recent years.
Chinese patent(CN 102229804 A)In refer to a kind of clay-based sand fixation material, the clay-based compound sand consolidating material
Material, for raw material, is mixed according to a certain percentage with clay, waterglass, lewis acid, organic polymer etc., adds water to be configured to certain dense
After the solution of degree, the surface of sand is sprayed onto, is spontaneously dried in open-air atmosphere by it, forms consolidation skin;Or first by clay and sand
Be well mixed according to a certain percentage, stack into grid, then in the sprinkling of its surface by waterglass, lewis acid, organic polymer and
The solution that water is made into, spontaneously dried in open-air atmosphere by it, form consolidation skin, be prepared into preventing and fixing sand firewood soil lattice.The invention
Shortcoming is that waterglass and high-molecular organic material have largely been used in raw material, and such sand-consolidating agent still results in secondary to environment
Harm.Chinese patent(CN 103289017 A)Using clay as primary raw material, graft copolymerization acrylic amide, biogum obtain
Sand-consolidating agent, although the invention refer to the effect of water conservation insulation, the costs of material are largely improved using polyacrylamide,
Reduce the degradation capability of material.
The content of the invention
The purpose of the present invention is to be directed to problems of the prior art, there is provided a kind of that there is water saving temperature adjustment to fix the sand function
Clay-based sand fixation material.
First, clay-based sand fixation material
The clay-based sand fixation material of function of the invention of being fixed the sand with water saving temperature adjustment, is with clay, biomass castoff, animal
Bone, animal wastes, perlite, potassium hydroxide, phosphoric acid, lactic acid, naturally occurring emulsifying agent, cellulose are prepared for raw material.It has
Body raw material proportioning and preparation technology are as follows:
Raw material proportioning:In parts by weight
60 ~ 85 parts of clay, 15 ~ 8 parts of biomass castoff, 5 ~ 2 parts of animal bone, 5 ~ 1 parts of animal wastes, perlite 2 ~ 1
Part, 3 ~ 1 parts of lactic acid, 3 ~ 0.3 parts of potassium hydroxide, phosphatase 11 ~ 0.1,1 ~ 0.6 part of naturally occurring emulsifying agent, 5 ~ 1 parts of cellulose.
Preparation technology:
(1)Biomass castoff, animal wastes dry, pulverize, mixed after crossing 400 mesh sieves, and quality is configured to water
Fraction is 55 ~ 80% suspension;After adding potassium hydroxide, 5 ~ 15h is activated at 55 ~ 100 DEG C, phosphoric acid neutralization is added, obtains
The biomass castoff and animal wastes suspension of activation;
(2)Animal bone is crushed, is configured to the suspension that mass fraction is 2 ~ 10% with water after 400 mesh sieves excessively, and 35
2 ~ 5h, the animal bone gelatinous solid activated are activated at ~ 100 DEG C;
(3)By the biomass castoff of activation and animal wastes suspension, the animal bone gelatinous solid of activation, stick
High-speed stirred after soil, perlite powder, lactic acid, cellulose and naturally occurring emulsifying agent mixing(Mixing speed is 800 ~ 1500r/min,
Time is 1 ~ 3h), then plus water is configured to the emulsion that mass fraction is 10 ~ 30%, produces the sand fixation material of the present invention.
Wherein clay is loess, laterite, carclazyte, black earth, palygorskite, montmorillonite, kaolin etc.;Its particle diameter 200 mesh with
On.The main function of clay forms clay skinning, and plays insulation effect, while provides nutrition for plant.
Biomass castoff uses straw(Maize straw, rice straw, peanut straw, wheat stalk, potato straw
Stalk, broomcorn straw, grain straw, sunflower straw, buckwheat stalk, sawdust, leaf), waste potato dregs etc..Biomass castoff
Mainly strengthen the weather-proof effect of clay skinning resistance to compression, biomass castoff can be clay skinning internal defect in addition, increase
Add the gas permeability of plant root.
Naturally occurring emulsifying agent can be at least one of lecithin, lanolin, lanonol, lanolin fatty acid, beeswax;It is natural emulsified
The effect of agent is each component in aqueous dispersion, each component is more uniformly mixed, and sand fixation material is existed
Reduction is separated during transporting use.
The particle diameter of the perlite is in 400 ~ 800 mesh;Perlite mainly cooperates with clay, and the temperature for increasing sand fixation material is adjusted
Control acts on.
Cellulose can be with methylcellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose.Cellulose is in solution state
When, play a part of lubrication so that the sprinkling of solution is more smoothly;After sand fixation material skinning, the material is in solid state energy
Enough improve the Resistance to wind Erosion of clay skinning.
Animal bone can be the bone of any animal, and it acts on the effect for mainly playing natural glue, and addition should
After material, the time that skinning is formed can greatly shorten, so that the efficiency of sand fixation material.
The excrement of any animal of animal wastes, it provides the effect of natural nutrition element for plant;Contain in the other material
There is substantial amounts of microorganism, the growth of the porousness of skinning, more conducively plant can be regulated and controled.Skinning too closely, is unfavorable for planting
The growth of thing.
Potassium hydroxide mainly activates to biomass castoff, can be preferably compatible with other components, from
And the Resistance to wind Erosion of skinning is improved, and introduced for plant and grow necessary potassium element.
Phosphoric acid is mainly to neutralize the alkaline problem that potassium hydroxide is brought, and is introduced for plant and grow necessary P elements.
The application method of above-mentioned sand fixation material:Desert surface, skinning thickness control are directly sprayed on using spray appliance
System is in 5 ~ 10mm.
2nd, sand fixation material performance test
It has selected Badain Jaran and rise the place that two large deserts have a common boundary in lattice, particular location is in Monitor in Minqin County Xi Qu towns
Huang Hui villages.The region sparse survive some sand-fixation plant sacsaouls and sand sagebrush (Artemisia filifolia), survived in addition almost without other plants.Strong wind
Weather is multiple, and with high temperature, dust and sand weather is very frequent, totally unfavorable to vegetative sand control and environment remediation.Geomorphic feature is
Mobility is medium, and soil constituent is practically free of in the grains of sand, can not supply nutrition to plant.
1st, temperature adjustment aptitude tests
Test method:Two pieces of 100m are selected under same environment2Experimental field, one piece of trial zone sprinkling 5mm is thick wherein
Sand-consolidating agent product prepared by the present invention of degree, the temperature variations of different desert depth are tried using surface temperature measurement.
Fig. 1 is that trial zone desert different depth temperature changes over time curve.Fig. 1 result shows that trial zone is 14:
When 00, desert temperature highest, desert surface temperature can reach 52 DEG C, and the desert temperature change of 20 ~ 25cm depths is little.Figure
2 be the influence after sprinkling sand-consolidating agent product of the present invention to desert temperature(B is the temperature change for not spraying this product, and C is sprinkling
The temperature variations in desert after this product).As seen from Figure 2, after desert surface sprays this product, to desert surface
Temperature adjustment ability be very the survival to plant it will be evident which reduces desert surface high temperature to be scorched to plant
Rate improves a lot.
2nd, water-saving ability is tested
Take the stainless steel cuboid container of 100 600 × 200 × 5mm sizes(Sand table), the container bottom is provided with some straight
Footpath 1mm hole facilitates water to ooze out.The drift sand of trial zone is put into the test chamber(Drift sand placement amount using fill just container as
Preferably), and its saturation is absorbed water, afterwards in product of the present invention thick arbitrary 50 sand table surfaces sprinkling 5mm(Record initially every
The weight of sand table), afterwards at regular intervals weigh sand table weight, so as to calculate the water-saving ability of sand-consolidating agent of the present invention(Section
Outlet capacity test is entirely to be completed in experiment desert areas).
Test result:Sand table basic moisture all evaporations after 2 hours of this product, percentage of water loss nearly 100% are not sprayed;Spray
The sand table percentage of water loss of sand-consolidating agent of the present invention has been spilt less than 20%;Sand table percentage of water loss is less than 30% after 8 hours;The dehydration of sand table 100% needs
130 hours.Therefore sand-consolidating agent of the present invention has good water-saving ability, can be that the region plant retains more water resources.
3rd, fix the sand aptitude tests
Tested using to weather-proof wind tunnel test.
Experiment one(Just Resistance to wind Erosion after sprinkling):It is 600 × 200 × 5mm stainless steel models in size(Sand table)It is interior, dress
Full trial zone drift sand simultaneously shakeouts it, and two kinds of commercially available chemical sand-fixing materialses 1,2 and sand-consolidating agent of the present invention are sprayed on sand table, sprayed
Thickness is 5mm, and after natural air drying, the model sample that fixes the sand is placed in into experimental section, and be allowed to respectively with wind-tunnel bottom it is mutually gentle with
Bottom is placed into 30 ° of angle two ways, and deflation experiment is carried out under 10 m/s, 20m/s net wind and saturation dust storm stream mode.
Test result part table 1.
Experiment two(After spraying sand-consolidating agent, Resistance to wind Erosion after being placed 60 days in desert test area):Method of testing is the same as experiment
One.Test result part table 2.
The result of table 1,2 shows, deflation amount of the model under different wind speed be much after sand-consolidating agent prepared by the sprinkling present invention
Less than commercially available sand-consolidating agent 1,2, show that sand-consolidating agent prepared by the present invention has good Resistance to wind Erosion, thus consolidate with good
Husky ability and preferably lasting sand-fixing effect.
In summary, the present invention has the characteristics that relative to prior art:
1st, product of the present invention integrates temperature-regulating and water-saving and fixed the sand, and has to desert area vegetation restoration and reconstruction and energetically makees
With;
2nd, all raw materials of sand-consolidating agent of the present invention are natural products(Without using any artificial synthesized industrial chemicals), use
After any secondary pollution will not be caused to environment;
3rd, the product after alkali activated biomass discarded object is become the material containing nutrient by the present invention, is not only avoided
The reprocessing of alkali lye, and certain nutritional ingredient is with the addition of to sand-consolidating agent, it is more conducive to the growth of plant;
4th, raw material sources of the present invention are extensive, and preparation technology is simple, and cost is cheap, easily popularization and application.
Brief description of the drawings
Fig. 1 is that trial zone desert different depth temperature changes over time curve.
Fig. 2 is the influence after sprinkling sand-consolidating agent product of the present invention to desert temperature.
Embodiment
It is described further below by preparation of the specific embodiment to sand fixation material of the present invention and performance.
Embodiment 1
Raw material proportioning:In parts by weight
60 parts of clay, 15 parts of biomass castoff, 5 parts of animal bone, 5 parts of animal wastes, 2 parts of perlite, 3 parts of lactic acid,
3 parts of potassium hydroxide, phosphatase 11 part, 1 part of lecithin, 5 parts of methylcellulose;
Preparation technology:
It is positioned over after the biomass castoff of crushing and animal wastes are mixed in a kettle, adds running water, configuration
Into the suspension that mass fraction is 75%;Potassium hydroxide is added, 15h is activated at 100 DEG C, phosphoric acid is then added and is neutralized, obtained
To the biomass castoff and animal wastes mixing suspension of activation;
Animal bone is crushed, cross 400 mesh sieves, be added to the water be configured to 10% suspension, be put into reactor, 100
2h is activated at DEG C, obtains the animal bone suspension of activation;
By the biomass castoff of activation and animal wastes suspension, activating animals bone suspension, clay, crushed crude pearlite
End(400 ~ 800 mesh), lactic acid, cellulose and naturally occurring emulsifying agent mixing, at a high speed(800r/min)Stir the 1h times, and add water configuration
Into the emulsion of mass percent 20%.
Embodiment 2
Raw material proportioning:In parts by weight
60 parts of clay, 10 parts of biomass castoff, 5 parts of animal bone, 5 parts of animal wastes, 2 parts of perlite, 3 parts of lactic acid,
3 parts of potassium hydroxide, phosphatase 11 part, 1 part of lanolin, 5 parts of hydroxypropyl methyl cellulose;
Preparation technology:
It is positioned over after the biomass castoff of crushing and animal wastes are mixed in a kettle, adds running water, configuration
Into the suspension that mass fraction is 65%;Potassium hydroxide is added, 15h is activated at 95 DEG C, phosphoric acid is then added and is neutralized, obtained
To the biomass castoff and animal wastes mixing suspension of activation;
Animal bone is crushed, cross 400 mesh sieves, be added to the water be configured to 5% suspension, be put into reactor, at 55 DEG C
Lower activation 5h, obtain the animal bone suspension of activation;
By the biomass castoff of activation and animal wastes suspension, activating animals bone suspension, clay, crushed crude pearlite
End, lactic acid, cellulose and naturally occurring emulsifying agent mixing, at a high speed(1000r/min)Stir the 2h times, and add water to be configured to quality percentage
The emulsion of number 15%.
Embodiment 3
Raw material proportioning:In parts by weight
85 parts of clay, 8 parts of biomass castoff, 2 parts of animal bone, 1 part of animal wastes, 1 part of perlite, 1 part of lactic acid, hydrogen
0.3 part of potassium oxide, phosphoric acid 0.1,0.6 part of lanonol, 1 part of hydroxyethyl cellulose;
Preparation technology:
It is positioned over after the biomass castoff of crushing and animal wastes are mixed in a kettle, adds running water, configuration
Into the suspension that mass fraction is 55%;Potassium hydroxide is added, 15h is activated at 85 DEG C, phosphoric acid is then added and is neutralized, obtained
To the biomass castoff and animal wastes mixing suspension of activation;
Animal bone is crushed, cross 400 mesh sieves, be added to the water be configured to 8% suspension, be put into reactor, at 65 DEG C
Lower activation 5h, obtain the animal bone suspension of activation;
By the biomass castoff of activation and animal wastes suspension, activating animals bone suspension, clay, crushed crude pearlite
End, lactic acid, cellulose and naturally occurring emulsifying agent mixing, at a high speed(800r/min)Stir the 3h times, and add water to be configured to quality percentage
The emulsion of number 25%.
Embodiment 4
Raw material proportioning:In parts by weight
75 parts of clay, 10 parts of biomass castoff, 3 parts of animal bone, 3 parts of animal wastes, 2 parts of perlite, 2 parts of lactic acid,
1.5 parts of potassium hydroxide, phosphoric acid 0.5,0.8 part of beeswax, 3 parts of methylcellulose;
Preparation technology:
It is positioned over after the biomass castoff of crushing and animal wastes are mixed in a kettle, adds running water, configuration
Into the suspension that mass fraction is 55%;Potassium hydroxide is added, 15h is activated at 55 DEG C, phosphoric acid is then added and is neutralized, obtained
To the biomass castoff and animal wastes mixing suspension of activation;
Animal bone is crushed, cross 400 mesh sieves, be added to the water be configured to 2% suspension, be put into reactor, at 35 DEG C
Lower activation 5h, obtain the animal bone suspension of activation;
By the biomass castoff of activation and animal wastes suspension, activating animals bone suspension, clay, crushed crude pearlite
End, lactic acid, cellulose and naturally occurring emulsifying agent mixing, at a high speed(1500r/min)Stir the 1h times, and add water to be configured to quality percentage
The emulsion of number 30%.
In the various embodiments described above, clay is loess, laterite, carclazyte, black earth, palygorskite, montmorillonite, kaolin etc., biology
Matter discarded object uses straw(Maize straw, rice straw, peanut straw, wheat stalk, potato stalk, broomcorn straw,
Grain straw, sunflower straw, buckwheat stalk, sawdust, leaf), waste potato dregs etc..Clay and biomass castoff can bases
The specific resource selection on the spot of various regions.
Claims (8)
- It is with clay, biomass castoff, animal bone, dynamic 1. fixed the sand the clay-based sand fixation material of function with water saving temperature adjustment Thing excrement, perlite, potassium hydroxide, phosphoric acid, lactic acid, naturally occurring emulsifying agent, cellulose are prepared for raw material:Each raw material is pressed Following weight:60 ~ 85 parts of clay, 15 ~ 8 parts of biomass castoff, 5 ~ 2 parts of animal bone, 5 ~ 1 parts of animal wastes, 2 ~ 1 parts of perlite, breast 3 ~ 1 parts of acid, 3 ~ 0.3 parts of potassium hydroxide, phosphatase 11 ~ 0.1,1 ~ 0.6 part of naturally occurring emulsifying agent, 5 ~ 1 parts of cellulose.
- 2. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:Preparation technology Comprise the following steps:(1)Biomass castoff, animal wastes dry, pulverize, mixed after crossing 400 mesh sieves, and mass fraction is configured to water For 55 ~ 80% suspension;Potassium hydroxide is added, 5 ~ 15h is activated at 55 ~ 100 DEG C, phosphoric acid neutralization is added, is activated Biomass castoff and animal wastes suspension;(2)Animal bone is crushed, is configured to the suspension that mass fraction is 2 ~ 10% with water after 400 mesh sieves excessively, and 35 ~ 100 2 ~ 5h, the animal bone gelatinous solid activated are activated at DEG C;(3)The biomass castoff of activation and animal wastes suspension, the animal bone gelatinous solid of activation, clay is precious High-speed stirred after pearl rock dust end, lactic acid, cellulose and naturally occurring emulsifying agent mixing, then plus water is configured to mass fraction as 10 ~ 30% Emulsion, produce sand fixation material.
- 3. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:The clay For at least one of loess, laterite, carclazyte, black earth, palygorskite, montmorillonite, kaolin, particle diameter is more than 200 mesh.
- 4. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:The biology Matter discarded object is straw, waste potato dregs, leaf, bark, rice husk, peanut shell, shell.
- 5. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:It is described natural Emulsifying agent is at least one of lecithin, lanolin, lanonol, lanolin fatty acid, beeswax.
- 6. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:The fiber Element is methylcellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose.
- 7. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:The pearl The particle diameter of rock is in 400 ~ 800 mesh.
- 8. the clay-based sand fixation material for function of being fixed the sand as claimed in claim 1 with water saving temperature adjustment, it is characterised in that:The high speed Mixing speed is 800 ~ 1500r/min, and mixing time is 1 ~ 3h.
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