CN104797959B - 可调节的比色湿气指示器 - Google Patents

可调节的比色湿气指示器 Download PDF

Info

Publication number
CN104797959B
CN104797959B CN201380059413.0A CN201380059413A CN104797959B CN 104797959 B CN104797959 B CN 104797959B CN 201380059413 A CN201380059413 A CN 201380059413A CN 104797959 B CN104797959 B CN 104797959B
Authority
CN
China
Prior art keywords
composition
metal oxide
glyoxime
relative humidity
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380059413.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN104797959A (zh
Inventor
姜明灿
E·K·L·Y·哈吉梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN104797959A publication Critical patent/CN104797959A/zh
Application granted granted Critical
Publication of CN104797959B publication Critical patent/CN104797959B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
    • G01N21/81—Indicating humidity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
    • G01N31/222—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating moisture content
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/49—Materials comprising an indicator, e.g. colour indicator, pH-indicator
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N2021/7793—Sensor comprising plural indicators

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • General Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Biophysics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Silicon Compounds (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
CN201380059413.0A 2012-11-14 2013-11-14 可调节的比色湿气指示器 Expired - Fee Related CN104797959B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261726251P 2012-11-14 2012-11-14
US61/726,251 2012-11-14
PCT/US2013/070061 WO2014078512A1 (en) 2012-11-14 2013-11-14 Adjustable colorimetric moisture indicators

Publications (2)

Publication Number Publication Date
CN104797959A CN104797959A (zh) 2015-07-22
CN104797959B true CN104797959B (zh) 2018-12-28

Family

ID=50731677

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380059413.0A Expired - Fee Related CN104797959B (zh) 2012-11-14 2013-11-14 可调节的比色湿气指示器

Country Status (5)

Country Link
US (1) US10119918B2 (https=)
EP (1) EP2920621A4 (https=)
JP (1) JP6329166B2 (https=)
CN (1) CN104797959B (https=)
WO (1) WO2014078512A1 (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105074455B (zh) * 2013-03-15 2018-02-16 3M创新有限公司 蒸汽灭菌后湿气指示制品
EP3389848B1 (en) * 2015-12-18 2023-11-15 3M Innovative Properties Company Metal-containing sorbents for nitrogen-containing compounds
WO2017112450A1 (en) 2015-12-22 2017-06-29 3M Innovative Properties Company Internally incorporated phenolic resins in water-based (meth)acrylate adhesive compositions, pre-adhesive reaction mixtures, methods, and articles
US10759980B1 (en) 2015-12-22 2020-09-01 3M Innovative Properties Company Packaged pre-adhesive composition including a polylactic acid-containing packaging material, adhesives, and articles
FR3066603B1 (fr) * 2017-05-22 2019-07-05 Universite D'aix-Marseille Dispositif optique de detection et de quantification de composes volatils
WO2018229689A2 (en) * 2017-06-16 2018-12-20 3M Innovative Properties Company Air filters comprising metal-containing sorbents for nitrogen-containing compounds
US11371945B2 (en) * 2018-11-23 2022-06-28 EWHA University—Industry Collaboration Foundation Ultrafast colorimetric humidity sensor and method of preparing the same
TWI867933B (zh) * 2024-01-08 2024-12-21 國立中山大學 二維丁二肟－銥奈米片及其製造方法
TWI903751B (zh) * 2024-01-08 2025-11-01 國立中山大學 比色系統

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1576801A (zh) * 2003-07-10 2005-02-09 佳能株式会社 环境传感器
US20080163673A1 (en) * 2007-01-08 2008-07-10 Attar Amir J Irreversible humidity exposure dose indicator device
CN101432617A (zh) * 2006-04-26 2009-05-13 共同印刷株式会社 湿度指示剂用涂料及其制备方法、使用该涂料形成的湿度指示剂
CN102046699A (zh) * 2008-05-26 2011-05-04 巴斯夫欧洲公司 制备多孔材料的方法和通过该方法制备的多孔材料

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2580737A (en) 1949-01-19 1952-01-01 Davison Chemical Corp Cobalt chloride humidity indicator
US2627505A (en) 1951-04-11 1953-02-03 Davison Chemical Corp Relative humidity indicator
US3121615A (en) 1960-09-02 1964-02-18 Mine Safety Appliances Co Colorimetric moisture indicator
US4034609A (en) 1976-01-02 1977-07-12 Fuller David L Digital sensing device
DE2829091A1 (de) 1978-07-03 1980-01-17 Dynamit Nobel Ag Insolubilisierte reagenzien enthaltene kieselgele
AU614170B2 (en) 1988-08-26 1991-08-22 Minnesota Mining And Manufacturing Company A steam sensitive composition and a sterilization indicator composition containing the same
US5320969A (en) 1992-10-22 1994-06-14 Miles Inc. Method, composition and device for the semiquantitative determination of specific gravity of a test sample
CN1202909A (zh) * 1995-11-27 1998-12-23 陶氏化学公司 含有束缚阳离子生成活化剂的负载型催化剂
US6698378B1 (en) 2000-09-12 2004-03-02 Sud-Chemie Inc. Irreversible humidity indicator cards
EP1213583A1 (en) * 2000-12-06 2002-06-12 Innosense S.r.l. General method for the covalent immobilisation of indicators in, or onto a support useful for the fabrication of optical sensors
US8545762B2 (en) * 2002-12-30 2013-10-01 Board Of Trustees Of Northern Illinois University Sensor for detecting compounds
US7098253B2 (en) 2004-05-20 2006-08-29 3M Innovative Properties Company Macroporous ion exchange resins
EP1799693A1 (en) 2004-09-22 2007-06-27 Benjamin David Hatton Method of transformation of bridging organic groups in organosilica materials
US7674835B2 (en) 2005-12-21 2010-03-09 3M Innovative Properties Company Method of making macroporous anion exchange resins
US7683100B2 (en) 2005-12-21 2010-03-23 3M Innovative Properties Company Method of making macroporous cation exchange resins
JP2007322345A (ja) 2006-06-05 2007-12-13 Iwatani Industrial Gases Corp 脱湿検知剤とその製造方法
US8067110B2 (en) * 2006-09-11 2011-11-29 3M Innovative Properties Company Organic vapor sorbent protective device with thin-film indicator
US20120045515A1 (en) 2009-02-04 2012-02-23 Ye Liu Hollow silica particle with a polymer thereon
US10464811B2 (en) * 2009-04-06 2019-11-05 Nanyang Technological University Method of forming a particulate porous metal oxide or metalloid oxide
US8671739B2 (en) 2010-12-10 2014-03-18 Clariant Prosukte (Deutschland) GmbH Indicator material and indicator device comprising said indicator material
US20140011287A1 (en) 2011-03-31 2014-01-09 Evan K.L.Y. Hajime Method and device for indicating moisture based on bis(glyoxime)-transition metal complexes
CN104781703A (zh) 2012-11-14 2015-07-15 3M创新有限公司 可调节的比色湿气指示器

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1576801A (zh) * 2003-07-10 2005-02-09 佳能株式会社 环境传感器
CN101432617A (zh) * 2006-04-26 2009-05-13 共同印刷株式会社 湿度指示剂用涂料及其制备方法、使用该涂料形成的湿度指示剂
US20080163673A1 (en) * 2007-01-08 2008-07-10 Attar Amir J Irreversible humidity exposure dose indicator device
CN102046699A (zh) * 2008-05-26 2011-05-04 巴斯夫欧洲公司 制备多孔材料的方法和通过该方法制备的多孔材料

Also Published As

Publication number Publication date
US10119918B2 (en) 2018-11-06
CN104797959A (zh) 2015-07-22
US20150293028A1 (en) 2015-10-15
JP2016505478A (ja) 2016-02-25
EP2920621A1 (en) 2015-09-23
WO2014078512A1 (en) 2014-05-22
JP6329166B2 (ja) 2018-05-23
EP2920621A4 (en) 2016-08-10

Similar Documents

Publication Publication Date Title
CN104797959B (zh) 可调节的比色湿气指示器
CN104781703A (zh) 可调节的比色湿气指示器
JP5819841B2 (ja) 複素環芳香族化合物等を捕捉、検出及び定量化するための材料及び方法
CN107250286B (zh) 具有高色度和高亮度的红色装饰颜料、其制造方法及其用途
CN107109079B (zh) 具有高透明性、高色饱和度和高亮度的效应颜料、其制备方法和用途
CN102308208B (zh) 具有微孔有机硅酸盐材料的有机化学传感器
ES2727632T3 (es) Pigmentos de efecto metálico con croma elevado y brillo elevado, procedimiento para su producción y empleo de los mismos
CN104781652A (zh) 蒸汽灭菌后湿气指示方法和制品
Damaceanu et al. The chromic and electrochemical response of CoCl2− filled polyimide materials for sensing applications
US9921199B2 (en) Method for indicating moisture based on bis(glyoxime)-transition metal complexes
EP2318471B1 (en) Conjugated nanoparticles and their use in detection of latent fingerprints
CN105277553B (zh) 茚三酮/纳米二氧化钛复合物及其制备方法和用途
CA2478430C (en) Modified oxidic nano-particle with hydrophobic inclusions, method for the production and use of said particle
US20180011025A1 (en) Retroreflector providing the functions of retroreflection and pickup of a parameter of the environment
Sedmak et al. Silane-modified lanthanide complexes for integration into hybrid coatings and nanoparticles: thermal sensing applications and live cell labeling
CN113943573A (zh) 一种空心莲子草制备荧光碳量子点及检测柠檬黄的方法
EP4484501A1 (en) Dye and method for producing same, solution, metal hydroxyl amount evaluation method, and metal hydroxyl processing rate evaluation method
CN121164259B (zh) 一种基于荧光传感器的检测系统及其制备方法和应用
CN108610483A (zh) 一种耐氧化高纯二甲基硅油及其合成方法
CN109337671A (zh) 层状光致变色薄膜及其制备方法
Wang et al. Multifunctional white-light-emission SQDs/Eu³⁺@ UIO-66: ratiometric sensing, smartphone-assisted antibiotics/Cr (VI) detection, and information encryption

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20181228

Termination date: 20191114

CF01 Termination of patent right due to non-payment of annual fee