CN104786163A - 陶瓷结合剂钻石磨具及其制备方法 - Google Patents
陶瓷结合剂钻石磨具及其制备方法 Download PDFInfo
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- 238000000227 grinding Methods 0.000 title claims abstract description 78
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 66
- 239000010432 diamond Substances 0.000 title claims abstract description 66
- 239000000919 ceramic Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000007767 bonding agent Substances 0.000 title abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 35
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 18
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 16
- 239000003595 mist Substances 0.000 claims description 15
- 238000005245 sintering Methods 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 claims 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 3
- 238000005498 polishing Methods 0.000 abstract description 11
- 238000005299 abrasion Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 210000001138 tear Anatomy 0.000 description 2
- 239000002969 artificial stone Substances 0.000 description 1
- 238000009414 blockwork Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
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- B24D3/14—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings
- B24D3/18—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings for porous or cellular structure
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Abstract
本发明提供一种陶瓷结合剂钻石磨具,以质量分数计,该陶瓷结合剂钻石磨具由20%~50%的磨粒和50%~80%的陶瓷结合剂组成。本发明还提供一种陶瓷结合剂钻石磨具的制备方法。上述陶瓷结合剂钻石磨具磨抛工件时所需压力小、磨耗小、使用寿命长、磨削力强、研磨效率大大提高。
Description
技术领域
本发明涉及磨具,特别是涉及一种陶瓷结合剂钻石磨具及其制备方法。
背景技术
瓷砖、石材(含人造石材)等板面的精磨、抛光加工,传统多采用碳化硅磨具和以金刚石为磨料的磨具。碳化硅磨具在磨抛工件时自身磨损较块,使用寿命极短,且碳化硅磨具磨抛工件时需要给予较大压力,容易造成工件破损、增加机器磨损及能耗。
此外,以金刚石为磨料的磨具广泛应用在切削、研磨等行业。这种磨具是以金刚石颗粒为磨粒,将其与结合剂混合后经成型、烧结(固结)而制备。传统的抛光砖及石材研磨抛光用的金刚石磨具使用的结合剂主要有两类:金属结合剂和树脂结合剂。以金属作为结合剂的金刚石磨块由于金属材料自锐性差,可用于粘结600目以粗的金刚石对抛光砖或石材进行粗磨。以树脂作为结合剂时由于树脂与金刚石颗粒间的结合力差,使得磨块磨削力弱、寿命较短、磨块工作时磨耗大,在大批量连续研磨抛光时需频繁更换磨块,使其应用场合收到很大限制。
发明内容
基于此,有必要针对传统的磨具磨削力弱、磨耗大、使用寿命短、研磨效率低的问题,提供一种磨削力强、磨耗小、使用寿命长及研磨效率高的陶瓷结合剂钻石磨具。
此外,还提供一种陶瓷结合剂钻石磨具的制备方法。
一种陶瓷结合剂钻石磨具,以质量分数计,所述陶瓷结合剂钻石磨具由20%~50%的磨粒和50%~80%的陶瓷结合剂组成。
在其中一个实施例中,以所述磨粒的质量为基准,所述磨粒中含有50%~90%的钻石微粉和10%~50%的碳化硅或三氧化二铝。
在其中一个实施例中,以所述陶瓷结合剂的质量为基准,所述陶瓷结合剂中含有1%~3%的纤维素、3%~15%的水及余量的陶瓷粉末。
在其中一个实施例中,所述钻石微粉粒度为22μm~36μm、12μm~22μm、8μm~12μm、4μm~8μm、2μm~4μm、1μm~2μm、0.5μm~1μm或0μm~0.5μm。
在其中一个实施例中,所述碳化硅或三氧化二铝的粒度比所述钻石微粉的粒度高一个粒度级。
在其中一个实施例中,以所述陶瓷粉末的质量为基准,所述陶瓷粉末中含有35%~45%的氧化硅、25%~35%的氧化铝、10%~20%的氧化镁和10%~20%的氧化锌。
上述陶瓷结合剂钻石磨具磨抛工件时所需压力小、磨耗小、使用寿命长、磨削力强、研磨效率大大提高。
一种陶瓷结合剂钻石磨具的制备方法,包括以下步骤:
将磨粒和陶瓷结合剂混合,冷压成型后高温烧结,得到陶瓷结合剂钻石磨具,所述陶瓷结合剂钻石磨具中磨粒的质量百分含量为20%~50%、陶瓷结合剂的质量百分含量为50%~80%。
在其中一个实施例中,以所述磨粒的质量为基准,所述磨粒中含有50%~90%的钻石微粉和10%~50%的碳化硅或三氧化二铝;
以所述陶瓷结合剂的质量为基准,所述陶瓷结合剂中含有1%~3%的纤维素、3%~15%的水及余量的陶瓷粉末。
在其中一个实施例中,所述冷压成型的条件为常温、2吨/cm2的压力。
在其中一个实施例中,所述高温烧结的温度为800℃~880℃。
上述陶瓷结合剂钻石磨具的制备方法简单、制备出的陶瓷结合剂钻石磨具磨抛工件时所需压力小、磨耗小、使用寿命长、磨削力强、研磨效率大大提高。
具体实施方式
为使本发明的上述目的、特征和优点能够更加明显易懂,下面对本发明的具体实施方式做详细的说明。在下面的描述中阐述了很多具体细节以便于充分理解本发明。但是本发明能够以很多不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本发明内涵的情况下做类似改进,因此本发明不受下面公开的具体实施的限制。
一种陶瓷结合剂钻石磨具,含有20%~50%质量百分含量的磨粒和50%~80%质量百分含量的陶瓷结合剂。
在本实施方式中,陶瓷结合剂钻石磨具中含有45%质量百分含量的磨粒和55%质量百分含量的陶瓷结合剂。
其中,磨粒中含有50%~90%质量含量的钻石微粉和10%~50%质量含量的碳化硅或三氧化二铝。
陶瓷结合剂中含有1%~3%质量百分含量的纤维素、3%~15%质量百分含量的水及余量的陶瓷粉末。
优选的,钻石微粉的粒度为22μm~36μm(通常写作22/36,单位为μm)、12μm~22μm(通常写作12/22,单位为μm)、8μm~12μm(通常写作8/12,单位为μm)、4μm~8μm(通常写作4/8,单位为μm)、2μm~4μm(通常写作2/4,单位为μm)、1μm~2μm(通常写作1/2,单位为μm)、0.5μm~1μm(通常写作0.5/1,单位为μm)或0μm~0.5μm(通常写作0/0.5,单位为μm)。
碳化硅或三氧化二铝的粒度为钻石微粉的粒度高一个粒度级。
例如,钻石微粉的粒度为4μm~8μm,碳化硅或三氧化二铝的粒度为8μm~12μm。
陶瓷粉末为纳米级陶瓷粉末。
陶瓷粉末中含有35%~45%质量百分含量的氧化硅、25%~35%质量百分含量的氧化铝、10%~20%质量百分含量的氧化镁和10%~20%质量百分含量的氧化锌。
上述陶瓷结合剂钻石磨具用于瓷砖、石材等板面的精磨、抛光加工,且磨抛工件时所需压力小、磨耗小、使用寿命长、磨削力强、研磨效率大大提高。
一种陶瓷结合剂钻石磨具的制备方法,包括以下步骤:
将磨粒和陶瓷结合剂混合,冷压成型后高温烧结,得到陶瓷结合剂钻石磨具,所述陶瓷结合剂钻石磨具中磨粒的质量百分含量为20%~50%、陶瓷结合剂的质量百分含量为50%~80%。
其中,磨粒中含有50%~90%质量百分含量的钻石微粉和10%~50%质量百分含量的碳化硅或三氧化二铝;
所述陶瓷结合剂中含有1%~3%质量百分含量的纤维素、3%~15%质量百分含量的水及余量的陶瓷粉末。
优选的,钻石微粉的粒度为22μm~36μm、12μm~22μm、8μm~12μm、4μm~8μm、2μm~4μm、1μm~2μm、0.5μm~1μm或0μm~0.5μm。
碳化硅或三氧化二铝的粒度为钻石微粉的粒度高一个粒度级。
例如,钻石微粉的粒度为4μm~8μm,碳化硅或三氧化二铝的粒度为8μm~12μm。
陶瓷粉末为纳米级陶瓷粉末。
陶瓷粉末中含有35%~45%质量百分含量的氧化硅、25%~35%质量百分含量的氧化铝、10%~20%质量百分含量的氧化镁和10%~20%质量百分含量的氧化锌。
其中,冷压成型的条件为常温、2吨/cm2的压力。
高温烧结的温度为800℃~880℃。
具体的,陶瓷结合剂钻石磨具的制备方法如下:
将上述粒度范围中某一粒度的钻石微粉与大一粒度级的碳化硅或三氧化二铝混合,得到磨粒;
在上述磨粒中加入少量(能覆盖磨粒即可)乙醇均匀润湿,再与陶瓷结合剂混合,搅拌均匀后,冷压成型后高温烧结,得到陶瓷结合剂钻石磨具。
上述陶瓷结合剂钻石磨具的制备方法简单,制备出的陶瓷结合剂钻石磨具磨抛工件时所需压力小、磨耗小、使用寿命长、磨削力强、研磨效率大大提高。
以下为具体实施例。
实施例1
将20kg磨粒和80kg陶瓷结合剂混合,常温、2吨/cm2的压力冷压成型后,在800℃高温烧结,得到陶瓷结合剂钻石磨具。
实施例2
将50kg磨粒和50kg陶瓷结合剂混合,常温、2吨/cm2的压力冷压成型后,在880℃高温烧结,得到陶瓷结合剂钻石磨具。
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。
Claims (10)
1.一种陶瓷结合剂钻石磨具,其特征在于,以质量分数计,所述陶瓷结合剂钻石磨具由20%~50%的磨粒和50%~80%的陶瓷结合剂组成。
2.根据权利要求1所述的陶瓷结合剂钻石磨具,其特征在于,以所述磨粒的质量为基准,所述磨粒中含有50%~90%的钻石微粉和10%~50%的碳化硅或三氧化二铝。
3.根据权利要求1所述的陶瓷结合剂钻石磨具,其特征在于,以所述陶瓷结合剂的质量为基准,所述陶瓷结合剂中含有1%~3%的纤维素、3%~15%的水及余量的陶瓷粉末。
4.根据权利要求2所述的陶瓷结合剂钻石磨具,其特征在于,所述钻石微粉粒度为22μm~36μm、12μm~22μm、8μm~12μm、4μm~8μm、2μm~4μm、1μm~2μm、0.5μm~1μm或0μm~0.5μm。
5.根据权利要求4所述的陶瓷结合剂钻石磨具,其特征在于,所述碳化硅或三氧化二铝的粒度比所述钻石微粉的粒度高一个粒度级。
6.根据权利要求3所述的陶瓷结合剂钻石磨具,其特征在于,以所述陶瓷粉末的质量为基准,所述陶瓷粉末中含有35%~45%的氧化硅、25%~35%的氧化铝、10%~20%的氧化镁和10%~20%的氧化锌。
7.一种陶瓷结合剂钻石磨具的制备方法,其特征在于,包括以下步骤:
将磨粒和陶瓷结合剂混合,冷压成型后高温烧结,得到陶瓷结合剂钻石磨具,所述陶瓷结合剂钻石磨具中磨粒的质量百分含量为20%~50%、陶瓷结合剂的质量百分含量为50%~80%。
8.根据权利要求7所述的陶瓷结合剂钻石磨具的制备方法,其特征在于,以所述磨粒的质量为基准,所述磨粒中含有50%~90%的钻石微粉和10%~50%的碳化硅或三氧化二铝;
以所述陶瓷结合剂的质量为基准,所述陶瓷结合剂中含有1%~3%的纤维素、3%~15%的水及余量的陶瓷粉末。
9.根据权利要求7或8所述的陶瓷结合剂钻石磨具的制备方法,其特征在于,所述冷压成型的条件为常温、2吨/cm2的压力。
10.根据权利要求7或8所述的陶瓷结合剂钻石磨具的制备方法,其特征在于,所述高温烧结的温度为800℃~880℃。
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CN105196201A (zh) * | 2015-09-22 | 2015-12-30 | 景德镇陶瓷学院 | 一种新型磨料、磨具及制备方法 |
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CN105196201A (zh) * | 2015-09-22 | 2015-12-30 | 景德镇陶瓷学院 | 一种新型磨料、磨具及制备方法 |
CN105622074A (zh) * | 2016-01-03 | 2016-06-01 | 安徽律正科技信息服务有限公司 | 一种用于金属精细研磨的研磨石 |
CN107457714A (zh) * | 2017-08-25 | 2017-12-12 | 郑州博特硬质材料有限公司 | 一种陶瓷纤维增强的陶瓷结合剂砂轮及其制备方法 |
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