CN104755515B - 用于改进的聚合物产品的混合相容齐格勒‑纳塔/铬催化剂 - Google Patents
用于改进的聚合物产品的混合相容齐格勒‑纳塔/铬催化剂 Download PDFInfo
- Publication number
- CN104755515B CN104755515B CN201380056610.7A CN201380056610A CN104755515B CN 104755515 B CN104755515 B CN 104755515B CN 201380056610 A CN201380056610 A CN 201380056610A CN 104755515 B CN104755515 B CN 104755515B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- titanium
- ziegler
- reacted product
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
- C08F4/24—Oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261721203P | 2012-11-01 | 2012-11-01 | |
| US61/721,203 | 2012-11-01 | ||
| PCT/US2013/067947 WO2014071119A1 (en) | 2012-11-01 | 2013-11-01 | Mixed compatible ziegler-natta/chromium catalysts for improved polymer products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104755515A CN104755515A (zh) | 2015-07-01 |
| CN104755515B true CN104755515B (zh) | 2017-08-25 |
Family
ID=49585601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380056610.7A Active CN104755515B (zh) | 2012-11-01 | 2013-11-01 | 用于改进的聚合物产品的混合相容齐格勒‑纳塔/铬催化剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10221263B2 (enExample) |
| EP (1) | EP2888298A1 (enExample) |
| CN (1) | CN104755515B (enExample) |
| BR (1) | BR112015009194B1 (enExample) |
| CA (1) | CA2886967C (enExample) |
| IN (1) | IN2015DN02467A (enExample) |
| RU (1) | RU2662936C2 (enExample) |
| WO (1) | WO2014071119A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107001516B (zh) * | 2014-11-24 | 2023-06-06 | 尤尼威蒂恩技术有限责任公司 | 用于烯烃聚合的铬基催化剂组合物 |
| CN113845612B (zh) * | 2020-06-28 | 2023-02-28 | 中国石油天然气股份有限公司 | 主催化剂的制备方法、催化剂及其应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4626520A (en) * | 1984-08-06 | 1986-12-02 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| CN100471882C (zh) * | 2003-11-20 | 2009-03-25 | 联合碳化化学及塑料技术有限责任公司 | 喷雾干燥的混合金属齐格勒催化剂组合物 |
| WO2012019276A1 (en) * | 2010-08-11 | 2012-02-16 | Nova Chemicals (International) S.A. | Combining activity modifiers and multi component catalysts for control of polymer architecture |
Family Cites Families (62)
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| US4376851A (en) | 1953-01-27 | 1983-03-15 | Phillips Petroleum Company | Solid polymers of olefins and production of such polymers |
| US3248455A (en) | 1963-08-14 | 1966-04-26 | Us Rubber Co | Method of recovering resinous polymer from latex |
| US3242099A (en) | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
| US3231550A (en) | 1964-06-04 | 1966-01-25 | Union Carbide Corp | Olefin polymerization |
| US3709954A (en) | 1970-03-16 | 1973-01-09 | Union Carbide Corp | Preparation of liquid polymers of olefins |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| US4077904A (en) | 1976-06-29 | 1978-03-07 | Union Carbide Corporation | Olefin polymerization process and catalyst therefor |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4376062A (en) | 1979-11-28 | 1983-03-08 | Union Carbide Corporation | Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization |
| US4263422A (en) * | 1979-12-31 | 1981-04-21 | The Dow Chemical Company | Polymerization of olefins with dual, independently supported catalysts |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4638029A (en) | 1983-02-22 | 1987-01-20 | Union Carbide Corporation | Ceramic composition and process for use thereof |
| US4988783A (en) | 1983-03-29 | 1991-01-29 | Union Carbide Chemicals And Plastics Company Inc. | Ethylene polymerization using supported vanadium catalyst |
| US5567665A (en) | 1994-03-31 | 1996-10-22 | Union Carbide Chemicals & Plastics Technology Corporation | Shape-shifted magnesium alkoxide component for polymerizing olefins |
| US5604172A (en) | 1984-03-31 | 1997-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Shape-shifted magnesium alkoxide component for polymerizing olefins |
| US4558024A (en) * | 1984-08-06 | 1985-12-10 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| US4728705A (en) | 1986-02-28 | 1988-03-01 | Shell Oil Company | Olefin polymerization catalyst composition |
| US4855370A (en) | 1986-10-01 | 1989-08-08 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| US5198400A (en) * | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5330950A (en) | 1987-12-29 | 1994-07-19 | Mobil Oil Corporation | Mixed Ziegler and chromium catalyst and process for preparing a broad molecular weight distribution HDPE |
| US5408015A (en) | 1987-12-29 | 1995-04-18 | Mobil Oil Corporation | Mixed chromium catalyst,and alkene and alkyl aluminum hydride-modified ziegler catalyst for multimodal HDPE |
| CA2021410C (en) * | 1989-08-10 | 1998-06-02 | William Kevin Reagen | Process for olefin polymerization |
| US5304588A (en) | 1989-09-28 | 1994-04-19 | Union Carbide Chemicals & Plastics Technology Corporation | Core-shell resin particle |
| US4994534A (en) | 1989-09-28 | 1991-02-19 | Union Carbide Chemicals And Plastics Company Inc. | Process for producing sticky polymers |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5068489A (en) | 1989-12-28 | 1991-11-26 | Union Carbide Chemicals And Plastics Technology Corporation | Preparation of very low molecular weight polyethylene in a fluidized bed |
| US5306350A (en) | 1990-12-21 | 1994-04-26 | Union Carbide Chemicals & Plastics Technology Corporation | Methods for cleaning apparatus using compressed fluids |
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| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5290745A (en) | 1992-08-10 | 1994-03-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing ethylene polymers having reduced hexane extractable content |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
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| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| US5459117A (en) | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
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| US5716558A (en) | 1994-11-14 | 1998-02-10 | Union Carbide Chemicals & Plastics Technology Corporation | Method for producing coating powders catalysts and drier water-borne coatings by spraying compositions with compressed fluids |
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| AU5630198A (en) | 1997-03-07 | 1998-09-10 | Phillips Petroleum Company | A process for polymerizing olefins |
| WO1998046653A1 (en) | 1997-04-11 | 1998-10-22 | Showa Denko K. K. | Process for preparing ethylene polymer and catalyst used therefor |
| US6255413B1 (en) | 1997-12-16 | 2001-07-03 | Phillips Petroleum Company | Process to produce branched polymers from ethylene feedstock |
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| DE60016176T2 (de) * | 2000-05-10 | 2005-12-01 | Repsol Quimica S.A. | Verfahren zur Herstellung von bimodalem Polyethylen |
| US6489408B2 (en) | 2000-11-30 | 2002-12-03 | Univation Technologies, Llc | Polymerization process |
| RU2177954C1 (ru) * | 2001-02-12 | 2002-01-10 | Казанское открытое акционерное общество "Органический синтез" | Способ получения полиэтилена низкого давления |
| US6649069B2 (en) | 2002-01-23 | 2003-11-18 | Bae Systems Information And Electronic Systems Integration Inc | Active acoustic piping |
| AU2002367755A1 (en) * | 2002-11-29 | 2004-06-23 | Borealis Technology Oy | Ziegler natta catalyst system and polymerisation process using said zn catalyst system for producing ethylene copolymers having a broad molecular weight distribution |
| US6989344B2 (en) | 2002-12-27 | 2006-01-24 | Univation Technologies, Llc | Supported chromium oxide catalyst for the production of broad molecular weight polyethylene |
| US7629422B2 (en) | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
| US20060155082A1 (en) | 2005-01-10 | 2006-07-13 | Mcdaniel Max P | Process for producing polymers |
| BRPI0819552A2 (pt) | 2007-12-31 | 2015-05-19 | Dow Global Technologies Inc | Processo para produzir um polímero a base de olefina |
| ES2568043T3 (es) | 2008-02-27 | 2016-04-27 | Univation Technologies, Llc | Catalizadores modificados a base de cromo y procedimientos de polimerización para usar los mismos |
| ES2399062T3 (es) * | 2008-12-22 | 2013-03-25 | Univation Technologies, Llc | Sistemas y métodos para fabricar polímeros |
| KR101593577B1 (ko) | 2009-11-16 | 2016-02-12 | 삼성전자주식회사 | 근거리 통신 기반 리스트 출력 방법 및 이를 지원하는 휴대 단말기 |
-
2013
- 2013-11-01 IN IN2467DEN2015 patent/IN2015DN02467A/en unknown
- 2013-11-01 US US14/433,220 patent/US10221263B2/en active Active
- 2013-11-01 BR BR112015009194-6A patent/BR112015009194B1/pt active IP Right Grant
- 2013-11-01 RU RU2015120465A patent/RU2662936C2/ru active
- 2013-11-01 WO PCT/US2013/067947 patent/WO2014071119A1/en not_active Ceased
- 2013-11-01 CN CN201380056610.7A patent/CN104755515B/zh active Active
- 2013-11-01 EP EP13792147.4A patent/EP2888298A1/en not_active Withdrawn
- 2013-11-01 CA CA2886967A patent/CA2886967C/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4626520A (en) * | 1984-08-06 | 1986-12-02 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| CN100471882C (zh) * | 2003-11-20 | 2009-03-25 | 联合碳化化学及塑料技术有限责任公司 | 喷雾干燥的混合金属齐格勒催化剂组合物 |
| WO2012019276A1 (en) * | 2010-08-11 | 2012-02-16 | Nova Chemicals (International) S.A. | Combining activity modifiers and multi component catalysts for control of polymer architecture |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014071119A1 (en) | 2014-05-08 |
| CA2886967A1 (en) | 2014-05-08 |
| US20150274859A1 (en) | 2015-10-01 |
| BR112015009194A2 (pt) | 2017-07-04 |
| BR112015009194B1 (pt) | 2022-04-26 |
| CA2886967C (en) | 2021-06-01 |
| RU2662936C2 (ru) | 2018-07-31 |
| RU2015120465A (ru) | 2016-12-20 |
| CN104755515A (zh) | 2015-07-01 |
| EP2888298A1 (en) | 2015-07-01 |
| IN2015DN02467A (enExample) | 2015-09-04 |
| US10221263B2 (en) | 2019-03-05 |
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| C06 | Publication | ||
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| GR01 | Patent grant | ||
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