CN104749094B - A kind of manufacture method of atmospheric corrosion monitoring sensor - Google Patents

A kind of manufacture method of atmospheric corrosion monitoring sensor Download PDF

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Publication number
CN104749094B
CN104749094B CN201310741687.XA CN201310741687A CN104749094B CN 104749094 B CN104749094 B CN 104749094B CN 201310741687 A CN201310741687 A CN 201310741687A CN 104749094 B CN104749094 B CN 104749094B
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wire
line
kinds
manufacture method
sensor
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CN104749094A (en
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郑弃非
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Youyan metal composite technology Co.,Ltd.
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Beijing General Research Institute for Non Ferrous Metals
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Abstract

The present invention relates to a kind of manufacture method of atmospheric corrosion monitoring sensor, the atmospheric corrosion for belonging to material monitors field.By two different kinds of wire or line wound side by side on the cylinder of surface insulation, two kinds of mutually insulateds between wire or line, the outer surface of every kind of wire or line individually makes electrical contact with atmospheric environment, and two kinds of wires or line are drawn into formation respectively with wire can cut down Buddhist nun's battery sensor.Material is easy to get in manufacturing process of the present invention, and by controlling the factors such as magnet wire insulation thickness degree, grinding depth to be easily controlled two kinds of intermetallic spacing distances, method is workable;Due to insulating cement need not be penetrated into deep metal slit, sensor metal be not present because corrode in metal slit and caused by damage, the reliability and durability of sensor greatly improve.

Description

A kind of manufacture method of atmospheric corrosion monitoring sensor
Technical field
The present invention relates to a kind of manufacture method of atmospheric corrosion monitoring sensor, the atmospheric corrosion monitoring for belonging to material is led Domain.
Background technology
The corrosion of material in an atmosphere is the important way of material damage, and the atmospheric corrosion of observation and research material is material Research and the important topic of application.It is conventional method by that can cut down Buddhist nun's battery-type sensors to detect material atmospheric corrosion.It General principle be by detect two kinds of different metal materials under thin liquid film state because material potential difference and caused by it is micro- Electric current and the corrosion for detecting material.
In order to obtain measurable electric current, the general manufacture method that can cut down Buddhist nun's battery sensor is by the more of two kinds of materials Piece thin plate is interlaced to be arranged under the overlay, and is separated among thin plate with very thin insulating materials, forms an assembly, and again by assembly Facade(Directly in sheet plane)It is polished flat and exposes two kinds of metallic matrixes, forms the sensitive surface of sensor.When have dewfall, Rain, snow etc. will produce an observable corrosion between two kinds of metal materials when producing thin liquid film in sensitive surface because of corrosion Electric current.This method manufacture can cut down Buddhist nun's battery sensor because to obtain as far as possible sensitive detectable electric current, it is necessary to ensure two kinds The spacing of sheet metal is as far as possible small, mutually insulated;Want multi-disc metal to be mutually staggered simultaneously, manufacture and acquire a certain degree of difficulty. Have the gap of certain depth because sheet metal is closely spaced, between piece, insulating cement penetrate into it is difficult, in sensor use often because Liquid in sensitive surface penetrate between sheet metal cause thin slice occur self-corrosion and caused by the change of sensor construction and broken Bad, sensor corrosion current value changes very greatly, often up to 10% with the extension of usage time;The service life of sensor(With electric current Change 20% is failure foundation)Only 1-2, at least half a year.
The content of the invention
It is an object of the invention to provide a kind of simplicity can reliably cut down Buddhist nun's battery sensor manufacture method, ensure manufacturing process In convenience and controllable, reduce during use and sensor self-corrosion breakoff phenomenon occur.
A kind of manufacture method of atmospheric corrosion monitoring sensor, comprises the following steps:By two different kinds of wire Or line is wound around on the cylinder of surface insulation side by side, two kinds of mutually insulateds between wire or line, every kind of wire or The outer surface of line individually makes electrical contact with atmospheric environment, and two kinds of wires or line are drawn into formation respectively with wire can cut down Buddhist nun's battery biography Sensor.
In the wire or line of two kinds of different materials, at least one is the wire or line that surface carries insulated paint;Two kinds The wire of different materials or the diameter of line are identical or essentially identical.The material of wire or line can from metals such as iron, copper, aluminium or Selected in alloy.
After two different kinds of wire or line wound side by side is scribbled on surface on the cylinder of uncured insulating cement, Wire or line outer surface re-coating insulating cement after winding, it is by being ground that metal surface is exposed after adhesive curing.
Described cylinder is lucite or plastic cylinder;It may also be metallic conductor of the surface through insulation processing, institute It is curable resin or glue to state insulating cement, such as epoxy resin.
The specific manufacturing process of the present invention:The cylinder of surface insulation is selected, its surface is applied into one layer of insulating cement;Select simultaneously Two kinds of diameters essentially identical wire or line are selected, wherein at least one is the insulated conductor that surface carries insulated paint;By two kinds Wire or line individual layer are closely wound in periphery side by side;Wire or line outer surface after winding applies one layer of insulation Glue, the space between tinsel is full of;After adhesive curing of insulating, it is ground since insulating cement outer surface, exposes two kinds of gold Belong to matrix, now insulated between two kinds of metals and have certain spacing, two kinds of wires or line are drawn into formation respectively with wire can Cut down Buddhist nun's battery sensor.
The advantages of the inventive method:Material is easy to get in manufacturing process, by controlling magnet wire insulation thickness degree, grinding depth Two kinds of intermetallic spacing distances are easily controlled etc. factor, method is workable;It is deep due to insulating cement need not be penetrated into Metal slit in, sensor metal be not present because corrode in metal slit and caused by damage, the reliability of sensor and resistance to Long property greatly improves.
Below by the drawings and specific embodiments, the present invention will be further described, but is not meant to protect the present invention Protect the limitation of scope.
Brief description of the drawings
Fig. 1 is that two kinds of metal wires wind schematic diagram on the cylinder.
Embodiment
As shown in figure 1, wherein, A is metal wire 1, B is metal wire 2, and C is cylinder.The specific manufacturing process of the present invention To select the cylinder C of a surface insulation, its surface being applied to the curable glue of one layer of thin insulation, while select two kinds of diameters basic Identical wire or line A and B, i.e. metal wire 1 and metal wire 2, wherein at least one are that insulation of the surface with insulated paint is led Line.Two kinds of metal wire A and B individual layers are closely wound in above-mentioned cylinder C Surface side by side, as shown in Figure 1.Form certain winding face One layer of glue is applied again in winding external surface after product, and the space between tinsel A and B is full of.After colloid solidification, outside colloid Surface starts to be ground, and exposes two kinds of metallic matrixes, is now insulated between two metals and has certain spacing.By two kinds of metal wires A and B Buddhist nun's battery sensor can be cut down with regard to being formed by being drawn respectively with wire.
Embodiment 1
From a diameter of 1mm iron wire and copper wire, wherein copper cash is enamel insulated wire.Justify in diameter 50mm lucite Coat a thin layer epoxy resin on post, before resin solidification, iron wire and copper cash wound side by side are enclosed in cylinder 50, then again in gold Category silk table face fills epoxy resin, and after epoxy resin cure, the cylinder outside diameter after winding is worn into 51mm by upper grinding machine, Now two kinds of wires are exposed, while it is good to insulate, and iron wire and copper wire are drawn into just formation one respectively can cut down Buddhist nun's electricity Pond corrosion sensor.
After the completion of sensor, immerse in the 1%NaCl aqueous solution and measure its initial current value I0.Again by sensor in natural bar Exposed to the open air under part(Use)Certain time, then surface polishing, immerse in the 1%NaCl aqueous solution and measure its current value Ii, calculate(Ii– I0)/I0Situation of change of its current value with exposure time is obtained, as a result as shown in table 1.Find out from the result of table 1, in the experiment of 4 years In cycle, the current variation value of sensor is no more than 6%, and the linearity is good, and the life-span is more than 4 years.
The sensor current value of table 1 is with usage time situation of change
Exposure time(Month) 3 6 12 18 24 36 48
Curent change(%) 4.0 5.0 3.1 6.0 3.5 4.0 5.1
Embodiment 2
From a diameter of 2mm aluminium wire and copper wire, wherein copper cash is enamel insulated wire, is justified in diameter 60mm engineering plastics A thin layer epoxy resin is coated on post, before resin solidification, aluminium wire and copper cash wound side by side 40 are enclosed on the cylinder, Ran Houzai Epoxy resin is filled in wire surface.After epoxy resin cure, upper grinding machine grinds the cylindrical outer surface diameter after winding Into 62mm, now two kinds of wires are exposed, while it is good to insulate, and aluminium wire and copper wire are drawn with wire respectively and just formed One can cut down Buddhist nun's battery corrosion sensor.
After sensor is carried out, immerse in the 1%NaCl aqueous solution and measure its initial current value I0.Again by sensor in natural bar Exposed to the open air under part(Use)Certain time, then surface polishing, immerse in the 1%NaCl aqueous solution and measure its current value Ii, calculate(Ii– I0)/I0Situation of change of its current value with exposure time is obtained, as a result as shown in table 2.Find out from the result of table 2, in the experiment of 5 years In cycle, the current variation value of sensor is no more than 8%, and the linearity is good, and the life-span is more than 5 years.
The sensor current value of table 2 is with usage time situation of change
Exposure time(Month) 6 12 24 36 48 60
Curent change(%) 5.3 3.3 3.3 8.0 5.0 7.0

Claims (5)

1. a kind of manufacture method of atmospheric corrosion monitoring sensor, comprises the following steps:By two different kinds of wire or Line wound side by side is on the cylinder of surface insulation, and in described wire or line, at least one is that surface carries insulated paint Wire or line, two kinds of mutually insulateds between wire or line, the outer surface of every kind of wire or line are individually electric with atmospheric environment Contact, two kinds of wires or line are drawn into formation respectively with wire can cut down Buddhist nun's battery sensor.
2. the manufacture method of atmospheric corrosion monitoring sensor according to claim 1, it is characterised in that:Two kinds of wires or The diameter of line is identical.
3. the manufacture method of atmospheric corrosion monitoring sensor according to claim 1, it is characterised in that:Two kinds of variety classeses Wire or line wound side by side scribbled on surface on the cylinder of uncured insulating cement, then wire or line after winding Outer surface is coated with insulating cement, by being ground that metal surface is exposed after adhesive curing.
4. the manufacture method of atmospheric corrosion monitoring sensor according to claim 1, it is characterised in that:Described cylinder For the metallic conductor of lucite, plastic cylinder or surface through insulation processing.
5. the manufacture method of atmospheric corrosion monitoring sensor according to claim 3, it is characterised in that:The insulating cement is Curable resin or glue.
CN201310741687.XA 2013-12-27 2013-12-27 A kind of manufacture method of atmospheric corrosion monitoring sensor Active CN104749094B (en)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105606668A (en) * 2015-12-21 2016-05-25 国网安徽省电力公司淮北供电公司 Electrochemical thin-film condensation sensor
CN107449727B (en) * 2017-07-28 2020-07-10 浙江钱浪智能信息科技有限公司 Method for continuously monitoring field environment corrosivity by using corrosion sensor
JP2019200141A (en) * 2018-05-16 2019-11-21 マツダ株式会社 Moisture sensor and corrosion test method using the same
CN108872049A (en) * 2018-06-21 2018-11-23 浙江钱浪智能信息科技有限公司 A kind of flexible sensor and monitoring method suitable for big data monitoring corrosiveness of the environment
CN109612918B (en) * 2018-12-07 2021-06-22 国网山东省电力公司电力科学研究院 Atmospheric corrosion sensor and manufacturing method thereof
CN109520920B (en) * 2018-12-07 2023-03-21 国网山东省电力公司电力科学研究院 Intelligent atmosphere corrosion detector
CN109612919B (en) * 2018-12-07 2021-06-18 国网山东省电力公司电力科学研究院 Method for detecting galvanic couple type atmospheric corrosion sensor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2432576Y (en) * 2000-06-28 2001-05-30 中国科学院金属研究所 Multifunctional corrosion real-time detection probe
CN101893544A (en) * 2010-07-02 2010-11-24 中国兵器工业第五九研究所 Surface wettability sensor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2432576Y (en) * 2000-06-28 2001-05-30 中国科学院金属研究所 Multifunctional corrosion real-time detection probe
CN101893544A (en) * 2010-07-02 2010-11-24 中国兵器工业第五九研究所 Surface wettability sensor

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