CN104738039A - Composite insecticidal composition containing pyridalyl and monosultap and use thereof - Google Patents
Composite insecticidal composition containing pyridalyl and monosultap and use thereof Download PDFInfo
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- CN104738039A CN104738039A CN201310731150.5A CN201310731150A CN104738039A CN 104738039 A CN104738039 A CN 104738039A CN 201310731150 A CN201310731150 A CN 201310731150A CN 104738039 A CN104738039 A CN 104738039A
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- Prior art keywords
- cupric sulfate
- fluoroform pyrrole
- pyrrole ether
- pesticide compositions
- ether
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Abstract
The invention discloses a composite insecticidal composition containing pyridalyl and monosultap and a use thereof. The composite insecticidal composition contains pyridalyl and monosultap as active insecticidal components and a weight ratio of pyridalyl to monosultap is 1-100: 1-80. The composite insecticidal composition can produce good synergism, overcomes and delays insect resistance to pesticides, has a fast insecticidal rate and a long persistent period, reduces a pesticide cost and has prevention and control effects obviously higher than that of a single-ingredient pesticide. The composite insecticidal composition can prevent and control lepidoptera pests of crops, especially can be used for preventing and controlling cotton bollworm and stem borers and has effects obviously higher than that of a single-ingredient pesticide.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of be principle active component Pesticidal combination and the application thereof of fluoroform pyrrole ether and Cupric sulfate.
Background technology
Fluoroform pyrrole ether (Pyridalyl), chemical name: 2-{3-[2.3-bis-chloro-4-(3,3-bis-chloro-2-acrylic oxygen base) phenoxy group] propoxyl group }-5-(trifluoromethyl) pyrimidine, structural formula:
Fluoroform pyrrole ether, also known as pyridalyl, is to be developed by SUMITOMO CHEMICAL chemical company and the novel pyrimidines developed is efficient, low toxic pesticide, has remarkable preventive effect, with existing lepidopteran insecticidal agent without cross resistance to lepidoptera pest.It has the effect of tagging with stomach toxicity, is mainly used in the lepidoptera pest larva preventing and treating damage to crops, also has good preventive effect in addition to thrips thrips, diptera leaf miner.
Cupric sulfate (Monosultap), molecular formula: C
5h
12nNaO
6s
4, chemical name: the two thiosulfonic acid sodium base propane of 2-dimethylamino-1,3-.
Cupric sulfate is the analog of the nereistoxin of Prof. Du Yucang, enters in insect bodies and is converted into rapidly nereistoxin or Dihydronereistoxin element.This medicine is acetylcholine competitive inhibitor, have stronger to tag, stomach toxicity and Uptake and translocation effect, have good control efficiency to the larva of lepidoptera pest.Belong to bionic type agricultural chemicals, little on natural enemy impact, non-resistant, without residual hazard, free from environmental pollution, be the comparatively ideal medicament of current comprehensive regulation insect pest.This medicament can prevent and treat the various pests on the crops such as paddy rice, vegetables, wheat, barley and highland barley, corn, tealeaves, fruit tree effectively, particularly has special efficacy to rice leaf roller, striped rice borer, paddy stem borer etc.To fish low toxicity, but large to the toxicity of silkworm.In China, registration crop is paddy rice, for preventing and treating snout moth's larva.
Containing the insecticide variety of single component often existing defects in agricultural chemicals control of insect: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, and can not provide comprehensive protection for crop, peasant's drug cost is high.Above-mentioned shortcoming can be overcome to a certain extent by the combination of two kinds or two or more various active component.There is two kinds of synergistic effect or the combination mixture of two or more active component, can preventive effect be improved, reduce active ingredient ground dosage, cost-saving, slow down pest resistance and to occur and can expanding prevention spectrum, play that many worms are double to be controlled, reduce the use cost of peasant.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate, this Pesticidal combination is the multifunctional insecticide composition of control lepidoptera pest.
Another object of the present invention is to provide this Pesticidal combination and is preparing the application prevented and treated on the insecticidal materials of resistance lepidoptera pest, the application particularly on the insecticidal materials preparing control cotton bollworm or snout moth's larva.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for fluoroform pyrrole ether and Cupric sulfate, this compound pesticide compositions is with fluoroform pyrrole ether and Cupric sulfate for principle active component, and wherein, the weight ratio of fluoroform pyrrole ether and Cupric sulfate is 1 ~ 100:1 ~ 80.
In this compound pesticide compositions, the weight ratio of fluoroform pyrrole ether (A) and Cupric sulfate (B) is preferably 0.5 ~ 10:1 ~ 30, and more preferably 1 ~ 10:1 ~ 10, most preferably are 1 ~ 10:1.
This compound pesticide compositions can only containing active component fluoroform pyrrole ether and Cupric sulfate, and also can add other components when using or prepare in active component, the effective ingredient in this Pesticidal combination can also be present in composition by enhancing effective amount.
In compound pesticide compositions of the present invention, both fluoroform pyrrole ether and the Cupric sulfate weight percentage in this compound pesticide compositions is 3% ~ 80%.Be preferably 5% ~ 55%, further preferably 20% ~ 55%, most preferably 20% ~ 30%.
Compound pesticide compositions of the present invention with fluoroform pyrrole ether and Cupric sulfate for active component or principle active component, any one formulation that agricultural chemicals allows is become, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersion granule with insecticides adjuvant and excipient.
Aforementionedly can be applicable to the not special restriction of insecticides adjuvant of the present invention, include, but are not limited to calcium dodecyl benzene sulfonate, agriculture breast 600
#, the rare block compound of polyoxyethylene polyoxy third is (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., aforementionedly can be applicable to excipient of the present invention and be also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can be alone or and use.
Compound pesticide compositions of the present invention has good preventive effect to the multiple Semiptera of the easy generation such as cotton bollworm and snout moth's larva resistance and lepidoptera pest; And suppress insect to produce the pesticide resistance of unitary agent (fluoroform pyrrole ether or Cupric sulfate arbitrary).
Compound pesticide compositions of the present invention can prepare the application prevented and treated on resistance lepidoptera pest insecticidal materials, and the effect especially on preparation control cotton bollworm or snout moth's larva insecticidal materials is remarkable.Described snout moth's larva is preferably rice-stem borer.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism lepidoptera pest is obvious synergistic function as cotton bollworm, snout moth's larva etc. have, and overcomes and has delayed pest resistance to insecticide, and expanding prevention is composed, desinsection speed is fast, significantly improves control efficiency; (2) control recruitment, drug cost is reduced; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) with fluoroform pyrrole ether compared with Cupric sulfate single dose, produce and use cost reduction; (6) suppress lepidoptera pest to strengthen the resistance of agricultural chemicals, its successful uses higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but do not limit the present invention in any way.
Embodiment 1:
30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil add to 100g altogether to take fluoroform pyrrole ether and Cupric sulfate.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and is mixed with the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 30%.Wherein the concrete ratio of fluoroform pyrrole ether and Cupric sulfate is in table 1 and 2.
Adopt feed to add malicious method and carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and often process repetition 3 times, every concentration process 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
Table 1 fluoroform pyrrole ether and Cupric sulfate is composite and the toxicity test of single dose antagonism cotton bollworm
As shown in Table 1, fluoroform pyrrole ether and Cupric sulfate composite, co-toxicity coefficient is all greater than 120, shows good synergistic function.
Adopt feed to add malicious method and carry out indoor synergy biologicall test, selection rice-stem borer is target pest, often processes repetition 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
Table 2 fluoroform pyrrole ether and Cupric sulfate is composite and single dose to the toxicity test of striped rice borer
Table 2 is known, fluoroform pyrrole ether and Cupric sulfate composite, co-toxicity coefficient is all greater than 120, shows good synergistic function.
Embodiment 2:
Take 5g fluoroform pyrrole ether, 50g Cupric sulfate, phenethyl phenol polyoxyethylene polyoxypropylene ether 3g, agriculture breast 33
#2g, agriculture breast 600
#1g, solvent naphtha 13g, adds water to 100g.The method above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms the fluoroform pyrrole ether Cupric sulfate aqueous emulsion that principle active component weight percentage is 55%.
Embodiment 3:
Take 2g fluoroform pyrrole ether, 18g Cupric sulfate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxyethylene polyoxypropylene ether 3g, agriculture breast 33
#2g, agriculture breast 600
#1g, cyclohexanone 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate microemulsion that principle active component weight percentage is 20%.
Carry out the control cotton bollworm test of pesticide effectiveness to embodiment 3, contrast medicament is 30% Cupric sulfate AS and 100g/l fluoroform pyrrole ether EC, and dilute according to the extension rate of form 3 li, look into 3 days after medicine, 7 days, the result of 14 days, result is in table 3:
Table 3: the field test results of the composite antagonism cotton bollworm of fluoroform pyrrole ether-Cupric sulfate
Field efficacy result shows, fluoroform pyrrole ether monosultap composition antagonism cotton bollworm has excellent control efficiency, and control efficiency is all better than the direct acting effect of single dose kind.
Carry out water prevention chilo suppressalis field medicine effect test to embodiment 3, contrast medicament is 30% Cupric sulfate AS and 100g/L fluoroform pyrrole ether EC, and dilute according to the extension rate of form 3 li, look into 3 days after medicine, 7 days, the result of 14 days, result is in table 4:
Table 4: the composite field test results to rice-stem borer of fluoroform pyrrole ether-Cupric sulfate
Field efficacy result shows, fluoroform pyrrole ether monosultap composition has excellent control efficiency to rice-stem borer, and control efficiency is all better than the direct acting effect of single dose kind.
Embodiment 4:
Take 1g fluoroform pyrrole ether, 5g Cupric sulfate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 6%.
Embodiment 5:
Take 50g fluoroform pyrrole ether, 20g Cupric sulfate, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 70%.
Embodiment 6:
Take 2g fluoroform pyrrole ether, 40g Cupric sulfate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 42%.
Embodiment 7:
Take 0.2g fluoroform pyrrole ether, 50g Cupric sulfate, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 50.2%.
Embodiment 8:
Take 5g fluoroform pyrrole ether, 0.5g Cupric sulfate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage is 5.5%.
Embodiment 9:
Take 5g fluoroform pyrrole ether, 30g Cupric sulfate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that principle active component weight percentage processed is 35%.
Embodiment 10:
Take 20g fluoroform pyrrole ether, 5g Cupric sulfate, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether Cupric sulfate missible oil that preparation principle active component weight percentage is 25%.
Embodiment 11:
Take 30g fluoroform pyrrole ether, 12g Cupric sulfate, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, the weight percentage forming principle active component under the effect of sand mill is the fluoroform pyrrole ether Cupric sulfate suspending agent of 42%.
Embodiment 12:
Take 2g fluoroform pyrrole ether, 5g Cupric sulfate, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite adds to 100g, is the fluoroform pyrrole ether Cupric sulfate water dispersion granule of 7% by above raw material by the weight percentage of water dispersible granular agent method formation principle active component.
Embodiment 13:
Take 50g fluoroform pyrrole ether, 3g Cupric sulfate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and the weight percentage forming principle active component is the fluoroform pyrrole ether Cupric sulfate missible oil of 53%.
Embodiment 14:
Take 2g fluoroform pyrrole ether, 18g Cupric sulfate, lignin 10g, Negel 2g, add to 100g with diatomite, mixed in micronizer by above raw material, the weight percentage forming principle active component is the fluoroform pyrrole ether Cupric sulfate wetting powder of 20%.
Embodiment 15:
Take 7g fluoroform pyrrole ether, 70g Cupric sulfate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and the weight percentage forming principle active component is the fluoroform pyrrole ether Cupric sulfate missible oil of 77%.
Embodiment 16:
Take 60g fluoroform pyrrole ether, 5g Cupric sulfate, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, above raw material is the fluoroform pyrrole ether Cupric sulfate water dispersible granules of 65% by the weight percentage of water dispersible granular agent method formation principle active component by kaolin 13g.
Claims (10)
1., containing a compound pesticide compositions for fluoroform pyrrole ether and Cupric sulfate, it is characterized in that this compound pesticide compositions with fluoroform pyrrole ether and Cupric sulfate for active insecticidal components, wherein, the weight ratio of fluoroform pyrrole ether and Cupric sulfate is 1 ~ 100:1 ~ 80.
2. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 1, is characterized in that the weight ratio of described fluoroform pyrrole ether and Cupric sulfate is 0.5 ~ 10:1 ~ 30.
3. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 2, is characterized in that the weight ratio of described fluoroform pyrrole ether and Cupric sulfate is 1 ~ 10:1 ~ 10.
4. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 3, is characterized in that the weight ratio of described fluoroform pyrrole ether and Cupric sulfate is 1 ~ 10:1.
5. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 1, is characterized in that both fluoroform pyrrole ether and the Cupric sulfate weight percentage in this compound pesticide compositions is 3% ~ 80%.
6. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 5, is characterized in that both fluoroform pyrrole ether and the Cupric sulfate weight percentage in this compound pesticide compositions is 5% ~ 55%.
7. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 1, is characterized in that this compound pesticide compositions with fluoroform pyrrole ether and Cupric sulfate for active insecticidal components and insecticides adjuvant are mixed with the formulation that agricultural chemicals allows.
8. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing fluoroform pyrrole ether and Cupric sulfate according to claim 1 is preparing the application prevented and treated on the insecticidal materials of resistance lepidoptera pest.
10. application according to claim 9, is characterized in that described resistance lepidoptera pest is cotton bollworm or snout moth's larva.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310731150.5A CN104738039A (en) | 2013-12-26 | 2013-12-26 | Composite insecticidal composition containing pyridalyl and monosultap and use thereof |
| PCT/CN2014/076327 WO2015096333A1 (en) | 2013-12-26 | 2014-04-28 | Composite pesticidal composition containing pyridalyl and monosultap, and uses thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310731150.5A CN104738039A (en) | 2013-12-26 | 2013-12-26 | Composite insecticidal composition containing pyridalyl and monosultap and use thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104738039A true CN104738039A (en) | 2015-07-01 |
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|---|---|---|---|
| CN201310731150.5A Pending CN104738039A (en) | 2013-12-26 | 2013-12-26 | Composite insecticidal composition containing pyridalyl and monosultap and use thereof |
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|---|---|
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| WO (1) | WO2015096333A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009209124A (en) * | 2008-02-06 | 2009-09-17 | Nissan Chem Ind Ltd | Insect- or acarian-controlling composition |
| CN101669471A (en) * | 2009-08-21 | 2010-03-17 | 成都皇牌作物科学有限公司 | Pesticide composition containing nitenpyram |
| CN103355299A (en) * | 2012-03-28 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing pyridalyl and nereistoxin |
-
2013
- 2013-12-26 CN CN201310731150.5A patent/CN104738039A/en active Pending
-
2014
- 2014-04-28 WO PCT/CN2014/076327 patent/WO2015096333A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009209124A (en) * | 2008-02-06 | 2009-09-17 | Nissan Chem Ind Ltd | Insect- or acarian-controlling composition |
| CN101669471A (en) * | 2009-08-21 | 2010-03-17 | 成都皇牌作物科学有限公司 | Pesticide composition containing nitenpyram |
| CN103355299A (en) * | 2012-03-28 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing pyridalyl and nereistoxin |
Non-Patent Citations (1)
| Title |
|---|
| 徐文平: ""啶虫丙醚：防治鳞翅目害虫的新颖杀虫剂"", 《世界农药》 * |
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| WO2015096333A1 (en) | 2015-07-02 |
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