CN104719332A - Pesticide composition for killing pests and preventing diseases - Google Patents
Pesticide composition for killing pests and preventing diseases Download PDFInfo
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- CN104719332A CN104719332A CN201310719530.7A CN201310719530A CN104719332A CN 104719332 A CN104719332 A CN 104719332A CN 201310719530 A CN201310719530 A CN 201310719530A CN 104719332 A CN104719332 A CN 104719332A
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- fluorine azoles
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Abstract
The invention discloses a pesticide composition for killing pests and preventing diseases. The composition is mainly characterized in that effective active ingredients consist of sedaxane and effective ingredients B, wherein the weight ratio of sedaxane to the effective ingredients B is (1: 80) to (80: 1), and the effective ingredients B consist of fipronil and chlorpyrifos. The composition has the advantages of good film forming property, coating uniformity, high suspension percentage, safety, low toxicity and the like and can be extensively applied to the seed treatment of crops, such as wheat, maize, rice, peanuts, cotton and watermelon; the composition has a sustained-release effect, the dosage of pesticides is reduced, and the composition is safe to human and livestock, is free from damage caused by chemicals and is good in environmental compatibility.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of composition pesticide of disinsection prophylaxis.
Background technology
Fluorine azoles ring bacterium amine (sedaxane), causes effect by suppressing germ succinate dehydrogenase.
Ethiprole (fipronil), chemical name: (±)-5-amino-1-(2,6-bis-chloro-α, α, α-trifluoro-p-tolyl)-4-trifluoromethyl sulfinyl pyrazoles-3-nitrile, molecular formula: C
12h
4cl
2f
6n
4oS, ethiprole is Phenylpyrazole insecticides.Insecticidal spectrum is wide, mainly hinders the fluoride metabolism that insect γ-aminobutyric acid controls, has very high insecticidal activity to a series of important pests such as Lepidoptera, fly class and coleopteras.
Chlopyrifos (chlorpyrifos), chemical name: O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) phosphorothionate, molecular formula: C
9h
11cl
3nO
3pS, chlopyrifos is anticholinesterase, and the residual life on blade is not long, but residual life in soil is then longer, good to the preventive effect of soil insect.Responsive to tobacco.
Seed coating technology is a kind of very universal seed treatment new technology grown up in traditional seed soaking or seed dressing technical foundation.By seed that is dry or moisture state; wrapped with compositions such as the agricultural chemicals containing binding agent or fertilizer; make to form the protective layer with certain function and coated intensity outward at seed; this process becomes seed pelleting; the composition wrapped in outside seed is referred to as seed coat agent, is a kind of for crop or other plant seed treatment, the pesticidal preparations with film forming characteristics.Seed coat agent great advantage is outside seed, to form one deck more firmly film.Seed coat agent imbibition and not dissolved in soil, allows normally germinate required moisture and air of seed to pass through, the material slow releasing such as contained agricultural chemicals and seed manure.So, seed coat agent have kill soil insect, seedling stage insect, control sprout term disease and systemic disease, improves percentage of seedgermination, promotes seedling healthy growth, the effects such as less seed consumption, finally reach preventing disease pest control, strong sprout of keeping a full stand of seedings, improves the object of output.
The problem that prevention and elimination of disease and pests the most easily produces is drug-fast generation, and secondly for control spectrum is single, repeatedly dispenser when peasant uses, cause environmental pollution serious, crop residue of pesticide are large, unfavorable to human health.Applicant is by the bactericide of the different mechanism of action and pesticide compositional, reach the two anti-object of a spray, effectively the various disease of control crop, expand the control spectrum of former single dose, do not directly act on crop, and residue of pesticide are decomposed between the crop growth stage, to crop noresidue or low-residual, to eater's safety, and synergistic effect is remarkable, Environmental compatibility is fabulous, considerably reduces pesticide usage amount, reduces the dispenser cost of peasant.
Summary of the invention
Fluorine azoles ring bacterium amine, chlopyrifos, the resistance that ethiprole single dose Long-Time Service may bring occurs, degradation problem under drug effect, the Pesticidal combination that the present invention proposes contains the composition pesticide of fluorine azoles ring bacterium amine, by fluorine azoles ring bacterium amine and chlopyrifos, Firponil compounded, add appropriate auxiliary agent and make preparation, for preventing and treating wheat, cotton, peanut, , vegetables, corn, paddy rice, the application of the insect on watermelon, be mainly used in anti-eliminating aphis, midge worm, root-knot nematode, wireworm, grub, cutworm, thrips, 2 committee noctuids, snout moth's larva, banded sclerotial blight, bakanae disease, blight dis-ease, rust, yellow rust, head blight, powdery mildew, anthracnose, head smut, the effect of full rot is very outstanding, there is the effect that a spray two is anti-.
A composition pesticide for disinsection prophylaxis, is characterized in that: fluorine azoles ring bacterium amine and active ingredient B, and wherein the weight ratio of fluorine azoles ring bacterium amine and active ingredient B is that 1 ︰ 80 ~ 80 ︰ 1, active ingredient B is selected from ethiprole, chlopyrifos; The weight ratio of fluorine azoles ring bacterium amine and active ingredient B is preferably 1 ︰ 60 ~ 60 ︰ 1; The weight ratio of fluorine azoles ring bacterium amine and ethiprole is more preferred from 20 ︰ 1 ~ 1 ︰ 30; The weight ratio of fluorine azoles ring bacterium amine and chlopyrifos is more preferred from 10 ︰ 1 ~ 1 ︰ 20.
Composition can make any formulation on agricultural chemicals, wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, seed treatment microcapsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent, seed treatment dry powder doses, seed treatment emulsion, seed treatment dispersible pulvis, seed dressing, suspension seed-coating agent, most preferably is suspension seed-coating agent.
When the formulation of composition is suspension seed-coating agent, the auxiliary agent of interpolation is: antifreeze, Ricinate, film forming agent, defoamer, tackifier, colouring agent, antifreeze, water add to 100%.
Composition comprises following constituent content when making suspension seed-coating agent: fluorine azoles ring bacterium amine 0.1% ~ 30%, active ingredient B0.1% ~ 30%, Ricinate 1.0% ~ 8.0%, film forming agent 0.5% ~ 10%, defoamer 0.1% ~ 1%, colouring agent 1% ~ 10%, antifreeze 1% ~ 5.0%, tackifier 0.1% ~ 2.0%, water add to 100%.
Composition comprises following component and content when making wetting powder: fluorine azoles ring bacterium amine 0.5% ~ 60%, active component B0.5% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
Composition comprises following component and content when making water dispersible granules: fluorine azoles ring bacterium amine 0.5% ~ 60%, active component B0.5% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Composition comprises following component and content when making suspending agent: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making aqueous emulsion: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microemulsion: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making suspension emulsion: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 1% ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspending agent: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 1% ~ 10%, dispersant 2% ~ 10%, solvent 1% ~ 10%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspension-suspendinagent agent: fluorine azoles ring bacterium amine 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 1% ~ 12%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, solvent 1% ~ 15%, emulsifier 1% ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described antifreeze is selected from: one or both in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, one or more in silkworm excrement, soapberry powder.
Selected film forming agent ensures that limited farm chemical ingredients is concentrated and acts on seed and root, difficult drop-off and dispersing, and decreases agricultural chemicals diffusion in the environment and to the contact of non-target target, described suspension seed-coating agent also needs to comprise film forming agent.According to one or more in the preferential gum Arabic of film forming agent of the present invention, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, sodium carboxymethylcellulose, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, polyvinylpyrrolidone, polyacrylamide or Sodium Polyacrylate.
Described preservative is selected from benzoic acid, benzaldehyde, Sodium Benzoate, Potassium Benzoate, sorbic acid, sodium salicylate, 2-xenol, parahydroxyben-zaldehyde or 1, one or more in 2 benzothiazoline-3-ketone.
One or more in described tackifier xanthans, methylcellulose, gum Arabic, carboxymethyl cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, PAA, sodium alginate, polyvinyl alcohol, polyacrylamide, Sodium Polyacrylate, aluminium-magnesium silicate.
Selected colouring agent: one or more in basic rhodamine, iron oxide red, water-based rhodo, acid scarlet, FGR-131, RED-131, RED8110.
Described defoamer is selected from: one or both in C8 ~ 10 aliphatic alcohols, C10 ~ 20 saturated fat acids, silicone defoaming agent.
The composition pesticide of fluorine azoles ring bacterium amine disclosed in this invention, ethiprole, chlorpyrifos mixture, its advantage is:
(1) after dispenser, active ingredient release is slow, and the lasting period reaches more than 120 ~ 150 days, and not only save medicament but also save man-hour, insect also not easily develops immunity to drugs.
(2) improve the stability of effective active composition, can be mixed with other agricultural chemicals, growth regulator, micro-fertilizer, and without poisoning, can avoid for seed dressing or when filling with root medicament to kind, seedling harm.
(3) active component is wrapped in cyst wall and improves safety, achieves that high-toxic pesticide is low to be poisoned.
(4) present invention reduces the stimulus to the sense organ of liquid pesticidal to human body, mask the bad smell of former medicine.
(5) the present invention carries out composite with fluorine azoles ring bacterium amine and ethiprole, chlopyrifos, the two is had complementary advantages, the object that a dispenser can reach desinsection, cure the disease, to wheat, cotton, peanut, vegetables, corn, paddy rice, the insect in seedling stage such as watermelon and disease have good preventive effect, has special efficacy phase length, safety, low toxicity, the obvious advantage of synergy.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
By wetting agent, dispersant, film forming agent, warning colouration, antifreeze (can add and can not add), tackifier (can add and can not add), defoamer, mix through high speed shear, add fluorine azoles ring bacterium amine, active component B, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, surplus deionized water is supplied, and can obtain of the present invention kind of clothing suspending agent product, specifically in table 1.
The each component of table 1 embodiment 1 ~ 5 and weight portion
The each component of table 2 embodiment 6 ~ 10 and weight portion
The each component of table 3 embodiment 11 ~ 15 and weight portion
The each component of table 4 embodiment 11 ~ 16 and weight portion
Application Example two:
For examination disease: maize head smut
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluorine azoles ring bacterium amine ethiprole, the former medicine of chlopyrifos and the two different ratio mixture.
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, synergy index is greater than 1 expression synergistic effect, is less than 1 for antagonism, is summation action, on this basis, then carries out field trial between equaling 1.
Computing formula is as follows:
According to survey data, the disease index respectively processed by following formulae discovery and control efficiency:
Be dependent variable (y) by the probit value of control efficiency, with the logarithm value of using dosage (gram of/kilogram of seed) be independent variable (x), input CASIO fx180p calculator, asks the 50 7.509085e-218ffective concentration EC of each medicament
50, EC
90, 95% confidence limit, b value, standard error SD, calculate co-toxicity coefficient.With fluorine azoles ring bacterium amine for bactericide, ethiprole and chlopyrifos are that synergist calculates synergy index, and synergy index is greater than 1 expression synergistic effect, are less than 1 for antagonism, are summation action between equaling 1.
EC when synergy index=medicament is alone
50eC when value/medicament adds synergist
50value.
The experimental result of table 5 fluorine azoles ring bacterium amine ethiprole
The experimental result of table 6 fluorine azoles ring bacterium amine chlopyrifos
When preventing and treating the proportioning 1:80 to 80:1 of maize head smut after can finding out fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture by table 5 and table 6, synergy index is greater than 1, both explanations mixture in 1:80 to 80:1 scope all shows synergistic effect, especially, when fluorine azoles ring bacterium amine and ethiprole, chlopyrifos are at 10:1 to 1:10, synergistic effect is more obviously given prominence to.
Application Example three:
For examination disease: wheat wireworm
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluorine azoles ring bacterium amine ethiprole, the former medicine of chlopyrifos and the two different ratio mixture.
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, synergy index is greater than 1 expression synergistic effect, is less than 1 for antagonism, is summation action, on this basis, then carries out field trial between equaling 1.
Computing formula is as follows:
According to investigation result, by following formulae discovery lethality and corrected mortality
Be dependent variable (y) by the probit value of corrected mortality, with the logarithm value of using dosage (gram of/kilogram of seed) be independent variable (x), input CASIO fx180p calculator, asks the LC of each medicament
50, LC
90, 95% confidence limit, b value, standard error SD, with ethiprole, chlopyrifos for contrast medicament (toxicity index is for 1), calculate the relative virus force index of fluorine azoles ring bacterium amine chlopyrifos or fluorine azoles ring bacterium amine ethiprole, evaluation fluorine azoles ring bacterium amine chlopyrifos or fluorine azoles ring bacterium amine ethiprole are to the biologically active of wheat aphid.With ethiprole and chlopyrifos for insecticide, fluorine azoles ring bacterium amine is that synergist calculates synergy index.
LC when synergy index=medicament is alone
50lC when value/medicament adds synergist
50value.
The experimental result of table 7 fluorine azoles ring bacterium amine ethiprole
The experimental result of table 8 fluorine azoles ring bacterium amine chlopyrifos
When preventing and treating the proportioning 1:80 to 80:1 of wheat wireworm after can finding out fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture by table 7 and table 8, synergy index is greater than 1, both explanations mixture in 1:80 to 80:1 scope all shows synergistic effect, especially, when fluorine azoles ring bacterium amine and ethiprole, chlopyrifos are at 10:1 to 1:10, synergistic effect is more obviously given prominence to.
Test of pesticide effectiveness part: test medicine is 3% fluorine azoles ring bacterium amine suspension seed-coating agent, 6% chlopyrifos suspension seed-coating agent, 50 grams per liter ethiprole suspension seed-coating agents, and the test medicine of this experiment provides by Shaanxi Meibang Pesticide Co., Ltd..
In order to understand invention further, below in conjunction with embodiment, the present invention is described in detail.According to the present invention, according to controlling object, a situation arises determines the consumption that is suitable for, and usual formulation rate is the weight ratio of seed dressing and seed is 1:30 ~ 60.
Application Example four: the damage by disease and insect test of pesticide effectiveness on fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture and composite control wheat thereof
This test arrangement in Xi'an City, Shanxi Province, pesticide-seeds ratio when 1:30 ~ 60 to the preventive effect of wheat powdery mildew more than 97%, to the preventive effect of take-all more than 97%, to seedling stage wireworm preventive effect more than 97%, to the preventive effect of cutworm more than 97%.Experimental result is as following table.
Table 9 fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture prevent and treat the test of pesticide effectiveness of the damage by disease and insect on wheat
As can be seen from Table 9, can effectively prevent and treat wheat powdery mildew, take-all, wireworm, cutworm after fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.Application Example five: the damage by disease and insect test of pesticide effectiveness on fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture and composite control paddy rice thereof
This test arrangement in Hanzhong, Shaanxi Province, pesticide-seeds ratio when 1:30 ~ 60 to the preventive effect of rice sheath blight disease more than 97%, to the preventive effect of bakanae disease of rice more than 97%, to rice hoppers preventive effect more than 97%, to Aphids in Rice Field preventive effect more than 97%.Experimental result is as following table.
Table 10 fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture prevent and treat the test of pesticide effectiveness of damage by disease and insect on paddy rice
As can be seen from Table 10, can effectively the water prevention rice sheath blight, bakanae disease of rice, rice hoppers, Aphids in Rice Field after fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example six: the damage by disease and insect test of pesticide effectiveness in fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture and composite control of maize thereof
This test arrangement is in Baoji, Shaanxi province city, pesticide-seeds ratio when 1:30-60 to the preventive effect of maize head smut more than 97%, to the preventive effect of corn rust more than 97%, to corn small brown rice planthopper preventive effect more than 97%, to the preventive effect of corn borer more than 97%, experimental result is as following table.
The test of pesticide effectiveness of table 11 fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture control of maize damage by disease and insect
As can be seen from Table 11, can effectively control of maize head smut, corn rust, corn 2 to entrust noctuid, corn borer after fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven: the damage by disease and insect test of pesticide effectiveness on fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture and composite control watermelon thereof
This test arrangement at Shaanxi Province's Weinan City, pesticide-seeds ratio when 1:30 ~ 60 to the preventive effect of watermelon anthrax more than 7%, to the preventive effect of watermelon grafting 7%, to the preventive effect of thrips more than 97%, to the preventive effect of root-knot nematode more than 97%, experimental result is as following table.
Table 12 fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture prevent and treat the test of pesticide effectiveness of the sick worm on watermelon
As can be seen from Table 12, can effectively prevent and treat watermelon anthrax, watermelon grafting, thrips, root-knot nematode after fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, to the aphid in various crop, midge worm, root-knot nematode, wireworm, grub, cutworm, thrips, 2 entrust noctuid, snout moth's larvas after fluorine azoles ring bacterium amine and ethiprole, chlorpyrifos mixture, the preventive effect of the common disease and pests such as banded sclerotial blight, bakanae disease, blight dis-ease, rust, yellow rust, head blight, powdery mildew, anthracnose, head smut, full rot is all more than 97%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. a composition pesticide for disinsection prophylaxis, is characterized in that: effective active composition is fluorine azoles ring bacterium amine and active ingredient B, and wherein the weight ratio of fluorine azoles ring bacterium amine and active ingredient B is that 1:80 ~ 80:1, active ingredient B are selected from ethiprole or chlopyrifos.
2. the composition pesticide of disinsection prophylaxis according to claim 1, is characterized in that: the weight ratio of fluorine azoles ring bacterium amine and active ingredient B is 1 ︰ 60 ~ 60 ︰ 1.
3. the composition pesticide of disinsection prophylaxis according to claim 2, is characterized in that: the weight ratio of fluorine azoles ring bacterium amine and ethiprole is 20 ︰ 1 ~ 1 ︰ 30; The weight ratio of fluorine azoles ring bacterium amine and chlopyrifos is 10 ︰ 1 ~ 1 ︰ 20.
4. the composition pesticide of disinsection prophylaxis according to claim 1, is characterized in that: combination dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, seed treatment microcapsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent, suspension seed-coating agent.
5. the composition pesticide of disinsection prophylaxis according to claim 1 is for preventing and treating the application to the damage by disease and insect on wheat, cotton, peanut, vegetables, corn, paddy rice, watermelon.
6. application according to claim 5, it is characterized in that: described insect pest be aphid, midge worm, root-knot nematode, wireworm, grub, cutworm, thrips, 2 committee noctuid, snout moth's larvas, described disease is banded sclerotial blight, bakanae disease, blight dis-ease, rust, yellow rust, head blight, powdery mildew, anthracnose, head smut, full rot.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101001527A (en) * | 2004-08-12 | 2007-07-18 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN102083315A (en) * | 2008-07-04 | 2011-06-01 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
| US20120108580A1 (en) * | 2010-04-14 | 2012-05-03 | Bayer Cropscience Ag | Use of Fungicidal Active Substances For Controlling Mycoses on Plants of the Palm Family |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101001527A (en) * | 2004-08-12 | 2007-07-18 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN102083315A (en) * | 2008-07-04 | 2011-06-01 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
| US20120108580A1 (en) * | 2010-04-14 | 2012-05-03 | Bayer Cropscience Ag | Use of Fungicidal Active Substances For Controlling Mycoses on Plants of the Palm Family |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Application publication date: 20150624 |
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