CN104703920A - 尖晶石材料的制造 - Google Patents

尖晶石材料的制造 Download PDF

Info

Publication number
CN104703920A
CN104703920A CN201380052901.9A CN201380052901A CN104703920A CN 104703920 A CN104703920 A CN 104703920A CN 201380052901 A CN201380052901 A CN 201380052901A CN 104703920 A CN104703920 A CN 104703920A
Authority
CN
China
Prior art keywords
powder
process according
microwave
lmn
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201380052901.9A
Other languages
English (en)
Chinese (zh)
Inventor
K·I·奥策梅纳
C·J·贾夫塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CSIR Corp
Original Assignee
CSIR Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CSIR Corp filed Critical CSIR Corp
Publication of CN104703920A publication Critical patent/CN104703920A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B1/00—Single-crystal growth directly from the solid state
    • C30B1/02—Single-crystal growth directly from the solid state by thermal treatment, e.g. strain annealing
    • C30B1/04—Isothermal recrystallisation
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/10—Inorganic compounds or compositions
    • C30B29/16—Oxides
    • C30B29/22—Complex oxides
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B30/00—Production of single crystals or homogeneous polycrystalline material with defined structure characterised by the action of electric or magnetic fields, wave energy or other specific physical conditions
    • C30B30/02—Production of single crystals or homogeneous polycrystalline material with defined structure characterised by the action of electric or magnetic fields, wave energy or other specific physical conditions using electric fields, e.g. electrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201380052901.9A 2012-08-10 2013-07-25 尖晶石材料的制造 Pending CN104703920A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA201206016 2012-08-10
ZA2012/06016 2012-08-10
PCT/IB2013/056103 WO2014024075A1 (en) 2012-08-10 2013-07-25 Production of a spinel material

Publications (1)

Publication Number Publication Date
CN104703920A true CN104703920A (zh) 2015-06-10

Family

ID=49304034

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380052901.9A Pending CN104703920A (zh) 2012-08-10 2013-07-25 尖晶石材料的制造

Country Status (10)

Country Link
US (1) US9834854B2 (https=)
EP (1) EP2882690B1 (https=)
JP (1) JP6316812B2 (https=)
KR (1) KR102085903B1 (https=)
CN (1) CN104703920A (https=)
AR (1) AR092069A1 (https=)
BR (1) BR112015002884B1 (https=)
CA (1) CA2880876C (https=)
WO (1) WO2014024075A1 (https=)
ZA (1) ZA201501121B (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108604673A (zh) * 2015-12-22 2018-09-28 Csir公司 尖晶石材料

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016001884A1 (en) 2014-07-03 2016-01-07 Csir Production of a layered lithium-manganese-nickel-cobalt oxide material
US9979011B2 (en) * 2014-09-26 2018-05-22 The United States Of America As Represented By The Secretary Of The Army LixMn2O4-y(C1z) spinal cathode material, method of preparing the same, and rechargeable lithium and li-ion electrochemical systems containing the same
BR112017009040B1 (pt) * 2014-10-31 2022-06-14 Csir Produção de um material de espinélio
US10505188B2 (en) * 2015-03-03 2019-12-10 The Government Of The United States As Represented By The Secretary Of The Army “B” and “O” site doped AB2O4 spinel cathode material, method of preparing the same, and rechargeable lithium and Li-ion electrochemical systems containing the same
CN105576231A (zh) * 2016-02-25 2016-05-11 江南大学 一种具有尖晶石结构的高电压锂离子电池正极材料及其制备方法
KR102219155B1 (ko) 2016-03-24 2021-02-23 후지필름 가부시키가이샤 감활성광선성 또는 감방사선성 조성물, 감활성광선성 또는 감방사선성 조성물의 제조 방법, 패턴 형성 방법, 및 전자 디바이스의 제조 방법
WO2017164018A1 (ja) 2016-03-24 2017-09-28 富士フイルム株式会社 感活性光線性又は感放射線性組成物、感活性光線性又は感放射線性組成物の精製方法、感活性光線性又は感放射線性組成物の製造方法、パターン形成方法、及び電子デバイスの製造方法
KR102212733B1 (ko) 2016-03-24 2021-02-05 후지필름 가부시키가이샤 감활성광선성 또는 감방사선성 조성물, 감활성광선성 또는 감방사선성 조성물의 정제 방법, 패턴 형성 방법, 및 전자 디바이스의 제조 방법
US10516156B2 (en) * 2016-05-25 2019-12-24 The Government Of The United States As Represented By The Secretary Of The Army Chlorinated lithium manganese oxide spinel cathode material with charge transfer catalyst coating, method of preparing the same, and Li electrochemical cell containing the same
KR101963251B1 (ko) * 2017-10-17 2019-03-29 한국과학기술연구원 양극 활물질 제조방법 및 이를 이용한 이차전지
CN114369863B (zh) * 2021-12-08 2023-02-14 中国科学院地球化学研究所 一种高温高压下制备锰铝榴石单晶的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2221213B (en) * 1988-07-12 1991-09-04 Csir Synthesizing lithium manganese oxide
CN1042377C (zh) * 1996-05-10 1999-03-03 中国科学院物理研究所 一种合成锂离子电池中正极材料的方法
JP2973299B2 (ja) * 1996-06-27 1999-11-08 本荘ケミカル株式会社 スピネル型構造を有するリチウム−マンガン複合酸化物の製造方法
US6348182B1 (en) * 1996-06-27 2002-02-19 The Honjo Chemical Corporation Process for producing lithium manganese oxide with spinel structure
JP3411488B2 (ja) * 1997-12-01 2003-06-03 本荘ケミカル株式会社 リチウムイオン二次電池用正極活物質の製造方法
JP2000281355A (ja) * 1999-03-29 2000-10-10 Nippon Chem Ind Co Ltd リチウム複合酸化物の製造方法
US8728666B2 (en) * 2005-04-28 2014-05-20 Nissan Motor Co., Ltd. Positive electrode material for lithium ion battery with nonaqueous electrolyte, and battery using the same
US8496855B2 (en) * 2009-07-27 2013-07-30 Samsung Electronics Co., Ltd. Cathode active material, cathode including cathode active material, and lithium battery including cathode
JP2011210463A (ja) * 2010-03-29 2011-10-20 Jx Nippon Mining & Metals Corp リチウムイオン電池用正極活物質の製造方法

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
HUGUES DUNCAN ET AL.: "Microwave-assisted sol-gel synthesis of high-voltage LiMn1.5Ni0.5O4 cathode material for Li-ion batteries", 《215TH ECS MEETING, ABSTRACT》 *
HUGUES DUNCAN ET AL.: "Microwave-assisted sol-gel synthesis of high-voltage LiMn1.5Ni0.5O4 cathode material for Li-ion batteries", 《215TH ECS MEETING, ABSTRACT》, 31 December 2009 (2009-12-31) *
M. KUNDURACI ET AL.: "Synthesis and Characterization of Nanostructured 4.7 V LixMn1.5Ni0.5O4 Spinels for High-Power Lithium-Ion Batteries", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 *
M. KUNDURACI ET AL.: "Synthesis and Characterization of Nanostructured 4.7 V LixMn1.5Ni0.5O4 Spinels for High-Power Lithium-Ion Batteries", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》, vol. 153, no. 7, 11 May 2006 (2006-05-11), pages 1345 - 1352, XP055095258, DOI: doi:10.1149/1.2198110 *
R. SANTHANAM ET AL.: "Research progress in high voltage spinel LiNi0.5Mn1.5O4 material", 《JOURNAL OF POWER SOURCES》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108604673A (zh) * 2015-12-22 2018-09-28 Csir公司 尖晶石材料

Also Published As

Publication number Publication date
AR092069A1 (es) 2015-03-18
US9834854B2 (en) 2017-12-05
CA2880876C (en) 2020-07-07
BR112015002884B1 (pt) 2021-06-08
EP2882690B1 (en) 2016-10-12
KR20150056542A (ko) 2015-05-26
EP2882690A1 (en) 2015-06-17
US20150197872A1 (en) 2015-07-16
CA2880876A1 (en) 2014-02-13
BR112015002884A2 (pt) 2019-10-08
KR102085903B1 (ko) 2020-03-06
JP6316812B2 (ja) 2018-04-25
ZA201501121B (en) 2016-01-27
WO2014024075A1 (en) 2014-02-13
JP2015525734A (ja) 2015-09-07

Similar Documents

Publication Publication Date Title
US11183692B2 (en) Production of a layered lithium-manganese-nickel-cobalt oxide material
JP7160075B2 (ja) リチウムイオン二次電池用正極活物質及びリチウムイオン二次電池
CN104703920A (zh) 尖晶石材料的制造
Chen et al. Oxygen vacancies in SnO2 surface coating to enhance the activation of layered Li-Rich Li1. 2Mn0. 54Ni0. 13Co0. 13O2 cathode material for Li-ion batteries
Lee et al. Synthetic optimization of Li [Ni1/3Co1/3Mn1/3] O2 via co-precipitation
Jang et al. Synthesis and improved electrochemical performance of Al (OH) 3-coated Li [Ni1/3Mn1/3Co1/3] O2 cathode materials at elevated temperature
Liu et al. Structural and electrochemical properties of Co–Mn–Mg multi-doped nickel based cathode materials LiNi0. 9Co0. 1− x [Mn1/2Mg1/2] xO2 for secondary lithium ion batteries
EP2351124A2 (en) Fluorine doped lithium rich metal oxide positive electrode battery materials with high specific capacity and corresponding batteries
EP2067198A2 (en) Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries
CN107108260B (zh) 尖晶石材料的制备
Ma et al. Effect of calcination temperature on microstructure and electrochemical performance of lithium-rich layered oxide cathode materials
Zhu et al. A layered/spinel heterostructured cathode for Li-ion batteries prepared by ultrafast Joule heating
JP2022001550A (ja) リチウム複合酸化物及びその製造方法
JP4833058B2 (ja) リチウム二次電池正極用のリチウム含有複合酸化物の製造方法
Jayachandran et al. Tailored solution combustion method for enhancing high voltage electrochemical performance Li1. 2Ni0. 1Mn0. 6Co0. 1O2 as cathode material for lithium-ion batteries
Li et al. Nickel-modified and zirconium-modified Li2MnO3 and applications in lithium-ion battery
KR100211179B1 (ko) 리튬 이차전지용 양극 활물질 LixMn2O4 분말 및 그 제조방법
Tang et al. Structure and electrochemical properties of Li1+ yNi0. 5AlxMn0. 5− xO2 synthesized by a new sol–gel method
Wang et al. Spinel lithium manganese oxide nanoparticles: unique molten salt synthesis strategy and excellent electrochemical performances
Thirunakaran et al. Malonic acid assisted sol-gel synthesis and characterization of chromium doped LiMn2O4 spinel
CN120282932A (zh) 用于处理正极活性材料粒子的方法、和正极活性材料以及采用其的非水电解质二次电池
Zhu et al. A High-Performance Layered/Spinel Heterostructured Cathode Enabled by Ultrafast Joule Heating
Selladurai et al. Structure and Electrochemistry of 4-V Positive Electrodes Prepared by Succinic Acid-Assisted Wet Chemistry
WO2001077023A1 (en) Lithium/manganese complex oxide and method for producing the same, and lithium cell using the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150610

RJ01 Rejection of invention patent application after publication