CN104703913A - 生产合成气的方法 - Google Patents

生产合成气的方法 Download PDF

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Publication number
CN104703913A
CN104703913A CN201380052959.3A CN201380052959A CN104703913A CN 104703913 A CN104703913 A CN 104703913A CN 201380052959 A CN201380052959 A CN 201380052959A CN 104703913 A CN104703913 A CN 104703913A
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China
Prior art keywords
gas
stage
synthesis gas
synthesis
stream
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Pending
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CN201380052959.3A
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English (en)
Chinese (zh)
Inventor
I·戴克加尔
R·马布劳克
K·阿斯伯格-彼得森
C·N·希奥特
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Topsoe AS
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Haldor Topsoe AS
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Publication of CN104703913A publication Critical patent/CN104703913A/zh
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/06—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by mixing with gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN201380052959.3A 2012-10-11 2013-10-10 生产合成气的方法 Pending CN104703913A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EPPCT/EP2012/070133 2012-10-11
PCT/EP2012/070133 WO2014056535A1 (en) 2012-10-11 2012-10-11 Process for the production of synthesis gas
PCT/EP2013/071113 WO2014057013A1 (en) 2012-10-11 2013-10-10 Process for the production of synthesis gas

Publications (1)

Publication Number Publication Date
CN104703913A true CN104703913A (zh) 2015-06-10

Family

ID=47351567

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380052959.3A Pending CN104703913A (zh) 2012-10-11 2013-10-10 生产合成气的方法

Country Status (6)

Country Link
US (1) US20150259202A1 (https=)
KR (1) KR20150065879A (https=)
CN (1) CN104703913A (https=)
EA (1) EA201590706A1 (https=)
IN (1) IN2015DN02626A (https=)
WO (2) WO2014056535A1 (https=)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018162A (zh) * 2015-07-07 2015-11-04 中石化宁波工程有限公司 费托合成油工艺循环尾气的处理方法
CN110944937A (zh) * 2017-07-25 2020-03-31 托普索公司 用于制备合成气的方法
CN110944938A (zh) * 2017-07-25 2020-03-31 托普索公司 用于制备合成气的方法
CN113474283A (zh) * 2019-02-28 2021-10-01 托普索公司 具有重整段的化工设备和生产化学产品的方法
CN115707648A (zh) * 2021-08-20 2023-02-21 气体产品与化学公司 生产h2和合成气的工艺

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10196266B2 (en) 2014-07-09 2019-02-05 Haldor Topsoe A/S Process for producing hydrogen
EA039544B1 (ru) 2016-02-02 2022-02-09 Хальдор Топсёэ А/С Способ и установка для производства аммиака на основе автотермического риформинга
US11345593B2 (en) * 2016-12-13 2022-05-31 Haldor Topsøe A/S System and process for synthesis gas production
HUE068047T2 (hu) * 2017-07-25 2024-12-28 Topsoe As Eljárás ammóniaszintézis-gázüzem hatékonyságának javítására
MY201333A (en) * 2017-07-25 2024-02-16 Haldor Topsoe As Method for the preparation of synthesis gas
WO2019021129A1 (en) * 2017-07-27 2019-01-31 Sabic Global Technologies B.V. APPARATUS AND METHOD RELATED TO THE USE OF SYNTHESIS GAS IN OLEFIN PRODUCTION
EP3953295A1 (en) * 2019-04-08 2022-02-16 Haldor Topsøe A/S Chemical synthesis plant
CA3126620A1 (en) * 2019-04-08 2020-10-15 Haldor Topsoe A/S Chemical synthesis plant and method for utilization of carbon dioxide
KR20220077135A (ko) 2019-10-01 2022-06-08 할도르 토프쉐 에이/에스 맞춤형 합성 가스
EP4717666A2 (en) 2019-12-04 2026-04-01 Topsoe A/S Electrically heated carbon monooxide reactor
AU2021359759A1 (en) * 2020-10-14 2023-06-08 Topsoe A/S Syngas stage for chemical synthesis plant
GB2600177B (en) 2020-10-21 2023-06-07 Velocys Tech Limited Gasification process
WO2025132844A1 (en) * 2023-12-20 2025-06-26 Topsoe A/S Method and system for improving carbon efficiency in production of syngas and synthetic fuels

Citations (3)

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US20100298449A1 (en) * 2006-08-08 2010-11-25 Ifp Method of producing synthetic gas with partial oxidation and steam reforming
WO2011112484A1 (en) * 2010-03-08 2011-09-15 Praxair Technology, Inc. Using fossil fuels to increase biomass-based fuel benefits
WO2011151012A1 (en) * 2010-06-01 2011-12-08 Haldor Topsøe A/S Process for the preparation of synthesis gas

Family Cites Families (5)

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US6872753B2 (en) 2002-11-25 2005-03-29 Conocophillips Company Managing hydrogen and carbon monoxide in a gas to liquid plant to control the H2/CO ratio in the Fischer-Tropsch reactor feed
BRPI0619933A2 (pt) 2005-12-15 2011-10-25 Sasol Tech Pty Ltd processo para a produção de hidrocarbonetos a partir de gás natural
EP1860063A1 (en) 2006-05-22 2007-11-28 Shell Internationale Researchmaatschappij B.V. Process for preparing a paraffin product
PL2141118T3 (pl) 2008-07-03 2014-01-31 Haldor Topsoe As Bezchromowy katalizator do konwersji gazu wodnego
US20110071229A1 (en) * 2009-09-21 2011-03-24 Synthesis Energy Systems, Inc. Synthetic Gas Recycle Apparatus and Methods

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100298449A1 (en) * 2006-08-08 2010-11-25 Ifp Method of producing synthetic gas with partial oxidation and steam reforming
WO2011112484A1 (en) * 2010-03-08 2011-09-15 Praxair Technology, Inc. Using fossil fuels to increase biomass-based fuel benefits
WO2011151012A1 (en) * 2010-06-01 2011-12-08 Haldor Topsøe A/S Process for the preparation of synthesis gas

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018162A (zh) * 2015-07-07 2015-11-04 中石化宁波工程有限公司 费托合成油工艺循环尾气的处理方法
CN105018162B (zh) * 2015-07-07 2018-08-17 中石化宁波工程有限公司 费托合成油工艺循环尾气的处理方法
CN110944937A (zh) * 2017-07-25 2020-03-31 托普索公司 用于制备合成气的方法
CN110944938A (zh) * 2017-07-25 2020-03-31 托普索公司 用于制备合成气的方法
CN113474283A (zh) * 2019-02-28 2021-10-01 托普索公司 具有重整段的化工设备和生产化学产品的方法
CN115707648A (zh) * 2021-08-20 2023-02-21 气体产品与化学公司 生产h2和合成气的工艺
CN115707648B (zh) * 2021-08-20 2024-05-14 气体产品与化学公司 生产h2和合成气的工艺

Also Published As

Publication number Publication date
US20150259202A1 (en) 2015-09-17
IN2015DN02626A (https=) 2015-09-18
WO2014056535A1 (en) 2014-04-17
EA201590706A1 (ru) 2015-09-30
WO2014057013A1 (en) 2014-04-17
KR20150065879A (ko) 2015-06-15

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