CN104693827A - Fireproof flame-retardant environment-friendly composite plate and preparation method thereof - Google Patents
Fireproof flame-retardant environment-friendly composite plate and preparation method thereof Download PDFInfo
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- CN104693827A CN104693827A CN201510060219.5A CN201510060219A CN104693827A CN 104693827 A CN104693827 A CN 104693827A CN 201510060219 A CN201510060219 A CN 201510060219A CN 104693827 A CN104693827 A CN 104693827A
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- 239000002131 composite material Substances 0.000 title claims abstract 7
- 238000002360 preparation method Methods 0.000 title claims abstract 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003063 flame retardant Substances 0.000 title abstract 3
- 239000000843 powder Substances 0.000 claims abstract 7
- 239000000463 material Substances 0.000 claims abstract 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract 5
- 239000000835 fiber Substances 0.000 claims abstract 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract 3
- 239000011425 bamboo Substances 0.000 claims abstract 3
- 239000011521 glass Substances 0.000 claims abstract 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000002699 waste material Substances 0.000 claims abstract 3
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 claims abstract 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims abstract 2
- 239000002994 raw material Substances 0.000 claims 5
- 238000003756 stirring Methods 0.000 claims 5
- 239000007767 bonding agent Substances 0.000 claims 3
- 244000144730 Amygdalus persica Species 0.000 claims 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 2
- 239000004327 boric acid Substances 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 2
- 239000000391 magnesium silicate Substances 0.000 claims 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims 2
- 235000019792 magnesium silicate Nutrition 0.000 claims 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 239000000230 xanthan gum Substances 0.000 claims 2
- 229920001285 xanthan gum Polymers 0.000 claims 2
- 229940082509 xanthan gum Drugs 0.000 claims 2
- 235000010493 xanthan gum Nutrition 0.000 claims 2
- 244000068988 Glycine max Species 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 238000007731 hot pressing Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- 241001330002 Bambuseae Species 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- 239000010428 baryte Substances 0.000 abstract 1
- 229910052601 baryte Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
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- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a fireproof flame-retardant environment-friendly composite plate. The composite plate is characterized by being prepared from the following materials in parts by weight: 5-10 parts of waste glass powder, 5-10 parts of barite, 20-30 parts of bamboo powder, 10-15 parts of coir fiber, 3-5 parts of asbestos fiber, 3-5 parts of zinc borate, 0.5-1 part of triethanolamine borate, 1-2 parts of sodium stearate, 3-5 parts of sodium hexametaphosphate, 3-5 parts of ammonium polyphosphate and 10-20 parts of adhesion additive. The composite plate disclosed by the invention has good high-temperature resistance, fireproof and flame-retardant effect, high hardness and high weatherability, and is low in price, simple in technology and toxic, harmless, green, environment-friendly, economic and practical, and the use performances and use safety coefficient of the composite plate prepared according to a preparation method disclosed by the invention are effectively improved.
Description
Technical field
The present invention relates to decoration material field, be specifically related to a kind of Fireproof fire retardation type Environment-friendlycomposite composite board and preparation method thereof.
Background technology
Along with the development of building trade, all kinds of material of construction emerges in an endless stream, and meets the demand of the various use of people.Wherein, decorative boards accounts for critical role in interior decoration.In dalle, the high and environmental protection of solid wood board use properties, be at the top of one's class material, but due to solid wood resource few, construction technology is comparatively complicated, has the restriction that cost is high; At present conventional sheet material is many to be prepared from by the complete processing such as gluing by fiber, wooden slag etc., and for meeting user demand, the performance needs such as its intensity, outward appearance, quality make improvements.And this type of sheet material prepares used raw material often containing objectionable impuritiess such as formaldehyde, slowly volatilize after making furniture or finishing, Long contact time, to human health, cannot meet the requirement of safety and environmental protection.
Summary of the invention
The object of this invention is to provide a kind of Fireproof fire retardation type Environment-friendlycomposite composite board, not containing formaldehyde, toxicological harmless, environmental protection, use properties is good, and safety coefficient is high, economical and practical.
The present invention is achieved by the following technical solutions:
A kind of Fireproof fire retardation type Environment-friendlycomposite composite board, it is obtained by the raw material of following weight parts:
Waste glass powder 5-10, ground barium sulfate 5-10, bamboo powder 20-30, coir fibre 10-15, fibrous magnesium silicate 3-5, zinc borate 3-5, triethanolamine borate 0.5-1, sodium stearate 1-2, Sodium hexametaphosphate 99 3-5, ammonium polyphosphate 3-5, bonding agent 15-25;
Wherein bonding agent is made up of the raw material of following weight part:
Starso 10-15, analysis for soybean powder 5-10, sticky rice flour 5-10, polyvinyl alcohol 2-4, peach gum 4-6, xanthan gum 2-4, boric acid 1-2, water 40-50;
The preparation method of bonding agent is:
First in water, add polyvinyl alcohol and stir 20-30min under 85-95 DEG C of condition, then add peach gum, xanthan gum and boric acid 60-80 DEG C, 400-600r/min stirs 1-2h, stir 4-6h under finally adding all the other raw material similarity conditions, to obtain final product.
A preparation method for Fireproof fire retardation type Environment-friendlycomposite composite board, comprises the following steps:
(1) take raw material by weight, first waste glass powder, ground barium sulfate and Sodium hexametaphosphate 99 are mixed, 300-400 DEG C of calcining 1-2h, then add bamboo powder, coir fibre and fibrous magnesium silicate, mix rear 160-180 DEG C of process 3-5h;
(2) after the material obtained in step (1) being mixed with zinc borate and ammonium polyphosphate 40-60 DEG C, 200-400r/min stirs 1-2h;
(3) material obtained in step (2) is mixed with all the other raw materials, 60-80 DEG C, 300-600r/min stirs 15-30min;
(4) material that step (3) obtains is mated formation shaping, and sheet material is made in hot pressing under 140-180 DEG C of condition, sheet material is dry under 50-60 DEG C of condition, then carry out cutting, deburring, surface treatment, to obtain final product.
Advantage of the present invention is:
1. by the improvement of recipe optimization, make the composite sheet obtained have good high temperature resistant, fireproof flame-retardant effect, hardness is high, and weathering resistance is strong, effectively improves use properties and the use safety coefficient of product, cheap, and technique is simple, economical and practical;
2. raw material is not containing volatile class objectionable impuritiess such as formaldehyde, nontoxic, environmental protection.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of Fireproof fire retardation type Environment-friendlycomposite composite board, is prepared from by the component raw material of following weight (kg):
Waste glass powder 8, ground barium sulfate 8, bamboo powder 25, coir fibre 12, fibrous magnesium silicate 4, zinc borate 4, triethanolamine borate 0.8, sodium stearate 1.5, Sodium hexametaphosphate 99 4, ammonium polyphosphate 4, bonding agent 20;
Wherein, bonding agent is made up of the raw material of following weight part:
Starso 12, analysis for soybean powder 8, sticky rice flour 8, polyvinyl alcohol 3, peach gum 5, xanthan gum 3, boric acid 1.5, water 45;
The preparation method of bonding agent is:
First in water, add polyvinyl alcohol and stir 30min under 90 DEG C of condition, then add peach gum, xanthan gum and boric acid 80 DEG C, 600r/min stirs 1h, stir 4h under finally adding all the other raw material similarity conditions, to obtain final product.
The preparation method of Fireproof fire retardation type Environment-friendlycomposite composite board comprises the following steps:
(1) take raw material by weight, first waste glass powder, ground barium sulfate and Sodium hexametaphosphate 99 are mixed, 400 DEG C of calcining 1h, then add bamboo powder, coir fibre and fibrous magnesium silicate, mix rear 180 DEG C of process 3h;
(2) material obtained in step (1) is mixed latter 60 DEG C with zinc borate and ammonium polyphosphate, 400r/min stirs 1h;
(3) material obtained in step (2) is mixed with all the other raw materials, 80 DEG C, 600r/min stirs 30min;
(4) material that step (3) obtains is mated formation shaping, and sheet material is made in hot pressing under 160 DEG C of conditions, sheet material is dry under 60 DEG C of conditions, then carry out cutting, deburring, surface treatment, to obtain final product.
The product obtained to above-described embodiment is tested, and performance index are as follows:
Ultimate compression strength: 37.7MPa.
Claims (2)
1. a Fireproof fire retardation type Environment-friendlycomposite composite board, is characterized in that, it is obtained by the raw material of following weight parts:
Waste glass powder 5-10, ground barium sulfate 5-10, bamboo powder 20-30, coir fibre 10-15, fibrous magnesium silicate 3-5, zinc borate 3-5, triethanolamine borate 0.5-1, sodium stearate 1-2, Sodium hexametaphosphate 99 3-5, ammonium polyphosphate 3-5, bonding agent 15-25;
Described bonding agent is made up of the raw material of following weight part:
Starso 10-15, analysis for soybean powder 5-10, sticky rice flour 5-10, polyvinyl alcohol 2-4, peach gum 4-6, xanthan gum 2-4, boric acid 1-2, water 40-50;
The preparation method of described bonding agent is:
First in water, add polyvinyl alcohol and stir 20-30min under 85-95 DEG C of condition, then add peach gum, xanthan gum and boric acid 60-80 DEG C, 400-600r/min stirs 1-2h, stir 4-6h under finally adding all the other raw material similarity conditions, to obtain final product.
2. the preparation method of a kind of Fireproof fire retardation type Environment-friendlycomposite composite board according to claim 1, is characterized in that, comprise the following steps:
(1) take raw material by weight, first waste glass powder, ground barium sulfate and Sodium hexametaphosphate 99 are mixed, 300-400 DEG C of calcining 1-2h, then add bamboo powder, coir fibre and fibrous magnesium silicate, mix rear 160-180 DEG C of process 3-5h;
(2) after the material obtained in step (1) being mixed with zinc borate and ammonium polyphosphate 40-60 DEG C, 200-400r/min stirs 1-2h;
(3) material obtained in step (2) is mixed with all the other raw materials, 60-80 DEG C, 300-600r/min stirs 15-30min;
(4) material that step (3) obtains is mated formation shaping, and sheet material is made in hot pressing under 140-180 DEG C of condition, sheet material is dry under 50-60 DEG C of condition, then carry out cutting, deburring, surface treatment, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510060219.5A CN104693827A (en) | 2015-02-05 | 2015-02-05 | Fireproof flame-retardant environment-friendly composite plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510060219.5A CN104693827A (en) | 2015-02-05 | 2015-02-05 | Fireproof flame-retardant environment-friendly composite plate and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104693827A true CN104693827A (en) | 2015-06-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510060219.5A Pending CN104693827A (en) | 2015-02-05 | 2015-02-05 | Fireproof flame-retardant environment-friendly composite plate and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104693827A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422905A (en) * | 2001-12-05 | 2003-06-11 | 叶科尼亚有限责任公司 | Preparation method for formed articles capable of biological degradation |
| CN101629019A (en) * | 2009-01-21 | 2010-01-20 | 郑州佰沃生物质材料有限公司 | Basic biomass synthetic resin and preparation method and application thereof |
| CN102021966A (en) * | 2010-06-08 | 2011-04-20 | 蒋道友 | Plant fibers and formaldehyde-free artificial board composited building wall panel |
| CN103525110A (en) * | 2013-09-26 | 2014-01-22 | 广东省石油化工研究院 | High-strength PE (polyethylene) wood-plastic composite material and preparation method thereof |
-
2015
- 2015-02-05 CN CN201510060219.5A patent/CN104693827A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422905A (en) * | 2001-12-05 | 2003-06-11 | 叶科尼亚有限责任公司 | Preparation method for formed articles capable of biological degradation |
| CN101629019A (en) * | 2009-01-21 | 2010-01-20 | 郑州佰沃生物质材料有限公司 | Basic biomass synthetic resin and preparation method and application thereof |
| CN102021966A (en) * | 2010-06-08 | 2011-04-20 | 蒋道友 | Plant fibers and formaldehyde-free artificial board composited building wall panel |
| CN103525110A (en) * | 2013-09-26 | 2014-01-22 | 广东省石油化工研究院 | High-strength PE (polyethylene) wood-plastic composite material and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150610 |
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| RJ01 | Rejection of invention patent application after publication |