CN104674566A - 可逆变色指示消毒剂的无纺抹布 - Google Patents
可逆变色指示消毒剂的无纺抹布 Download PDFInfo
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- CN104674566A CN104674566A CN201510075681.2A CN201510075681A CN104674566A CN 104674566 A CN104674566 A CN 104674566A CN 201510075681 A CN201510075681 A CN 201510075681A CN 104674566 A CN104674566 A CN 104674566A
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- MGUKYHHAGPFJMC-UHFFFAOYSA-N 4-[3-(4-hydroxy-2,5-dimethylphenyl)-1,1-dioxo-2,1$l^{6}-benzoxathiol-3-yl]-2,5-dimethylphenol Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C)C=2)C)=C1C MGUKYHHAGPFJMC-UHFFFAOYSA-N 0.000 claims description 4
- BELBBZDIHDAJOR-UHFFFAOYSA-N Phenolsulfonephthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2S(=O)(=O)O1 BELBBZDIHDAJOR-UHFFFAOYSA-N 0.000 claims description 4
- NUHCTOLBWMJMLX-UHFFFAOYSA-N bromothymol blue Chemical compound BrC1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=C(Br)C(O)=C(C(C)C)C=2)C)=C1C NUHCTOLBWMJMLX-UHFFFAOYSA-N 0.000 claims description 4
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- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 3
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- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000001069 triethyl citrate Substances 0.000 claims description 3
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000013769 triethyl citrate Nutrition 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid group Chemical group C(CCCCC(=O)O)(=O)O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 4
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- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims 2
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- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
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- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical class [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/004—Dyeing with phototropic dyes; Obtaining camouflage effects
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
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Abstract
一种无纺抹布具有用于多种用途的可逆消毒指示剂并能提供再次补充。所述无纺抹布包括涂有可逆变色油墨制剂的似布无纺纤维。在使用过程中,无纺抹布被浸渍有源于季铵化合物的消毒剂。当自由季铵化合物的水平下降到限定值之下时,变色油墨制剂从第一颜色变为第二颜色,指示需要再次给抹布补充。当无纺抹布被再次补充消毒剂溶液后,变色油墨制剂变回第一颜色。
Description
本申请是申请日为2010年3月4日、国际申请号为PCT/US2010/026172、国家申请号为201080020025.8、发明名称为“可逆变色指示消毒剂的无纺抹布”的发明专利申请的分案申请。
相关申请的交叉引用
本申请要求了2009年3月31日递交的美国临时申请61/211,505的权益。该临时申请在此通过参考其全部被并入本申请中,包括但不限于具体地出现在下文中的这些部分。
发明领域
本发明涉及一种无纺抹布,当消毒杀菌剂的浓度下降到限定值之下时,该无纺抹布的颜色从第一颜色改变为第二颜色,并且当消毒杀菌剂的浓度再次上升到限定值之上时,无纺抹布的颜色从第二颜色变为第一颜色。
背景技术
授予给Fenn等人的美国专利4,311,479公开了具有颜色指示剂的布巾,授予给Fellows.Fenn等人的美国专利4,678,704公开了浸渍了抗菌成分的布料,该抗菌成分一旦与液体如水接触就会被激活,并且离子地结合到布料上。浸渍的布料的小部分用指示剂染料染色,该指示剂染料优先地与抗菌成分结合以便当抗菌成分耗尽时,染料将从布料上消失。
Fellows公开了一种浸渍织物材料,该浸渍织物材料具有结合到它的织物基底的活性阳离子浸渍剂。与添加的阳离子组分结合的阴离子指示剂染料也结合到基底。与基底相比,染料更加易于结合到添加的阳离子成分上,并且添加的阳离子成分与浸渍剂相竞争以便结合到染料上。就抹布来说,当染料已经被去除用以表明活性成分的耗尽时,足够的活性成分余留在布料上以提供安全界限。
虽然这些以及类似的现有技术的织物具有颜色指示剂以指示浸渍剂的消耗,但指示剂仅仅作用一次,并且仅改变颜色一次。如果织物随后再被补充浸渍剂,如通过将其浸入桶中,原色将不会恢复并且指示剂功能将不会恢复。
有必要或需要一种能多次补充以使用多次的浸渍有去污溶液、消毒剂等等的织物,并且当洗液或消毒剂的水平每次变低时其能进行指示。
发明内容
本发明涉及用于多种用途和再补充的具有可逆变色消毒指示剂的无纺抹布。该无纺抹布能被用于将桌子和工作台面擦干净,例如,直到抹布上的消毒剂的浓度下降到限定浓度之下。此时,该无纺抹布的颜色从第一颜色变为第二颜色。该无纺抹布随后能被再次补充,例如通过将无纺抹布浸入到消毒剂溶液的桶中。再次补充的无纺抹布随后变回第一颜色,并且被使用直到消毒剂的浓度下降到限定浓度并且颜色再次变为第二颜色。无纺抹布被再次补充,循环重复直到该无纺抹布由于变脏或损坏变得耗尽或者清洁工作完成。
无纺抹布包括似布的无纺织物,该似布的无纺织物至少部分地由吸收性无纺纤维形成,该吸收性无纺纤维由纤维素或其他合适材料形成。吸收性纤维能被制成人造纤维。无纺纤维能被单独使用或与强化无纺纤维结合使用,其无需有吸收能力。结构纤维可由聚酯或另外的合适材料制成。
似布无纺纤维涂有可逆变色油墨制剂,该可逆变色油墨制剂持久地将其本身粘合到无纺纤维并且在重复使用循环过程中保持粘合。以油墨制剂的干重计,该可逆变色油墨制剂包括约10-50%重量的聚合物粘合剂、约10-50%重量的増塑剂、约10-50%重量的润湿剂、约0-10%重量的离子稳定剂和约1-10%重量的阴离子指示剂化合物。该油墨的成分溶解在挥发性的有机溶剂中以应用到似布的无纺织物上。当完全变干时,该油墨不会浸出(leach)或从无纺抹布上脱离,并且能够可逆的改变颜色来指示无纺抹布中消毒剂的相对浓度。
无纺抹布浸渍有消毒剂,合适的一种消毒剂是基于季铵化合物。无纺抹布可以是已经浸渍有消毒剂。另外,无纺抹布也可不具有消毒剂,而可以由使用者来浸渍消毒剂。在优选的实施例中,基于无纺抹布的干重,无纺抹布中的季铵化合物的所需最小浓度(其能引起变色)在180ppm-250ppm的范围内。如下所述,无纺抹布浸渍有更高量的季铵化合物。当在使用过程中季铵化合物的浓度下降到限定值之下时,产生颜色改变指示需要再次补充。季铵化合物经常被提供于水溶液中,并且其能通过将无纺抹布浸泡在包含消毒剂溶液的桶中而得到应用。
通过在使用中可逆地改变颜色,由于消毒剂的消耗,该无纺抹布在使用中能可靠地指示何时需要进行补充。通过维持适当的消毒杀菌剂浓度,该无纺抹布能被用于所需要完成的手边的工作,或者直到抹布被损坏或严重弄脏。
鉴于上述内容,本发明的特征和优点在于提供了具有可逆的变色消毒指示剂的无纺抹布,该无纺抹布能被再次补充并使用多次,同时提供对消毒剂浓度的可靠的指示。
本发明的还具有的特征和优点在于提供了具有延长的使用寿命的无纺抹布,由于具有持久耐用的指示剂,该指示剂重复并可逆地指示无纺抹布中的消毒剂浓度的变化。
附图说明
图1为根据本发明的无纺抹布的透视图。
具体实施方式
参考图1,本发明的可逆变色指示消毒的无纺抹布8包括似布无纺织物10,该似布无纺织物10包括多块无纺纤维12。该无纺纤维12包括有吸收性的无纺纤维14和可选择性地包括有吸收性或无吸收性的强化无纺纤维16。吸收性无纺纤维14可由纤维素或另外的合适的吸收性材料制成。合适的纤维素纤维包括但不限于由木材、棉花、丝、稻草、干草和其他植物制成的纤维。人造丝纤维特别地适合于吸收性无纺纤维14。人造丝纤维是由棉绒、木片或其他纤维素通过用苛性钠和二硫化碳对其进行处理,并将所产生的粘胶溶液通过喷丝头而制成的纺织细丝。
当使用时,强化无纺纤维16可由任何结实的、弹性的聚合材料制成。合适的聚合材料包括但不限于聚酯、聚丙烯、高密度聚乙烯、线性低密度聚乙烯、聚酰胺、聚四氟乙烯和它们的组合。似布无纺织物10,特别是无纺纤维12,可包括约50-100%重量的吸收性无纺纤维14和约0-50%重量的强化无纺纤维16,合适地是约55-90%重量的吸收性无纺纤维14和约10-45%重量的强化纤维16,或者约60-80%重量的吸收性无纺纤维和约20-40%重量的强化无纺纤维16。
根据本发明,似布无纺织物10被涂有对无纺抹布8中的季铵化合物的浓度敏感的可逆变色油墨制剂。以干重计,变色油墨制剂包括约10-50%重量的聚合物粘合剂,合适的是约20-45%的重量,或约30-40%的重量。聚合物粘合剂有助于将织物10的无纺纤维12粘合在一起,并且还形成无纺织物10和变色油墨制剂剩余的成分之间的持久粘合。相对高的量和粘合强度的聚合物粘合剂有助于确保油墨制剂的可逆变色成分将对无纺抹布8使用寿命保持完整并有效。
合适的聚合物粘合剂化合物包括但不限于醋酸纤维素和醋酸纤维素衍生物。一种合适的聚合物粘合剂是由Aldrich Chemical公司出售的具有平均分子量数目约为3000的醋酸纤维素。其他合适的聚合物粘合剂为由EastmanChemical公司出售的在商品名分别为CAB 551-0.01,CAB 553-0.4和CAB551-0.2下的具有平均分子量数目约为16000、20000和30000的乙酸丁酸纤维素(cellulose acetate butyrates)。其他合适的聚合物粘合剂包括但不限于醋酸丙酸纤维素、羧甲基纤维素的聚合物、硝化纤维素的聚合物和它们的组合。
可逆变色油墨制剂也包括以干重计的约10-50%重量的增塑剂,合适地约为15-40%的重量或约20-30%的重量。増塑剂有助于保持施加了变色油墨制剂的无纺抹布8的弹性,即通过软化变色油墨制剂以不使无纺抹布8硬化。合适的增塑剂包括但不限于由Aldrich Chemical公司出售的酞酸二丁酯和柠檬酸三乙酯。其他合适的增塑剂包括但不限于双-(2-丁氧基乙基)己二酸酯、癸二酸二异辛酯、酞酸二乙酯和它们的组合。
可逆变色油墨制剂也包括以干重计约10-50%重量的润湿剂(wettingagent),合适地约为15-40%的重量或约20-35%的重量。该润湿剂引起变色油墨制剂扩散、覆盖并将织物10的无纺纤维12包封(到一定程度),使得变色油墨制剂和无纺织物10之间更加持久的粘合。合适的润湿剂包括但不限于由Aldrich Chemical公司出售的乙二醇和乙二醇单乙醚。其他合适的润湿剂包括但不限于三甘醇、山梨醇和它们的组合。
以油墨制剂的干重计,可逆变色油墨制剂可包括约0-5%重量的,合适地约为0-3%的重量的离子稳定剂。当使用时,离子稳定剂可为季铵化合物,并可与使用于消毒剂溶液中的季铵化合物的化学性质相似或相同,该消毒剂溶液较后渗透到无纺抹布8中去。当使用时,离子稳定剂的浓度不会大到阻止变色油墨响应于由无纺抹布中的消毒剂溶液产生的季铵化合物的浓度。合适的离子稳定剂包括但不限于二(长链烷基)二甲胺氯(di(long chain alkyl)dimethyl ammonium chlorides);N-甲基-N;N-二(长链链烷酰基乙基)-N-(2-羟甲基)甲基硫酸铵(N-methyl-N,N-bis(long chain alkanoyl oxyethyl)-N-(2-hydroxymethyl)ammonium methylsulfates);乙烯苯甲基二甲基椰油氯化铵(vinylbenzyl dimethylcocoammonium chlorides);辛基三甲基氯化铵(methyl trioctyl ammonium chlorides)。一种合适的离子稳定剂是可从斯蒂芬公司(Stepan Company)获得的这种产品是由约50%重量的N-烷基(60%C 14,30%C16,5%C12和5%C18)二甲基苄基氯化铵和约50%重量的N-烷基(68%C12和32%C14)氨苄氯乙酸甲酯(dimethyl ethyl benzyl ammonium chlorides)。
可逆变色油墨制剂包括以干重计的约1-10%重量的阴离子指示剂化合物,合适地为约1.5-7%的重量或2-4%的重量。阴离子指示剂的量相对少于聚合物粘合剂的量,因此确保持久的、永久的粘合到无纺织物10上。当消毒剂溶液中季铵化合物的量在任一方向上超过预定水平时,阴离子指示剂可逆地改变颜色。在无纺抹布的使用过程中,当无纺抹布中的季铵化合物的浓度下降到选定水平之下时,阴离子指示剂引起油墨从第一颜色变为第二颜色。随后,当无纺抹布被再次补充基于季铵化合物的消毒剂时,阴离子指示剂使得油墨从第二颜色变回第一颜色。
所使用的阴离子的具体类型取决于引起颜色改变的阴离子指示剂的所需的界限浓度。不同的阴离子指示剂引发不同浓度的季铵化合物的颜色改变。如果希望在季铵化合物的两种或者更多不同的浓度上指示两种或更多的颜色改变,也可以使用多种阴离子指示剂。阴离子指示剂可包括但不限于一种或多种选自溴百里酚蓝、百里酚蓝、甲酚紫(m-cresol purple)、二甲酚蓝、二甲酚橙、酚红及其组合的化合物。
可逆变色油墨制剂也可包括约1-25%的重量,合适地约为10-20%重量的无机填料颗粒。已经发现所包含的填料有助于改善颜色改变的强度,以便使颜色改变变得更加明显和显著。合适的颗粒填料包括但不限于二氧化硅、二氧化钛、碳酸钙和它们的组合。一种特别合适的填料是可从W.R.Grace &Co.购得的在商品名C 803项下的无定形氧化硅(无定形二氧化硅(amorphous silicon dioxide))。
油墨成分能在挥发性有机溶剂中混合在一起,该挥发性有机溶剂占以油墨成分和溶剂相加的重量计的总的油墨成分15-50%的重量。合适的溶解油墨成分的挥发性有机溶剂包括但不限于醋酸正丙酯(n-propyl acetate)和挥发性酮,如丙酮、丁酮、甲苯、四氢呋喃、乙酸乙酯和它们的组合。变色油墨溶液能通过浸泡、滴注、浸入、喷涂、刷涂布、辊式涂布、印刷或任何合适的技术被应用到无纺织物10上。涂布的无纺织物10随后能在具有热量和/或真空存在的情况下被干燥以去除挥发性有机溶剂,从而让变色油墨组分牢固地粘合到无纺织物10上。约40℃-60℃的干燥温度通常足够了。干燥时间可在几分钟到几小时的范围内,这取决于无纺织物10的特定的组分、结构和基重,以及取决于变色油墨组合物的特定的组分。
干燥之后,可逆变色油墨组合物组成无纺抹布8约1.0-10%的重量,适当地约为3-5%的重量。这些重量是基于在无纺抹布8被充满基于季铵化合物的消毒剂溶液之前干的无纺抹布8的重量。
在使用中,通常将无纺抹布8浸泡或浸入含有消毒剂溶液(通常用水稀释)的清洁桶中,使得无纺抹布8充满基于季铵化合物的消毒剂溶液。提供的无纺抹布8也可以为已经包含基于季铵化合物的消毒剂溶液的预充满的抹布。一种合适的基于季铵化合物的消毒剂是上述的2125M-P40,可以从斯蒂芬公司(Stepan Company)购得。再者,这种产品是约50%重量的N-烷基(60%C14,30%C16,5%C12和5%C 18)二甲基苄基氯化铵和约50%重量的N-烷基(68%C 12和32%C 14)二甲基乙基苄基氯化铵。这种产品可以是粉末形式。为了用作卫生洗涤剂溶液,粉末能被加入到一定量的水中得到具有约0.195-0.225%重量浓度的季铵化合物的水溶液。
如上所述,通过将无纺抹布8浸泡或浸入消毒剂溶液中,消毒剂水溶液被施加到无纺抹布8上。消毒剂溶液被无纺抹布8吸收的量取决于无纺抹布的结构特征、基重(basis weight)和吸收特性。如上所述,消毒剂溶液可包含约180-400ppm,合适地约为180-250ppm的季铵化合物。当完全饱和时,无纺抹布8通常将包含约150-350%重量的,合适地约为250-300%重量的以无纺抹布8干重计的消毒剂水溶液。如上所述,消毒剂溶液可包含约180-约400ppm,合适地约为180-约250ppm的季铵化合物。以无纺抹布8的干重计,无纺抹布8的自由季铵化合物的含量合适地为约300-1200ppm,或约500ppm-约1000ppm。术语“自由季铵化合物含量”是指消毒剂溶液贡献的季铵化合物的量,并且不包括任何包含在变色油墨组合物中作为离子稳定剂的季铵化合物。
为了确定无纺抹布中在使用时使得特定施加的油墨组合物从第一颜色变为第二颜色的自由季铵化合物的界限浓度,遵循下述步骤。首先,测定施加有油墨组合物的干的无纺抹布8的重量“D”。然后,无纺抹布8被浸渍消毒剂水溶液并称重,以确定完全饱和时的重量“C”。在完全饱和的无纺抹布中的季铵化合物的量“Q”通过将在清洁水溶液中的季铵化合物的重量比“R”乘以C和D之差,根据下述等式:Q=R(C-D)得出。
在无纺抹布8中的季铵化合物的完全饱和的浓度“P”(百万分之),以无纺抹布8的干重计,为(Q/D)X 106。
为了确定在使用中引发颜色改变的季铵化合物的界限浓度,简单地用无纺抹布8擦拭桌子或台面直到颜色开始从第一颜色变为第二颜色,并且再次称量无纺抹布8的重量以确定减少的重量“L”。界限浓度“T”(百万分之(in parts per million))能确定从下述等式确定:
通过遵循前述步骤,特定的无纺抹布8中的不同的油墨组合物能被测定,以开发出在所需的界限浓度T改变颜色的油墨组合物。在多数情况下,无纺抹布8所需的界限浓度T约为180-250ppm,合适地约为190-220ppm。当在无纺抹布8中的季铵化合物的浓度下降到限定值之下时,无纺抹布8对消毒的应用变得不太有效,并且对无纺抹布8再次补充消毒剂溶液变得很重要。
一旦特定的油墨组合物的界限浓度T已经被确定,可使用更加简单的步骤来确定不同油墨组合物的相对的灵敏性,即是否不同的油墨组合物将在季铵化合物的更高或更低值下将改变颜色。为了确定不同油墨组合物的相对的灵敏性,包含几种不同的浓度的季铵化合物的消毒剂溶液被准备在分别的桶或容器中。例如,可准备浓度在0ppm、50ppm、125ppm、250ppm、500ppm和1000ppm的含有季铵化合物的溶液。随后,每一种用不同的变色油墨组合物喷涂的无纺抹布被顺序地浸泡入消毒剂溶液,从最低浓度开始,以确定引发颜色改变的季铵化合物的浓度。而这种更简单的步骤能被用于确定是否一种油墨相对于另一种油墨在更高或更低季铵化合物含量下改变颜色,这将不会确定无纺抹布中的季铵化合物的界限浓度。
提供一种清洁表面的方法也包括在本发明的范围内。该方法包括提供一种无纺抹布的步骤,该无纺抹布包括无纺织物和粘合到无纺织物的可逆变色油墨制剂。提供消毒剂溶液,并且无纺抹布被浸渍消毒剂溶液。用无纺抹布擦拭表面直到变色油墨制剂从指示有充足的消毒剂溶液的第一颜色变为指示不充足的消毒剂溶液的第二颜色。无纺抹布随后浸渍额外的消毒剂溶液至少直到变色油墨制剂变回第一颜色。
实例
准备了下述可逆变色油墨组合物。
每种油墨组合物的组分混合直到醋酸纤维素完全溶解并且包含所有的组分。如果需要,更多溶剂可被加入以达到所需的粘度。每种油墨组合物被印刷在24英寸X24英寸(61厘米x61厘米)的由80%重量的人造丝和20%重量的聚酯纤维组成的无纺抹布的图案中。被喷涂的抹布在50℃的烤炉上干燥12小时,之后抹布在离子水中冲洗以去除任何过量油墨组分。之后每种被喷涂的抹布被放置在下述溶液中并且观察到下述颜色。
当首先放置在含水季铵化合物消毒剂中的抹布之后被放置到水中时其颜色反转,并且反之亦然。由于来自抹布的油墨的某些溶滤作用(leaching),在四个循环后仅观察到轻微的褪色。由持续的可逆变色可证明大部分油墨仍然持久地粘合。
然而在本发明中描述的实施例是示例性的,在不脱离本发明的精神和范围内可以做各种变型和改进。本发明的范围通过所附的权利要求表明,并且落入等同物的含义和范围内的所有变化将被包含在本发明中。
Claims (25)
1.一种可逆变色指示消毒剂无纺抹布,包括:
无纺织物;
使用聚合物粘合剂持久地粘合到所述无纺织物的可逆变色油墨制剂;以及
消毒剂成分,所述消毒剂成分包括游离季铵化合物并浸渍在所述无纺抹布中;
其中所述可逆变色油墨制剂使得无纺抹布在当所述无纺抹布中的所述游离季铵化合物超过阈值浓度时的第一颜色和当所述无纺抹布中的所述游离季铵化合物下降到阈值浓度之下时的第二颜色之间来回变化。
2.根据权利要求1所述的无纺抹布,以所述油墨制剂的干重计,其中所述可逆变色油墨制剂包括约10-50%重量的所述聚合物粘合剂、约10-50%重量的增塑剂、约10-50%重量的润湿剂和约1-10%重量的阴离子指示剂化合物。
3.根据权利要求1所述的无纺抹布,以所述无纺抹布的干重计,其中所述游离季铵化合物的阈值浓度为约180-250ppm。
4.根据权利要求1所述的无纺抹布,其中所述游离季铵化合物包括N-烷基二甲基苄基氯化铵。
5.根据权利要求1所述的无纺抹布,其中所述游离季铵化合物包括N-烷基二甲基乙基苄基氯化铵。
6.根据权利要求1所述的无纺抹布,其中所述阴离子指示剂包括化合物,该化合物选自溴百里酚蓝、百里酚蓝、间甲酚紫、二甲酚蓝、二甲酚橙、酚红和其组合物组成的组。
7.根据权利要求2所述的无纺抹布,其中所述变色油墨制剂包括约20-45%重量的所述聚合物粘合剂、约15-40%重量的所述增塑剂、约15-40%重量的所述润湿剂和约1.5-7%重量的所述阴离子指示剂化合物。
8.根据权利要求1所述的无纺抹布,其中所述无纺织物包括约50-100%重量的吸收性无纺纤维和约0-50%重量的强化无纺纤维。
9.根据权利要求8所述的无纺抹布,其中所述吸收性纤维包括纤维素纤维。
10.根据权利要求1所述的无纺抹布,其中所述聚合物粘合剂包括聚合物,该聚合物选自醋酸纤维素、醋酸纤维素衍生物、羧甲基纤维素、乙基纤维素、硝化纤维和其组合物组成的组。
11.根据权利要求2所述的无纺抹布,其中所述增塑剂包括化合物,该化合物选自酞酸二丁酯、柠檬酸三乙酯、己二酸双(2-丁氧基乙)酯、癸二酸二异辛酯、酞酸二乙酯和其组合物组成的组。
12.根据权利要求2所述的无纺抹布,其中所述润湿剂包括化合物,该化合物选自乙二醇、乙二醇单乙醚、三甘醇、山梨醇和其组合物组成的组。
13.根据权利要求2所述的无纺抹布,其中所述阴离子指示剂包括化合物,该化合物选自溴百里酚蓝、百里酚蓝、间甲酚紫、二甲酚蓝、二甲酚橙、酚红和其组合物组成的组。
14.一种制造具有可逆变色性能的物品的方法,包括以下步骤:
提供由挠性的聚合材料制成的织物;
将包括可逆变色油墨制剂和溶剂的溶液应用到所述织物;
将所述织物上的溶液干燥以去除所述溶剂;以及
将所述可逆变色油墨制剂持久地粘合到所述织物;
其中所述可逆变色油墨制剂包括聚合物粘合剂、增塑剂、润湿剂和阴离子指示剂化合物,并且所述干燥使得所述可逆变色油墨制剂持久地粘合到所述织物。
15.根据权利要求14所述的方法,还包括加热所述织物以完成所述干燥的步骤。
16.根据权利要求15所述的方法,其中所述织物被加热到约40℃到约60℃的温度。
17.根据权利要求14所述的方法,还包括将真空应用到所述织物的步骤。
18.根据权利要求14所述的方法,以所述可逆变色油墨制剂的干重计,其中所述可逆变色油墨制剂包括约10-50%重量的所述聚合物粘合剂、约10-50%重量的所述增塑剂、约10-50%重量的所述润湿剂和约1-10%重量的所述阴离子指示剂化合物。
19.根据权利要求14所述的方法,其中所述溶液包括约15-50%重量的所述可逆变色油墨制剂。
20.根据权利要求14所述的方法,其中所述溶剂选自醋酸正丙酯、丙酮、丁酮、甲苯、四氢呋喃、乙酸乙酯和其组合物组成的组。
21.根据权利要求14所述的方法,其中所述聚合物粘合剂包括聚合物,该聚合物选自醋酸纤维素、醋酸纤维素衍生物、羧甲基纤维素、乙基纤维素、硝化纤维和其组合物组成的组。
22.根据权利要求14所述的方法,其中所述增塑剂包括化合物,该化合物选自酞酸二丁酯、柠檬酸三乙酯、己二酸双(2-丁氧基乙)酯、癸二酸二异辛酯、酞酸二乙酯和其组合物组成的组。
23.根据权利要求14所述的方法,其中所述润湿剂包括化合物,该化合物选自乙二醇、乙二醇单乙醚、三甘醇、山梨醇和其组合物组成的组。
24.根据权利要求14所述的方法,其中所述阴离子指示剂包括化合物,该化合物选自溴百里酚蓝、百里酚蓝、间甲酚紫、二甲酚蓝、二甲酚橙、酚红和其组合物组成的组。
25.根据权利要求14所述的方法,其中所述挠性的聚合材料选自聚酯、聚丙烯、高密度聚乙烯、线性低密度聚乙烯、聚酰胺、聚四氟乙烯和其组合物组成的组。
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- 2010-03-04 WO PCT/US2010/026172 patent/WO2010117520A2/en active Application Filing
- 2010-03-04 EP EP15171687.5A patent/EP2952626A1/en not_active Withdrawn
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US20140255597A1 (en) | 2014-09-11 |
CN102414363B (zh) | 2015-03-18 |
US8772186B2 (en) | 2014-07-08 |
WO2010117520A3 (en) | 2011-01-27 |
US20130104325A1 (en) | 2013-05-02 |
US8772184B2 (en) | 2014-07-08 |
EP2952626A1 (en) | 2015-12-09 |
EP2414579A2 (en) | 2012-02-08 |
CN102414363A (zh) | 2012-04-11 |
CA2756044C (en) | 2013-11-26 |
US20100247371A1 (en) | 2010-09-30 |
CN104674566B (zh) | 2020-02-07 |
EP3150760A1 (en) | 2017-04-05 |
EP2414579B1 (en) | 2016-09-14 |
US9861245B2 (en) | 2018-01-09 |
MX2011010455A (es) | 2012-03-26 |
EP3150760B1 (en) | 2021-05-05 |
CA2756044A1 (en) | 2010-10-14 |
WO2010117520A2 (en) | 2010-10-14 |
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