CN104672857A - 低光泽抗静电耐候pc材料及其制备方法 - Google Patents

低光泽抗静电耐候pc材料及其制备方法 Download PDF

Info

Publication number
CN104672857A
CN104672857A CN201310630772.9A CN201310630772A CN104672857A CN 104672857 A CN104672857 A CN 104672857A CN 201310630772 A CN201310630772 A CN 201310630772A CN 104672857 A CN104672857 A CN 104672857A
Authority
CN
China
Prior art keywords
antistatic
low gloss
weather resistant
antistatic weather
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310630772.9A
Other languages
English (en)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Jiayiyang Industry and Trade Co Ltd
Original Assignee
Qingdao Jiayiyang Industry and Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Jiayiyang Industry and Trade Co Ltd filed Critical Qingdao Jiayiyang Industry and Trade Co Ltd
Priority to CN201310630772.9A priority Critical patent/CN104672857A/zh
Publication of CN104672857A publication Critical patent/CN104672857A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种低光泽抗静电耐候PC材料及其制备方法。本发明的低光泽抗静电耐候PC材料，其组分按质量百分数配比为：PC树脂80%～90%、消光剂4%～8%、抗静电剂1%～3%、光稳定剂1%～3%、抗氧剂0.1%～1%、润滑剂0.1%～1%。本发明的有益效果是，与现有技术相比，本发明制得的PC材料，不仅具有低光泽、外观哑光效果佳，而且还具有优良的抗静电性能和耐候抗老化性能，其制品表面电阻可达108～1010Ω，并且在保持PC原有物理、机械、电性能同时提高其强度、韧性和耐热性能，在汽车、电器件外壳、运动器械、医疗、包装、家庭用品等方面的应用具有很好的前景。

Description

低光泽抗静电耐候PC材料及其制备方法
技术领域
本发明涉及高分子材料技术领域，具体地说是一种低光泽抗静电耐候PC材料及其制备方法。
背景技术
聚碳酸酯（PC）作为综合性能优异、用途极为广泛的重要工程塑料品种，广泛用于汽车、电子电气、建筑材料、机械零件、办公自动化设备、包装业、运动器械、医疗、保健、光盘和家庭用品等领域。但PC在生产、贮存和使用中，极易产生静电积累而造成静电吸尘、静电放电等不良现象，严重时可产生火花，引起火灾或爆炸等；同时由于受内外因素的综合作用，PC性能也将逐渐变坏、老化；在PC的一些应用场合也常常要求其制品外观具有低光泽，如汽车塑料内饰件等。因此，根据需要对PC进行低光泽、抗静电、耐候等方面的改性是非常必要的，以改善其性能和扩大应用场合。
发明内容
本发明的目的在于提供一种低光泽抗静电耐候PC材料及其制备方法。
本发明解决其技术问题所采用的技术方案是：低光泽抗静电耐候PC材料，其组分按质量百分数配比为：PC树脂80%～90%、消光剂4%～8%、抗静电剂1%～3%、光稳定剂1%～3%、抗氧剂0.1%～1%、润滑剂0.1%～1%。
所述的PC树脂为双酚A型芳香族聚碳酸酯，重均分子量为20000～40000g/mol。
所述的消光剂为纳米消光剂PC-500，是由纳米氧化铝、氧化镁、氧化钙、三氧化二铁四种原料组成和表面活化的混合物，其兼有消光、增强、增韧作用。
所述的抗静电剂为磺酸盐类阴离子表面活性剂与非离子表面活性剂相复配的抗静电剂HKD-912。
所述的光稳定剂为质量比1：1的受阻胺光稳定剂HS-944和HS-622的复配物。
所述的抗氧剂为质量比1：2的受阻酚类抗氧剂1076与亚磷酸酯类抗氧剂168的复配物。
所述的润滑剂为季戊四醇硬脂酸酯（PETS）。
上述的一种低光泽抗静电耐候PC材料的制备方法为：按重量配比称取各组分，并分别加入高速混合中一起搅拌5～30分钟，使充分混合和均匀分散后，出料加入双螺杆挤出机中，在230℃～260℃下经熔融混炼挤出、冷却造粒，即得成品。
本发明的有益效果是，与现有技术相比，本发明制得的PC材料，不仅具有低光泽、外观哑光效果佳，而且还具有优良的抗静电性能和耐候抗老化性能，其制品表面电阻可达108～1010Ω，并且在保持PC原有物理、机械、电性能同时提高其强度、韧性和耐热性能，在汽车、电器件外壳、运动器械、医疗、包装、家庭用品等方面的应用具有很好的前景。
具体实施方式
下面结合具体实施例来进一步说明本发明的技术方案。
实施例1：
一种低光泽抗静电耐候PC材料，其组分按质量百分数配比为：PC树脂90%、消光剂5%、磺酸盐类阴离子表面活性剂与非离子表面活性剂相复配的抗静电剂HKD-912 2%、质量比1：1的受阻胺光稳定剂HS-944和HS-622的复配物2%、质量比1：2的受阻酚类抗氧剂1076与亚磷酸酯类抗氧剂168的复配物0.3%、季戊四醇硬脂酸酯（PETS）0.7%。其中，所述的PC树脂为双酚A型芳香族聚碳酸酯，重均分子量为20000～40000g/mol；所述的消光剂为纳米消光剂PC-500，是由纳米氧化铝、氧化镁、氧化钙、三氧化二铁四种原料组成和表面活化的混合物，其兼有消光、增强、增韧作用。
制备方法：按重量配比称取各组分，并分别加入高速混合中一起搅拌5～30分钟，使充分混合和均匀分散后，出料加入双螺杆挤出机中，在230℃～260℃下经熔融混炼挤出、冷却造粒，即得成品。
实施例2：
一种低光泽抗静电耐候PC材料，其组分按质量百分数配比为：PC树脂85%、消光剂8%、磺酸盐类阴离子表面活性剂与非离子表面活性剂相复配的抗静电剂HKD-912 3%、质量比1：1的受阻胺光稳定剂HS-944和HS-622的复配物2.5%、质量比1：2的受阻酚类抗氧剂1076与亚磷酸酯类抗氧剂168的复配物0.3%、季戊四醇硬脂酸酯（PETS）1.2%。其中，所述的PC树脂为双酚A型芳香族聚碳酸酯，重均分子量为20000～40000g/mol；所述的消光剂为纳米消光剂PC-500，是由纳米氧化铝、氧化镁、氧化钙、三氧化二铁四种原料组成和表面活化的混合物，其兼有消光、增强、增韧作用。
制备方法：按重量配比称取各组分，并分别加入高速混合中一起搅拌5～30分钟，使充分混合和均匀分散后，出料加入双螺杆挤出机中，在230℃～260℃下经熔融混炼挤出、冷却造粒，即得成品。

Claims (7)

1.一种低光泽抗静电耐候PC材料，其特征在于，其组分按质量百分数配比为：PC树脂80%～90%、消光剂4%～8%、抗静电剂1%～3%、光稳定剂1%～3%、抗氧剂0.1%～1%、润滑剂0.1%～1%。
2.根据权利要求1所述的低光泽抗静电耐候PC材料，其特征在于，所述的消光剂为纳米消光剂PC-500，是由纳米氧化铝、氧化镁、氧化钙、三氧化二铁四种原料组成和表面活化的混合物。
3.根据权利要求1所述的低光泽抗静电耐候PC材料，其特征在于，所述的抗静电剂为磺酸盐类阴离子表面活性剂与非离子表面活性剂相复配的抗静电剂HKD-912。
4.根据权利要求1所述的低光泽抗静电耐候PC材料，其特征在于，所述的光稳定剂为质量比1：1的受阻胺光稳定剂HS-944和HS-622的复配物。
5.根据权利要求1所述的低光泽抗静电耐候PC材料，其特征在于，所述的抗氧剂为质量比1：2的受阻酚类抗氧剂1076与亚磷酸酯类抗氧剂168的复配物。
6.根据权利要求1所述的低光泽抗静电耐候PC材料，其特征在于，所述的润滑剂为季戊四醇硬脂酸酯（PETS）。
7.根据权利要求1所述的低光泽抗静电耐候PC材料的制备方法，其特征在于，包括以下步骤：按重量配比称取各组分，并分别加入高速混合中一起搅拌5～30分钟，使充分混合和均匀分散后，出料加入双螺杆挤出机中，在230℃～260℃下经熔融混炼挤出、冷却造粒，即得成品。
CN201310630772.9A 2013-12-02 2013-12-02 低光泽抗静电耐候pc材料及其制备方法 Pending CN104672857A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310630772.9A CN104672857A (zh) 2013-12-02 2013-12-02 低光泽抗静电耐候pc材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310630772.9A CN104672857A (zh) 2013-12-02 2013-12-02 低光泽抗静电耐候pc材料及其制备方法

Publications (1)

Publication Number Publication Date
CN104672857A true CN104672857A (zh) 2015-06-03

Family

ID=53308470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310630772.9A Pending CN104672857A (zh) 2013-12-02 2013-12-02 低光泽抗静电耐候pc材料及其制备方法

Country Status (1)

Country Link
CN (1) CN104672857A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111732878A (zh) * 2020-06-16 2020-10-02 苏州特普乐新材料有限公司 一种防静电液及其配制方法
CN112111139A (zh) * 2020-08-31 2020-12-22 太仓市华鼎塑料有限公司 一种低光泽pc材料及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111732878A (zh) * 2020-06-16 2020-10-02 苏州特普乐新材料有限公司 一种防静电液及其配制方法
CN112111139A (zh) * 2020-08-31 2020-12-22 太仓市华鼎塑料有限公司 一种低光泽pc材料及其制备方法

Similar Documents

Publication Publication Date Title
CN104629338A (zh) 永久抗静电的pc/abs改性合金及其制备方法
CN104672857A (zh) 低光泽抗静电耐候pc材料及其制备方法
CN104845144A (zh) 一种填充改性pet/ptt/tpee复合材料
CN104710737A (zh) 一种无机粒子增强pc/pet合金及其制备方法
CN104845111A (zh) 一种增韧聚对苯二甲酸乙二醇酯合金材料
CN104845121A (zh) 玻纤增强pet/ptt/tpee复合材料
CN104861528A (zh) 一种ptt/petg复合材料及其制备方法
CN104419160A (zh) 永久抗静电的阻燃改性pc复合材料
CN104725815A (zh) 一种耐候抗静电pc薄膜材料及其制备方法
CN104419179A (zh) 无机粒子增强pc复合材料及其制备方法
CN104419162A (zh) 一种耐磨擦抗静电阻燃pc薄膜材料
CN104419186A (zh) 低光泽抗冲耐候pc复合材料
CN104672858A (zh) 低光泽耐候抗划伤改性pc复合材料
CN104845193A (zh) 一种阻燃pet/ptt/纳米二氧化钛复合材料
CN104845098A (zh) 抗静电pet/ptt/tpee复合纤维及其制备方法
CN104693746A (zh) 一种矿物增强的pc/pbt改性合金及其制备方法
CN104693724A (zh) 一种耐老化性能优良的pc/pet合金
CN105385129A (zh) 高韧改性材料
CN104650562A (zh) 无卤阻燃改性pc/pbt合金及其制备方法
CN104672870A (zh) 一种高抗冲增强阻燃耐老化pc和pet共混合金
CN104845277A (zh) 一种pet/ptt/无机填料的复合材料
CN104845284A (zh) 一种改性pet/ptt/petg复合材料
CN104845089A (zh) 一种以ptt改性pet的合金材料
CN104845274A (zh) 一种pet/ptt/纳米二氧化钛复合材料
CN104845181A (zh) 一种抗静电改性pet/ptt/petg复合材料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150603