CN104672017B - A kind of selenium-rich zoology foliage bacterial fertilizer - Google Patents

A kind of selenium-rich zoology foliage bacterial fertilizer Download PDF

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Publication number
CN104672017B
CN104672017B CN201510090675.4A CN201510090675A CN104672017B CN 104672017 B CN104672017 B CN 104672017B CN 201510090675 A CN201510090675 A CN 201510090675A CN 104672017 B CN104672017 B CN 104672017B
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parts
selenium
fertilizer
rich
rich zoology
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CN104672017A (en
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宋宇
安霞光
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Henan Agricultural University
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Henan Agricultural University
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

A kind of selenium-rich zoology foliage bacterial fertilizer, belongs to technical field of fertilizers, is made up of each raw material of following weight parts:2.8~3 parts of 1~1.5 part of sodium selenite, 65~75 parts of potassium dihydrogen phosphate, 8~10 parts of boric acid, 5~10 parts of turf, 5~10 parts of humic acid, 0.2~0.4 part of compound sodium nitrophenolate, 3~3.5 parts of mepiquat chloride, 10~15 parts of active bacteria and kaolin.The selenium-rich zoology foliar fertilizer of the present invention, effect of increasing production and Resistant are than solely good product effect containing selenium, its advantage be with efficient fixed nitrogen, phosphorus decomposing, potassium decomposing, it is photosynthetic, growth isoreactivity microorganism outside, also containing abundant organic matter and constant, trace element, the needs for there are enough organic matters to provide crop growth can be ensured, simultaneously, improved soil, improve crop quality, reduce chemical fertilizer, the pollution of agricultural chemicals uses, it is to realize " ecological agriculture ", function agricultural, the preferable selenium-rich zoology foliar fertilizer of developing ecology function agricultural product.

Description

A kind of selenium-rich zoology foliage bacterial fertilizer
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of selenium-rich zoology foliage bacterial fertilizer.
Background technology
Foliar fertilizer is the fertilizer that nutrient needed for crop is directly applied to blade face for the purpose of Foliage Absorption, referred to as foliar fertilizer. Foliar fertilizer is that nutrient is applied to crops blade surface, and a kind of fertilizer class of its function is played by the absorption of blade Type, the blade of plant have two layers of epidermis up and down, are made up of epidermal cell, there is cuticula and wax on table on the outside of cell, can be with Protect the mesophyll cell under epidermal tissue to exercise the functions such as photosynthetic, breathing, do not influenceed by the change of extraneous unfavorable conditions, blade table Now there are many small stomatas, exercise the function that gas is changed.Research shows, cuticula is by a kind of with hydroxyl and carboxyl Long carbon chain fatty acid polymer forms, and the hydroxyl, carboxylated hydrophilic group on the molecular gap and molecule of this polymer can allow The aqueous solution is penetrated into leaf, and certainly, the stomata of blade surface is that foliar fertilizer enters blade more easily passage.It is generally divided into four Class:Nutritious type leaf leaven, adjustment type foliar fertilizer, bion foliar fertilizer and composite foliage fertilizer.
The content of the invention
It is an object of the invention to provide a kind of selenium-rich zoology foliage bacterial fertilizer.
Based on above-mentioned purpose, this invention takes following technical scheme:
A kind of selenium-rich zoology foliage bacterial fertilizer, it is made up of each raw material of following weight parts:1~1.5 part of sodium selenite, di(2-ethylhexyl)phosphate 65~75 parts of hydrogen potassium, 8~10 parts of boric acid, 5~10 parts of turf, 5~10 parts of humic acid, 0.2~0.4 part of compound sodium nitrophenolate, mepiquat chloride 3 2.8~3 parts of~3.5 parts, 10~15 parts of active bacteria and kaolin.
Further, it is made up of each raw material of following weight parts:1 part of sodium selenite, 65 parts of potassium dihydrogen phosphate, 8 parts of boric acid, 5 parts of turf, 5 parts of humic acid, 0.2 part of compound sodium nitrophenolate, 3 parts of mepiquat chloride, 10 parts of active bacteria, 2.8 parts of kaolin.
Described active bacteria is black brill bacterium(Purchased from Beijing China of Air China Ben Nong developments in agricultural science and technology Co., Ltd).
The preparation method of above-mentioned selenium-rich zoology foliage bacterial fertilizer:Above-mentioned each raw material is weighed in proportion, by sodium selenite, di(2-ethylhexyl)phosphate Hydrogen potassium, compound sodium nitrophenolate, mepiquat chloride and kaolin are added in boric acid, are well mixed, are obtained mixture 1;By turf, humic acid both Organic matter and black brill bacterium mix with said mixture 1 again after mixing.
, can for crop by the inertia nitrogen transformation in air using the vital movement of microorganism after black brill bacterial manure is manured into soil The ionic state nitrogen directly absorbed, the inorganic matter of indissoluble in soil is become into soluble inorganic matter, increased effective in soil Nitrogen, phosphorus, potassium content;The material that crop can not directly utilize from soil changes into the material that can be absorbed and used, manufacture and Assist crops to absorb nutrition, improve crop nutritional condition, suppress the activity of pathogen, so as to reduce high anti-continuous cropping, dead seedling The generation of rotten, enhancing crop is waterlogging-resistant, drought-resistant ability;The activity of a large amount of microorganisms makes Organic Matter Transformation form corruption in soil Matter is grown, promotes the formation of soil granular structure, increases soil fertility, improves soil physical and chemical property, enhancing soil fertilizer, water conservation energy Power, so as to improve the yield and quality of crop.In a word, black brill bacterium can play fixed nitrogen, phosphorus decomposing, potassium decomposing, growth promotion and diseases prevention, resist The big effect of the three of disease, is finally embodied in volume increase, increases income, on synergy and improving quality.
In the present invention, sodium selenite, potassium dihydrogen phosphate and boric acid contain constant trace element, and turf, humic acid conduct have Machine matter, compound sodium nitrophenolate, mepiquat chloride as plant growth regulator, kaolin as auxiliary material, black brill bacterium and constant trace element, After organic matter and plant growth regulator mixing, microorganism is attracted in organic matter, and inorganic elements is blended in biological organic In matter, interaction, activation, so as to play synergy, interaction, the effect strengthened, these effects are individual element or single class fertilizer Composition is difficult to what is played.
The present invention by machinery blending and biological activity method made of selenium-rich zoology foliar fertilizer, its advantage be with Efficient fixed nitrogen, phosphorus decomposing, potassium decomposing, outside photosynthetic, growth isoreactivity microorganism, also containing abundant organic matter and constant, trace element, The needs for there are enough organic matters to provide crop growth can be ensured, meanwhile, improved soil, improve crop quality, reductionization The pollution of fertilizer, agricultural chemicals uses, and is to realize " ecological agriculture ", function agricultural, the preferable selenium-rich life of developing ecology function agricultural product State foliar fertilizer.
Brief description of the drawings
Fig. 1 is wheat Wintering Period spray clear water(It is left)With selenium-rich zoology foliage bacterial fertilizer(Right, every mu of 0.1kg)Root system contrasts;
Fig. 2 is wheat Wintering Period spray clear water(It is right)With selenium-rich zoology foliage bacterial fertilizer(Left, every mu of 0.1kg)It is withered to root system line Sick preventive effect contrast;
Fig. 3 boot stages are sprayed containing influence of the selenium to product wheat yield;
Fig. 4 pustulation periods spray influence of the product containing selenium to wheat yield;
Fig. 5 boot stages spray influence of the product containing selenium to wheat seed Se content;
Fig. 6 pustulation periods spray influence of the product containing selenium to wheat seed Se content.
Embodiment
Technical scheme is described in further detail below in conjunction with specific embodiment, but the protection of the present invention Scope is not limited thereto.
Embodiment 1
A kind of selenium-rich zoology foliage bacterial fertilizer, forms and is:Sodium selenite 1g, potassium dihydrogen phosphate 65g, boric acid 8g, turf 5g, corruption Phytic acid 5g, compound sodium nitrophenolate 0.2g, mepiquat chloride 3g, black brill bacterium 10g and kaolin 2.8g.
Embodiment 2
A kind of selenium-rich zoology foliage bacterial fertilizer, forms and is:Sodium selenite 1.5g, potassium dihydrogen phosphate 70g, boric acid 10g, turf 10g, humic acid 10g, compound sodium nitrophenolate 0.4g, mepiquat chloride 3.1g, black brill bacterium 12g and kaolin 3g.
Embodiment 3
A kind of selenium-rich zoology foliage bacterial fertilizer, forms and is:Sodium selenite 1.1g, potassium dihydrogen phosphate 75g, boric acid 9g, turf 9g, humic acid 9g, compound sodium nitrophenolate 0.4g, mepiquat chloride 3.5g, the black brill g of bacterium 15 and kaolin 3g.
The application method of this product, every mu of 100 grams of dosage, is watered 40kg(Or 40 times of dilution), in wheat jointing or/and Pustulation period sprays 1-2 times, mu volume increase 5-11%.
Fig. 1, Fig. 2 are that 2 months 2014 Mangshan Mountain area Du Zhuan and Yingyang City Guang Wu towns use the foliage bacterial fertilizer of embodiment 1 in wheat Wintering Period spray with do not spray growing way, disease resisting effect comparison diagram, as shown in figure 1, spraying selenium-rich foliage bacterial fertilizer and spraying clear Water is compared, and root long lengthens, and root amount increase, root hair increases, well developed root system;As shown in Fig. 2 the anti-root system of wheat using the present invention The positive effect enhancing of banded sclerotial blight.
Had the advantage that in addition, the wheat for spraying selenium-rich zoology foliage bacterial fertilizer also has:Drought resistance strengthens(Show after jointing Substantially);Wheat seed Se content brings up to Se-rich wheat standard(0.1-0.3ug/g);SOD activity improves in wheat leaf blade, MDA Content declines.
Test example 1
1.1 test procedure:
Experiment sets two processing altogether, and using matched-pair design, each pair repeats three times.
Processing 1:Experiment is carried out in Henan safety Seed company experimental plot, using the selenium-rich zoology foliage bacterial fertilizer of embodiment 1, Sprayed in wheat grain filling mid-term on wheat leaf blade, every mu of ground dosage is 100g, and 70 times of dilution sprays, 10 points of progress of the morning, nothing Wind fine day.Species test after wheat harvest on June 6, units increased in production is calculated, the results are shown in Table 1.
Processing 2:With processing 1 same period sprinkling equivalent clear water(Represented with CK).
The wheat grain filling mid-term of table 1 sprays and does not spray the influence to wheat yield
Volume increase:671.1 kilograms -604.4 kilograms=66.7 kilograms
1.2 conclusion
As seen from the above table, mu increases production 66.7 kilograms, yield increase by 11%.
Test example 2
In the experiment that Zhengzhou hair Pingzhuang experimental plots are carried out:
2.1 experiments are designed using randomized block experiment, and kind uses Henan wheat 70-36 solids system, sowing on October 10, October Final singling on the 25th.Experiment takes essence amount machine sowing to sow with a drill kind, line-spacing 23cm, plot area 15m2, it is repeated 3 times(Each processing repeats 3 Secondary sowing, the difference between detection repetition).Poured water in breeding time 2 times, May controlling disease 3 times, aphid 3 times.
Design 4 amount of application levels:Sodium selenite 105g.ha-1, sodium selenite 150g.ha-1, selenium-rich zoology foliar fertilizer 7500g.ha-1, Se-rich agent for promoting growth of crops 7500mL ha-1, for the ease of description, represented respectively with C1, C2, C3, C4, at 2 Phase:Boot stage(T1)And Early filling stage(T2), it is 1 time to spray number.Control group is clear water, is represented with CK, boot stage it is clear Water control represents that the clear water control of Early filling stage is represented with CK2 with CK1.Concentration(C)And period(T)Two factors.It is calm in fine day 16:After 00, uniformly sprayed, be repeated 3 times with 5 miniaturised nebulisers equipped with above-mentioned 5 concentration selenium, use the 1/3 of scheduled volume every time. To prevent spraying diffusion interference, each cell uses plastic sheeting high-wall enclosure during spray.By decoction 5v%HNO during spray3Adjust pH extremely 6.0, to strengthen absorptivity.
The measure of seed Se content:Using sepectrophotofluorometer, using 2,3- diaminonaphthalene methods(Send the Inner Mongol permanent green agriculture Industry new technology development research institute determines), as a result see Fig. 5, Fig. 6.
Determination of yield:Each cell gathers in 3m after wheat maturation2, manual threshing meter production(As a result Fig. 3, Fig. 4 are seen).
Test data analyzer method:Test data is using DPS network analysis softwares to analyzing and processing.
Influence of 2.2 selenium to wheat yield
As shown in Figure 3, Figure 4, C4 processing (Se-rich agent for promoting growth of crops 7500mL.ha-1) and C3 (selenium-rich zoology foliar fertilizers 7500g.ha-1) used in selenium concentration compare C2(Sodium selenite 150g.ha-1)Low, yield performance is but all higher than C2.Through statistical Analysis, reaches the level of signifiance with comparing, volume increase 5%~9.8%;T1 (boot stage) sprays to be shown than T2 (Early filling stage) effect of increasing production Write, show under this experimental condition, selenium can improve the yield of winter wheat.
The interpretation of result of 2.3 seed Se contents
From Fig. 5, Fig. 6, selenium significantly improves the Se content of wheat seed, and 4~9 times are improved with comparing.Through Variance analysis, spray selenium processing compare with clear water, reach the pole level of signifiance, between spray selenium processing, C2(Sodium selenite 150g.ha-1)With C3 (selenium-rich zoology fertilizer 7500g.ha-1) and C1 (sodium selenite 105g.ha-1) and C4 (Se-rich agent for promoting growth of crops 7500mL.ha-1) reach the level of signifiance;C2(Sodium selenite 150g.ha-1)With C3 (selenium-rich zoology fertilizer 7500g.ha-1) difference do not have Have and reach the level of signifiance.Show the selenium accumulated in wheat seed, be proportionate with applying selenium dosage outside, it may be possible to pustulation period photosynthetic production Thing concentrates the reason transported to reproductive organs.Spray on period, T2 (Early filling stage) sprays more favorably more with Accumulation in Grains Selenium.This experiment shows, C4 (Se-rich agent for promoting growth of crops 7500mL.ha-1) processing seed in Se content dramatically increase (be respectively 0.286 Mg/g and 0.275 mg/g), and meet national Se-rich wheat standard(GB13105-91).C1, C2 and C3 should reduce spray selenium Amount, to convert into pure selenium(Sodium selenite)90g.ha-1It is advisable.

Claims (2)

1. a kind of wheat selenium-rich zoology foliage bacterial fertilizer, it is characterised in that be made up of each raw material of following weight parts:Sodium selenite 1 ~1.5 parts, 65~75 parts of potassium dihydrogen phosphate, 8~10 parts of boric acid, 5~10 parts of turf, 5~10 parts of humic acid, compound sodium nitrophenolate 0.2 2.8~3 parts of~0.4 part, 3~3.5 parts of mepiquat chloride, black 10~15 parts of bacterium of brill and kaolin.
2. wheat selenium-rich zoology foliage bacterial fertilizer according to claim 1, it is characterised in that by each raw material of following weight parts Composition:1 part of sodium selenite, 65 parts of potassium dihydrogen phosphate, 8 parts of boric acid, 5 parts of turf, 5 parts of humic acid, 0.2 part of compound sodium nitrophenolate, casing coupling 3 parts of amine, black 10 parts of bacterium of brill, 2.8 parts of kaolin.
CN201510090675.4A 2015-02-28 2015-02-28 A kind of selenium-rich zoology foliage bacterial fertilizer Expired - Fee Related CN104672017B (en)

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CN105123203A (en) * 2015-08-20 2015-12-09 孙群 Method for planting spinach rich in selenium
CN105732190A (en) * 2016-01-20 2016-07-06 深圳市夸克生物科技有限公司 Agricultural high-efficiency polynary selenium-rich viable bacteria leaf fertilizer and production process
CN107778091A (en) * 2017-11-30 2018-03-09 广西正匠农业科技有限公司 A kind of vegetables dedicated liquid foliar fertilizer

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RS49786B (en) * 1997-12-11 2008-06-05 dr. Ivana Đujić Procedure of foliar feeding for obtaining plants with desired content and distribution of selenium
CN1318355C (en) * 2005-09-01 2007-05-30 宋家永<Del/> Selenium-enriched foliage fertilizer
CN102173927B (en) * 2011-01-10 2013-02-13 金盈 Nanometer selenium probiotics composite leaf surface nutrient solution and application thereof in production of selenium-enriched pears
CN102674948A (en) * 2012-03-27 2012-09-19 常熟市海虹苗木花卉有限公司 Special foliage fertilizer for selenium-enriched radishes
CN102617247B (en) * 2012-04-13 2013-12-11 常熟市平冶机械有限公司 Selenium-rich nutrient solution

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