CN104663675B - A kind of bactericidal composition containing mould spirit and fluopyram and application thereof - Google Patents
A kind of bactericidal composition containing mould spirit and fluopyram and application thereof Download PDFInfo
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- CN104663675B CN104663675B CN201510057884.9A CN201510057884A CN104663675B CN 104663675 B CN104663675 B CN 104663675B CN 201510057884 A CN201510057884 A CN 201510057884A CN 104663675 B CN104663675 B CN 104663675B
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- fluopyram
- mould spirit
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- bactericidal composition
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Abstract
The present invention relates to a kind of bactericidal composition containing mould spirit and fluopyram and application thereof.Described compositions contains mould spirit and fluopyram, and the weight ratio of described mould spirit and fluopyram is 1 40:1 35.Said composition can be applicable to prevent and treat industrial crops, Cereal or flowers and other crops disease control.Said composition is applied widely, effective, low cost, residual are low, safe for human, animal and environment.
Description
Technical field
The present invention relates to a kind of bactericidal composition and purposes, particularly relate to a kind of killing containing mould spirit and fluopyram
Bacteria composition and application thereof, is mainly used in the preventing and treating of industrial crops disease.
Background technology
Mould spirit (Hymexazol, CAS 10004-44-1) is the systemic fungicide of a kind of wide spectrum.Can directly be planted
Thing root absorption, enters in plant, mobile extremely rapid.Move in root system and within only 3 hours, just move to stem, 24 little time shifts
Move to plant whole body.This product mechanism of action is unique, efficiently, low toxicity, nuisanceless, can suppress the mycelial normal life of pathogenic fungi
Grow or directly kill pathogenic bacteria, plant growing can be promoted again.
Fluopyram (Fluopyram, CAS 658066-35-4) is pyridinylethylbenzamderivatives class disinfecting
Agent, a kind of broad spectrum type antibacterial.Mechanism of action is that the succinate dehydrogenase in the Complex II of mitochondrial respiratory chain is risen suppression
Effect, thus suppress the kind spore germination of target fungus, germ tube and mycelial growth.Tool Uptake and translocation so that it is old in protection
Plant tissue simultaneously, the blade newly grown out, flower and fruit are also had good protective effect.Transmit through xylem,
Speed is fast, the position of two days young sprouts of arriving;It can also transmit through phloem, is applied on blade and just can be passed to rapidly other
Position.In addition, moreover it is possible to active at plant surface, permeability is the strongest, it is possible to penetrates into and goes in the cell of plant, tool
Thin layer is had to penetrate activity.
Mould spirit is applied relatively broad at present, but due to life-time service, many places all occur in that resistance problem, cause using
Amount continues to increase, and residual risk increases, and is unfavorable for food safety.Seek scientific and rational agriculture chemical compounding, be to solve this problem
Preferably way.Fluopyram fungicidal spectrum is wide, excellent to control of crop disease, but with high costs, applies the most at home very
Few.
There are no at present mould spirit and the compounding relevant report of fluopyram both at home and abroad.If both can compound one
Rise, it becomes possible to preferably solve above-mentioned produced problem, compare single dose after the two is compounding simultaneously and there is synergistic function, improve
The effect that single dose is used alone.The most also there is no the relevant report that mould spirit and fluopyram compound at present.
Summary of the invention
An object of the present invention is to overcome above-mentioned deficiency, it is provided that one is applied widely, effective, consumption is low, one-tenth
This is the lowest, lasting period length, remain little and have potentiation containing mould spirit and the bactericidal composition of fluopyram.
The two of the purpose of the present invention are to provide a kind of bactericidal composition containing mould spirit and fluopyram for preventing
Control the purposes of industrial crops disease.
The object of the present invention is achieved like this:
A kind of containing mould spirit with the bactericidal composition of fluopyram, the activity contained by described compositions becomes to include
Mould spirit and fluopyram, the weight ratio of described mould spirit and fluopyram is 1-40:1-35.
The preferred weight ratio of described mould spirit and fluopyram is 3-5:20-30.
It is highly preferred that the weight ratio of the two is 1-12:1-10;
Most preferably, the weight ratio of the two is 1:1.
Described combination dosage form is any one dosage form allowed on pesticide.Such as wettable powder, water dispersible granules, outstanding
Floating agent, aqueous emulsion, cream or seed coat agent etc..
Described mould spirit and fluopyram percentage by weight in above-mentioned dosage form are 5~75%.
Further, the present invention provides a kind of bactericidal composition containing mould spirit and fluopyram as above
Purposes, by described Bactericidal composite for being used for control economic disease of pests evil;Preferably, described disease is: powdery mildew of strawberry, grey mold
Disease, anthrax, droop, peach tree shot hole, anthrax, brown rot, tomato late blight, early blight, gray mold, Citrullus vulgaris is climing withered
Disease, droop, anthrax, cucumber downy mildew, powdery mildew, gray mold, Camellia sinensis anthrax, gall of tea, bud blight, Fructus Vitis viniferae downy mildew
Disease, gray mold, white rot, anthrachose of grape, tobacco downy mildew, balck shank, damping off, pear scab, rust, ring spot, rot
Sick, melasma, scab of apple, brown spot, citrus anthracnose, foot rot, blossom-end rot, capsicum epidemic disease, leaf spot of peanut, vertical withered
Disease, sclerotinia rot of colza, the late blight of potato, cotton seedling blight, red rot, coffee rust, brown spot, mango anthracnose, white lead
Sick, blossom-end rot, sigatoka, scab, bunchy top, sheath maize ear rot, sclerotinia rot of colza, downy mildew etc..It is preferred for Sclerotina Sclerotiorum in Winter Rape
Core disease, pear scab, Fructus Mangifera Indicae blossom-end rot, apple marssonina leaf spot and the preventing and treating of Fructus Fragariae Ananssae droop.
Compared with prior art, the invention has the beneficial effects as follows:
(1) potentiation that the present composition is done well in certain ratio range, the bactericidal effect ratio of compositions
Single dose is obviously improved, and its co-toxicity coefficient is at least more than 120, reduces Pesticide use dosage and cost simultaneously, decreases
Residual, also mitigates the harmful effect to environment;
(2) in the present invention, the mechanism of action of two kinds of active component is different, and the application of compositions can delay or overcome cause of disease
The resistance of bacterium, extends the service life of product;
(3) present composition is excellent to industrial crops disease preventive effect, additionally, can also be used for the anti-of its corps diseases
Control.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, the present invention enters with following instantiation
Row explanation, but the present invention is not limited to these examples.
The present composition, with mould spirit and fluopyram as effective ingredient, finds through indoor bioassay test, two
After person is compounding, antagonistic drug sexually transmitted disease (STD) evil has obvious synergistic function, is specifically illustrated with following bioassay example.
The example 1 that measures in kind: mould spirit and the compounding toxicity test to oilseed rape downy mildew bacterium of fluopyram
1, subjects: oilseed rape downy mildew bacterium [Classification system: Peronospora parasitica (Pers.) Fr.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.3-2006 ", uses pastille culture medium
Method.
3, data statistic analysis: be analyzed with SAS 6.12 statistical software.Calculate mycelial growth according to test data to press down
Rate processed (%), obtains virulence regression equation formula, correlation coefficient (r), EC50And co-toxicity coefficient.
4, evaluation methodology: with reference to " pesticide bioassay test rule NY/T 1156.3-2006 ", according to Sun&Johnson
(1960) it is antagonism that co-toxicity coefficient method (CTC) evaluates the potentiation of pharmacy mix, i.e. CTC≤80,80 < CTC <
120 is summation action, and CTC >=120 are potentiation.
5, result and analysis
The toxicity test of Sclerotinia sclerotiorum is tied by the mixture combination of mould spirit, fluopyram and the two different proportion thereof
Fruit is shown in Table 1, in table 1 ": fluorine " it is writing a Chinese character in simplified form of " mould spirit: fluopyram ".
The mould spirit of table 1 and the fluopyram mixture toxicity test result to oilseed rape downy mildew bacterium
Indoor biometrics result shows: mould spirit and fluopyram are with 1: 15,1: 10,1: 5,1: 1,5: 1,10: 1 and 15:
1 ratio carries out mixture, and it all shows potentiation to oilseed rape downy mildew bacterium, wherein with 15: 1,1: 10,1: 5,1:1 and 5: 1
Ratio mixed synergies is the most obvious.Consider the preventing and treating to oilseed rape downy mildew of mould spirit and fluopyram with 1-5:1-15
Compounding preferable.
The example 2 that measures in kind: mould spirit and the compounding toxicity test to pear scab bacterium of fluopyram
1, subjects: pear scab bacterium [Classification system: (Venturia piritna Aderh),
(V.nashicola Tanak et Yamamota)Fusicladium plrinum(Lib)Fuck]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", uses pastille culture medium
Method.
3, data statistic analysis: be analyzed with SAS 6.12 statistical software.Calculate mycelial growth according to test data to press down
Rate processed (%), obtains virulence regression equation formula, correlation coefficient (r), EC50And co-toxicity coefficient.
4, evaluation methodology: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun&Johnson
(1960) it is antagonism that co-toxicity coefficient method (CTC) evaluates the potentiation of pharmacy mix, i.e. CTC≤80,80 < CTC <
120 is summation action, and CTC >=120 are potentiation.
5, result and analysis
The toxicity test of pear scab bacterium is tied by the mixture combination of mould spirit, fluopyram and the two different proportion thereof
Fruit is shown in Table 2, in table 2 ": fluorine " it is writing a Chinese character in simplified form of " mould spirit: fluopyram ".
The mould spirit of table 2 and the fluopyram mixture toxicity test result to pear scab bacterium
Indoor biometrics result shows: mould spirit and fluopyram are with 1: 20,1: 10,1: 5,1: 1,5: 1,10: 1 and 20:
1 ratio carries out mixture, and it all shows potentiation to pear scab bacterium, wherein with 1: 10,1: 5,1:1,5:1 and 10: 1
Ratio mixed synergies is the most obvious.Consider the preventing and treating to pear scab of mould spirit and fluopyram with 1-10:1-
10 is compounding preferable.
The example 3 that measures in kind: mould spirit and the compounding toxicity test to Fructus Mangifera Indicae blossom-end rot bacterium of fluopyram
1, subjects: Fructus Mangifera Indicae blossom-end rot bacterium [Classification system: Phomopsis mangiferae Ahmad]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", uses pastille culture medium
Method.
3, data statistic analysis: be analyzed with SAS 6.12 statistical software.Calculate mycelial growth according to test data to press down
Rate processed (%), obtains virulence regression equation formula, correlation coefficient (r), EC50And co-toxicity coefficient.
4, evaluation methodology: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun&Johnson
(1960) it is antagonism that co-toxicity coefficient method (CTC) evaluates the potentiation of pharmacy mix, i.e. CTC≤80,80 < CTC <
120 is summation action, and CTC >=120 are potentiation.
5, result and analysis
The toxicity test of Fructus Mangifera Indicae blossom-end rot bacterium is tied by the mixture combination of mould spirit, fluopyram and the two different proportion thereof
Fruit is shown in Table 3, in table 3 ": fluorine " it is writing a Chinese character in simplified form of " mould spirit: fluopyram ".
The mould spirit of table 3 and the fluopyram mixture toxicity test result to Fructus Mangifera Indicae blossom-end rot bacterium
Indoor biometrics result shows: mould spirit and fluopyram are with 1: 18,1: 12,1: 6,1: 1,6: 1,12: 1 and 18: 1
Ratio carries out mixture, and it shows potentiation to Fructus Mangifera Indicae blossom-end rot bacterium, wherein with 1: 12,1: 6, the ratio mixture of 1:1 and 6:1
Potentiation is the most obvious.Consider mould spirit compounding relatively with 1-6:1-12 to the preventing and treating of Fructus Mangifera Indicae blossom-end rot with fluopyram
Good.
The example 4 that measures in kind: mould spirit and the compounding toxicity test to marssonina coronaria of fluopyram
1, subjects: marssonina coronaria [Classification system: Marssonina coronaria (Ell.et Davis)
Davis,(Diplocarpon mali Harada et Sawamura)]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", uses pastille culture medium
Method.
3, data statistic analysis: be analyzed with SAS 6.12 statistical software.Calculate mycelial growth according to test data to press down
Rate processed (%), obtains virulence regression equation formula, correlation coefficient (r), EC50And co-toxicity coefficient.
4, evaluation methodology: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun&Johnson
(1960) it is antagonism that co-toxicity coefficient method (CTC) evaluates the potentiation of pharmacy mix, i.e. CTC≤80,80 < CTC <
120 is summation action, and CTC >=120 are potentiation.
5, result and analysis
The toxicity test of marssonina coronaria is tied by the mixture combination of mould spirit, fluopyram and the two different proportion thereof
Fruit is shown in Table 4, in table 4 ": fluorine " it is writing a Chinese character in simplified form of " mould spirit: fluopyram ".
The mould spirit of table 4 and the fluopyram mixture toxicity test result to marssonina coronaria
Indoor biometrics result shows: mould spirit and fluopyram are with 1: 9,1: 3,1: 3,1: 1,3: 1,6: 1 and 9: 1 ratios
Carrying out mixture, it shows potentiation to marssonina coronaria, wherein with the ratio mixture potentiation of 1: 3,1: 1,3:1 and 6: 1
Act on the most obvious.Consider mould spirit compounding preferably with 1-6:1-3 to the preventing and treating that apple marssonina leaf spot is sick with fluopyram.
The example 5 that measures in kind: mould spirit and the compounding toxicity test to Strawberry anthracnose bacterium of fluopyram
1, subjects: Strawberry anthracnose bacterium [Classification system: Colletotrichum fragariae Brooks]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.14-2008 ", uses pastille culture medium
Method.
3, data statistic analysis: be analyzed with SAS 6.12 statistical software.Calculate mycelial growth according to test data to press down
Rate processed (%), obtains virulence regression equation formula, correlation coefficient (r), EC50 and co-toxicity coefficient.
4, evaluation methodology: with reference to " pesticide bioassay test rule NY/T 1156.14-2008 ", according to Sun&
It is antagonism that the co-toxicity coefficient method (CTC) of Johnson (1960) evaluates the potentiation of pharmacy mix, i.e. CTC≤80,80
<CTC<120 is summation action, and CTC>=120 are potentiation.
5, result and analysis
The toxicity test of Strawberry anthracnose bacterium is tied by the mixture combination of mould spirit, fluopyram and the two different proportion thereof
Fruit is shown in Table 5, in table 5 ": fluorine " it is writing a Chinese character in simplified form of " mould spirit: fluopyram ".
The mould spirit of table 5 and the fluopyram mixture toxicity test result to Strawberry anthracnose bacterium
Indoor biometrics result shows: mould spirit is compared with 10: 1,1: 5,1: 3,1: 1,3: 1,5: 1 and 10: 1 with fluopyram
Example carries out mixture, and it shows potentiation to Strawberry anthracnose bacterium, wherein with the ratio of 1: 5,1: 3,1:1,3:1,5: 1 and 10:1
Example mixed synergies is the most obvious.Consider mould spirit multiple with 1-10:1-5 to the preventing and treating of Strawberry anthracnose with fluopyram
Join preferably.
The present composition can with known auxiliary agent and adjuvant, prepare in being suitable for agriculturally using by known method
Any one dosage form, the most reasonable dosage form has water dispersible granules, suspending agent, aqueous emulsion, cream or seed coat agent, and these are known
Auxiliary agent, adjuvant have dispersant, diffusant, defoamer, wetting agent, disintegrating agent, film former and filler etc..
Illustrate with instantiation below.
Embodiment 1:
Mould spirit 12g, fluopyram 3g, Ketohexamethylene 15g, soybean oil are added to 100g, and mixing, to homogeneous liquid phase, prepares
Cream.
Embodiment 2:
By mould spirit 20g, fluopyram 10g, NPE 8g, sodium lauryl sulphate 6g, aluminium silicate
Magnesium 1g, kieselguhr add to 100g, and blended, superfine grinding, pelletize prepare water dispersible granules.
Embodiment 3:
By mould spirit 5g, fluopyram 20g, polyoxyethylene carboxylate 5g, alkylphenol polyoxyethylene 6g, xanthan gum
0.5g, propylene glycol 2g, organosilicon 0.5g, add water to 100g, mixes through wet grinding, homogenizing, prepares suspending agent.
Embodiment 4:
By mould spirit 22g, fluopyram 10g, sodium lignin sulfonate 8g, sodium lauryl sulphate 5g, white carbon 10g,
Bentonite adds to 100g, and mixing prepares wettable powder through comminution by gas stream.
Embodiment 5:
By mould spirit 10g, fluopyram 15g, Oleum Terebinthinae 6g, NPE 10g, alkylphenol-polyethenoxy
Ether phosphate 1g, polyvinyl alcohol 2g, xanthan gum 0.1g, add water to 100g, prepare oil phase, prepare aqueous phase, under high shear, by oil
Add in oil phase in phase homogeneous aqueous phase or by aqueous phase, shear and prepare aqueous emulsion.
Embodiment 6:
By mould spirit 2.5g, fluopyram 2.5g, polyoxyethylene carboxylate 6g, NPE 5g, silicon
Acid magnalium 1g, polyvinyl alcohol 2g, organosilicon 0.5g, ethylene glycol 2g, basic rhodamine 0.5g, add water to 100g, and mixing is through wet method
Grind, homogenizing, prepare suspension seed-coating agent.
A kind of bactericidal composition containing mould spirit and fluopyram of the present invention is carried out by concrete example
Describing, those skilled in the art can use for reference present invention, and the link such as suitable feed change, process conditions realizes accordingly
Other purpose, its relevant change is all without departing from present disclosure, and all similar replacements and change are for art technology
It is apparent from for personnel, is considered as being included within the scope of the present invention.
Claims (3)
1. the application in preparation preventing and treating pear scab medicine of the bactericidal composition containing mould spirit and fluopyram,
It is characterized in that, the mass ratio of mould spirit and fluopyram is 1:10 or 1:5.
2. the application in preparation biocontrol of mango blossom-end rot medicine of the bactericidal composition containing mould spirit and fluopyram,
It is characterized in that, the mass ratio of mould spirit and fluopyram is 1:6.
Application the most according to claim 1 and 2, it is characterised in that described combination dosage form is wettable powder, water-dispersible
Granule, suspending agent, aqueous emulsion, cream or seed coat agent.
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Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1570738A1 (en) * | 2004-02-12 | 2005-09-07 | Bayer CropScience S.A. | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
EP2100506A2 (en) * | 2009-01-23 | 2009-09-16 | Bayer CropScience AG | Uses of fluopyram |
CN103004819A (en) * | 2012-11-30 | 2013-04-03 | 王学权 | Fluopicolide-containing bactericide composition |
CN103918677A (en) * | 2013-01-12 | 2014-07-16 | 王学权 | Thifluzamide-containing sterilization composition |
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