CN104630794A - Metal product cleaning and brightening agent - Google Patents
Metal product cleaning and brightening agent Download PDFInfo
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- CN104630794A CN104630794A CN201510073473.9A CN201510073473A CN104630794A CN 104630794 A CN104630794 A CN 104630794A CN 201510073473 A CN201510073473 A CN 201510073473A CN 104630794 A CN104630794 A CN 104630794A
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- water
- diatomite
- metal products
- thiocarbamide
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a metal product cleaning and brightening agent, belonging to the technical field of processing of cleaning products for daily use. The metal product cleaning and brightening agent is prepared from thiourea, oxalic acid, reduced glutathione, water soluble silicone oil, EM (effective microorganism) original liquid, diatomite, 1 to 2 lauric acid diethanolamide, and the like, and can be used for removing dirt, rust and black spots from metal products and restoring the original gloss and brightness.
Description
Technical field
The invention belongs to the processing technique field of daily cleaning washing composition, particularly relate to a kind of metal products cleaning and smoothing agent.
Background technology:
The daily necessities such as the steel pot in life, iron pan, copper basin, aluminium basin have been grown duration of service, and can be oxidized and produce rust staining, blackspot, dirt and lose original gloss, dark and gloomy dirty stain is indecency.A kind of metal products cleaning and smoothing agent of the application can solve the above problems.
Summary of the invention:
A kind of metal products cleaning and smoothing agent, thiocarbamide, oxalic acid, reduced glutathion, water-soluble silicon oil, EM original solution, diatomite, 1:2 type lauric acid diethyl amide etc. is adopted to be prepared from, the dirt of metal products can be eliminated, rust staining, blackspot, original gloss brightness can also be recovered.
The technical measures that the present invention takes:
A kind of metal products cleaning and smoothing agent, takes raw material by weight: thiocarbamide 1.5-4.5 part, oxalic acid 5-15 part, reduced glutathion 15-45 part, water-soluble silicon oil 8-25 part, EM original solution 20-60 part, diatomite 10-30 part, 1:2 type lauric acid diethyl amide 6-24 part, water 10-300 part.
Diatomite was dried be ground into again end stand-by, water is put into mixing vessel, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Compared with prior art, the present invention has following beneficial effect:
1, metal products cleaning and smoothing agent of the present invention adds reduced glutathion and beneficial microorganism EM original solution, the toxin of metal and the erosion of other organic substance and murder by poisoning can be removed, various smelly, peculiar smell can be decomposed, EM original solution has optimum circulation help to environmental and ecological, and EM original solution prevents corrosion from increasing the effect of gloss in addition.
2, add water-soluble silicon oil and thiocarbamide, can make the gloss that metal products recovers original, the diatomite of powdery cleans metal products, makes its surface more smooth careful glittering.
3, the convenient and simple practicality of product of the present invention, can decontamination dirt oil stain, de-black of derusting spot, metal products is not corroded, also there is corrosion-resisting function.The 1:2 type lauric acid diethyl amide particularly adopted has the good effects of decontamination dirt, rust protection, and product washing function is comprehensive.
Embodiment:
A kind of metal products cleaning and smoothing agent, it comprises: take raw material by weight: thiocarbamide 1.5-4.5 part, oxalic acid 5-15 part, reduced glutathion 15-45 part, water-soluble silicon oil 8-25 part, EM original solution 20-60 part, diatomite 10-30 part, 1:2 type lauric acid diethanolamine 6-24 part, water 10-300 part.
Diatomite was dried be ground into again end stand-by, water is put into mixing vessel, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 1
A kind of metal products cleaning and smoothing agent, takes raw material by weight: thiocarbamide 1.5 parts, oxalic acid 5 parts, reduced glutathion 15 parts, water-soluble silicon oil 8 parts, EM original solution 20 parts, 10 parts, diatomite, 1:2 type lauric acid diethanolamine 6 parts, 100 parts, water.
Diatomite was dried be ground into again end stand-by, water is put into mixing vessel, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 2
A kind of metal products cleaning and smoothing agent, takes raw material by weight: thiocarbamide 3 parts, oxalic acid 10 parts, reduced glutathion 30 parts, water-soluble silicon oil 16 parts, EM original solution 40 parts, 20 parts, diatomite, 1:2 type lauric acid diethanolamine 12 parts, 200 parts, water.
Diatomite was dried be ground into again end stand-by, water is put into the molten device of mixing, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 3
A kind of metal products cleaning and smoothing agent, takes raw material by weight: thiocarbamide 4.5 parts, oxalic acid 15 parts, reduced glutathion 45 parts, water-soluble silicon oil 25 parts, EM original solution 60 parts, 30 parts, diatomite, 1:2 type lauric acid diethanolamine 24 parts, 300 parts, water.
Diatomite was dried be ground into again end stand-by, water is put into mixing vessel, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Note: use pure water or distilled water, as need tap water be used, just available after diel must be placed, because containing chlorinated lime in tap water, unsuitable with biological EM original solution.
Using method: both hands wear Rubber gloves, shakes up this product, pours out and on one piece of wet cloth, cleans metal products on a small quantity, and the spot spot of metal products disappears for a moment, and rinse well with clear water, clean dry cloth is dried, and namely gloss is bright as new.
Wherein, the physico-chemical property of each raw material and purposes as follows:
Thiocarbamide: white or light yellow glossiness sheet, column or needle crystal, have bitter taste.Relative density (d204) 1.405.Water-soluble and the ethanol of energy, is dissolved in ether hardly, in atmosphere easy deliquescence.Fusing point 180 ~ 182 DEG C.Ammonium thiocyanate is transformed into 150 DEG C time.Under vacuo 150 ~ 160 DEG C time distillation, when 180 DEG C decompose.There is reductibility, free state iodine can be made to be reduced into iodide ion.This product is imbued with reactivity, in order to prepare various compound.Urea, sulfuric acid and other organic compound can be generated with multiple oxidant reaction, also can make diffluent addition compound with mineral compound.Here be used as metal antirusting agent, increase gloss-imparting agent.
Oxalic acid: have another name called oxalic acid, dicarboxylic acid.The simplest di-carboxylic acid, is present in natural plant with calcium salt forms, water white transparency xln or white powder.Taste acid, normal containing two molecular crystal water.Anhydrous oxalic acid is water white transparency crystallization, has two kinds of crystal habits, i.e. α type (rhombus) and β type (monoclinic form).Relative density, α type: 1.900 (17 DEG C); β type: 1.895 (17 DEG C).Fusing point α type: 189.5 DEG C; β type: 182 DEG C.The relative density 1.653 (20 DEG C) of oxalic acid dihydrate, fusing point 101.5 DEG C.When being heated to 100 DEG C, then losing crystal water and form anhydride, to 165 DEG C, then part distillation, a part resolves into formic acid and carbonic acid gas, or the resolvent of formic acid.Water-soluble and ethanol, the solubility with temperature in water raises and increases, and is slightly soluble in ether, is insoluble to benzene, chloroform and sherwood oil.Be acid the strongest in binary carboxylic, except there is the character of general carboxylic, also there is strong reducing property.Ferric iron back can be also ferrous iron by oxalic acid, because ferrous iron is soluble in water, therefore can by the iron rust removing on clothing.Also can with much metal oxalic salt, except divalent iron salt and an alkali metal salt, all the other oxalate are all insoluble in water.Oxalic acid is poisonous, the irritant and corrosive nature to skin, mucous membrane, easily by epidermis, mucosal absorption and cause poisoning.Here oxalic acid is used as the rust cleaning of metal except verdigris agent, bate pits agent, sequestrant.
Reduced glutathion: white crystals, general merchandise is pale yellow powder, water-soluble, Diluted Alcohol liquid.Fusing point 195 DEG C, [α] D25-18.9 ° (4.5%), [α] D27-21 ° (2.7%).Gsh, through oxidation deoxidation, makes two molecule gsh be combined into Sleep-promoting factor B (GSSG; Relative molecular mass 612.64).GSSG, without physiological function, is still (reduced form) gsh after reduction.Only has reduced glutathion competence exertion physiological action.Detoxification is had to protect body from the murder by poisoning of heavy metal and epoxy compounds.All there is certain detoxification to the poisoning of CO, heavy metal, organic solvent, carcinogenic substance etc., excrete after combining with it.Play a protective role to by symptoms such as radioactive rays, radiopharmaceuticals or the oligoleukocythemia that causes due to antitumor drug.Here reduced form toxinicide is used as.
Water-soluble silicon oil: have another name called silicone oil, colourless yellowish transparent oily liquid.Relative density 0.96 ~ 1.02.Can dissolve each other with any ratio with water.Belong to non-ionic type, surface tension is very low, has emulsification lubrication.Here smooth, the gloss effect that increase metallic surface is used as.
EM original solution: the good effect flora liquid be made up of many beneficial microorganisms, can kill and stop harmful microorganism to the oxidative attack effect of organic substance, can also decompose various toxin and effect that is smelly, peculiar smell.Metal products is commonly used EM original solution dilution spray and is wiped, and can prevent corrosion.Wash one's face, the rust stain EM original solution of Porcelain Jar of having a bath, porcelain plate directly wipes and can remove rusty stain, sparkling clean.
Diatomite: a kind of biogenic white or slight yellow powdery siliceous rock, be made up of amorphous SiO2, and containing a small amount of Fe2O3, CaO, MgO, Al2O3 and organic impurity.Light weight and soft, easy grinding powder, vesicular, porosity reaches about 90%.There is very strong adsorptive power, the water of himself weight 1.5 ~ 4.0 times can be absorbed, also have good filterableness, Bleachability, chemical stability and thermal insulation.Here be used as decontamination, decolouring, deodorizing, deacidify and polish effect.
1:2 type lauric acid diethyl amide: another name JH2-110 alkylolamide, this product is bale of straw wax, water-soluble, washing composition is had to the performances such as obvious thickening, foaming, and decontamination, antirust, antistatic property.
Claims (4)
1. a metal products cleaning and smoothing agent, it is characterized in that, take raw material by weight: thiocarbamide 1.5-4.5 part, oxalic acid 5-15 part, reduced glutathion 15-45 part, water-soluble silicon oil 8-25 part, EM original solution 20-60 part, diatomite 10-30 part, 1:2 type lauric acid diethanolamine 6-24 part, water 10-300 part;
Diatomite was dried be ground into again end stand-by, water is put into mixing vessel, add thiocarbamide, oxalic acid mixes dissolving thoroughly, add reduced glutathion, water-soluble silicon oil and EM original solution, stir while adding evenly, add 1:2 type lauric acid diethyl amide and mix thoroughly, finally add diatomite powder and fully mix thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
2. a kind of metal products cleaning and smoothing agent according to claim 1, it is characterized in that, described raw material is counted by weight: thiocarbamide 1.5 parts, oxalic acid 5 parts, reduced glutathion 15 parts, water-soluble silicon oil 8 parts, EM original solution 20 parts, 10 parts, diatomite, 1:2 type lauric acid diethanolamine 6 parts, 100 parts, water.
3. a kind of metal products cleaning and smoothing agent according to claim 1, it is characterized in that, described raw material is counted by weight: thiocarbamide 3 parts, oxalic acid 10 parts, reduced glutathion 30 parts, water-soluble silicon oil 16 parts, EM original solution 40 parts, 20 parts, diatomite, 1:2 type lauric acid diethanolamine 12 parts, 200 parts, water.
4. a kind of metal products cleaning and smoothing agent according to claim 1, it is characterized in that, described raw material is counted by weight: thiocarbamide 4.5 parts, oxalic acid 15 parts, reduced glutathion 45 parts, water-soluble silicon oil 25 parts, EM original solution 60 parts, 30 parts, diatomite, 1:2 type lauric acid diethanolamine 24 parts, 300 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510073473.9A CN104630794A (en) | 2015-02-11 | 2015-02-11 | Metal product cleaning and brightening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510073473.9A CN104630794A (en) | 2015-02-11 | 2015-02-11 | Metal product cleaning and brightening agent |
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| CN104630794A true CN104630794A (en) | 2015-05-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510073473.9A Pending CN104630794A (en) | 2015-02-11 | 2015-02-11 | Metal product cleaning and brightening agent |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62250189A (en) * | 1986-04-21 | 1987-10-31 | Kurita Water Ind Ltd | Chemical cleaning agent |
| CN103740517A (en) * | 2014-02-12 | 2014-04-23 | 北京戴斯科技有限公司 | Sand cylinder cleaning agent |
-
2015
- 2015-02-11 CN CN201510073473.9A patent/CN104630794A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62250189A (en) * | 1986-04-21 | 1987-10-31 | Kurita Water Ind Ltd | Chemical cleaning agent |
| CN103740517A (en) * | 2014-02-12 | 2014-04-23 | 北京戴斯科技有限公司 | Sand cylinder cleaning agent |
Non-Patent Citations (4)
| Title |
|---|
| 凌关庭: "《抗氧化食品与健康》", 30 April 2004, 化学工业出版社 * |
| 宋小平等: "《洗涤剂实用生产技术500例》", 31 March 2011, 中国纺织出版社 * |
| 未署名: "EM(技术)在环保方面的应用", 《农业新技术》 * |
| 李东光: "《洗涤剂化妆品原料手册》", 31 January 2002, 化学工业出版社 * |
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Application publication date: 20150520 |