CN104630776A - Metal product cleaning brightening agent - Google Patents

Metal product cleaning brightening agent Download PDF

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Publication number
CN104630776A
CN104630776A CN201510074932.5A CN201510074932A CN104630776A CN 104630776 A CN104630776 A CN 104630776A CN 201510074932 A CN201510074932 A CN 201510074932A CN 104630776 A CN104630776 A CN 104630776A
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CN
China
Prior art keywords
parts
water
diatomite
urea
methylpyrrolidone
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Pending
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CN201510074932.5A
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Chinese (zh)
Inventor
黎秋萍
邓智广
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Foshan Shunde Baotong Metal Technology Co Ltd
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Foshan Shunde Baotong Metal Technology Co Ltd
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Priority to CN201510074932.5A priority Critical patent/CN104630776A/en
Publication of CN104630776A publication Critical patent/CN104630776A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a metal product cleaning brightening agent and belongs to the technical field of processing of cleaning products for daily use. The metal product cleaning brightening agent is prepared from urea, citric acid, glycerol borate fatty acid, N-methyl-2-pyrrolidone, reduced glutathione, water soluble silicone oil, EM original liquid and diatomite. The metal product cleaning brightening agent is capable of eliminating oil stains, rusty spots and black spots of metal products such as steel, aluminum and copper, and also capable of recovering the glossiness of the metal products.

Description

A kind of metal products cleaning and smoothing agent
Technical field:
The invention belongs to the processing technique field of daily cleaning product washing composition, particularly relate to a kind of metal products cleaning and smoothing agent.
Background technology:
The steel often used in daily life, aluminium, brass work time have been grown, and just oxidation produces rust staining, blackspot and greasy dirt dirt stain, dark and gloomy indecency.A kind of metal products cleaning and smoothing agent of the application can solve the fouling problem of above-mentioned metal products.
Summary of the invention:
A kind of metal products cleaning and smoothing agent, urea, citric acid, glycerol boric acid fatty acid ester, METHYLPYRROLIDONE, reduced glutathion, water-soluble silicon oil, EM original solution and diatomite is adopted to be prepared from, greasy dirt dirt and rust staining, the blackspot of the metal productss such as steel, aluminium, copper can be removed, its gloss brightness can also be recovered.
The technical measures that the present invention takes:
A kind of metal products cleaning and smoothing agent, takes raw material by weight: urea 3-9 part, citric acid 5-15 part, glycerol boric acid fatty acid ester 6-18 part, METHYLPYRROLIDONE 4-12 part, reduced glutathion 8-24 part, water-soluble silicon oil 12-36 part, EM original solution 15-45 part, diatomite 12-36 part, water 100-300 part.
Diatomite was dried be ground into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Compared with prior art, the present invention has following beneficial effect:
1, adopt the METHYLPYRROLIDONE that solvency power is strong as sanitising agent, solubilizing agent, biological degradability is good, nontoxic to aquatic organism.The toxic substance of reduced glutathion energy decomposing metal, EM original solution can prevent and remove the action of rust of metal, increases the gloss of metal, decomposes peculiar smell, also helps ecological, environmental protective.
2, adopt water-soluble silicon oil can increase the gloss brightness on steel, aluminium, brass work surface, urea can remove the spot film of metal, and the diatomite of powdery cleans metallic surface, makes it more smooth bright.
3, product of the present invention can remove oil stain dirt, and de-black of derusting spot, does not corrode metal, and also have the effect of rust protection, its washing function is more comprehensive.
Embodiment:
A kind of metal products cleaning and smoothing agent, it comprises: take raw material by weight: urea 3-9 part, citric acid 5-15 part, glycerol boric acid fatty acid ester 6-18 part, METHYLPYRROLIDONE 4-12 part, reduced glutathion 8-24 part, water-soluble silicon oil 12-36 part, EM original solution 15-45 part, diatomite 12-36 part, water 100-300 part.
Diatomite was dried be ground into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 1
A kind of metal products cleaning and smoothing agent, takes raw material by weight: 3 parts, urea, citric acid 5 parts, glycerol boric acid fatty acid ester 6 parts, METHYLPYRROLIDONE 4 parts, reduced glutathion 8 parts, water-soluble silicon oil 12 parts, EM original solution 15 parts, 12 parts, diatomite, 100 parts, water.
Diatomite was dried be ground into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 2
A kind of metal products cleaning and smoothing agent, takes raw material by weight: 6 parts, urea, citric acid 10 parts, glycerol boric acid fatty acid ester 12 parts, METHYLPYRROLIDONE 8 parts, reduced glutathion 16 parts, water-soluble silicon oil 24 parts, EM original solution 30 parts, 24 parts, diatomite, 200 parts, water.
Diatomite was dried be ground into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Embodiment 3
A kind of metal products cleaning and smoothing agent, takes raw material by weight: 9 parts, urea, citric acid 15 parts, glycerol boric acid fatty acid ester 18 parts, METHYLPYRROLIDONE 12 parts, reduced glutathion 24 parts, water-soluble silicon oil 36 parts, EM original solution 45 parts, 36 parts, diatomite, 300 parts, water.
Diatomite was dried be ground into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
Note: use pure water or distilled water, as need tap water be used, just available after diel must be placed, because containing chlorinated lime in tap water, unsuitable with EM original solution.
Using method: both hands wear Rubber gloves, shakes up this product, pours out and on one piece of wet cloth, cleans metal products on a small quantity, and the spot spot of steel, aluminium, brass work disappears for a moment, and rinse well with clear water, clean dry cloth is dried, and namely gloss becomes clear.
Wherein, the physico-chemical property of each raw material and purposes as follows:
Urea: another name carbonyl diamine; Urea, white, the crystal of tasteless, odorless or powder, fusing point 132.9 DEG C, heat of crystallization 14.5kj/mol-1, relative density 1.335,10% pH value of water solution is 7.2.Soluble in water, ethanol and benzene, be slightly soluble in ether, be insoluble to chloroform.There is certain water absorbability.Decompose when being heated beyond fusing point.Here be used as solubilizing agent, remove spot film.
Citric acid: another name citric acid, white translucent crystal or powder.Fusing point 153 DEG C (anhydride).Relative density D4181.665 (anhydride) d4181.542 (monohydrate).The citric acid crystallized out from cold solution contains a part water, in dry air, easily promote crystal water.Soluble in water and ethanol, is dissolved in ether.Flammable.Be widely used in raw material and the additive of makeup, metal cleaner, mordant, non-toxic plasticizer and boilercomposition.Foodstuffs industry is used as acidic flavoring agent, health care industry hematinic, blood transfusion agent and alkalosis toxinicide.
Glycerol boric acid fatty acid ester: another name BS product series (BS-20, BS-40, BS-60, BS-80, BS-83, BS-160, BS-260) these series product lipid acid difference used, can obtain the product that outward appearance is different, they are all water insoluble, are soluble in organic solvent.As metal hydraulic rust-inhibiting additive, be widely used as in fiber process, dyeing, ink and makeup, be used as metal cleaner, rust-preventive agent here.
METHYLPYRROLIDONE: another name NMP, colourless liquid, has ammonia taste.Effective solvent, the resin that solubilized is numerous, chemistry and Heat stability is good, all miscible with water at any temperature, and mix with most of organic solvent.There is extremely strong water absorbability, weakly alkaline.Toxicity is low.With strong oxidizer as hydrogen peroxide, nitric acid and sulfuric acid reaction, there is very strong dissolving power with many kinds of substance.It is also in metal parts cleaning procedure, with alternative 1,1,1-trichloroethane.It can be recycled by distillation, and biological degradability is good, nontoxic to aquatic organism.Here surface cleaner, solubilizing agent is used as.
Reduced glutathion: white crystals, general merchandise is pale yellow powder, water-soluble, Diluted Alcohol liquid.Fusing point 195 DEG C, [α] D25-18.9 ° (4.5%), [α] D27-21 ° (2.7%).Gsh, through oxidation deoxidation, makes two molecule gsh be combined into Sleep-promoting factor B (GSSG; Relative molecular mass 612.64).GSSG, without physiological function, is still (reduced form) gsh after reduction.Only has reduced glutathion competence exertion physiological action.Detoxification is had to protect body from the murder by poisoning of heavy metal and epoxy compounds.All there is certain detoxification to the poisoning of CO, heavy metal, organic solvent, carcinogenic substance etc., excrete after combining with it.Play a protective role to by symptoms such as radioactive rays, radiopharmaceuticals or the oligoleukocythemia that causes due to antitumor drug.Here reduced form toxinicide is used as.
Water-soluble silicon oil: have another name called silicone oil, colourless yellowish transparent oily liquid.Relative density 0.96 ~ 1.02.Can dissolve each other with any ratio with water.Belong to non-ionic type, surface tension is very low, has emulsification lubrication.Here smooth, the gloss effect that increase metallic surface is used as.
EM original solution: the good effect flora liquid be made up of many beneficial microorganisms, can kill and stop harmful microorganism to the oxidative attack effect of organic substance, can also decompose various toxin and effect that is smelly, peculiar smell.Metal products is commonly used EM original solution dilution spray and is wiped, and can prevent corrosion.Wash one's face, the rust stain EM original solution of Porcelain Jar of having a bath, porcelain plate directly wipes and can remove rusty stain, sparkling clean.
Diatomite: a kind of biogenic white or slight yellow powdery siliceous rock, be made up of amorphous SiO2, and containing a small amount of Fe2O3, CaO, MgO, Al2O3 and organic impurity.Light weight and soft, easy grinding powder, vesicular, porosity reaches about 90%.There is very strong adsorptive power, the water of himself weight 1.5 ~ 4.0 times can be absorbed, also have good filterableness, Bleachability, chemical stability and thermal insulation.Here be used as decontamination, decolouring, deodorizing, deacidify and polish effect.

Claims (4)

1. a metal products cleaning and smoothing agent, it is characterized in that, take raw material by weight: urea 3-9 part, citric acid 5-15 part, glycerol boric acid fatty acid ester 6-18 part, METHYLPYRROLIDONE 4-12 part, reduced glutathion 8-24 part, water-soluble silicon oil 12-36 part, EM original solution 15-45 part, diatomite 12-36 part, water 100-300 part;
Diatomite in powder is broken into end stand-by, glycerol boric acid fatty acid ester and METHYLPYRROLIDONE are put into mixing vessel and mixes dissolving thoroughly, then add water to mix thoroughly, add urea, citric acid is mixed thoroughly, add reduced glutathion, water-soluble silicon oil is mixed thoroughly, finally add EM original solution and diatomite powder is fully mixed thoroughly, after sub-bottle packaging is good, namely become a kind of metal products cleaning and smoothing agent.
2. according to claim 1, a kind of metal products cleaning and smoothing agent, it is characterized in that, described raw material is counted by weight: 3 parts, urea, citric acid 5 parts, glycerol boric acid fatty acid ester 6 parts, METHYLPYRROLIDONE 4 parts, reduced glutathion 8 parts, water-soluble silicon oil 12 parts, EM original solution 15 parts, 12 parts, diatomite, 100 parts, water.
3. according to claim 1, a kind of metal products cleaning and smoothing agent, it is characterized in that, described raw material is counted by weight: 6 parts, urea, citric acid 10 parts, glycerol boric acid fatty acid ester 12 parts, METHYLPYRROLIDONE 8 parts, reduced glutathion 16 parts, water-soluble silicon oil 24 parts, EM original solution 30 parts, 24 parts, diatomite, 200 parts, water.
4. according to claim 1, a kind of metal products cleaning and smoothing agent, it is characterized in that, described raw material is counted by weight: 9 parts, urea, citric acid 15 parts, glycerol boric acid fatty acid ester 18 parts, METHYLPYRROLIDONE 12 parts, reduced glutathion 24 parts, water-soluble silicon oil 36 parts, EM original solution 45 parts, 36 parts, diatomite, 300 parts, water.
CN201510074932.5A 2015-02-11 2015-02-11 Metal product cleaning brightening agent Pending CN104630776A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763375A (en) * 1994-01-26 1998-06-09 Daikin Industries, Ltd. Cleaning agents and cleaning method
CN1436228A (en) * 2000-06-16 2003-08-13 巴斯福股份公司 Oxoalcohol-based detergent
CN103003923A (en) * 2010-07-16 2013-03-27 高级技术材料公司 Aqueous cleaner for the removal of post-etch residues
CN103556160A (en) * 2013-10-30 2014-02-05 青岛良力精铸有限公司 Metal derusting agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763375A (en) * 1994-01-26 1998-06-09 Daikin Industries, Ltd. Cleaning agents and cleaning method
CN1436228A (en) * 2000-06-16 2003-08-13 巴斯福股份公司 Oxoalcohol-based detergent
CN103003923A (en) * 2010-07-16 2013-03-27 高级技术材料公司 Aqueous cleaner for the removal of post-etch residues
CN103556160A (en) * 2013-10-30 2014-02-05 青岛良力精铸有限公司 Metal derusting agent

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
无: "EM(技术)在环保方面的应用", 《农业新技术》 *
王慎敏等: "《精细化工原材料及中间体手册 日用化学品》", 30 June 2005, 化学工业出版社化学与应用化学出版中心 *
韩熙麟等: "《机械制造清洗技术》", 31 January 1988, 机械工业出版社 *

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Application publication date: 20150520