CN102304718A - Derusting cleaning agent - Google Patents
Derusting cleaning agent Download PDFInfo
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- CN102304718A CN102304718A CN201110278698A CN201110278698A CN102304718A CN 102304718 A CN102304718 A CN 102304718A CN 201110278698 A CN201110278698 A CN 201110278698A CN 201110278698 A CN201110278698 A CN 201110278698A CN 102304718 A CN102304718 A CN 102304718A
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Abstract
The invention discloses a derusting cleaning agent. The derusting cleaning agent consists of the following components in part by mass: 5 to 10 parts of acid-alkali compounding agent, 5 to 10 parts of oxidizing-reducing agent, 5 to 10 parts of metal ion chelating agent, 1 to 10 parts of surfactant, 1 to 5 parts of sterilizing algicide and the balance of organic solvent, wherein the total number of all the components is 100 parts; the acid-alkali compounding agent is sodium nitrite or sodium benzoate; the oxidizing-reducing agent is one of potassium permanganate, ferric trichloride and hydrogen chloride; the metal ion chelating agent is GY-409; the surfactant is nonpolar hydrocarbon chain, such as the hydrocarbon chain with more than 8 carbon atoms; the sterilizing algicide is dodecyl dimethyl benzyl ammonium chloride; and the organic solvent is one of methanol, ethanol, methyl ether, diethyl ether, methylphenol and diethylstilbestrol. The derusting cleaning agent has strong derusting effect and is simple in manufacturing process.
Description
Technical field
The invention belongs to the detergents and cosmetic technical field, be specifically related to a kind of derusting and cleaning agent.
Background technology
In the actual life, because accumulating over a long period in the life process, many dead angles appear in the sanitary condition that makes family, hotel, restaurant etc. locate; Some dirts that are difficult to remove appear in each corner, and these long-term accumulative dirts only rely on common clean-out system clean effect not strong; Be difficult to realize fast, clean completely; Cause cleaning course to be wasted time and energy, inefficiency, cleaning effect is undesirable.
Summary of the invention
The purpose of this invention is to provide a kind of derusting and cleaning agent, it is not strong to have solved the existing derusting and cleaning agent effect of derusting, and causes cleaning course to be wasted time and energy, ineffective problem.
The technical scheme that the present invention adopted is that a kind of derusting and cleaning agent is made up of according to mass parts following component: acid-alkali ingredients 5-10 part; Oxidation-reduction agent 5-10 part; Metal ion chelation agent 5-10 part; Tensio-active agent 1-10 part; Biocidal algae-killing agent 1-5 part; Surplus is an organic solvent, amounts to 100 parts.
The invention has the beneficial effects as follows that the effect of derusting is strong, cleaning course is simple, high efficiency, and simultaneously, manufacture craft is simple, and raw materials cost is low.
Embodiment
Below in conjunction with embodiment the present invention is elaborated.
Derusting and cleaning agent of the present invention is made up of according to mass parts following component: acid-alkali ingredients 5-10 part; Oxidation-reduction agent 5-10 part; Metal ion chelation agent 5-10 part; Tensio-active agent 1-10 part; Biocidal algae-killing agent 1-5 part; Surplus is an organic solvent, amounts to 100 parts.
Acid-alkali ingredients is wherein selected Sodium Nitrite or Sodium Benzoate for use; One of potassium permanganate, iron trichloride, hydrogenchloride are selected in the oxidation-reduction agent for use; Metal ion chelation agent is selected GY-409 for use; Tensio-active agent select for use carboxylic acid, sulfonic acid, hydroxyl the combination of corresponding nonpolar hydrocarbon chain, like 8 above hydrocarbon chains of carbon atom; Biocidal algae-killing agent is selected dodecyl benzyl dimethyl ammonium chloride for use; Organic solvent is selected one of methyl alcohol, ethanol, methyl ether, ether, cresols, diethylstilbestrol for use.
In the derusting and cleaning agent of the present invention, the action principle of the various components of interpolation is respectively:
1), organic solvent
Comprise hydrocarbon and halon, alcohol, ether, ketone, ester, phenol etc. and composition thereof, be mainly used in the organic dirt of dissolving, like grease and some organic cpds dirt.
2), tensio-active agent
Tensio-active agent (surfactant) is meant to have fixed hydrophilic and oleophilic group, aligns at the surface energy of solution, and the material that surface tension is significantly descended.Tensio-active agent is divided into ionogenic surfactant and non-ionics etc.The molecular structure of tensio-active agent has amphipathic: an end is a hydrophilic radical, and the other end is the hydrophobic group; Hydrophilic radical often is the polar group, like carboxylic acid, sulfonic acid, sulfuric acid, amino or amido and salt thereof, and also hydroxyl, carboxamido-group, ehter bond etc.; And the hydrophobic group is nonpolar hydrocarbon chain often, like 8 above hydrocarbon chains of carbon atom.Have hydrophilic polar group and lipophilic non-polar group in its molecule simultaneously; When its add-on seldom the time; Can reduce the surface tension and the light-liquid interfacial tension of solvent (generally being water) greatly, and have effects such as lubricated, solubilising, emulsification, dispersion and washing.Tensio-active agent has been widely used in family life and industrial cleaning.
3). the acid-alkali ingredients
The auxiliary agent that most of acid-alkali clean-out systems all add necessity by the aqueous solution sour, alkali is formed.Another kind of under hot conditions with the acid or the alkali of molten state and dirt digestion, make and originally do not dissolve or difficultly be dissolved in the dirt in the cleaning medium, be converted into diffluent compound, this type acid and alkali are commonly referred to the fusion agent.This clean-out system has good effect during for the dirt that is difficult to remove with solvent or solution.Select the Sodium Nitrite or the Sodium Benzoate of the rust cleaning that can neutralize for use.
4). the oxidation-reduction agent
Mainly, be cleaning, comprise the fusion agent with oxygenant or reductive agent by the preparation that takes out stains with dirt generation redox reaction.Oxygenant has the dirt of reductibility in order to removing, like many organic dirts.Reductive agent is used to remove the dirt of oxidisability, like rust deposite.
It is one of following that oxygenant is selected for use:
(1) (the strong and weak and nonmetal reactivity basically identicals of its oxidisability) such as typical non-metal simple-substance such as fluorine, oxygen, chlorine, bromine, iodine, sulphur;
(2) contain the high price compound of valence variation element, like potassium permanganate, the vitriol oil, nitric acid, Manganse Dioxide, iron trichloride etc.;
(3) metallic cation is like ferric ion, bivalent cupric ion, monovalence hydrogen ion.
It is one of following that reductive agent is selected for use:
(1) typical metal simple-substance is like K, Ca, Na, Mg etc. (its reductibility strong and weak with metal reactivity basically identical);
(2) the minimum valence state compound that valence variation element arranged is like hydrogen sulfide, hydrogen iodide, hydrogen bromide, hydrogenchloride;
(3) metalloid anion is like iodide ion, bromide anion, cl ions.
5). metal ion chelation agent
By with dirt in metals ion generation complex reaction, dirt is changed be soluble in into the inner complex of clean-out system, this clean-out system or auxiliary agent are sequestrant.It is commonly used in the cleaning of rust deposite and inorganic salt crust.
Use GY-409 as metal ion chelation agent, can replace EDTA.Cost is far below EDTA, and these article sequestering power is strong, effective, easy handling.These article are organic phosphine compound; For divalent-metal ion; As: the sequestering power of calcium, magnesium, iron, copper etc. is strong especially, can form stable complex compound, even to the inorganic salts of these metals as: calcium sulfate, lime carbonate, Magnesium Silicate q-agent etc. also have decontamination activation preferably; Thereby be widely used in daily use chemicals industries such as washing composition, daily cosmetics, perfumed soap as metal ion chelation agent, can improve the quality of daily chemical products.
6). Biocidal algae-killing agent
It can kill the bacterium algae of surface to be cleaned, peels off the chemical agent of mikrobe mud.Biocidal algae-killing agent selects for use dodecyl benzyl dimethyl ammonium chloride (to be called for short 1227; Another name: geramine, benzalkonium chloride, Benzalkonium Chloride 80(BKC80) DDBAC); (Dodecyl Dimethyl Benzyl ammonium Chloride); [CAS] 8001-54-5 or 63449-41-2139-07-1, molecular formula: C21H38NCl relative molecular mass: 340.0.The 1227th, a kind of cats product; Belong to non-oxidizable sterilant; Have wide spectrum, sterilization algae removal ability efficiently; Can control bacterium algae propagation and foundry loam growth in the water effectively, and have the effect of peeling off of good foundry loam and certain dispersion, osmosis, have simultaneously certain deoil, deodorizing capability and corrosion inhibition.1227 toxicity are little, do not have accumulation property toxicity, and soluble in water; Not influenced by the water hardness; Therefore be widely used in growing in order to Control Circulation cooling water system bacterium algae in the recirculating cooling water system of industries such as oil, chemical industry, electric power, weaving, special efficacy arranged killing sulphate reducing bacteria.
Quality index meets HG/T 2890-2011.
The preparation method of clean-out system of the present invention, implement according to following steps:
Step 1, according to the following component of mass parts weighing: acid-alkali ingredients 5-10 part; Oxidation-reduction agent 5-10 part; Metal ion chelation agent 5-10 part; Tensio-active agent 1-10 part; Biocidal algae-killing agent 1-5 part; Surplus is an organic solvent, amounts to 100 parts;
Step 2, at normal temperatures adds acid-alkali ingredients 5-10 part, oxidation-reduction agent 5-10 part respectively the organic solvent of equivalent earlier, stirs respectively, mixes then, obtains mixed liquor A;
Step 3, in mixed liquor A, add tensio-active agent 1-10 part, stir after 3-5 minute, add metal ion chelation agent 5-10 part again, continue stirring after, obtain mixed liquid B;
Step 4, in mixed liquid B, add the organic solvent of surplus, stirs after 3-5 minute, add Biocidal algae-killing agent 1-5 part at last, fully stirring.
Embodiment 1
Step 1, according to the following component of mass parts weighing: 5 parts of acid-alkali ingredients Sodium Nitrites; 10 parts in oxidation-reduction agent potassium permanganate; 10 parts of metal ion chelation agents; 1 part in tensio-active agent (carboxylic acid the combination of corresponding nonpolar hydrocarbon chain, 8 above hydrocarbon chains of carbon atom); 3 parts of Biocidal algae-killing agents; Surplus is a methyl alcohol, amounts to 100 parts;
Step 2, at normal temperatures adds acid-alkali ingredients, oxidation-reduction agent respectively the organic solvent of equivalent earlier, stirs respectively, mixes then, obtains mixed liquor A;
Step 3, in mixed liquor A, add tensio-active agent, stir after 3-5 minute, add metal ion chelation agent again, after continuing to stir, obtain mixed liquid B;
Step 4, in mixed liquid B, add the methyl alcohol of surplus, stirs after 3-5 minute, add Biocidal algae-killing agent at last, fully stirring.
Embodiment 2
Step 1, according to the following component of mass parts weighing: 10 parts of acid-alkali ingredients Sodium Benzoates; 5 parts in oxidation-reduction agent potassium permanganate; 5 parts of metal ion chelation agents; 10 parts in tensio-active agent (sulfonic acid the combination of corresponding nonpolar hydrocarbon chain, 10 above hydrocarbon chains of carbon atom); 5 parts of Biocidal algae-killing agents; Surplus is an ether, amounts to 100 parts;
Step 2, at normal temperatures adds acid-alkali ingredients, oxidation-reduction agent respectively the organic solvent of equivalent earlier, stirs respectively, mixes then, obtains mixed liquor A;
Step 3, in mixed liquor A, add tensio-active agent, stir after 3-5 minute, add metal ion chelation agent again, after continuing to stir, obtain mixed liquid B;
Step 4, in mixed liquid B, add the ether of surplus, stirs after 3-5 minute, add Biocidal algae-killing agent at last, fully stirring.
Embodiment 3
Step 1, according to the following component of mass parts weighing: 8 parts of acid-alkali ingredients Sodium Nitrites; 7 parts of oxidation-reduction agent iron trichlorides; 9 parts of metal ion chelation agents; 3 parts in tensio-active agent (hydroxyl the combination of corresponding nonpolar hydrocarbon chain, 12 above hydrocarbon chains of carbon atom); 1 part of Biocidal algae-killing agent; Surplus is an ethanol, amounts to 100 parts;
Step 2, at normal temperatures adds acid-alkali ingredients, oxidation-reduction agent respectively the organic solvent of equivalent earlier, stirs respectively, mixes then, obtains mixed liquor A;
Step 3, in mixed liquor A, add tensio-active agent, stir after 3-5 minute, add metal ion chelation agent again, after continuing to stir, obtain mixed liquid B;
Step 4, in mixed liquid B, add the ethanol of surplus, stirs after 3-5 minute, add Biocidal algae-killing agent at last, fully stirring.
Embodiment 4
Step 1, according to the following component of mass parts weighing: 6 parts of acid-alkali ingredients Sodium Benzoates; 9 parts in oxidation-reduction agent hydrogenchloride; 6 parts of metal ion chelation agents; 6 parts in tensio-active agent (carboxylic acid the combination of corresponding nonpolar hydrocarbon chain, 16 above hydrocarbon chains of carbon atom); 2 parts of Biocidal algae-killing agents; Surplus is a diethylstilbestrol, amounts to 100 parts;
Step 2, at normal temperatures adds acid-alkali ingredients, oxidation-reduction agent respectively the organic solvent of equivalent earlier, stirs respectively, mixes then, obtains mixed liquor A;
Step 3, in mixed liquor A, add tensio-active agent, stir after 3-5 minute, add metal ion chelation agent again, after continuing to stir, obtain mixed liquid B;
Step 4, in mixed liquid B, add the diethylstilbestrol of surplus, stirs after 3-5 minute, add Biocidal algae-killing agent at last, fully stirring.
When using clean-out system of the present invention to clean, adopt spray method to clean, only need 1～2 minute, use flushing with clean water again, just can reach the degree of cleaning more than 99%.Clean-out system blending process of the present invention is simple, and production cost is low, and cleaning speed is fast, and efficient is high, and is safe and reliable.
Claims (7)
1. a derusting and cleaning agent is characterized in that: be made up of according to mass parts following component: acid-alkali ingredients 5-10 part; Oxidation-reduction agent 5-10 part; Metal ion chelation agent 5-10 part; Tensio-active agent 1-10 part; Biocidal algae-killing agent 1-5 part; Surplus is an organic solvent, amounts to 100 parts.
2. derusting and cleaning agent according to claim 1 is characterized in that: described acid-alkali ingredients is selected Sodium Nitrite or Sodium Benzoate for use.
3. derusting and cleaning agent according to claim 1 is characterized in that: one of potassium permanganate, iron trichloride, hydrogenchloride are selected in described oxidation-reduction agent for use.
4. derusting and cleaning agent according to claim 1 is characterized in that: described metal ion chelation agent is selected GY-409 for use.
5. derusting and cleaning agent according to claim 1 is characterized in that: described tensio-active agent is selected nonpolar hydrocarbon chain for use, like 8 above hydrocarbon chains of carbon atom.
6. derusting and cleaning agent according to claim 1 is characterized in that: described Biocidal algae-killing agent is selected dodecyl benzyl dimethyl ammonium chloride for use.
7. derusting and cleaning agent according to claim 1 is characterized in that: described organic solvent is selected one of methyl alcohol, ethanol, methyl ether, ether, cresols, diethylstilbestrol for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110278698A CN102304718A (en) | 2011-09-21 | 2011-09-21 | Derusting cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110278698A CN102304718A (en) | 2011-09-21 | 2011-09-21 | Derusting cleaning agent |
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|---|---|
| CN102304718A true CN102304718A (en) | 2012-01-04 |
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| CN201110278698A Pending CN102304718A (en) | 2011-09-21 | 2011-09-21 | Derusting cleaning agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264168A (en) * | 2014-09-29 | 2015-01-07 | 无锡阳工机械制造有限公司 | Nickel-base alloy rust-removing water |
| CN105369263A (en) * | 2015-11-26 | 2016-03-02 | 安徽天思朴超精密模具股份有限公司 | Metal rust remover material combination and method for preparing metal rust remover |
-
2011
- 2011-09-21 CN CN201110278698A patent/CN102304718A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264168A (en) * | 2014-09-29 | 2015-01-07 | 无锡阳工机械制造有限公司 | Nickel-base alloy rust-removing water |
| CN105369263A (en) * | 2015-11-26 | 2016-03-02 | 安徽天思朴超精密模具股份有限公司 | Metal rust remover material combination and method for preparing metal rust remover |
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Application publication date: 20120104 |