CN102010229B - Granite rust remover - Google Patents
Granite rust remover Download PDFInfo
- Publication number
- CN102010229B CN102010229B CN 200910090696 CN200910090696A CN102010229B CN 102010229 B CN102010229 B CN 102010229B CN 200910090696 CN200910090696 CN 200910090696 CN 200910090696 A CN200910090696 A CN 200910090696A CN 102010229 B CN102010229 B CN 102010229B
- Authority
- CN
- China
- Prior art keywords
- parts
- acid
- granite
- rust remover
- rust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 239000010438 granite Substances 0.000 title claims abstract description 22
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 36
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 26
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000015165 citric acid Nutrition 0.000 claims abstract description 14
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 14
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 10
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims abstract description 5
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 5
- 235000002949 phytic acid Nutrition 0.000 claims abstract description 5
- 239000000467 phytic acid Substances 0.000 claims abstract description 5
- 229940068041 phytic acid Drugs 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 16
- 239000003643 water by type Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 abstract description 11
- 239000002798 polar solvent Substances 0.000 abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract description 3
- 239000001530 fumaric acid Substances 0.000 abstract description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002932 luster Substances 0.000 abstract description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- 150000007522 mineralic acids Chemical class 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 239000001630 malic acid Substances 0.000 abstract 1
- 235000011090 malic acid Nutrition 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000013543 active substance Substances 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000001680 brushing effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004575 stone Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a granite rust remover which is prepared by mixing the following components in parts by weight: 15-50 parts of one or more of inorganic acids and organic acids, 1-15 parts of surface active agent, 1-15 parts of hydrogen peroxide and 30-80 parts of polar solvents. The inorganic acid is preferably phosphoric acid and/or hydrochloric acid, the organic acid is preferably at least one of glycolic acid, glyoxylate, oxalic acid, phytic acid, citric acid, malic acid, maleic acid and fumaric acid, and the surface active agent is sodium dodecyl benzene sulfonate or op-10 emulsifier. The rust remover of the invention is smeared on the granite surface, can form a stable colorless complex with iron after reacting for 1-2 days, remove rusty points and rusty lines of the granite in a short time without influencing the granite luster or leaving trails and rapidly remove rust on the granite surface with high efficiency.
Description
Technical field
The present invention relates to a kind of remove rust staining on the grouan rust remover.
Background technology
Along with expanding economy, the application of decorative stone in people's life is also more and more extensive.Wherein, grouan is subject to people's favor because of its good physicals and stable chemical property, be widely used in the decoration of household and public place.But grouan also has the problem of himself, and the rust staining on surface is exactly one of them, and rust cleaning has also become an emphasis of grouan surface treatment work.The reason that rust staining appears in the granite material surface mainly comes from two aspects: the external rusty stain of the first pollutes, as the rust that is placed on the hardware on the stone surface will pollute stone surface, stays rusty stain thereon; It two is reasons of stone material itself, contains ferric oxide in some grouan minerals, further oxidation under the condition of humidity, and with diffusion of moisture, show step by step on the surface of stone material.Present most grouan rust cleaning product rust cleaning cycle is very long, and the rust cleaning effect is undesirable, therefore also there is not desirable solution granite rust remover can reach the effective and short problem of rust cleaning time that eliminates rust.
Summary of the invention
The purpose of this invention is to provide a kind of novel granite rust remover prescription, better rust cleaning effect to be provided and to shorten the rust cleaning time.
For achieving the above object, the present invention adopts following technical scheme:
A kind of granite rust remover is mixed according to the weight part proportioning by following component:
Mineral acid and organic acid one or more, 15-50 part;
Tensio-active agent, 1-15 part;
Hydrogen peroxide, 1-15 part;
Polar solvent, 30-80 part.
Granite rust remover preferably is mixed according to the weight part proportioning by following component:
Mineral acid and organic acid one or more, 20 parts;
Tensio-active agent, 1 part;
Hydrogen peroxide, 5 parts;
Polar solvent, 80 parts.
Described mineral acid is preferably and is phosphoric acid and/or hydrochloric acid.
Described organic acid is preferably at least a in oxyacetic acid, oxoethanoic acid, oxalic acid, phytic acid, citric acid, oxysuccinic acid, toxilic acid and the fumaric acid.
Described tensio-active agent is preferably Sodium dodecylbenzene sulfonate or op-10 emulsifying agent.
Described polar solvent is preferably water.
Beneficial effect of the present invention is:
The compound reaction of the inner iron of the mineral acid that granite rust remover of the present invention uses or organic acid and grouan generates iron ion, then by the acid with complexing action the iron ion complexing is become colourless product, thereby reaches the purpose of rust cleaning.The tensio-active agent that the present invention uses reduces surface tension to increase the penetrating power of rust remover when finite concentration, granite rust remover dispersion, absorption, perviousness are improved.The hydrogen peroxide that the present invention uses provides hydrogen ion and utilizes its bleaching action to make the rust cleaning effect more obvious.
Rust remover of the present invention is embrocated behind the grouan surface, reaction through 1-2 days can form stable colourless complex compound with iron, remove at short notice rust spot and the rust line of grouan, and do not affect the color and luster of grouan, train is not stayed on the surface, reaches quickly and efficiently the work of grouan surface derusting.
Proterties of the present invention is water white acidic solution, does not fire, not quick-fried, and environmentally friendly and with low cost, application prospect is extensive.
Embodiment
Most preferred embodiment is: get respectively weight part and be 20 mineral acid and organic acid one or more; Weight part is 1 tensio-active agent; Weight part is 5 hydrogen peroxide; Weight part is 80 polar solvent.
Embodiment 1
Mineral acid is phosphoric acid, and organic acid is oxalic acid and citric acid, and tensio-active agent is Sodium dodecylbenzene sulfonate or op-10 emulsifying agent, and polar solvent is deionized water, and each composition weight proportioning is as follows:
3 parts of phosphoric acid; 10 parts of oxalic acid; 10 parts of citric acids; 5 parts in hydrogen peroxide; 71 parts of deionized waters.With stirring after the said components mixing, can suitably heat to help the dissolvings such as oxalic acid.Add Sodium dodecylbenzene sulfonate or op-10 emulsifying agent in solution, weight proportion is 1 part, can carry out the brushing on grouan surface after stirring again.
Use rust remover to process the grouan process: in grouan surface derusting process, processed object will carry out under the condition of ventilation illumination as far as possible, and processed grouan will be used to its free of contamination material cushion overhead.The nylon brush brushing of totally not falling hair is adopted in brushing, is coated with emphatically the place of rust spot, rust line during brushing.Brushing interval number of times can be selected every day 3 times, interval 3 hours.React and clean processed surface with clear water after one day, still have the place of rust to continue to smear by the method for first day.Usually rust spot and rust line meeting full scale clearance if obstinate not being eliminated arranged, is coated with the place of rust again after can cleaning with the 3rd day, be coated with 1-2 time and get final product.
Embodiment 2
Organic acid is phytic acid, oxalic acid and citric acid, and tensio-active agent is Sodium dodecylbenzene sulfonate or op-10 emulsifying agent, and polar solvent is deionized water, and each composition weight proportioning is as follows:
5 parts of phytic acid; 10 parts of oxalic acid; 10 parts of citric acids; 5 parts in hydrogen peroxide; 69 parts of deionized waters.With the said components mixing and stirring, suitably heating.Add Sodium dodecylbenzene sulfonate or op-10 emulsifying agent in solution, weight proportion is 1 part, stirs again.
Process the grouan process with embodiment 1.
Embodiment 3
Organic acid is oxyacetic acid, citric acid and toxilic acid, and tensio-active agent is Sodium dodecylbenzene sulfonate or op-10 emulsifying agent, and polar solvent is deionized water, and each composition weight proportioning is as follows:
15 parts of oxyacetic acids; 10 parts of citric acids; 15 parts of toxilic acids; 15 parts in hydrogen peroxide; 80 parts of deionized waters.With the said components mixing and stirring, suitably heating.Add Sodium dodecylbenzene sulfonate or op-10 emulsifying agent in solution, weight proportion is 10 parts, stirs again.
Process the grouan process with embodiment 1.
Embodiment 4
Organic acid is oxalic acid, citric acid and oxysuccinic acid, and tensio-active agent is Sodium dodecylbenzene sulfonate or op-10 emulsifying agent, and polar solvent is deionized water, and each composition weight proportioning is as follows:
5 parts of oxalic acid; 5 parts of citric acids; 5 parts of oxysuccinic acid; 3 parts in hydrogen peroxide; 40 parts of deionized waters.With the said components mixing and stirring, suitably heating.Add Sodium dodecylbenzene sulfonate or op-10 emulsifying agent in solution, weight proportion is 1 part, stirs again.
Process the grouan process with embodiment 1.
Claims (4)
1. a granite rust remover is characterized in that, it consists of:
3 parts of phosphoric acid; 10 parts of oxalic acid; 10 parts of citric acids; 5 parts in hydrogen peroxide; 71 parts of deionized waters; The described umber of each component is weight part;
To stir after the said components mixing, heating adds Sodium dodecylbenzene sulfonate or op-10 emulsifying agent again to promote each components dissolved in solution, and weight proportion is 1 part, can obtain described granite rust remover after stirring.
2. a granite rust remover is characterized in that, it consists of:
5 parts of phytic acid; 10 parts of oxalic acid; 10 parts of citric acids; 5 parts in hydrogen peroxide; 69 parts of deionized waters; The described umber of each component is weight part;
To stir after the said components mixing, heating adds Sodium dodecylbenzene sulfonate or op-10 emulsifying agent again to promote each components dissolved in solution, and weight proportion is 1 part, can obtain described granite rust remover after stirring.
3. a granite rust remover is characterized in that, it consists of:
15 parts of oxyacetic acids; 10 parts of citric acids; 15 parts of toxilic acids; 15 parts in hydrogen peroxide; 80 parts of deionized waters; The described umber of each component is weight part;
To stir after the said components mixing, heating adds Sodium dodecylbenzene sulfonate or op-10 emulsifying agent again to promote each components dissolved in solution, and weight proportion is 10 parts, can obtain described granite rust remover after stirring.
4. a granite rust remover is characterized in that, it consists of:
5 parts of oxalic acid; 5 parts of citric acids; 5 parts of oxysuccinic acid; 3 parts in hydrogen peroxide; 40 parts of deionized waters; The described umber of each component is weight part;
To stir after the said components mixing, heating adds Sodium dodecylbenzene sulfonate or op-10 emulsifying agent again to promote each components dissolved in solution, and weight proportion is 1 part, can obtain described granite rust remover after stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910090696 CN102010229B (en) | 2009-09-08 | 2009-09-08 | Granite rust remover |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910090696 CN102010229B (en) | 2009-09-08 | 2009-09-08 | Granite rust remover |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102010229A CN102010229A (en) | 2011-04-13 |
| CN102010229B true CN102010229B (en) | 2013-02-06 |
Family
ID=43840586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910090696 Expired - Fee Related CN102010229B (en) | 2009-09-08 | 2009-09-08 | Granite rust remover |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102010229B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102383138B (en) * | 2011-10-14 | 2013-08-28 | 赵炜楠 | Metal cleaning solution |
| CN110204360B (en) * | 2018-10-26 | 2020-03-10 | 杭州悦山科技有限公司 | Preparation method of environment-friendly rust remover |
| CN113045338A (en) * | 2019-12-28 | 2021-06-29 | 江苏苏博特新材料股份有限公司 | Environment-friendly rust remover for stone containing iron impurities and preparation method thereof |
| CN111118516A (en) * | 2020-03-15 | 2020-05-08 | 林晓军 | Preparation method of efficient rust remover for outdoor building steel and stone |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095412A (en) * | 1993-05-17 | 1994-11-23 | 刘小珍 | Universal cleaning powder and working method thereof |
| CN1232726A (en) * | 1998-04-20 | 1999-10-27 | 任天胜 | Derusting, radioactive contamination eliminating and slate coloring method |
-
2009
- 2009-09-08 CN CN 200910090696 patent/CN102010229B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095412A (en) * | 1993-05-17 | 1994-11-23 | 刘小珍 | Universal cleaning powder and working method thereof |
| CN1232726A (en) * | 1998-04-20 | 1999-10-27 | 任天胜 | Derusting, radioactive contamination eliminating and slate coloring method |
Non-Patent Citations (2)
| Title |
|---|
| 蔡元兴等.《花岗石锈斑的清洗》.《石材》.2006,(第8期),第9页配方成分表配方2. * |
| 赵吉寿等.《装饰石材、地砖污染清楚和病症治理》.《云南民族学院学报(自然科学版)》.2001,第10卷(第4期),第506-507,517页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102010229A (en) | 2011-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101538512B (en) | Water-based cleaner | |
| CN102154655B (en) | Normal temperature spraying detergent for aluminum alloy and preparation method thereof | |
| CN102978022B (en) | Phosphorus-free and foam-free low-temperature steel plate surface cleaner and preparation method thereof | |
| CN103469236A (en) | Copper base material cleaning agent and preparation method thereof | |
| CN102925908B (en) | Water-based normal-temperature rustproof spray cleaning agent and preparation method thereof | |
| CN102010229B (en) | Granite rust remover | |
| CN102925913A (en) | Water-based phosphor copper anode cleaning agent and preparation method thereof | |
| CN103725436A (en) | Cleaning agent | |
| CN101113524B (en) | Cleaning antirust agent and preparation method thereof | |
| CN103643226A (en) | Oil-removing and antirust cleaning liquid for steel substrate chemical copper plating | |
| CN104962943B (en) | A kind of without phosphorus water base degreasing agent and preparation method and application | |
| CN101205609A (en) | Composition for magnesium alloy surface activation | |
| CN110628519A (en) | A kind of water-based cleaning agent and its preparation method and application | |
| CN107937168A (en) | A kind of production method of environment-friendly type degreasing cleaning agent | |
| JP5295673B2 (en) | Detergent composition for surface-treated steel sheet | |
| CN106400036A (en) | Environment-friendly technology for replacing hydrochloric acid for rust removal | |
| CN104451735A (en) | Non-phosphorus cleaning agent and preparation method thereof | |
| CN106894030B (en) | Metal conditioner | |
| JP2021195622A (en) | Cleaning agent for steel sheets | |
| CN107794561A (en) | A kind of steel electrolytic degreasing powder and its preparation and application | |
| CN109097209A (en) | Environmentally friendly water-free dry washing agent and preparation method thereof | |
| CN104233337A (en) | Method for cleaning copper pendant or ornament | |
| CN108660460A (en) | A kind of high-efficiency environment friendly plays wax water and preparation method thereof | |
| JP7042199B2 (en) | Detergent composition for steel sheet | |
| CN104388216A (en) | Electronic element cleaning agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130206 Termination date: 20180908 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |