CN104629621B - 建筑用固体涂料 - Google Patents
建筑用固体涂料 Download PDFInfo
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- CN104629621B CN104629621B CN201510068049.5A CN201510068049A CN104629621B CN 104629621 B CN104629621 B CN 104629621B CN 201510068049 A CN201510068049 A CN 201510068049A CN 104629621 B CN104629621 B CN 104629621B
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- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 239000007787 solid Substances 0.000 title claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 108010010803 Gelatin Proteins 0.000 claims abstract description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000004202 carbamide Substances 0.000 claims abstract description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000159 gelatin Polymers 0.000 claims abstract description 4
- 239000008273 gelatin Substances 0.000 claims abstract description 4
- 235000019322 gelatine Nutrition 0.000 claims abstract description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 4
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims abstract description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 4
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910052613 tourmaline Inorganic materials 0.000 claims description 6
- 239000011032 tourmaline Substances 0.000 claims description 6
- 229940070527 tourmaline Drugs 0.000 claims description 6
- 229910052771 Terbium Inorganic materials 0.000 claims description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- -1 polyoxy Polymers 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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Abstract
本发明公开了一种建筑用固体涂料，包括下述重量份的组分：明胶100份，六偏磷酸钠10‑20份，环烷酸钴5‑10份，碳酸钙40‑60份，过氧化环己酮70‑80份，滑石粉10‑30份，十二烷基聚氧乙烯醚硫酸钠15‑25份，邻苯二甲酸二丁酯4‑8份，尿素35‑45份。本发明的建筑用固体涂料附着力强，贮存稳定性好，涂膜耐擦拭3000次以上，并能持久释放负离子。
Description
技术领域
本发明涉及一种涂料，尤其涉及一种建筑用固体涂料。
背景技术
涂料涂饰于物体表面能与基体材料很好粘结并形成完整而坚韧保护膜的物料，称为涂料。涂料与油漆是同一概念。油漆是人们沿用已久的习惯名称，引进我国后，就一直利用在建筑行业。涂料的作用可以概括为三个方面：保护作用，装饰作用，特殊功能作用。涂料的一般组成：包含成膜物质、颜填料、溶剂、助剂。
中国涂料产业在下游产业的推动下日益壮大，而作为其中一个分支的建筑涂料，也得到了长足的发展。统计数据显示，2011年中国建筑涂料总计产量约351.82万吨，同比增长30％以上。由此可见，中国建筑涂料产业虽然经历了2008年全球性金融危机的影响、原材料价格上涨及央行加息带来的压力，但其发展势头依然不减，且还保持着较高的增长率。
在行业政策的引导和市场的拉动下，我国建筑装修业将进入新的发展时期，建筑涂料的需求会持续增加，行业市场发展潜力巨大。另外，正在兴起的新农村建设也极大地刺激了各类建筑涂料的推广应用。由此推断，中国的建筑业至少还有10余年的稳定发展期，也将是国内建筑涂料生产企业高速发展的10年。
发明内容
本发明所要解决的技术问题是提供一种建筑用固体涂料。
一种建筑用固体涂料，包括下述重量份的组分：明胶100份，六偏磷酸钠10-20份，环烷酸钴5-10份，碳酸钙40-60份，过氧化环己酮70-80份，滑石粉10-30份，十二烷基聚氧乙烯醚硫酸钠15-25份，邻苯二甲酸二丁酯4-8份，尿素35-45份。
一种建筑用固体涂料，包括下述重量份的组分：明胶100份，六偏磷酸钠10-20份，环烷酸钴5-10份，碳酸钙40-60份，过氧化环己酮70-80份，滑石粉10-30份，十二烷基聚氧乙烯醚硫酸钠15-25份，邻苯二甲酸二丁酯4-8份，尿素35-45份，建筑用负离子粉20-40份。
优选地，所述建筑用负离子粉由下述重量份原料组成：电气石70份，氧化钕10-20份，七氧化四铽10-20份。
氧化钕，中文别名：三氧化二钕，CAS：1313-97-9。七氧化四铽，CAS：12037-01-3。
将各原料混合均匀，粉碎，即可制得所述建筑用固体涂料。进一步地，粉碎步骤可以采用球磨机进行粉碎20-60分钟。
本发明的建筑用固体涂料附着力强，贮存稳定性好，涂膜耐擦拭3000次以上，并能持久释放负离子。
具体实施方式
下面将结合本发明的实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。
分别按表1对应各实施例或对比例数据称取各原料，混合均匀，采用球磨机进行粉碎40分钟，控制粒度D50≤0.5微米，即可制得所述建筑用固体涂料。电气石选用石家庄托玛琳矿产品有限公司生产的电气石粉。
表1：建筑用固体涂料配方表单位：公斤
测试例：
取1000克本发明制得的建筑用固体涂料置于密封箱中均匀摊开，密闭24小时，用美国Alphalab公司生产的AIC-1000负离子检测仪每隔1小时检测一次，每次取20个数据，求得各数据的平均值作为最终检测结果，测试数据见表2。
表2：负离子发生量测试数据表
| 负离子发生量，个/cm3 | |
| 实施例1 | 585 |
| 实施例2 | 495 |
| 实施例3 | 540 |
| 实施例4 | 25 |
比较实施例1与实施例2-3，电气石与氧化钕和七氧化四铽复配，效果明显优于电气石与氧化钕复配或电气石与七氧化四铽复配。
实施例4，产品附着力100％，贮存稳定性12个月，涂膜耐擦拭3100次。
本发明的建筑用固体涂料附着力强，贮存稳定性好，涂膜耐擦拭3000次以上，并能持久释放负离子。
Claims (1)
1.一种建筑用固体涂料，其特征在于，包括下述重量份的组分：明胶100份，六偏磷酸钠10-20份，环烷酸钴5-10份，碳酸钙40-60份，过氧化环己酮70-80份，滑石粉10-30份，十二烷基聚氧乙烯醚硫酸钠15-25份，邻苯二甲酸二丁酯4-8份，尿素35-45份，建筑用负离子粉20-40份；
所述建筑用负离子粉由下述重量份原料组成：电气石70份，氧化钕10-20份，七氧化四铽10-20份。
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| CN201510068049.5A CN104629621B (zh) | 2015-02-10 | 2015-02-10 | 建筑用固体涂料 |
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| CN104629621A CN104629621A (zh) | 2015-05-20 |
| CN104629621B true CN104629621B (zh) | 2017-02-22 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035122A (zh) * | 1988-02-09 | 1989-08-30 | 李镇亚 | 一种固体建筑涂料 |
| CN1386550A (zh) * | 2002-07-08 | 2002-12-25 | 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 | 能高效产生空气负离子的电气石复合粉体及其制备方法 |
| CN1958690A (zh) * | 2005-10-31 | 2007-05-09 | 吴志峰 | 改进型固体涂料 |
| CN101993595A (zh) * | 2009-08-13 | 2011-03-30 | 徐成龙 | 一种无毒抗菌负离子材料 |
| CN104119797A (zh) * | 2014-08-06 | 2014-10-29 | 苏州靖羽新材料有限公司 | 一种建筑用固体涂料 |
-
2015
- 2015-02-10 CN CN201510068049.5A patent/CN104629621B/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035122A (zh) * | 1988-02-09 | 1989-08-30 | 李镇亚 | 一种固体建筑涂料 |
| CN1386550A (zh) * | 2002-07-08 | 2002-12-25 | 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 | 能高效产生空气负离子的电气石复合粉体及其制备方法 |
| CN1958690A (zh) * | 2005-10-31 | 2007-05-09 | 吴志峰 | 改进型固体涂料 |
| CN101993595A (zh) * | 2009-08-13 | 2011-03-30 | 徐成龙 | 一种无毒抗菌负离子材料 |
| CN104119797A (zh) * | 2014-08-06 | 2014-10-29 | 苏州靖羽新材料有限公司 | 一种建筑用固体涂料 |
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