CN104576863A - High-brightness light emitting diode and fabricating method thereof - Google Patents

High-brightness light emitting diode and fabricating method thereof Download PDF

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Publication number
CN104576863A
CN104576863A CN201510061354.1A CN201510061354A CN104576863A CN 104576863 A CN104576863 A CN 104576863A CN 201510061354 A CN201510061354 A CN 201510061354A CN 104576863 A CN104576863 A CN 104576863A
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magnesium
contact point
resilient coating
high brightness
gap current
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CN104576863B (en
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马祥柱
白继锋
杨凯
李俊承
张双翔
张银桥
王向武
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Yangzhou Changelight Co Ltd
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Yangzhou Changelight Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/14Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0095Post-treatment of devices, e.g. annealing, recrystallisation or short-circuit elimination
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/025Physical imperfections, e.g. particular concentration or distribution of impurities
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • H01L33/22Roughened surfaces, e.g. at the interface between epitaxial layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/40Materials therefor
    • H01L33/42Transparent materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2933/00Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
    • H01L2933/0008Processes
    • H01L2933/0016Processes relating to electrodes

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

The invention discloses a high-brightness light emitting diode and a fabricating method thereof, and belongs to the technical field of photoelectrons. The fabricating method comprises the following steps: when a P-GaP current expanding layer of an epitaxial wafer is fabricated, using magnesium as a doping element; when a pattered contact is fabricated, roughening the surface of the P-GaP current expanding layer except for the contact point by adopting a wet process, wherein the roughening depth is 200-400nm; fabricating a first electrode behind a deposition material on one surface of the P-GaP current expanding layer with the pattered contact point is a transparent conductive film of indium tin oxide; and fabricating a second electrode on the other surface of a permanent substrate GaAs. Because the transparent conductive film of indium tin oxide has a good current expanding capability, the electrode is used for uniformly injecting a current into the surface of the whole chip by virtue of the transparent film of indium tin oxide and then the contact point, the accumulation of the current below the electrode is reduced, the invalid injection of the current is reduced, and the light emitting efficiency of a product is improved.

Description

A kind of high brightness LED and manufacture method thereof
Technical field
The invention belongs to photoelectron technical field, particularly the manufacturing technology field of AlGaInP quaternary series LED.
Background technology
Quaternary system AlGaInP is a kind of semi-conducting material with direct broad-band gap, has been widely used in the preparation of multiple opto-electronic device.Due to material emission wave band can the ruddiness of covering visible light to yellow green wave band, the visible light emitting diode made thus is subject to extensive concern.
Traditional AlGaInP light-emitting diode in vertical structure by thick P-GaP current extending carry out extending transversely after by pulse current injectingt luminous zone, but because P-GaP current expansion is limited in one's ability, base part near zone current density is higher, the zone current density that ionization electrode is far away is lower, cause overall current injection efficiency on the low side, thus reduce the light extraction efficiency of light-emitting diode.
High brightness reversed polarity AlGaInP chip adopts bonding technology to realize substrate displacement, the silicon substrate (thermal conductivity of silicon is about 1.5W/K.cm) using good in thermal property replaces gallium arsenide substrate (thermal conductivity of GaAs is about 0.8W/K.cm), chip has more low-heat resistance, and heat dispersion is better.The Omni-directional reflector technology of high reflectance is adopted to improve reflection efficiency.Adopt surface texture technology to improve the total reflection of chip and encapsulating material interface, brightness can be higher.But because making step is various, technique is very complicated, and cause cost of manufacture higher, rate of finished products is low.
Summary of the invention
The present invention seeks to propose a kind of high brightness LED that can promote light-emitting diode light extraction efficiency.
Technical solution of the present invention is: set gradually N-GaAs transition zone, AlAs/AlGaAs reflector, N-AlGaInP lower limit layer, MQW multiple quantum well active layer, P-AlGaInP upper limiting layer, P-GaInP resilient coating, magnesium-doped P-GaP current extending, indium tin oxide transparent film and the first electrode in the one side of permanent substrate GaAs, second electrode is set at the another side of permanent substrate GaAs, it is characterized in that arranging patterned contact point between described magnesium-doped P-GaP current extending and indium tin oxide transparent film.
Because indium tin oxide transparent film has good current expansion ability, uniform current by this indium tin oxide transparent film, then is injected into whole chip surface by contact point by electrode, thus reduces electric current the gathering of side under the electrodes, decrease the invalid injection of electric current, improve luminous efficiency.
The thickness of magnesium-doped P-GaP current extending of the present invention is 2000nm ~ 4000nm.
Wherein, in described magnesium-doped P-GaP current extending, the doping content close to the magnesium of resilient coating is 4 × 10 17cm -3~ 8 × 10 17cm -3, the doping content away from the magnesium of resilient coating is 8 × 10 17cm -3~ 1 × 10 19cm -3, the doping depth away from the magnesium of resilient coating is 300nm ~ 500nm.
Namely concentration magnesium-doped in the magnesium-doped P-GaP current extending longitudinally distribution in staged, the doping content more close to the magnesium of resilient coating is lower.Its role is to, the region that longitudinal concentration adopts staged distribution can ensure that surface is roughened still can form certain electricity with indium tin oxide and contact, and alleviates contact point contact.P-GaP close to resilient coating does not need the contact that just can be formed of adulterating, and top layer needs to form electricity contact, so need high doping content with indium tin oxide.
Doping content close to the magnesium of resilient coating is 4 × 10 17cm -3~ 8 × 10 17cm -3, can ensure that P-GaP has good current expansion ability; Doping content away from the magnesium of resilient coating is 8 × 10 17cm -3~ 1 × 10 19cm -3, same P-GaP can be guaranteed and form good electricity contact; Away from 300nm ~ 500nm doping depth of the magnesium of resilient coating, can ensure still can form good electricity contact, to alleviate the pressure of contact point pulse current injectingt with P-GaP after alligatoring.
In addition, the thickness of indium tin oxide transparent film of the present invention is 250 ~ 300nm.This thickness is the best optical thickness being played enhanced shine by the corresponding ruddiness of optical computing gained.
Contact point of the present invention is cylindrical, and diameter is 3 ~ 5 μm, is highly 200 ~ 400nm.The cylindrical wet processing that is easy to is implemented, and not easily by lateral erosion, diameter 3 ~ 5 μm, is highly that 200 ~ 400nm optimizes preferred process window for contrast, under the prerequisite ensureing enough electricity contacts area, does not affect bright dipping.
Another object of the present invention proposes a kind of manufacture method that can realize the above-mentioned high brightness LED of high finished product rate and low cost.
Manufacture method of the present invention comprises the following steps:
1) epitaxial wafer is made: at one side epitaxial growth N-GaAs resilient coating, AlAs/AlGaAs reflector, N-AlGaInP lower limit layer, MQW multiple quantum well active layer, P-AlGaInP upper limiting layer, P-GaInP resilient coating, the P-GaP current extending successively of permanent substrate GaAs;
2) graphical contact point is made on epitaxial wafer surface;
3) at laminated whole the deposit transparent conductive film of the P-GaP current expansion with graphical contact point;
4) on transparent conductive film, the first electrode is made;
5) the second electrode is made at the another side of permanent substrate GaAs;
6) RTA is adopted to carry out annealing in process;
The invention is characterized in:
When making the P-GaP current extending of epitaxial wafer, take magnesium as doped chemical;
While the graphical contact point of making, the P-GaP current extending surface beyond butt contact adopts wet method to carry out roughening treatment, and the alligatoring degree of depth is 200 ~ 400nm;
The material of deposit transparent conductive film is indium tin oxide.
The P-GaP current extending making contact point that the present invention has staged doping content forms good ohmic contact with indium tin oxide, the alligatoring degree of depth of certain depth is guaranteed indium tin oxide can not be too high with the contact berrier in alligatoring face, thus change the distribution of pulse current injectingt, effective motor current injection efficiency, improve the luminous intensity of light-emitting diode, highly doped regions is made into patterned contact point, ohmic contact is formed with indium and tin oxide film, surface roughening process is carried out by wet solution in other regions of contact point, reduce the generation of P-GaP surface total reflection, promote light extraction efficiency.Electric current flows into indium and tin oxide film layer through the first electrode, indium and tin oxide film layer lateral resistance is less than the contact resistance of same P-GaP, electric current first carry out on indium tin oxide extending transversely after, be injected in P-GaP current extending through equally distributed contact point, and then be with active layer, motor current injection efficiency greatly, improves the luminous intensity of light-emitting diode.Simultaneously because technique is simple, have traditional structure light-emitting diode cost low, the advantage that yield is high, suitable batchization is produced, and is beneficial to the product obtaining high-quality, low cost.
In addition, in order to ensure that indium tin oxide forms good electricity contact with P-GaP, ensure that substrate GaAs forms good electricity contact with the second electrode, RTA annealing temperature of the present invention is 350 ~ 450 DEG C, annealing time 5 ~ 20s.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of finished product of the present invention.
Embodiment
One, be that manufacturing step of the present invention is as follows as shown in Figure 1:
1, epitaxial wafer is made: utilize MOCVD device on a permanent substrate GaAs101 face, grow N-GaAs transition zone 102, AlAs/AlGaAs reflector 103, N-AlGaInP lower limit layer 104, MQW multiple quantum well active layer 105, P-AlGaInP upper limiting layer 106, P-GaInP resilient coating 107, magnesium-doped P-GaP current extending 108 successively.
Wherein magnesium-doped P-GaP current extending 108 preferred thickness 3000nm, doped chemical is magnesium (Mg), to guarantee to form good ohmic contact, the top layer doping content longitudinally distribution in staged: the doping content close to the magnesium of resilient coating is 7 × 10 17cm -3, away from the doping content of the magnesium of resilient coating (i.e. top layer) from 8 × 10 17cm -3to 1 × 10 19cm -3, top layer doping depth is 400nm.
2, utilize 511 cleaning fluid cleaning P-GaP current extendings 108, spin coating positive photoresist on P-GaP current extending 108, by exposure, development, produces circular pattern.After playing glue by plasma again, utilize the acid iodide that volume ratio is 1:5:5: hydrofluoric acid: glacial acetic acid mixed liquor, alligatoring 90s, alligatoring goes out the rough morphology of surface uniform, and the alligatoring degree of depth is 200 ~ 400nm.Produce patterned contact point 110, by removing photoresist, liquid removes photomask surface glue simultaneously.That is, protected with photoresist in the region prepared as contact point 110, wet method alligatoring is carried out in other regions, should both realize simultaneously.
Patterned contact point 110 to be equally distributedly cylindrically made up of multiple, and each columniform diameter is 3 μm, is highly 200nm.
3, sample good for alligatoring is immersed acetone soln and carry out ultrasonic cleaning 10min, adopt electron beam evaporation plating mode, at the indium tin oxide transparent film 109 that the magnesium-doped P-GaP current extending 108 of alligatoring and contact point 110 surface deposition thickness are 250nm, indium tin oxide transparent film 109 transmitance ensures that, more than 95%, square resistance is within 10.
4, the sample of complete for evaporation tin indium oxide is immersed acetone soln and carry out ultrasonic cleaning 10min, spin coating negative photoresist, through overbaking, exposure, baking, produces electrode pattern after development, after sample being spin-dried for by high speed spinner, adopt electron beam evaporation plating mode evaporation first electrode 111, electrode material is Cr, Ti, Pt, Au, and thickness is respectively 30nm, 50nm, 100nm, 3000nm.
5, by grinder, chip is ground to 200 μm of thickness.
6, ground sample is immersed acetone soln and carry out ultrasonic cleaning 10min, adopt the mode of electron beam evaporation plating to make the second electrode 112 at the back side of substrate GaAs101, electrode material is AuGe, Au, and thickness is respectively 100nm, 20nm.
7, RTA annealing furnace is adopted to anneal to chip, annealing temperature 400 DEG C, annealing time 10s.Namely the making of device is completed.
Two, the product structure feature made:
As shown in Figure 1, a permanent substrate GaAs101 one side is disposed with N-GaAs transition zone 102, AlAs/AlGaAs reflector 103, N-AlGaInP lower limit layer 104, MQW multiple quantum well active layer 105, P-AlGaInP upper limiting layer 106, P-GaInP resilient coating 107, P-GaP current extending 108, transparency conducting layer 109, first electrode 111, the second electrode 112 is set at the another side of a permanent substrate GaAs101.
Due to the current expansion ability that Indium-tin Oxide Transparent Conductive Film is good, uniform current by tin indium oxide, then is injected into whole chip surface by contact point by electrode, thus reduces electric current the gathering of side under the electrodes, decrease the invalid injection of electric current, improve luminous efficiency.

Claims (10)

1. a high brightness LED, N-GaAs transition zone, AlAs/AlGaAs reflector, N-AlGaInP lower limit layer, MQW multiple quantum well active layer, P-AlGaInP upper limiting layer, P-GaInP resilient coating, magnesium-doped P-GaP current extending, indium tin oxide transparent film and the first electrode is set gradually in the one side of permanent substrate GaAs, second electrode is set at the another side of permanent substrate GaAs, it is characterized in that arranging patterned contact point between described magnesium-doped P-GaP current extending and indium tin oxide transparent film.
2. high brightness LED according to claim 1, is characterized in that the thickness of described magnesium-doped P-GaP current extending is 2000nm ~ 4000nm.
3. high brightness LED according to claim 1 or 2, is characterized in that in described magnesium-doped P-GaP current extending, the doping content close to the magnesium of resilient coating is 4 × 10 17cm -3~ 8 × 10 17cm -3, the doping content away from the magnesium of resilient coating is 8 × 10 17cm -3~ 1 × 10 19cm -3, the doping depth away from the magnesium of resilient coating is 300nm ~ 500nm.
4. high brightness LED according to claim 1, is characterized in that the thickness of described indium tin oxide transparent film is 250 ~ 300nm.
5. high brightness LED according to claim 1, it is characterized in that described contact point is cylindrical, diameter is 3 ~ 5 μm, is highly 200 ~ 400nm.
6. the manufacture method of high brightness LED as claimed in claim 1, comprises the following steps:
1) epitaxial wafer is made: at one side epitaxial growth N-GaAs resilient coating, AlAs/AlGaAs reflector, N-AlGaInP lower limit layer, MQW multiple quantum well active layer, P-AlGaInP upper limiting layer, P-GaInP resilient coating, the P-GaP current extending successively of permanent substrate GaAs;
2) graphical contact point is made on epitaxial wafer surface;
3) at laminated whole the deposit transparent conductive film of the P-GaP current expansion with graphical contact point;
4) on transparent conductive film, the first electrode is made;
5) the second electrode is made at the another side of permanent substrate GaAs;
6) RTA is adopted to carry out annealing in process;
It is characterized in that:
When making the P-GaP current extending of epitaxial wafer, take magnesium as doped chemical;
While the graphical contact point of making, the P-GaP current extending surface beyond butt contact adopts wet method to carry out roughening treatment, and the alligatoring degree of depth is 200 ~ 400nm;
The material of deposit transparent conductive film is indium tin oxide.
7. the manufacture method of high brightness LED according to claim 5, is characterized in that: in described magnesium-doped P-GaP current extending, the doping content close to the magnesium of resilient coating is 4 × 10 17cm -3~ 8 × 10 17cm -3, the doping content away from the magnesium of resilient coating is 8 × 10 17cm -3~ 1 × 10 19cm -3, the doping depth away from the magnesium of resilient coating is 300nm ~ 500nm.
8. the manufacture method of high brightness LED according to claim 5, is characterized in that: the thickness of described indium tin oxide transparent film is 250 ~ 300nm.
9. the manufacture method of high brightness LED according to claim 5, it is characterized in that: described contact point is cylindrical, diameter is 3 ~ 5 μm, is highly 200 ~ 400nm.
10. the manufacture method of high brightness LED according to claim 5, is characterized in that: described RTA annealing temperature is 350 ~ 450 DEG C, annealing time 5 ~ 20s.
CN201510061354.1A 2015-02-06 2015-02-06 A kind of high brightness LED and its manufacture method Active CN104576863B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105428485A (en) * 2015-12-21 2016-03-23 扬州乾照光电有限公司 GaP surface roughened AlGaInP-based LED and manufacturing method therefor
CN105932131A (en) * 2016-06-22 2016-09-07 扬州乾照光电有限公司 Vertical structure AlGaInP-based light-emitting diode and manufacturing method thereof
CN106098917A (en) * 2016-08-24 2016-11-09 扬州乾照光电有限公司 A kind of patterning high brightness AlGaInP light emitting diode and manufacture method thereof
CN108269895A (en) * 2017-12-22 2018-07-10 南昌凯迅光电有限公司 A kind of ito thin film LED chip and its manufacturing method
CN108321264A (en) * 2017-12-22 2018-07-24 南昌凯迅光电有限公司 High brightness ito thin film LED chip and its manufacturing method
CN109285924A (en) * 2018-12-10 2019-01-29 合肥彩虹蓝光科技有限公司 A kind of manufacturing method of semiconductor chip
CN110197790A (en) * 2019-06-17 2019-09-03 苏州长瑞光电有限公司 A kind of method for annealing of Group III-V semiconductor wafer
CN111180561A (en) * 2019-12-27 2020-05-19 华灿光电(苏州)有限公司 AlGaInP-based light emitting diode chip and manufacturing method thereof

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CN104300065B (en) * 2014-10-14 2017-01-25 扬州乾照光电有限公司 Light-emitting diode with novel extension electrode structure and manufacturing method thereof
CN104319332A (en) * 2014-10-29 2015-01-28 华灿光电(苏州)有限公司 Light-emitting diode and manufacturing method thereof
CN204441319U (en) * 2015-02-06 2015-07-01 扬州乾照光电有限公司 A kind of high brightness LED

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Publication number Priority date Publication date Assignee Title
CN105428485A (en) * 2015-12-21 2016-03-23 扬州乾照光电有限公司 GaP surface roughened AlGaInP-based LED and manufacturing method therefor
CN105428485B (en) * 2015-12-21 2019-06-21 扬州乾照光电有限公司 The AlGaInP base LED and its manufacturing method of GaP roughing in surface
CN105932131A (en) * 2016-06-22 2016-09-07 扬州乾照光电有限公司 Vertical structure AlGaInP-based light-emitting diode and manufacturing method thereof
CN106098917A (en) * 2016-08-24 2016-11-09 扬州乾照光电有限公司 A kind of patterning high brightness AlGaInP light emitting diode and manufacture method thereof
CN108269895A (en) * 2017-12-22 2018-07-10 南昌凯迅光电有限公司 A kind of ito thin film LED chip and its manufacturing method
CN108321264A (en) * 2017-12-22 2018-07-24 南昌凯迅光电有限公司 High brightness ito thin film LED chip and its manufacturing method
CN109285924A (en) * 2018-12-10 2019-01-29 合肥彩虹蓝光科技有限公司 A kind of manufacturing method of semiconductor chip
CN110197790A (en) * 2019-06-17 2019-09-03 苏州长瑞光电有限公司 A kind of method for annealing of Group III-V semiconductor wafer
CN111180561A (en) * 2019-12-27 2020-05-19 华灿光电(苏州)有限公司 AlGaInP-based light emitting diode chip and manufacturing method thereof
CN111180561B (en) * 2019-12-27 2021-06-29 华灿光电(苏州)有限公司 AlGaInP-based light emitting diode chip and manufacturing method thereof

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