CN104562648A - Emulsion paraffin for textile - Google Patents
Emulsion paraffin for textile Download PDFInfo
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- CN104562648A CN104562648A CN201510021758.8A CN201510021758A CN104562648A CN 104562648 A CN104562648 A CN 104562648A CN 201510021758 A CN201510021758 A CN 201510021758A CN 104562648 A CN104562648 A CN 104562648A
- Authority
- CN
- China
- Prior art keywords
- parts
- weaving
- paraffin
- polyacrylamide
- emulsified wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012188 paraffin wax Substances 0.000 title claims abstract description 15
- 239000004753 textile Substances 0.000 title abstract description 6
- 239000000839 emulsion Substances 0.000 title abstract 5
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 25
- 238000009941 weaving Methods 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 18
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 18
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 18
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000008116 calcium stearate Substances 0.000 claims abstract description 9
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229940099259 vaseline Drugs 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000001993 wax Substances 0.000 claims description 30
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 15
- 239000005018 casein Substances 0.000 claims description 15
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 15
- 235000021240 caseins Nutrition 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 10
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004744 fabric Substances 0.000 abstract description 13
- 239000000835 fiber Substances 0.000 abstract description 5
- 229920000742 Cotton Polymers 0.000 abstract description 2
- -1 stearic acid monoglycerides Chemical class 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract 1
- 102000011632 Caseins Human genes 0.000 abstract 1
- 108010076119 Caseins Proteins 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 235000005607 chanvre indien Nutrition 0.000 abstract 1
- 238000009990 desizing Methods 0.000 abstract 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 abstract 1
- 239000011487 hemp Substances 0.000 abstract 1
- 229940074096 monoolein Drugs 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 229940080237 sodium caseinate Drugs 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 3
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 241000237502 Ostreidae Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses emulsion paraffin for textile. The emulsion paraffin is prepared by following raw materials in parts by weight: 100 to 120 parts of paraffin, 10 to 15 parts of calcium stearate, 3 to 6 parts of carboxymethylcellulose, 3 to 6 parts of stearic acid monoglycerides, 6 to 12 parts of sorbitol mono-olein, 2 to 5 parts of Vaseline, 3 to 6 parts of crylic acid, 20 to 40 parts of ethanol, 0.5 to 1.5 parts of triethylhexyl phosphate, 12 to 15 parts of an emulsifier and 180 to 200 parts of water, wherein the emulsifier is a mixture of sodium dodecyl sulfate, Arabic gum, sodium caseinate and polyacrylamide. The emulsion paraffin is suitable for various fiber fabrics such as chemical fibers, blended fabric, silk, pure cotton and hemp, the weaving friction coefficient can be effectively reduced, the weaving end broken rate is reduced, the opening of the fabric is clear, the first-grade ratio of the cloth can be increased, and the efficiency of a weaving machine can be greatly improved; moreover, the emulsion paraffin is easy in desizing, suitable for printing and little in consumption, and the cost can be reduced by 10 to 12 Yuan for each bolt of cloth.
Description
Technical field:
The present invention relates to a kind of weaving emulsified wax, belong to industrial chemical field.
Background technology:
Emulsified wax is a kind of very important textile auxiliary, and it is widely used in textile industry.Fabric is after padding emulsified wax solution and baking, yam surface forms lubricating layer with the brilliant particulate of wax, make the lubricity of fabric fibre and flexibility be improved significantly, thus decrease the defect easily going out pinprick when making, decrease the phenomenon that fabric face easily fluffs, enhance the smoothness of fabric face and sewing line.But for many years, the quality of China's emulsified wax is always unsatisfactory, shows as particle thick, less stable more, after standing time, slightly length just there will be layering, separate out the phenomenon of wax.
Summary of the invention:
The present invention seeks to, be used for making up the deficiencies in the prior art, and a kind of weaving emulsified wax is provided.
To achieve these goals, technical scheme of the present invention is as follows:
A kind of weaving emulsified wax, be made up of the raw material of following parts by weight: paraffin 100-120 part, calcium stearate 10-15 part, carboxymethyl cellulose 3-6 part, stearic acid monoglyceride 3-6 part, sorbierite list olein 6-12 part, vaseline 2-5 part, acrylic acid 3-6 part, ethanol 20-40 part, triethyl group hexyl phosphoric acid 0.5-1.5 part, emulsifying agent 12-15 part and water 180-200 part, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Described one weaving emulsified wax, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 20-30 part, Arabic gum 4-8 part, casein sodium 2-6 part and polyacrylamide 12-24 part.
Described one weaving emulsified wax, the weight ratio of Arabic gum and polyacrylamide is 1:3.
Described one weaving emulsified wax, the weight ratio of described stearic acid monoglyceride and sorbierite list olein is 1:2.
Described one weaving emulsified wax, the gross weight of described second alcohol and water and the weight ratio of paraffin are 2:1.
The using method of emulsified wax: after warp sizing is dried, waxed by wax roller wax pan, the temperature of emulsified wax is 40-60 DEG C, and the amount of waxing is 0.6-1.2%.
Beneficial effect of the present invention is as follows:
Emulsified wax of the present invention is applicable to textile industry, is applicable to the various fabrics such as chemical fibre, blending, silk, cotton textiles, fiber crops, has good flatness, volt hair convergence and antistatic behaviour.Effectively can reduce and weave coefficient of friction, weave end breakage rate and decline, fabric openings is clear, improves cloth top-quality product rate and loom efficiency is significantly promoted, and easily destarch, be applicable to printing and dyeing, and consumption is few, every cost-saving 10-12 unit of cloth.
Emulsified wax outward appearance of the present invention is oyster white, and its average grain diameter is 0.271-0.285 μm, and dispersiveness is 0.234-0.243.With the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide for emulsifying agent, emulsify well, makes emulsified wax more stable and even by being aided with calcium stearate, carboxymethyl cellulose, stearic acid monoglyceride, sorbierite list olein, vaseline, acrylic acid, ethanol, triethyl group hexyl phosphoric acid, emulsifying agent and water.
Detailed description of the invention:
The technological means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
In the present embodiment, a kind of weaving emulsified wax, be made up of the raw material of following parts by weight: 100 parts, paraffin, calcium stearate 15 parts, carboxymethyl cellulose 6 parts, stearic acid monoglyceride 3 parts, sorbierite list olein 6 parts, 5 parts, vaseline, 6 parts, acrylic acid, ethanol 20 parts, triethyl group hexyl phosphoric acid 0.5 part, emulsifying agent 12 parts and 180 parts, water, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 20 parts, Arabic gum 4 parts, casein sodium 6 parts and polyacrylamide 12 parts.
Embodiment 2
In the present embodiment, a kind of weaving emulsified wax, be made up of the raw material of following parts by weight: 120 parts, paraffin, calcium stearate 10 parts, carboxymethyl cellulose 3 parts, stearic acid monoglyceride 6 parts, sorbierite list olein 12 parts, 2 parts, vaseline, 3 parts, acrylic acid, ethanol 40 parts, triethyl group hexyl phosphatase 11 .5 part, emulsifying agent 15 parts and 200 parts, water, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 30 parts, Arabic gum 8 parts, casein sodium 2 parts and polyacrylamide 24 parts.
Embodiment 3
In the present embodiment, a kind of weaving emulsified wax, be made up of the raw material of following parts by weight: 105 parts, paraffin, calcium stearate 13 parts, carboxymethyl cellulose 4 parts, stearic acid monoglyceride 5, sorbierite list olein 10 parts, 3 parts, vaseline, 5 parts, acrylic acid, ethanol 30 parts, triethyl group hexyl phosphoric acid 0.8 part, emulsifying agent 14 parts and 180 parts, water, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 22 parts, Arabic gum 5 parts, casein sodium 4 parts and polyacrylamide 15 parts.
Embodiment 4
In the present embodiment, a kind of weaving emulsified wax, be made up of the raw material of following parts by weight: 110 parts, paraffin, calcium stearate 11 parts, carboxymethyl cellulose 5 parts, stearic acid monoglyceride 5, sorbierite list olein 10 parts, 5 parts, vaseline, 5 parts, acrylic acid, ethanol 25 parts, triethyl group hexyl phosphatase 11 .3 part, emulsifying agent 13 parts and 195 parts, water, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 26 parts, Arabic gum 7 parts, casein sodium 5 parts and polyacrylamide 21 parts.
Embodiment 5
In the present embodiment, a kind of weaving emulsified wax, be made up of the raw material of following parts by weight: 116 parts, paraffin, calcium stearate 14 parts, carboxymethyl cellulose 4 parts, stearic acid monoglyceride 6, sorbierite list olein 12 parts, 4 parts, vaseline, 3 parts, acrylic acid, ethanol 32 parts, triethyl group hexyl phosphatase 11 .1 part, emulsifying agent 15 parts and 200 parts, water, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 25 parts, Arabic gum 5 parts, casein sodium 5 parts and polyacrylamide 15 parts.
Claims (5)
1. a weaving emulsified wax, it is characterized in that, be made up of the raw material of following parts by weight: paraffin 100-120 part, calcium stearate 10-15 part, carboxymethyl cellulose 3-6 part, stearic acid monoglyceride 3-6 part, sorbierite list olein 6-12 part, vaseline 2-5 part, acrylic acid 3-6 part, ethanol 20-40 part, triethyl group hexyl phosphoric acid 0.5-1.5 part, emulsifying agent 12-15 part and water 180-200 part, described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.
2. a kind of weaving emulsified wax according to claim 1, it is characterized in that, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 20-30 part, Arabic gum 4-8 part, casein sodium 2-6 part and polyacrylamide 12-24 part.
3. a kind of weaving emulsified wax according to claim 2, it is characterized in that, the weight ratio of Arabic gum and polyacrylamide is 1:3.
4. a kind of weaving emulsified wax according to claim 1, it is characterized in that, the weight ratio of described stearic acid monoglyceride and sorbierite list olein is 1:2.
5. a kind of weaving emulsified wax according to claim 1, it is characterized in that, the gross weight of described second alcohol and water and the weight ratio of paraffin are 2:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021758.8A CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021758.8A CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104562648A true CN104562648A (en) | 2015-04-29 |
| CN104562648B CN104562648B (en) | 2016-08-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510021758.8A Expired - Fee Related CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104562648B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107988797A (en) * | 2016-10-26 | 2018-05-04 | 上海天坛助剂有限公司 | A kind of environment-friendly water-soluble textile wax and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
| CN1570038A (en) * | 2004-04-26 | 2005-01-26 | 杨建军 | Paraffin emulsifier and its making method |
| CN101280516A (en) * | 2007-04-05 | 2008-10-08 | 上海肯多拉蜡业有限公司 | Formula and production method of textile wax |
| CN101597482A (en) * | 2009-07-06 | 2009-12-09 | 广西丰林木业集团股份有限公司 | A kind of emulsion paraffin water repellent for fiber board |
| CN102532919A (en) * | 2011-12-27 | 2012-07-04 | 深圳市乐普泰科技股份有限公司 | Nano wax emulsion and preparation method for nano wax emulsion |
| CN102876053A (en) * | 2011-07-12 | 2013-01-16 | 上海诺科生物科技有限公司 | Alkali-resisting wax emulsion composition |
| CN102978933A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Smoothing agent for spinning |
| CN103147294A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Textile wax auxiliary and preparation method thereof |
-
2015
- 2015-01-15 CN CN201510021758.8A patent/CN104562648B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
| CN1570038A (en) * | 2004-04-26 | 2005-01-26 | 杨建军 | Paraffin emulsifier and its making method |
| CN101280516A (en) * | 2007-04-05 | 2008-10-08 | 上海肯多拉蜡业有限公司 | Formula and production method of textile wax |
| CN101597482A (en) * | 2009-07-06 | 2009-12-09 | 广西丰林木业集团股份有限公司 | A kind of emulsion paraffin water repellent for fiber board |
| CN102876053A (en) * | 2011-07-12 | 2013-01-16 | 上海诺科生物科技有限公司 | Alkali-resisting wax emulsion composition |
| CN102532919A (en) * | 2011-12-27 | 2012-07-04 | 深圳市乐普泰科技股份有限公司 | Nano wax emulsion and preparation method for nano wax emulsion |
| CN102978933A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Smoothing agent for spinning |
| CN103147294A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Textile wax auxiliary and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107988797A (en) * | 2016-10-26 | 2018-05-04 | 上海天坛助剂有限公司 | A kind of environment-friendly water-soluble textile wax and preparation method thereof |
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| Publication number | Publication date |
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| CN104562648B (en) | 2016-08-31 |
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