CN104562648B - A kind of weaving emulsified wax - Google Patents
A kind of weaving emulsified wax Download PDFInfo
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- CN104562648B CN104562648B CN201510021758.8A CN201510021758A CN104562648B CN 104562648 B CN104562648 B CN 104562648B CN 201510021758 A CN201510021758 A CN 201510021758A CN 104562648 B CN104562648 B CN 104562648B
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- CN
- China
- Prior art keywords
- parts
- weaving
- emulsified wax
- emulsifying agent
- polyacrylamide
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- 238000009941 weaving Methods 0.000 title claims abstract description 24
- 239000001993 wax Substances 0.000 claims abstract description 33
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011734 sodium Substances 0.000 claims abstract description 19
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 19
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 16
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 16
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 16
- 239000005018 casein Substances 0.000 claims abstract description 15
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000021240 caseins Nutrition 0.000 claims abstract description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims abstract description 10
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000008116 calcium stearate Substances 0.000 claims abstract description 9
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 9
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229940099259 vaseline Drugs 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 Stearic acid monoglycerides Chemical class 0.000 claims description 6
- 210000000481 breast Anatomy 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims 2
- 239000003292 glue Substances 0.000 claims 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 2
- 239000008117 stearic acid Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 abstract description 18
- 239000004744 fabric Substances 0.000 abstract description 12
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 abstract description 9
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 abstract description 9
- 239000004753 textile Substances 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 238000009990 desizing Methods 0.000 abstract description 2
- 238000004043 dyeing Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- HCIQUGMKXQZZMG-UHFFFAOYSA-N ethyl hexyl hydrogen phosphate Chemical compound CCCCCCOP(O)(=O)OCC HCIQUGMKXQZZMG-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Abstract
The invention discloses a kind of weaving emulsified wax.Emulsified wax is made up of the raw material of following parts by weight: 100 120 parts of paraffin, calcium stearate 10 15 parts, carboxymethylcellulose calcium 36 parts, glycerol monostearate 36 parts, sorbitol monooleate 6 12 parts, 25 parts of vaseline, 36 parts of acrylic acid, ethanol 20 40 parts, triethyl group hexyl phosphoric acid 0.5 1.5 parts, emulsifying agent 12 15 parts and 180 200 parts of water, and described emulsifying agent is the mixture of dodecyl sodium sulfate, Arabic gum, casein sodium and polyacrylamide.The emulsified wax of the present invention is applicable to the various fabrics such as chemical fibre, blending, silk, cotton textiles, fiber crops, can effectively reduce weaving coefficient of friction, weaving end breakage rate declines, fabric openings is clear, improve cloth top-quality product rate and make loom efficiency be substantially improved, and easily desizing, it is adaptable to printing and dyeing, and consumption is few, cost-effective 10 12 yuan of every cloth.
Description
Technical field:
The present invention relates to a kind of weaving emulsified wax, belong to industrial chemical field.
Background technology:
Emulsified wax is a kind of highly important textile auxiliary, and it is widely used in textile industry
In.Fabric is after padding emulsified wax solution and baking, and yam surface forms profit with wax crystalline substance particulate
Slip layer, make the lubricity of fabric fibre and flexibility be improved significantly, thus decrease sewing
Shi Yi goes out the defect of pinprick, decreases the phenomenon that fabric face easily fluffs, and enhances fabric table
Face and the smoothness of sewing line.But for many years, the quality of China's emulsified wax is the most not to the utmost
People's will, shows as particle thick more, less stable, and standing time, slightly length arose that layering
The phenomenon of rear precipitation wax.
Summary of the invention:
The present invention seeks to, be used for making up the deficiencies in the prior art, and a kind of weaving breast is provided
Fossil waxes.
To achieve these goals, technical scheme is as follows:
A kind of weaving emulsified wax, is made up of the raw material of following parts by weight: paraffin 100-120
Part, calcium stearate 10-15 part, carboxymethylcellulose calcium 3-6 part, glycerol monostearate 3-6
Part, sorbitol monooleate 6-12 part, vaseline 2-5 part, acrylic acid 3-6 part, ethanol
20-40 part, triethyl group hexyl phosphoric acid 0.5-1.5 part, emulsifying agent 12-15 part and water 180-200
Part, described emulsifying agent is dodecyl sodium sulfate, Arabic gum, casein sodium and poly-third
The mixture of acrylamide.
Described a kind of weaving emulsified wax, the parts by weight of each component of described emulsifying agent are respectively
For dodecyl sodium sulfate 20-30 part, Arabic gum 4-8 part, casein sodium 2-6 part and
Polyacrylamide 12-24 part.
Described a kind of weaving emulsified wax, the weight ratio of Arabic gum and polyacrylamide is
1:3。
Described a kind of weaving emulsified wax, described glycerol monostearate and sorbierite list oleic acid
The weight ratio of ester is 1:2.
Described a kind of weaving emulsified wax, the gross weight of described second alcohol and water and the weight of paraffin
Amount ratio is 2:1.
The using method of emulsified wax: after warp sizing is dried, waxed by wax roller wax pan, breast
The temperature of fossil waxes is 40-60 DEG C, and the amount of waxing is 0.6-1.2%.
Beneficial effects of the present invention is as follows:
The emulsified wax of the present invention is applicable to textile industry, it is adaptable to chemical fibre, blending, silk,
The various fabrics such as textile, numb, have a good flatness, volt hair convergence and antistatic
Property.Can effectively reduce weaving coefficient of friction, weaving end breakage rate declines, and fabric openings is clear, carries
High cloth top-quality product rate also makes loom efficiency be substantially improved, and easily desizing, it is adaptable to printing and dyeing,
And consumption is few, every cloth cost-effective 10-12 unit.
The emulsified wax outward appearance of the present invention is milky, and its average grain diameter is 0.271-0.285 μ
M, dispersiveness is 0.234-0.243.With dodecyl sodium sulfate, Arabic gum, caseinic acid
The mixture of sodium and polyacrylamide is emulsifying agent, and emulsifying effectiveness is good, by be aided with calcium stearate,
Carboxymethylcellulose calcium, glycerol monostearate, sorbitol monooleate, vaseline, acrylic acid,
Ethanol, triethyl group hexyl phosphoric acid, emulsifying agent and water make emulsified wax more stable and uniform.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and be prone to effect
Understand and understand, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
In the present embodiment, a kind of weaving emulsified wax, it is made up of the raw material of following parts by weight:
100 parts of paraffin, calcium stearate 15 parts, carboxymethylcellulose calcium 6 parts, glycerol monostearate 3
Part, sorbitol monooleate 6 parts, 5 parts of vaseline, 6 parts of acrylic acid, ethanol 20 parts,
Triethyl group hexyl phosphoric acid 0.5 part, emulsifying agent 12 parts and 180 parts of water, described emulsifying agent is ten
The mixture of dialkyl sulfonates, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 20
Part, Arabic gum 4 parts, casein sodium 6 parts and polyacrylamide 12 parts.
Embodiment 2
In the present embodiment, a kind of weaving emulsified wax, it is made up of the raw material of following parts by weight:
120 parts of paraffin, calcium stearate 10 parts, carboxymethylcellulose calcium 3 parts, glycerol monostearate 6
Part, sorbitol monooleate 12 parts, 2 parts of vaseline, 3 parts of acrylic acid, ethanol 40 parts,
Triethyl group hexyl phosphatase 11 .5 part, emulsifying agent 15 parts and 200 parts of water, described emulsifying agent is ten
The mixture of dialkyl sulfonates, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 30
Part, Arabic gum 8 parts, casein sodium 2 parts and polyacrylamide 24 parts.
Embodiment 3
In the present embodiment, a kind of weaving emulsified wax, it is made up of the raw material of following parts by weight:
105 parts of paraffin, calcium stearate 13 parts, carboxymethylcellulose calcium 4 parts, glycerol monostearate 5,
Sorbitol monooleate 10 parts, 3 parts of vaseline, 5 parts of acrylic acid, ethanol 30 parts, three
Ethylhexyl phosphoric acid 0.8 part, emulsifying agent 14 parts and 180 parts of water, described emulsifying agent is 12
The mixture of sodium alkyl sulfonate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 22
Part, Arabic gum 5 parts, casein sodium 4 parts and polyacrylamide 15 parts.
Embodiment 4
In the present embodiment, a kind of weaving emulsified wax, it is made up of the raw material of following parts by weight:
110 parts of paraffin, calcium stearate 11 parts, carboxymethylcellulose calcium 5 parts, glycerol monostearate 5,
Sorbitol monooleate 10 parts, 5 parts of vaseline, 5 parts of acrylic acid, ethanol 25 parts, three
Ethylhexyl phosphoric acid 1.3 parts, emulsifying agent 13 parts and 195 parts of water, described emulsifying agent is 12
The mixture of sodium alkyl sulfonate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 26
Part, Arabic gum 7 parts, casein sodium 5 parts and polyacrylamide 21 parts.
Embodiment 5
In the present embodiment, a kind of weaving emulsified wax, it is made up of the raw material of following parts by weight:
116 parts of paraffin, calcium stearate 14 parts, carboxymethylcellulose calcium 4 parts, glycerol monostearate 6,
Sorbitol monooleate 12 parts, 4 parts of vaseline, 3 parts of acrylic acid, ethanol 32 parts, three
Ethylhexyl phosphoric acid 1.1 parts, emulsifying agent 15 parts and 200 parts of water, described emulsifying agent is 12
The mixture of sodium alkyl sulfonate, Arabic gum, casein sodium and polyacrylamide.
Wherein, the parts by weight of each component of described emulsifying agent are respectively dodecyl sodium sulfate 25
Part, Arabic gum 5 parts, casein sodium 5 parts and polyacrylamide 15 parts.
Claims (5)
1. a weaving emulsified wax, it is characterised in that by the raw material system of following parts by weight
Become: paraffin 100-120 part, calcium stearate 10-15 part, carboxymethylcellulose calcium 3-6 part,
Stearic acid monoglycerides 3-6 part, sorbitol monooleate 6-12 part, vaseline 2-5 part,
Acrylic acid 3-6 part, ethanol 20-40 part, triethyl group hexyl phosphoric acid 0.5-1.5 part, breast
Agent 12-15 part and water 180-200 part, described emulsifying agent be dodecyl sodium sulfate, Ah
Draw the mixture of primary glue, casein sodium and polyacrylamide.
A kind of weaving emulsified wax the most according to claim 1, it is characterised in that
The parts by weight of each component of described emulsifying agent be respectively dodecyl sodium sulfate 20-30 part, Ah
Draw primary glue 4-8 part, casein sodium 2-6 part and polyacrylamide 12-24 part.
A kind of weaving emulsified wax the most according to claim 2, it is characterised in that
The weight ratio of Arabic gum and polyacrylamide is 1:3.
A kind of weaving emulsified wax the most according to claim 1, it is characterised in that
The weight ratio of described stearic acid monoglycerides and sorbitol monooleate is 1:2.
A kind of weaving emulsified wax the most according to claim 1, it is characterised in that
The gross weight of described second alcohol and water and the weight ratio of paraffin are 2:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021758.8A CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021758.8A CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104562648A CN104562648A (en) | 2015-04-29 |
| CN104562648B true CN104562648B (en) | 2016-08-31 |
Family
ID=53079670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510021758.8A Expired - Fee Related CN104562648B (en) | 2015-01-15 | 2015-01-15 | A kind of weaving emulsified wax |
Country Status (1)
| Country | Link |
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| CN (1) | CN104562648B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107988797A (en) * | 2016-10-26 | 2018-05-04 | 上海天坛助剂有限公司 | A kind of environment-friendly water-soluble textile wax and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
| CN1570038A (en) * | 2004-04-26 | 2005-01-26 | 杨建军 | Paraffin emulsifier and its making method |
| CN101280516A (en) * | 2007-04-05 | 2008-10-08 | 上海肯多拉蜡业有限公司 | Formula and production method of textile wax |
| CN101597482A (en) * | 2009-07-06 | 2009-12-09 | 广西丰林木业集团股份有限公司 | A kind of emulsion paraffin water repellent for fiber board |
| CN102532919A (en) * | 2011-12-27 | 2012-07-04 | 深圳市乐普泰科技股份有限公司 | Nano wax emulsion and preparation method for nano wax emulsion |
| CN102876053A (en) * | 2011-07-12 | 2013-01-16 | 上海诺科生物科技有限公司 | Alkali-resisting wax emulsion composition |
| CN102978933A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Smoothing agent for spinning |
| CN103147294A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Textile wax auxiliary and preparation method thereof |
-
2015
- 2015-01-15 CN CN201510021758.8A patent/CN104562648B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
| CN1570038A (en) * | 2004-04-26 | 2005-01-26 | 杨建军 | Paraffin emulsifier and its making method |
| CN101280516A (en) * | 2007-04-05 | 2008-10-08 | 上海肯多拉蜡业有限公司 | Formula and production method of textile wax |
| CN101597482A (en) * | 2009-07-06 | 2009-12-09 | 广西丰林木业集团股份有限公司 | A kind of emulsion paraffin water repellent for fiber board |
| CN102876053A (en) * | 2011-07-12 | 2013-01-16 | 上海诺科生物科技有限公司 | Alkali-resisting wax emulsion composition |
| CN102532919A (en) * | 2011-12-27 | 2012-07-04 | 深圳市乐普泰科技股份有限公司 | Nano wax emulsion and preparation method for nano wax emulsion |
| CN102978933A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Smoothing agent for spinning |
| CN103147294A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Textile wax auxiliary and preparation method thereof |
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| CN104562648A (en) | 2015-04-29 |
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