CN104559595A - Spraying waterborne wood primer and preparation method thereof - Google Patents

Spraying waterborne wood primer and preparation method thereof Download PDF

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Publication number
CN104559595A
CN104559595A CN201410826237.5A CN201410826237A CN104559595A CN 104559595 A CN104559595 A CN 104559595A CN 201410826237 A CN201410826237 A CN 201410826237A CN 104559595 A CN104559595 A CN 104559595A
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CN
China
Prior art keywords
priming paint
wooden ware
aqueous wooden
spraying
ware priming
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410826237.5A
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Chinese (zh)
Inventor
洪杰
何玲玲
张伟
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Skshu Paint Co Ltd
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Skshu Paint Co Ltd
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Priority to CN201410826237.5A priority Critical patent/CN104559595A/en
Publication of CN104559595A publication Critical patent/CN104559595A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to spraying waterborne wood primer and a preparation method thereof. The spraying waterborne wood primer is prepared from the following components in parts by weight: emulsion, a waterborne multifunctional additive, a film-forming additive, a defoamer, a substrate wetter, an anti-freezer, a preservative, a thickener and water, wherein the emulsion is pure acrylate copolymer. The spraying waterborne wood primer prepared with the method can not only remove formaldehyde in artificial boards but also prevent release of formaldehyde.

Description

Aqueous wooden ware priming paint of spraying and preparation method thereof
Technical field
The present invention relates to a kind of architectural decoration coating, aqueous wooden ware priming paint of particularly a kind of spraying and preparation method thereof.
Background technology
Along with expanding economy and growth in the living standard, people are to environmental protection, healthy requirement is more and more higher, haze pollution problem is more and more paid attention to, the resolution of government to environmental improvement is increasing, tighten up with the appearance enforcement of new environmental law and various places environmental protection policy step by step, national policy is all the more harsh to the restriction of solvent based coating, society grows to even greater heights to the cry of environmental protection, the coating industry being once regarded as high pollution industry can not be escaped by luck the destiny of transition and upgrade naturally, simultaneously the Environmentally friendly coatings such as water-miscible paint has welcome unprecedented development a lot of coatings enterprises on opportunity and joins one after another and produce in aqueous woodware paint ranks.
Current aqueous woodware paint construction on still some difficulty, modal be lines dark base material (darker wood grain ground such as such as Cortex Fraxini mandshuricae, oak etc.) spraying, be a difficult point of aqueous woodware paint.Because aqueous woodware paint is solvent with water, surface tension is larger, often because lines darker base material is soaked bad, darker wood grain is caused to occur the not problem such as japanning or pin hole, be difficult to reach desirable decorative effect, thus make the application of aqueous woodware paint be confined to brush or spray on the base material of some more shallow lines.Therefore, aqueous woodware paint dark lines ground sprayingization be realized, the hand-hole sex chromosome mosaicism of aqueous wooden ware priming paint will be solved, the working efficiency of aqueous woodware paint construction could be improved.
Summary of the invention
The object of the invention is to overcome weak point of the prior art, aqueous wooden ware priming paint that a kind of spraying is provided and preparation method thereof, the aqueous wooden ware priming paint of spraying prepared by the present invention not only solves the problem that aqueous wooden ware basecoat paint there will be pin hole on base material, and after spraying, paint film adhesion is good.
The present invention is achieved in that a kind of aqueous wooden ware priming paint of spraying, by following component and ratio of weight and number formulated:
Further prioritization scheme: described emulsion is pure acrylic acid ester copolymer, its MFFT (minimum film-forming temperature) about 30-40 DEG C, particle diameter be about 1.5-2 μm, solid containing for 40 ± 1%, pH value is 7-8, viscosity (3#12 turns) < 100mPa.s, not containing APEO milky white liquid.
Further prioritization scheme: described water-soluble multifunctional auxiliary agent adopts amino-2 methyl isophthalic acids-propyl alcohol of 2-.Described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of any mixture, contributes to film forming matter film forming at low temperatures.
Further prioritization scheme: described defoamer refers to modified dimethyl polysiloxane solution, as a kind of molecular antifoaming agent, it can suppress bubble to produce in system, prevents from producing bubble in brushing and spraying process, and good with the system intermiscibility of water soluble acrylic acid.
Further prioritization scheme: described substrate wetting agents is polyether siloxane copolymer, is used to the surface tension reducing water, makes coating can soak base material fast and penetrate in the wood grain of base material in coating process, ensure the planarization of paint film.
Further prioritization scheme: described frostproofer is 1,2-PD; Described 1,2-PD preferentially adopts purity >=99.7%, moisture≤0.08%, and boiling range is 184-190 DEG C, and relative density is the colourless transparent liquid of 1.037-1.039, colourity≤10.Described sanitas is isothiazolinone disinfecting agent.
Further prioritization scheme: described thickening material is alkali-soluble emulsion type thickening material, a kind of cross-linked type macromolecule emulsion thickener containing acidic-group, when with water latting drown and with in alkali and time, its emulsion particle expands very soon, under these conditions, emulsion is by change clarification and very thickness; It is solid containing being 28%, proportion is 1.054g/ml, pH value is 3.5, brookfield viscosity LVTO (25 DEG C 1# rotor 12 revs/min) is < 50 (centipoise), after application, system can form tridimensional network, produce thixotropy, make system have time enough to soak base material.
The preparation method of the aqueous wooden ware priming paint of above-mentioned spraying, it comprises following step:
75-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.2-0.25 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 0.2-0.3 part defoamer, 0.4-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4.9-15.1 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint sprayed.
The aqueous wooden ware priming paint tool of spraying prepared by the present invention has the following advantages: the aqueous wooden ware priming paint adopting component of the present invention and proportioning to combine the spraying of preparation not only solves the problem that aqueous wooden ware basecoat paint there will be pin hole on base material, and after spraying, paint film adhesion is good.
The selected various Material cladding collocation of the present invention, adopt experiment of many factor method of design, orthogonal experimental design determination component and weight proportion thereof, be the aqueous wooden ware priming paint of a kind of spraying for aqueous woodware paint exploitation, aqueous wooden ware priming paint tool compared with traditional aqueous wooden ware priming paint of the present invention's spraying has the following advantages:
(1), increase work efficiency: need not brush the base material such as Cortex Fraxini mandshuricae, oak and just easily can solve aqueous wooden ware priming paint pin hole problems, and improve the working efficiency of constructor.
(2), rate of drying is fast, grinability good: surface drying time is less than 20 minutes, and normal drying just can be polished for 4 hours, and polishing 20 not scab paper.
(3), easy to control: need not to add water and can just can directly construct, also specially need not control flow and the pressure of spray gun, only need normal spraying just can reach and want uniform paint film.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
(1) embodiment is as follows:
An aqueous wooden ware priming paint for spraying, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of spraying, it comprises following step:
75-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.2-0.25 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 0.2-0.3 part defoamer, 0.4-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4.9-15.1 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint sprayed.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts DPNB or the DPM film coalescence aid of Eastman Chemical.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer adopts propylene glycol.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.Described often kind of component also can adopt other type product similar.
(2) embodiment is as follows:
Embodiment 1: a kind of aqueous wooden ware priming paint of spraying, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of spraying, it comprises following step:
85 parts of emulsions are added in dispersion cylinder, under 1000r/min rotating speed, add 0.25 part of water-soluble multifunctional auxiliary agent, 7.2 parts of film coalescence aid, 0.25 part of defoamer, 0.5 part of substrate wetting agents, 1.0 parts of frostproofers, 0.1 part of sanitas, 0.8 part of thickening material and 4.9 parts of water successively, after disperseing 20 clocks, namely obtain the aqueous wooden ware priming paint sprayed.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPNB film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 2: a kind of aqueous wooden ware priming paint of spraying, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of spraying, it comprises following step:
75 parts of emulsions are added in dispersion cylinder, under 800r/min rotating speed, add 0.2 part of water-soluble multifunctional auxiliary agent, 6.8 parts of film coalescence aid, 0.2 part of defoamer, 0.5 part of substrate wetting agents, 0.8 part of frostproofer, 0.2 part of sanitas, 1.2 parts of thickening materials and 15.1 parts of water successively, after disperseing 30 clocks, namely obtain the aqueous wooden ware priming paint sprayed.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPNB film coalescence aid of Eastman Chemical.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 3: a kind of aqueous wooden ware priming paint of spraying, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of spraying, it comprises following step:
80 parts of emulsions are added in dispersion cylinder, under 900r/min rotating speed, add 0.23 part of water-soluble multifunctional auxiliary agent, 7.0 parts of film coalescence aid, 0.25 part of defoamer, 0.4 part of substrate wetting agents, 0.9 part of frostproofer, 0.15 part of sanitas, 1.0 parts of thickening materials and 10.02 parts of water successively, after disperseing 25 clocks, namely obtain the aqueous wooden ware priming paint sprayed.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPM film coalescence aid of Eastman Chemical.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 4: a kind of aqueous wooden ware priming paint of spraying, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of spraying, it comprises following step:
83 parts of emulsions are added in dispersion cylinder, under 1000r/min rotating speed, add 0.25 part of water-soluble multifunctional auxiliary agent, 7.2 parts of film coalescence aid, 0.3 part of defoamer, 0.45 part of substrate wetting agents, 1.0 parts of frostproofers, 0.1 part of sanitas, 1.0 parts of thickening materials and 6.7 parts of water successively, after disperseing 22 clocks, namely obtain the aqueous wooden ware priming paint sprayed.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPM film coalescence aid of Eastman Chemical.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Through the test to each embodiment, every technical performance index of the aqueous wooden ware priming paint of the present invention's spraying and experimental data are as follows respectively shown in table:
Following is table 1-1---the experimental data of the indices that each embodiment of aqueous wooden ware priming paint of the present invention's spraying measures according to national standard (GB/T23999-2009) D class.
As apparent from table 1-1 can, the indices of each embodiment of the aqueous wooden ware priming paint of the present invention's spraying all meets the requirement of national standard (GB/T23999-2009); Need not brush the base material such as Cortex Fraxini mandshuricae, oak and just easily can solve aqueous wooden ware priming paint pin hole problems, and paint film is even, sticking power is good.
Above-mentioned embodiment is just explained in detail technical scheme of the present invention, and the present invention has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.

Claims (9)

1. spraying an aqueous wooden ware priming paint, it is characterized in that, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
2. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described water-soluble multifunctional auxiliary agent is amino-2 methyl isophthalic acids-propyl alcohol of 2-.
3. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of any mixture.
4. the aqueous wooden ware priming paint of spraying according to claim 1, described defoamer is modified dimethyl polysiloxane solution.
5. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described substrate wetting agents is polyether siloxane copolymer.
6. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described thickening material is alkali-soluble emulsion type thickening material.
7. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described frostproofer is 1,2-PD.
8. the aqueous wooden ware priming paint of spraying according to claim 1, is characterized in that: described sanitas is isothiazolinone disinfecting agent.
9. a preparation method for the aqueous wooden ware priming paint of the spraying according to any one of claim 1-8, is characterized in that: it comprises following step:
75-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.2-0.25 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 0.2-0.3 part defoamer, 0.4-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4.9-15.1 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint sprayed.
CN201410826237.5A 2014-12-26 2014-12-26 Spraying waterborne wood primer and preparation method thereof Pending CN104559595A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927470A (en) * 2015-07-17 2015-09-23 广东华兹卜化学工业有限公司 Water-based thick-coated carpentry transparent base paint and preparation method thereof
CN107916036A (en) * 2017-10-30 2018-04-17 合肥林邦门业有限公司 A kind of preparation method of woodenware water-borne acrylic coatings
CN108084832A (en) * 2018-01-31 2018-05-29 徐州力泰钢结构有限公司 A kind of stone similar paint spraying priming paint applied to steel plate
CN108676435A (en) * 2018-04-28 2018-10-19 佛山市莱威化工科技有限公司 It can prevent the aqueous transparent seal coat coating and its preparation and construction technology that solid wood cracks
CN112920710A (en) * 2021-03-26 2021-06-08 台州市万胜涂料有限公司 Wear-resistant water-based woodware anti-expansion bar sealing primer and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020794A (en) * 2007-03-23 2007-08-22 陈晓鹏 Green water-base lacquer without formaldehyde and its prepn
CN101812260A (en) * 2010-04-12 2010-08-25 中华制漆(深圳)有限公司 Multifunctional water-based white primer and preparation method thereof
CN102134434A (en) * 2011-03-08 2011-07-27 三棵树涂料股份有限公司 High-performance water-based white sealing primer
CN102618135A (en) * 2012-04-12 2012-08-01 刘娜 Aqueous environment-friendly wood lacquer and application and use method thereof
CN103992709A (en) * 2014-05-23 2014-08-20 三棵树涂料股份有限公司 Water-based wood ware seal primer with aldehyde removal function and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020794A (en) * 2007-03-23 2007-08-22 陈晓鹏 Green water-base lacquer without formaldehyde and its prepn
CN101812260A (en) * 2010-04-12 2010-08-25 中华制漆(深圳)有限公司 Multifunctional water-based white primer and preparation method thereof
CN102134434A (en) * 2011-03-08 2011-07-27 三棵树涂料股份有限公司 High-performance water-based white sealing primer
CN102618135A (en) * 2012-04-12 2012-08-01 刘娜 Aqueous environment-friendly wood lacquer and application and use method thereof
CN103992709A (en) * 2014-05-23 2014-08-20 三棵树涂料股份有限公司 Water-based wood ware seal primer with aldehyde removal function and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927470A (en) * 2015-07-17 2015-09-23 广东华兹卜化学工业有限公司 Water-based thick-coated carpentry transparent base paint and preparation method thereof
CN107916036A (en) * 2017-10-30 2018-04-17 合肥林邦门业有限公司 A kind of preparation method of woodenware water-borne acrylic coatings
CN108084832A (en) * 2018-01-31 2018-05-29 徐州力泰钢结构有限公司 A kind of stone similar paint spraying priming paint applied to steel plate
CN108676435A (en) * 2018-04-28 2018-10-19 佛山市莱威化工科技有限公司 It can prevent the aqueous transparent seal coat coating and its preparation and construction technology that solid wood cracks
CN112920710A (en) * 2021-03-26 2021-06-08 台州市万胜涂料有限公司 Wear-resistant water-based woodware anti-expansion bar sealing primer and preparation method thereof

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Application publication date: 20150429