CN104403568A - Novel waterborne wood paint - Google Patents

Novel waterborne wood paint Download PDF

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Publication number
CN104403568A
CN104403568A CN201410699135.1A CN201410699135A CN104403568A CN 104403568 A CN104403568 A CN 104403568A CN 201410699135 A CN201410699135 A CN 201410699135A CN 104403568 A CN104403568 A CN 104403568A
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CN
China
Prior art keywords
parts
novel aqueous
wood lacquer
aqueous wood
model
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410699135.1A
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Chinese (zh)
Inventor
黄宏亭
谢志超
黎司华
蔡森
王悦辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG VALSPAR CHEMICAL INDUSTRY Co Ltd
Original Assignee
GUANGDONG VALSPAR CHEMICAL INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG VALSPAR CHEMICAL INDUSTRY Co Ltd filed Critical GUANGDONG VALSPAR CHEMICAL INDUSTRY Co Ltd
Priority to CN201410699135.1A priority Critical patent/CN104403568A/en
Publication of CN104403568A publication Critical patent/CN104403568A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to novel waterborne wood paint. The waterborne wood paint is prepared from the following ingredients in parts by weight: 12.5-18 parts of deionized water, 0.1 part of a wetting agent, 0.2 part of a preservative, 0.4 part of a defoaming agent, 2 parts of a cosolvent, 1.5-2 parts of a coalescing agent, 80-85 parts of water-based resin, and 0.5 part of a thickening agent. The waterborne primer for the wood product disclosed by the invention can prevent the rib swelling phenomenon caused by moisture entering into the wood fibers.

Description

A kind of novel aqueous wood lacquer
Technical field
The present invention relates to paint field, be specifically related to a kind of novel aqueous wood lacquer.
Background technology
Timber is a kind of porous fiber tissue of porous of polyose, wood surface after scraping or polishing exist many xylon tissues and fine gap, infiltrate in hydrophilic xylon and gap and diffusion when having water to exist, the xylon after water suction expands and increases slightly, shows especially in wood surface.Remain unchanged after water volatilization, or else can bounce back reinstatement, makes the coarse injustice of wood surface.And aqueous woodware paint itself take water as medium, when aqueous woodware paint is sprayed on woodwork, moisture content can spread over lumber fibre surface or penetrate between lumber fibre, causes " bulging tendons " phenomenon.
Summary of the invention
The object of the present invention is to provide a kind of novel aqueous wood lacquer that can prevent from moisture from entering between lumber fibre causing " rise muscle " phenomenon.
For solving the problem, the technical solution adopted in the present invention is as follows:
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 12.5-18 part, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5-2 part, water-base resin 80-85 part, thickening material 0.5 part.
In the present invention, preferred scheme is that described woodwork use priming paint is made up of the following component according to parts by weight: deionized water 18 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5 parts, water-base resin 80 parts, thickening material 0.5 part.
In the present invention, preferred scheme is described wetting agent is polysiloxane.
In the present invention, preferred scheme is described sanitas is isothiazolinone.
In the present invention, preferred scheme is described thickening material is polyurethane thickener.
In the present invention, preferred scheme is described solubility promoter is 1-Methoxy-2-propyl acetate.
In the present invention, preferred scheme is described film coalescence aid is dipropylene.
In the present invention, preferred scheme is described water-base resin is waterborne cation resin, and described waterborne cation resin includes but not limited to waterborne cation type acrylate copolymer dispersion.Contriver finds, in paint field, resin cation (R.C.) can form ionic linkage with the Weibull in timber and amount of grease class material molecule, and the salts substances that reaction is formed is coated to be fixed on interface, and can not move under hot and humid condition and ooze out; For timber, the amine groups in resin cation (R.C.) can form hydrogen bond with the hydroxyl in lumber fibre, thus produces good sticking power, thus moisture can be avoided to enter in lumber fibre, avoids the generation of " rise muscle " phenomenon.
In the present invention, preferred scheme is described defoamer is highly-branched silicone polymer.
In the present invention, to be described wetting agent be preferred scheme that model that Henkel KGaA company produces is the polysiloxane of KL245, described sanitas is the model that Sol company of Britain produces is the isothiazolinone of RS, described thickening material is the model that Ya Shilan company produces is the polyurethane thickener of NLS200, described solubility promoter is the model that the Dow Chemical Company produces is the 1-Methoxy-2-propyl acetate of PMA, described film coalescence aid is the model that the Dow Chemical Company produces is the dipropylene of DPNB, described water-base resin is the model that German Yin Tai company produces is the waterborne cation resin of SYNTRAN6305, described defoamer is the model that Kening Co., Ltd produces is the highly-branched silicone polymer of A10.
Compared with prior art, the invention has the advantages that: the resin cation (R.C.) in formula can form ionic linkage with the Weibull in timber and amount of grease class material molecule, the salts substances that reaction is formed coatedly is fixed on interface, and can not move under hot and humid condition and ooze out; For timber, the amine groups in resin cation (R.C.) can form hydrogen bond with the hydroxyl in lumber fibre, thus produces good sticking power, thus moisture can be avoided to enter in lumber fibre, avoids the generation of " rise muscle " phenomenon; In addition, select unique formula of the present invention, between each composition produce synergy, make the sticking power of the woodwork use priming paint obtained and closed performance better.
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment
Embodiment 1
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 18 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5 parts, water-base resin 80 parts, thickening material 0.5 part.Described wetting agent is the model that Henkel KGaA company produces is the polysiloxane of KL245, described sanitas is the model that Sol company of Britain produces is the isothiazolinone of RS, described thickening material is the model that Ya Shilan company produces is the polyurethane thickener of NLS200, described solubility promoter is the model that the Dow Chemical Company produces is the 1-Methoxy-2-propyl acetate of PMA, described film coalescence aid is the model that the Dow Chemical Company produces is the dipropylene of DPNB, described water-base resin is the model that German Yin Tai company produces is the waterborne cation resin of SYNTRAN6305, described defoamer is the model that Kening Co., Ltd produces is the highly-branched silicone polymer of A10.
Above-mentioned each component has been taken respectively by formula, add deionized water, water-base resin and defoamer successively in order, drop in dispersion machine, with the rotating speed of 500r/min, said components is stirred 25min, then wetting agent, solubility promoter, film coalescence aid, thickening material and sanitas is dropped into again successively (after often adding a kind of component, utilize dispersion machine system to be stirred, then drop into next component), after all components adds, whole system is stirred, obtains product.
Embodiment 2
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 12.5 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 2 parts, water-base resin 85 parts, thickening material 0.5 part.In the present embodiment, the concrete material of each component used and preparation technology are all with embodiment 1.
Embodiment 3
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 16 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5 parts, water-base resin 82 parts, thickening material 0.5 part.In the present embodiment, the concrete material of each component used and preparation technology are all with embodiment 1.
Embodiment 4
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 15 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.8 parts, water-base resin 84 parts, thickening material 0.5 part.In the present embodiment, the concrete material of each component used and preparation technology are all with embodiment 1.
Embodiment 5
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 11 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2.3 parts, film coalescence aid 1.6 parts, water-base resin 78 parts, thickening material 0.4 part.In the present embodiment, the concrete material of each component used and preparation technology are all with embodiment 1.
Embodiment 6
A kind of novel aqueous wood lacquer, it is made up of the following component according to parts by weight: deionized water 10 parts, wetting agent 0.2 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 3 parts, film coalescence aid 1.5 parts, water-base resin 87 parts, thickening material 0.5 part.In the present embodiment, the concrete material of each component used and preparation technology are all with embodiment 1.
Embodiment 7
A kind of novel aqueous wood lacquer, described wetting agent is tween-80, and the concrete material of all the other each components used and preparation technology are all with embodiment 4.
Embodiment 8
A kind of novel aqueous wood lacquer, described thickening material is Natvosol, and the concrete material of each component used and preparation technology are all with embodiment 4.
Embodiment 9
Respectively the novel aqueous wood lacquer of Example 1-8, then gets 8 pieces of sheet glass, these 8 pieces of sheet glass is coated with the titanium dioxide slurry that a layer thickness is 75 μm respectively, and then drying and processing 30 minutes at the temperature of 100 DEG C, is then cooled to room temperature; Then, it is novel aqueous wood lacquer in the present embodiment 1-8 of 150 μm (corresponding is carrying out mark) that these 8 pieces of sheet glass are coated with a layer thickness respectively, Air drying 72 hours, sticking power is tested (namely with scotch tape, be bonded in stripping with scotch tape, then transparent adhesive tape is peeled off, then observes and calculate the area ratio of the titanium dioxide that transparent adhesive tape is stained with), concrete outcome refers to following table 1:
The novel aqueous wood lacquer sticking power table with test results of table 1: embodiment 1-8
Group Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Titanium dioxide area ratio on adhesive tape 0% 0% 0% 0.1%
Group Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Titanium dioxide area ratio on adhesive tape 20% 23% 8% 6%
Get the novel aqueous wood lacquer of Example 1-8 respectively, then a kind of commercially available wood lacquer (hereinafter referred to as commercially available prod) is got, then test its anti-" rise muscle " performance, test index comprises time of drying of these wood lacquers, water tolerance, alkali resistance, sticking power, water-permeable, the accumulation of salt in the surface soil and salting-out resistance; Wherein adopt time of drying the method for defined in GB/T 1728-1979 to carry out testing, water tolerance employing GB/T1733-1993 prescriptive procedure carries out testing, alkali resistance adopts the method specified in GB/T 9265-2009 to carry out testing, sticking power adopts the method specified in GB/T 9286-1998 to carry out testing, water-permeable adopts the method specified in GB/T328.3-1989 to carry out testing, alkali burnout resistance and salting-out resistance adopt the method specified in JG/T210-2007 to test.
Concrete outcome refers to following table 2:
Table 2: anti-" rise muscle " the performance test results table
Above-mentioned embodiment is only the preferred embodiment of the present invention; can not limit the scope of protection of the invention with this, change and the replacement of any unsubstantiality that those skilled in the art does on basis of the present invention all belong to the present invention's scope required for protection.

Claims (10)

1. a novel aqueous wood lacquer, is characterized in that being made up of the following component according to parts by weight: deionized water 12.5-18 part, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5-2 part, water-base resin 80-85 part, thickening material 0.5 part.
2. novel aqueous wood lacquer according to claim 1, is characterized in that being made up of the following component according to parts by weight: deionized water 18 parts, wetting agent 0.1 part, sanitas 0.2 part, defoamer 0.4 part, solubility promoter 2 parts, film coalescence aid 1.5 parts, water-base resin 80 parts, thickening material 0.5 part.
3. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described wetting agent is polysiloxane.
4. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described sanitas is isothiazolinone.
5. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described thickening material is polyurethane thickener.
6. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described solubility promoter is 1-Methoxy-2-propyl acetate.
7. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described film coalescence aid is dipropylene.
8. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described water-base resin is waterborne cation resin.
9. novel aqueous wood lacquer according to claim 1 and 2, is characterized in that: described defoamer is highly-branched silicone polymer.
10. novel aqueous wood lacquer according to claim 1 and 2, it is characterized in that: described wetting agent is the model that Henkel KGaA company produces is the polysiloxane of KL245, described sanitas is the model that Sol company of Britain produces is the isothiazolinone of RS, described thickening material is the model that Ya Shilan company produces is the polyurethane thickener of NLS200, described solubility promoter is the model that the Dow Chemical Company produces is the 1-Methoxy-2-propyl acetate of PMA, described film coalescence aid is the model that the Dow Chemical Company produces is the dipropylene of DPNB, described water-base resin is the model that German Yin Tai company produces is the waterborne cation resin of SYNTRAN6305, described defoamer is the model that Kening Co., Ltd produces is the highly-branched silicone polymer of A10.
CN201410699135.1A 2014-11-26 2014-11-26 Novel waterborne wood paint Pending CN104403568A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927605A (en) * 2015-05-30 2015-09-23 广东华兹卜化学工业有限公司 Water-based alkyd carpentry paint and preparation method thereof
CN105001729A (en) * 2015-07-09 2015-10-28 上海展辰涂料有限公司 Aqueous white primer for sealing wood oil and tannic acid
CN106752959A (en) * 2016-12-15 2017-05-31 江门市蓬江区文森装饰材料有限公司 A kind of white primer and preparation method thereof
CN108641573A (en) * 2018-04-20 2018-10-12 河北晨阳工贸集团有限公司 A kind of sealer and preparation method thereof with the efficiently anti-muscle energy that rises

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010126543A (en) * 2008-11-25 2010-06-10 Nippon Sutakko Kk Aqueous primer composition
CN102888163A (en) * 2012-10-25 2013-01-23 南京长江涂料有限公司 Water-based paint for Christmas glass ornaments, and preparation method and application thereof
CN103113828A (en) * 2013-01-18 2013-05-22 上海金强粘合剂有限公司 Water-based paint special for pinewood of furniture for children
CN103642342A (en) * 2013-12-06 2014-03-19 叶氏化工研发(上海)有限公司 Bleeding-resistant waterborne wood sealing primer
CN103965758A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne wood lacquer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010126543A (en) * 2008-11-25 2010-06-10 Nippon Sutakko Kk Aqueous primer composition
CN102888163A (en) * 2012-10-25 2013-01-23 南京长江涂料有限公司 Water-based paint for Christmas glass ornaments, and preparation method and application thereof
CN103113828A (en) * 2013-01-18 2013-05-22 上海金强粘合剂有限公司 Water-based paint special for pinewood of furniture for children
CN103965758A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne wood lacquer
CN103642342A (en) * 2013-12-06 2014-03-19 叶氏化工研发(上海)有限公司 Bleeding-resistant waterborne wood sealing primer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927605A (en) * 2015-05-30 2015-09-23 广东华兹卜化学工业有限公司 Water-based alkyd carpentry paint and preparation method thereof
CN105001729A (en) * 2015-07-09 2015-10-28 上海展辰涂料有限公司 Aqueous white primer for sealing wood oil and tannic acid
CN106752959A (en) * 2016-12-15 2017-05-31 江门市蓬江区文森装饰材料有限公司 A kind of white primer and preparation method thereof
CN108641573A (en) * 2018-04-20 2018-10-12 河北晨阳工贸集团有限公司 A kind of sealer and preparation method thereof with the efficiently anti-muscle energy that rises

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