CN104559596A - Anti-formaldehyde waterborne wood primer and preparation method thereof - Google Patents
Anti-formaldehyde waterborne wood primer and preparation method thereof Download PDFInfo
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- CN104559596A CN104559596A CN201410826628.7A CN201410826628A CN104559596A CN 104559596 A CN104559596 A CN 104559596A CN 201410826628 A CN201410826628 A CN 201410826628A CN 104559596 A CN104559596 A CN 104559596A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to anti-formaldehyde waterborne wood primer and a preparation method thereof. The anti-formaldehyde waterborne wood primer is prepared from the following components in parts by weight: emulsion, a waterborne multifunctional additive, a film-forming additive, imidazolidone, a defoamer, a substrate wetter, an anti-freezer, a preservative, a thickener and water, wherein the emulsion is pure acrylate copolymer. The anti-formaldehyde waterborne wood primer prepared with the method can not only remove formaldehyde in artificial boards but also prevent release of formaldehyde.
Description
Technical field
The present invention relates to a kind of architectural decoration coating, particularly a kind of aqueous wooden ware priming paint and preparation method thereof of anti-formaldehyde.
Background technology
At present, Global Forests area sharply reduces, timber resources worsening shortages, and artificial board has become the important substitute of mankind's solid wood consumption.It is reported, the artificial board overwhelming majority be by wood particulate after spray urea-formaldehyde resin adhesive, be pressed into plate through High Temperature High Pressure.Urea-formaldehyde resin is the direct compound of formaldehyde and urea, and the shortcoming of urea-formaldehyde resin is chemical property extremely unstable, all can be reduced to formaldehyde and urea by last decomposition in its natural state.Therefore, use the furniture that wood-based plate is made, at it at first whole use procedure, all along with the continuous decomposition of urea-formaldehyde resin and the continuous release of formaldehyde.
Due to the limitation of living space volume and the limited of ventilation condition, the formaldehyde of common Wood-based Panel Furniture sustained release easily forms formaldehyde local buildup and exceeds standard in room, form harm to the physical and mental health of the user being in room.State health standards specifies: Indoor Air Formaldehyde concentration value is 0.1 milligram every cubic metre, and formaldehyde is very large to physical effects.Formaldehyde can and air in ionic muriate reaction generation dichlormetbylether, and dichlormetbylether is a kind of carcinogenic substance.The formaldehyde that long-term suction is excessive, people can be made to suffer from slow breathing tract disease, allergy, and the cancers such as nasopharyngeal carcinoma, uremia, leukemia, cause infertile, and the miscarriage of pregnant woman, fetal anomaly etc.; So formaldehyde in removing wood-based plate or effectively stop the wood lacquer product of Form aldehyde release to be more and more subject to liking of human consumer.
Summary of the invention
The object of the invention is to overcome weak point of the prior art, aqueous wooden ware priming paint of a kind of anti-formaldehyde and preparation method thereof is provided, the aqueous wooden ware priming paint of anti-formaldehyde prepared by the present invention not only can remove the formaldehyde in wood-based plate, and can stop the release of formaldehyde.
The present invention is achieved in that a kind of aqueous wooden ware priming paint of anti-formaldehyde, by following component and ratio of weight and number formulated:
Further prioritization scheme: described emulsion is pure acrylic acid ester copolymer, its MFFT (minimum film-forming temperature) about 30-40 DEG C, particle diameter be about 1.5-2 μm, solid containing for 40 ± 1%, pH value is 7-8, viscosity (3#12 turns) < 100mPa.s, not containing the milky white liquid of APEO; Described emulsion is film forming matter, and the carrier also as formaldehyde-trapping agent is seeped into the coating that sheet material inside forms one deck densification afterwards, reduces the burst size of artificial board formaldehyde.
Further prioritization scheme: described water-soluble multifunctional auxiliary agent adopts amino-2 methyl isophthalic acids-propyl alcohol of 2-.Described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of any mixture, contributes to film forming matter film forming at low temperatures.Described imidazolidone adopts 2-imidazolidone, and having another name called ethylene urea, is the formaldehyde-trapping agent of white crystalline.
Further prioritization scheme: described defoamer refers to modified dimethyl polysiloxane solution, as a kind of molecular antifoaming agent, it can suppress bubble to produce in system, prevents from producing bubble in brushing and spraying process, and good with the system intermiscibility of water soluble acrylic acid.
Further prioritization scheme: described substrate wetting agents is polyether siloxane copolymer, is used to the surface tension reducing water, makes coating can soak base material fast and penetrate in base material in coating process, ensure the planarization of paint film.
Further prioritization scheme: described frostproofer is 1,2-PD; Described 1,2-PD preferentially adopts purity >=99.7%, moisture≤0.08%, and boiling range is 184-190 DEG C, and relative density is the colourless transparent liquid of 1.037-1.039, colourity≤10.Described sanitas is isothiazolinone disinfecting agent.
Further prioritization scheme: described thickening material is alkali-soluble emulsion type thickening material, a kind of cross-linked type macromolecule emulsion thickener containing acidic-group, when with water latting drown and with in alkali and time, its emulsion particle expands very soon, under these conditions, emulsion is by change clarification and very thickness; It is solid containing being 28%, proportion is 1.054g/ml, pH value is 3.5, brookfield viscosity LVTO (25 DEG C 1# rotor 12 revs/min) is < 50 (centipoise), after application, system can form tridimensional network, produce thixotropy, make system have time enough to soak base material.
The preparation method of the aqueous wooden ware priming paint of above-mentioned anti-formaldehyde, it comprises following step:
80-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.1-0.2 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 2.0-3.0 part imidazolidone, 0.15-0.3 part defoamer, 0.3-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4-10 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
The aqueous wooden ware priming paint tool of anti-formaldehyde prepared by the present invention has the following advantages: the aqueous wooden ware priming paint adopting component of the present invention and proportioning to combine the anti-formaldehyde of preparation not only can remove the formaldehyde in wood-based plate, and can stop the further release of formaldehyde.
The selected various Material cladding collocation of the present invention, adopt experiment of many factor method of design, orthogonal experimental design determination component and weight proportion thereof, be the one anti-formaldehyde aqueous wooden ware priming paint for aqueous woodware paint exploitation, the present invention's anti-formaldehyde aqueous wooden ware priming paint tool compared with traditional aqueous wooden ware priming paint has the following advantages:
(1), anti-formaldehyde function: the formaldehyde in various wood-based plate (as shaving board, medium density fibre board (MDF), glued board) can be removed, and stop the release of its formaldehyde, effectively reduce the content of formaldehyde in artificial board.
(2), rate of drying is fast, grinability good: surface drying time is less than 20 minutes, and normal drying just can be polished for 4 hours, and polishing 20 not scab paper.
(3), excellent envelope look: general its closed performance of aqueous wooden ware priming paint is poor, can not close or be difficult to close water-soluble colored component in artificial board; The envelope look of excellence of the present invention not only to close the Weibull in solid wood or solid wood veneer timber, can also close water-soluble colored component in wood-based plate.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
(1) embodiment is as follows:
An aqueous wooden ware priming paint for anti-formaldehyde, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of anti-formaldehyde, it comprises following step:
80-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.1-0.2 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 2.0-3.0 part imidazolidone, 0.15-0.3 part defoamer, 0.3-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4-10 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts DPNB or the DPM film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.Described often kind of component also can adopt other type product similar.
(2) embodiment is as follows:
Embodiment 1: a kind of aqueous wooden ware priming paint of anti-formaldehyde, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of anti-formaldehyde, it comprises following step:
85 parts of emulsions are added in dispersion cylinder, under 1000r/min rotating speed, add 0.1 part of water-soluble multifunctional auxiliary agent, 7.2 parts of film coalescence aid, 2.0 parts of imidazolidones, 0.25 part of defoamer, 0.4 part of substrate wetting agents, 1.0 parts of frostproofers, 0.15 part of sanitas, 0.8 part of thickening material and 4 parts of water successively, after disperseing 20 clocks, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPNB film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 2: a kind of aqueous wooden ware priming paint of anti-formaldehyde, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of anti-formaldehyde, it comprises following step:
80 parts of emulsions are added in dispersion cylinder, under 800r/min rotating speed, add 0.2 part of water-soluble multifunctional auxiliary agent, 6.8 parts of film coalescence aid, 3.0 parts of imidazolidones, 0.15 part of defoamer, 0.5 part of substrate wetting agents, 0.8 part of frostproofer, 0.2 part of sanitas, 1.2 parts of thickening materials and 6.7 parts of water successively, after disperseing 30 clocks, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPNB film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 3: a kind of aqueous wooden ware priming paint of anti-formaldehyde, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of anti-formaldehyde, it comprises following step:
83 parts of emulsions are added in dispersion cylinder, under 900r/min rotating speed, add 0.15 part of water-soluble multifunctional auxiliary agent, 7.0 parts of film coalescence aid, 2.8 parts of imidazolidones, 0.2 part of defoamer, 0.3 part of substrate wetting agents, 0.9 part of frostproofer, 0.2 part of sanitas, 1.0 parts of thickening materials and 10 parts of water successively, after disperseing 25 clocks, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPM film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Embodiment 4: a kind of aqueous wooden ware priming paint of anti-formaldehyde, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
A preparation method for the aqueous wooden ware priming paint of anti-formaldehyde, it comprises following step:
85 parts of emulsions are added in dispersion cylinder, under 1000r/min rotating speed, add 0.2 part of water-soluble multifunctional auxiliary agent, 7.2 parts of film coalescence aid, 2.5 parts of imidazolidones, 0.3 part of defoamer, 0.5 part of substrate wetting agents, 1.0 parts of frostproofers, 0.1 part of sanitas, 1.0 parts of thickening materials and 4.7 parts of water successively, after disperseing 22 clocks, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
Emulsion described in said components adopts the W-2010 emulsion of Ahmedabad richness.Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant of Tao Shi.Described film coalescence aid adopts the DPM film coalescence aid of Eastman Chemical.Described imidazolidone adopts the 2-imidazolidone of Cangzhou Kang Zhuan Chemical Manufacture.Described defoamer adopts the NXZ defoamer of Hai Chuan.Described substrate wetting agents adopts 270 wetting agents of TEGO.Described frostproofer is 1,2-PD.Described sanitas adopts the RS sanitas of THOR.Described thickening material adopts the ASE-60 thickening material of ROHM AND HAAS.
Through the test to each embodiment, every technical performance index of the aqueous wooden ware priming paint of the anti-formaldehyde of the present invention and experimental data are as follows respectively shown in table:
Following is table 1-1---the experimental data of the indices that each embodiment of the present invention's anti-formaldehyde aqueous wooden ware priming paint measures according to national standard (GB/T23999-2009) D class.
As apparent from table 1-1 can, the indices of each embodiment of anti-formaldehyde aqueous wooden ware priming paint of the present invention all meets the requirement of national standard (GB/T23999-2009).
Following is table 1-2---the experimental data of the envelope look of the present invention's anti-formaldehyde aqueous wooden ware priming paint.
As apparent from table 1-2 can, the envelope look of each embodiment of the present invention's anti-formaldehyde aqueous wooden ware priming paint is excellent, not only can close the Weibull in solid wood or solid wood veneer timber, can also close the water-soluble colored component in artificial board.
Following table 2 be each embodiment of aqueous wooden ware priming paint of the anti-formaldehyde of the present invention according to JC/T1074-2008 " function of purifying indoor air coating material purifying property " air purifying paint I class standard detected result:
| Project | Standard performance | Example 1 | Example 2 | Example 3 | Example 4 |
| Purifying property (purifying formaldehyde efficiency) | ≥75％ | 80.2 | 90.1 | 85.6 | 82.1 |
| Decontamination effect improving persistence (purifying formaldehyde efficiency) | ≥60％ | 73.2 | 78.3 | 75.5 | 74.4 |
As can be seen from Table 2, the purifying formaldehyde of each embodiment of the aqueous wooden ware priming paint of the anti-formaldehyde of the present invention meets the requirement that JC/T1074-2008 " function of purifying indoor air coating material purifying property " air purifying paint I class standard detects.
Test result from the above embodiments: the aqueous wooden ware priming paint of anti-formaldehyde prepared by the present invention not only can remove the formaldehyde in wood-based plate, and can stop the further release of formaldehyde.
Above-mentioned embodiment is just explained in detail technical scheme of the present invention, and the present invention has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (10)
1. an aqueous wooden ware priming paint for anti-formaldehyde, is characterized in that, by following component and ratio of weight and number formulated:
Described emulsion is pure acrylic acid ester copolymer.
2. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described water-soluble multifunctional auxiliary agent is amino-2 methyl isophthalic acids-propyl alcohol of 2-.
3. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of any mixture.
4. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described imidazolidone is 2-imidazolidone.
5. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described defoamer is modified dimethyl polysiloxane solution.
6. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described substrate wetting agents is polyether siloxane copolymer.
7. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described thickening material is alkali-soluble emulsion type thickening material.
8. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described frostproofer is 1,2-PD.
9. the aqueous wooden ware priming paint of anti-formaldehyde according to claim 1, is characterized in that: described sanitas is isothiazolinone disinfecting agent.
10. a preparation method for the aqueous wooden ware priming paint of the anti-formaldehyde according to any one of claim 1-9, is characterized in that: it comprises following step:
80-85 part emulsion is added in dispersion cylinder, under 800-1000r/min rotating speed, add 0.1-0.2 part water-soluble multifunctional auxiliary agent, 6.8-7.2 part film coalescence aid, 2.0-3.0 part imidazolidone, 0.15-0.3 part defoamer, 0.3-0.5 part substrate wetting agents, 0.8-1.0 part frostproofer, 0.1-0.2 part sanitas, 0.8-1.2 part thickening material and 4-10 part water successively, after dispersion 20-30 clock, namely obtain the aqueous wooden ware priming paint of anti-formaldehyde.
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| CN201410826628.7A CN104559596A (en) | 2014-12-26 | 2014-12-26 | Anti-formaldehyde waterborne wood primer and preparation method thereof |
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| CN201410826628.7A CN104559596A (en) | 2014-12-26 | 2014-12-26 | Anti-formaldehyde waterborne wood primer and preparation method thereof |
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Cited By (8)
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| CN105086679A (en) * | 2015-09-06 | 2015-11-25 | 三棵树涂料股份有限公司 | Novel and environment-friendly interior wall coating for efficiently removing formaldehyde in air and preparation method thereof |
| CN105566993A (en) * | 2016-03-03 | 2016-05-11 | 复旦大学 | Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof |
| CN106349797A (en) * | 2016-06-12 | 2017-01-25 | 北京化工大学 | Ethylene urea composite nano-material for capturing formaldehyde and preparation method |
| CN106366795A (en) * | 2015-07-23 | 2017-02-01 | 广东顺德嘉乐士新材料有限公司 | Reaction compounding type aldehyde-removing aqueous wood paint and preparation method thereof |
| CN106700938A (en) * | 2016-11-18 | 2017-05-24 | 上海展辰涂料有限公司 | Water-based woodwork varnish with formaldehyde removal effect and preparation method of water-based woodwork varnish |
| CN106987186A (en) * | 2017-05-10 | 2017-07-28 | 佛山彩孔雀化工有限公司 | Anti- formaldehyde mineral paint and preparation method |
| CN114517040A (en) * | 2022-03-04 | 2022-05-20 | 韩玉梅 | Formaldehyde treating agent for artificial board and preparation method and application thereof |
| CN114849441A (en) * | 2022-05-25 | 2022-08-05 | 李晓雅 | Formaldehyde scavenging agent and formaldehyde scavenging method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366795A (en) * | 2015-07-23 | 2017-02-01 | 广东顺德嘉乐士新材料有限公司 | Reaction compounding type aldehyde-removing aqueous wood paint and preparation method thereof |
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| CN106349797A (en) * | 2016-06-12 | 2017-01-25 | 北京化工大学 | Ethylene urea composite nano-material for capturing formaldehyde and preparation method |
| CN106700938A (en) * | 2016-11-18 | 2017-05-24 | 上海展辰涂料有限公司 | Water-based woodwork varnish with formaldehyde removal effect and preparation method of water-based woodwork varnish |
| CN106987186A (en) * | 2017-05-10 | 2017-07-28 | 佛山彩孔雀化工有限公司 | Anti- formaldehyde mineral paint and preparation method |
| CN114517040A (en) * | 2022-03-04 | 2022-05-20 | 韩玉梅 | Formaldehyde treating agent for artificial board and preparation method and application thereof |
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Application publication date: 20150429 |