CN105566993A - Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof - Google Patents
Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof Download PDFInfo
- Publication number
- CN105566993A CN105566993A CN201610119187.6A CN201610119187A CN105566993A CN 105566993 A CN105566993 A CN 105566993A CN 201610119187 A CN201610119187 A CN 201610119187A CN 105566993 A CN105566993 A CN 105566993A
- Authority
- CN
- China
- Prior art keywords
- environment
- friendly type
- formaldehyde
- type water
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to an anti-formaldehyde environment-friendly type water-soluble assistant and a preparation method of the anti-formaldehyde environment-friendly type water-soluble assistant. The anti-formaldehyde environment-friendly type water-soluble assistant is specifically a chemical mixture, is an assistant which is added into a coating material which is used for decorating and treating wooden surfaces of various furniture and the like and is an efficient anti-formaldehyde environment-friendly assistant. The efficient anti-formaldehyde environment-friendly type water-soluble assistant is prepared from water, hydroxypropyl methyl fiber, pH (Potential of Hydrogen) value regulator, a dispersing agent, a defoaming agent, a preservative, rutile type titanium dioxide, wollastonite powder, polymer emulsion, a coalescing agent and an ammonia-silver solution. According to the efficient anti-formaldehyde environment-friendly type water-soluble assistant disclosed by the invention, all raw materials in a formula of the efficient anti-formaldehyde environment-friendly type water-soluble assistant are water-based materials and do not contain oily matters, so that the efficient anti-formaldehyde environment-friendly type water-soluble assistant is beneficial for environment protection; the polymer emulsion adopted by the efficient anti-formaldehyde environment-friendly type water-soluble assistant is a film forming matter, so that wash resistance, acid and alkali resistance, soft texture and strong weather resistance are realized, the leveling performance is good, and the polymer emulsion is a good environment-friendly type water-soluble anti-formaldehyde assistant; by using the anti-formaldehyde environment-friendly type water-soluble assistant for decoration and furniture, harmful gas can be reduced to the minimum, and the requirement of indoor environment can be met.
Description
Technical field
The present invention relates to environment-friendly water-soluble auxiliary agent of a kind of Effective Anti formaldehyde and preparation method thereof, the environment-friendly water-soluble auxiliary agent of described Effective Anti formaldehyde is a kind of chemical mixture, a kind of auxiliary agent making an addition to the wooden surfaces process coating such as finishing, various furniture, be a kind of can the environmental protection auxiliary agent of Effective Anti formaldehyde.
Background technology
The housing industry of China is interior over the next several years will continue maintenance high speed development situation, and be widely used in upholstery and finished product furniture in house decoration and a large amount of synthetic material, the volatility toxic compounds such as the formaldehyde that they discharge cause to indoor environment and seriously pollute, it is the main inducing of cancer, respiratory tract disease, leukemia, immunizing power reduction, fetus teratogenesis etc., the various disease caused thus and indoor environment case, have a strong impact on physical and mental health and the orthobiosis of the people.Room air pollution becomes the another killer of infringement human health.In this context, China formulate << IAQ (indoor air quality) national standard >> and relevant laws and regulations also formally implement.Air pollution problem inside rooms also receives unprecedented attention, and the demand of indoor air purification goods and environmental friendly indoor service is growing, and this provides boundless development platform for we this " environmental protection functional materials ".
Summary of the invention
The object of this invention is to provide a kind of can the environment-friendly water-soluble auxiliary agent of Effective Anti formaldehyde and preparation method.
The environment-friendly type water soluble additive of a kind of anti-formaldehyde that the present invention proposes, described environment-friendly type water soluble additive group is by the solution composition of water, hydroxypropyl methyl fiber, pH value mediator agent, dispersion agent, defoamer, sanitas, Rutile type Titanium Dioxide, wollastonite powder, polymer emulsion, film coalescence aid and ammonia silver, and the ratio of weight and number of each component is:
Water 18.8 ~ 38.8
Hydroxypropyl methyl fiber 0.2 ~ 0.9
PH value mediator agent 0.1 ~ 0.8
Dispersion agent 0.6 ~ 1.3
Defoamer 0.4 ~ 0.6
Sanitas 0.2 ~ 0.6
Rutile type Titanium Dioxide 28.8 ~ 32.8
Wollastonite powder 2.9 ~ 8.9
Polymer emulsion 46.9 ~ 53.7
Film coalescence aid 1.3 ~ 2.1
Ammonia silver solution 0.1 ~ 15.9.
In the present invention, polymer emulsion is water-based poly ACRYLIC EMULSION, and described ammonia silver solution is Ag (NH
3)
2+ OH
-solution.
The preparation method of the aqueous, environmental protective auxiliary agent of the anti-formaldehyde that the present invention proposes, concrete steps are as follows:
(1) each component of precise;
(2) first water joined in portable reactor, then add hydroxypropyl methyl fiber, high speed dispersion, add the dispersion of pH value mediator agent, then add dispersion agent, defoamer, wollastonite powder dispersion successively, add Rutile type Titanium Dioxide dispersion again, make mixed solution;
(3) water-based poly ACRYLIC EMULSION is joined under 500rpm/min agitation condition the mixed solution that step (2) is prepared into;
(4) film coalescence aid is joined under 300rpm/min agitation condition in step (3) products therefrom;
(5) by ammonia silver solution and water mixing, the ammonia silver aqueous solution is made;
(1) ammonia silver aqueous solution step (5) prepared is added drop-wise in step (4) products therefrom under 1000rpm/min agitation condition;
(6) drip sanitas after froth breaking at a slow speed, modulation 300rpm/min stirs 60min.
Beneficial effect of the present invention is: in the environment-friendly type coating of nontoxic pollution-free, add anti-Formaldehyde as Additives.The nontoxic pollution-free of environment-friendly type aqueous coating of described anti-formaldehyde own, spreads upon the woodenware surface containing a large amount of binding agent, is enclosed in wherein by woodenware toxic substances.In woodenware containing formaldehyde substance release by being absorbed in a large number by the auxiliary agent of formaldehyde anti-in water-miscible paint during coating, eliminate poisonous and harmful substances.By release slowly except formaldehyde material, this coating can also the obnoxious flavour such as the formaldehyde that discharges of absorption chamber other objects interior.The environment-friendly type aqueous auxiliary agent of described anti-formaldehyde a kind ofly uses simple to operate, and can eliminate the obnoxious flavoures such as benzene homologues that formaldehyde toxic gas can avoid again common paint to bring and TVOC to the pollution of indoor, be the anti-Formaldehyde as Additives coating excellent effect.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Described environment-friendly type water soluble additive group is by the solution composition of water, hydroxypropyl methyl fiber, pH value mediator agent, dispersion agent, defoamer, sanitas, Rutile type Titanium Dioxide, wollastonite powder, polymer emulsion, film coalescence aid and ammonia silver, and the ratio of weight and number of each component is:
Water 20.8
Hydroxypropyl methyl fiber 0.2
PH value mediator agent 0.1
Dispersion agent 0.6
Defoamer 0.3
Sanitas 0.2
Rutile type Titanium Dioxide 26.8
Wollastonite powder 2.6
Polymer emulsion 46.9
Film coalescence aid 1.3
Ammonia silver solution 0.1
Wherein: described polymer emulsion is water-based poly ACRYLIC EMULSION, described film coalescence aid is 1-Methoxy-2-propyl acetate, described dispersion agent is TEGODispers740W wetting dispersing agent, described defoamer is glycerine polyethenoxy ether, described sanitas is ROHM AND HAAS sanitas, described pH value mediator agent is dimethylaminoethanol, and described ammonia silver solution is Ag (NH
3)
2+ OH
-solution.
Preparation method's concrete steps are as follows:
(1) each component of precise;
(2) first water joined in portable reactor, then add hydroxypropyl methyl fiber, high speed dispersion, add the dispersion of pH value mediator agent, then add dispersion agent, defoamer, wollastonite powder dispersion successively, add Rutile type Titanium Dioxide dispersion again, make mixed solution;
(3) water-based poly ACRYLIC EMULSION is joined under 500rpm/min agitation condition the mixed solution that step (2) is prepared into;
(4) film coalescence aid is joined under 300rpm/min agitation condition the mixed solution that step (3) is prepared into;
(5) by ammonia silver solution and water mixing, the ammonia silver aqueous solution is made;
(1) ammonia silver aqueous solution step (5) prepared is added drop-wise to the aqueous solution prepared by step (4) under 1000rpm/min agitation condition;
(1) drip sanitas after froth breaking at a slow speed, modulation 300rpm/min stirs 60min.
Embodiment 2
Described environment-friendly type water soluble additive group is by the solution composition of water, hydroxypropyl methyl fiber, pH value mediator agent, dispersion agent, defoamer, sanitas, Rutile type Titanium Dioxide, wollastonite powder, polymer emulsion, film coalescence aid and ammonia silver, and the ratio of weight and number of each component is:
Water 19.8
Hydroxypropyl methyl fiber 0.2
PH value mediator agent 0.2
Dispersion agent 0.4
Defoamer 0.5
Sanitas 0.1
Rutile type Titanium Dioxide 25.8
Wollastonite powder 2.9
Polymer emulsion 48.6
Film coalescence aid 1.3
Ammonia silver solution 0.1
Wherein: described polymer emulsion is water-based poly ACRYLIC EMULSION, described film coalescence aid is 1-Methoxy-2-propyl acetate, described dispersion agent is TEGODispers740W wetting dispersing agent, described defoamer is glycerine polyethenoxy ether, described sanitas is ROHM AND HAAS sanitas, described pH value mediator agent is dimethylaminoethanol, and described ammonia silver solution is Ag (NH
3)
2+ OH
-solution.
Described preparation method is with embodiment 1.Described film coalescence aid is 1-Methoxy-2-propyl acetate, described dispersion agent is TEGODispers740W wetting dispersing agent, and described defoamer is glycerine polyethenoxy ether, and described sanitas is ROHM AND HAAS sanitas, described pH value mediator agent is dimethylaminoethanol
Embodiment 3
The positively effect that the present invention produces: the present invention adds anti-Formaldehyde as Additives material by common ring water-retentivity paint, becomes a kind of not only nontoxic but also can except the coating of formaldehyde.Relative common water borne paint effect of the present invention is obvious, for wood-based plate: the encloses container wood-based plate that the market of 25cm*25cm is bought (seven centimetres) two blocks of plates being put into respectively 20L, measure concentration of formaldehyde value in each encloses container with 4160 type methylene oxide detecting instruments after 24 hours, and record this numerical value.Then take out wood-based plate and brush the finished product of filling a prescription described in common ring water-retentivity paint and the present embodiment respectively, brushed one times every 1 hour, brush three times, puts into encloses container after 24 hours finish-dryings more altogether.Measure concentration of formaldehyde value in encloses container with 4160 type methylene oxide detecting instruments again after airtight 24 hours, and record this numerical value.
Detecting instrument: detecting instrument is the imported from America 4160 type methylene oxide detecting instrument that national standard metering is assert, display density value numeral while detection.4160 type methylene oxide detecting instruments measure numerical value and laboratory chemical method detected value obtain deviation, generally within 5%, maximum can not more than 25%.
Experimental results:
After 24 hours, formaldehyde clearance is: No. 1 (2.33-1.85)/2.33=20.6%
No. 2 (2.45-0.27)/2.45=88.9%
Comparative test result illustrates: No. 1 and No. 2 Experimental Comparison data can be found out, the successful of anti-formaldehyde water-miscible paint than common water borne paint successful many.
Claims (3)
1. the environment-friendly type water soluble additive of an anti-formaldehyde, it is characterized in that described environment-friendly type water soluble additive group is by the solution composition of water, hydroxypropyl methyl fiber, pH value mediator agent, dispersion agent, defoamer, sanitas, Rutile type Titanium Dioxide, wollastonite powder, polymer emulsion, film coalescence aid and ammonia silver, the ratio of weight and number of each component is:
Water 18.8 ~ 38.8
Hydroxypropyl methyl fiber 0.2 ~ 0.9
PH value mediator agent 0.1 ~ 0.8
Dispersion agent 0.6 ~ 1.3
Defoamer 0.4 ~ 0.6
Sanitas 0.2 ~ 0.6
Rutile type Titanium Dioxide 28.8 ~ 32.8
Wollastonite powder 2.9 ~ 8.9
Polymer emulsion 46.9 ~ 53.7
Film coalescence aid 1.3 ~ 2.1
Ammonia silver solution 0.1 ~ 15.9.
2. the environment-friendly type water soluble additive of anti-formaldehyde according to claim 1, described polymer emulsion is water-based poly ACRYLIC EMULSION, and described ammonia silver solution is Ag (NH
3)
2+ OH
-solution.
3. a preparation method for the aqueous, environmental protective auxiliary agent of anti-formaldehyde as claimed in claim 1, is characterized in that concrete steps are as follows:
(1) each component of precise;
(2) first water joined in portable reactor, then add hydroxypropyl methyl fiber, high speed dispersion, add the dispersion of pH value mediator agent, then add dispersion agent, defoamer, wollastonite powder dispersion successively, add Rutile type Titanium Dioxide dispersion again, make mixed solution;
(3) water-based poly ACRYLIC EMULSION is joined under 500rpm/min agitation condition the mixed solution that step (2) is prepared into;
(4) film coalescence aid is joined under 300rpm/min agitation condition in step (3) products therefrom;
(5) by ammonia silver solution and water mixing, the ammonia silver aqueous solution is made;
(6) ammonia silver aqueous solution step (5) prepared is added drop-wise in step (4) products therefrom under 1000rpm/min agitation condition;
(7) drip sanitas after froth breaking at a slow speed, modulation 300rpm/min stirs 60min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610119187.6A CN105566993A (en) | 2016-03-03 | 2016-03-03 | Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610119187.6A CN105566993A (en) | 2016-03-03 | 2016-03-03 | Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105566993A true CN105566993A (en) | 2016-05-11 |
Family
ID=55877657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610119187.6A Pending CN105566993A (en) | 2016-03-03 | 2016-03-03 | Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105566993A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325611A (en) * | 2017-06-28 | 2017-11-07 | 安徽慕曼德家具有限公司 | A kind of furniture anticorrosive paint additive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101020794A (en) * | 2007-03-23 | 2007-08-22 | 陈晓鹏 | Green water-base lacquer without formaldehyde and its prepn |
| CN104559596A (en) * | 2014-12-26 | 2015-04-29 | 三棵树涂料股份有限公司 | Anti-formaldehyde waterborne wood primer and preparation method thereof |
| CN104845481A (en) * | 2015-05-20 | 2015-08-19 | 上海韬鸿化工科技有限公司 | Environment-friendly coating capable of removing formaldehyde |
-
2016
- 2016-03-03 CN CN201610119187.6A patent/CN105566993A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101020794A (en) * | 2007-03-23 | 2007-08-22 | 陈晓鹏 | Green water-base lacquer without formaldehyde and its prepn |
| CN104559596A (en) * | 2014-12-26 | 2015-04-29 | 三棵树涂料股份有限公司 | Anti-formaldehyde waterborne wood primer and preparation method thereof |
| CN104845481A (en) * | 2015-05-20 | 2015-08-19 | 上海韬鸿化工科技有限公司 | Environment-friendly coating capable of removing formaldehyde |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325611A (en) * | 2017-06-28 | 2017-11-07 | 安徽慕曼德家具有限公司 | A kind of furniture anticorrosive paint additive |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104046146A (en) | Building coating capable of removing methyl aldehyde and preparation method of building coating | |
| CN102277059A (en) | Novel stone paint | |
| CN106634377B (en) | A kind of aqueous metallic finishe and preparation method thereof suitable for common aluminium powder | |
| CN105086650A (en) | Environment-friendly architectural paint capable of absorbing formaldehyde and preparation method of architectural paint | |
| CN105017906A (en) | Water-in-water multi-color water paint and preparation method thereof | |
| CN106147487A (en) | Interior anion is except methanal paint and preparation method thereof | |
| CN105418044B (en) | A kind of preparation method of mould proof Thistle board | |
| CN106243961A (en) | Display screen processing aqueous peelable glue and preparation method thereof | |
| CN107459874A (en) | A kind of sealer and preparation method thereof | |
| CN105713498B (en) | A kind of aqueous handfeel paint and its film build method for automobile interior decoration | |
| CN101684395A (en) | Additive composite for eliminating formaldehyde in adhesive and preparation method thereof | |
| CN105566993A (en) | Anti-formaldehyde environment-friendly type water-soluble assistant and preparation method thereof | |
| CN102775897B (en) | Environmentally-friendly polyurethane finish capable of decomposing formaldehyde and preparation method thereof | |
| CN103242729A (en) | Anti-mosquito water-soluble environmental-friendly nanometer activated carbon wall paint and preparation method thereof | |
| CN103232775B (en) | A kind of water soluble anti-corrosion paint and preparation method thereof | |
| CN103232776A (en) | Water-soluble environment-friendly anticorrosive coating and preparation method thereof | |
| CN103232774A (en) | Corrosion-resisting and rust-resisting paint | |
| CN103265861B (en) | A kind of Water-soluble low-bubble environment-friendlyantiseptic antiseptic coating and preparation method thereof | |
| CN112358832A (en) | Carpet adhesive for removing formaldehyde, preparation method and application thereof | |
| CN108610934A (en) | Single-component polyurethane water-proof paint and preparation method thereof and the composition for being used to prepare the single-component polyurethane water-proof paint | |
| CN102964964B (en) | Self-drying epoxy anticorrosive paint and application method | |
| CN112772669A (en) | Iprodione and procymidone suspending agent and preparation method thereof | |
| CN112795213A (en) | Inorganic aldehyde-removing coating and application thereof | |
| CN105567035A (en) | Negative ion coating and preparation method thereof | |
| CN108822650A (en) | A kind of low-cost internal-external wall emulsion paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160511 |
|
| WD01 | Invention patent application deemed withdrawn after publication |