CN103232774A - Corrosion-resisting and rust-resisting paint - Google Patents
Corrosion-resisting and rust-resisting paint Download PDFInfo
- Publication number
- CN103232774A CN103232774A CN2013102124451A CN201310212445A CN103232774A CN 103232774 A CN103232774 A CN 103232774A CN 2013102124451 A CN2013102124451 A CN 2013102124451A CN 201310212445 A CN201310212445 A CN 201310212445A CN 103232774 A CN103232774 A CN 103232774A
- Authority
- CN
- China
- Prior art keywords
- parts
- resisting
- antirusting paint
- paint
- corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a corrosion-resisting and rust-resisting paint. A raw material portion of the corrosion-resisting and rust-resisting paint consists of the following ingredients in parts by weight: 36-47 parts of water-soluble acrylic resin, 13-20 parts of sodium citrate, 10-15 parts of zinc chloride and 8-10 parts of nano aluminum chloride. The paint further comprises an adjuvant portion which consists of a dispersant, a lubricant and a biological preservative. The corrosion-resisting and rust-resisting paint disclosed by the invention has the TVOC (Total Volatile Organic Compound) value of 0 g/l and the formaldehyde emission of 0 g/l; and one or more of essential oils and tea polyphenols serve as the biological preservative, so that the corrosion-resisting and rust-resisting paint is environment-friendly and has a good corrosion resisting effect.
Description
Technical field
The present invention relates to a kind of coating, relate to a kind of anti-corrosive antirusting paint specifically, belong to the chemistry painting industry technical field.
Background technology
A large amount of chemical that use such as referring to various buildings materials and finishing material discharge in the fitment process pollution and sterilant, reodorant, perfume compound are polluted in house decoration, the pollution that indoor environment is caused.People have accounted for 80～90 parts of whole day in the time of indoor study, work and life; " room air pollution " paid attention to by increasing people; and coating pollution is the arch-criminal of indoor environmental pollution, and the material that is coated on the fine bonding of body surface and other materials and forms whole and tough and tensile protective membrane is called coating.Be identical concept at architectural coating and paint.Coating in the market mainly is divided into water-borne coatings and solvent based coating.Just can detect more than 50 kind of organism such as a large amount of benzene, toluene, ethylbenzene, dimethylbenzene, acetone, N-BUTYL ACETATE, acetaldehyde, butanols, formic acid in the space air of brushing paint, produce organic solvent volatile matter (voc) contaminate environment.The contained above-mentioned organic volatile of traditional solvent based coating can damage people's respiratory system, hematopoietic function, immunity system, even causes the disease of aspects such as some heredity.
Because to environmental protection and the attention of health at home, water-borne coatings has progressively replaced conventional solvent type coating, because the technology content of water-borne coatings is higher, most domestic manufacturers production difficulty is bigger, and solvent reducible coatings is still propagated its belief on a large scale, and accounts for absolute main flow.
For the loss that external world infringement is caused is reduced to minimum level, guarantee the tolerance that the surface behind the sprayed coating is attacked to external world, add anticorrosion in the coating as far as possible and be imperative.Sanitas in the adding coating of using always comprises organic mercury, lead, organotin, phenol, formaldehyde or dichromate at present, but because big to the person poultry toxicity, environmental pollution is serious, and part developed country has forbidden its use.
Summary of the invention
The objective of the invention is provides a kind of anti-corrosive antirusting paint in order to overcome above-mentioned the deficiencies in the prior art, and the nonpoisonous and tasteless poisonous chemical organic solvent of routine that do not contain of this anti-corrosive antirusting paint does not add poisonous coating antiseptic, is conducive to environmental requirement.
Anti-corrosive antirusting paint of the present invention is realized with following technical scheme:
A kind of anti-corrosive antirusting paint, it is characterized in that, partly fill a prescription composed of the following components in its raw material of weight part: water soluble acrylic resin 40-42 part, Sodium Citrate 18-20 part, zinc chloride 12-15 part, 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride 9-10 parts, barium sulfate 6-15 part, red lead 3-9 part, pimelinketone 10-12 part; Described coating also comprises by dispersion agent, lubricant, the auxiliary material part that biological preservative is formed; The TVOC value of described anti-corrosive antirusting paint is 0 g/l., and burst size of methanal is 0 g/l.
Preferably, described dispersion agent is derivatived cellulose.Here the derivatived cellulose that allows to use comprises cellulose nitrate, cellulose ethanoate, cellulose acetate butyrate and cellulose xanthate.Cellulose ethers has: a kind of in methylcellulose gum, carboxymethyl cellulose, ethyl cellulose, Natvosol, cyanoethyl cellulose, hydroxypropylcellulose and the Vltra tears or two or more mixture.
Preferably, described lubricant is the mixture of silicone oil and phosphoric acid ester, and the volume ratio of described silicone oil and phosphoric acid ester is 5:1.
More preferably, described biological preservative is selected from the mixture into volatile oil extracted from eucalyptus' leaves or twigs and tea-polyphenol, and described volatile oil extracted from eucalyptus' leaves or twigs is 5:3 with the mixed volume ratio of tea-polyphenol.
The preparation method of anti-corrosive antirusting paint coating of the present invention comprises the steps:
(1) takes by weighing following component according to mass parts: water soluble acrylic resin 40-42 part, Sodium Citrate 18-20 part, zinc chloride 12-15 part, 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride 9-10 parts, barium sulfate 6-15 part, red lead 3-9 part, pimelinketone 10-12 part is evenly mixed, obtain the composition of raw materials mixture, add deionized water in the composition of raw materials mixture, use agitator to stir, agitator speed is 20 rev/mins, stirring at normal temperature 30 minutes obtains the partially mixed solution of raw material;
(2) in the above-mentioned raw materials partially aqueous solution, add dispersion agent, lubricant, anti-settling agent, biological preservative, adjusting rotating speed is 150 rev/mins, stirring at normal temperature 60 minutes, regulating the ph value simultaneously is 7.5, obtains the crude product mixed solution;
(3) above-mentioned crude product mixed solution normal temperature is ground to no particle, obtains anti-corrosive antirusting paint.
The invention has the beneficial effects as follows: this anti-corrosive antirusting paint coating with water is solvent, and is nonpoisonous and tasteless, and wherein the sanitas of Tian Jiaing, rust-preventive agent are biological preservative, and the TVOC value is less than 0.0001mg/l after testing.
The present invention will be further described below in conjunction with embodiment:
Embodiment:
Embodiment 1
1.1 the preparation of anti-corrosive antirusting paint
A kind of anti-corrosive antirusting paint, partly fill a prescription composed of the following components in its raw material of weight part: water soluble acrylic resin 40-42 part, Sodium Citrate 18-20 part, zinc chloride 12-15 part, 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride 9-10 parts, barium sulfate 6-15 part, red lead 3-9 part, pimelinketone 10-12 part; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
The preparation method of described anti-corrosive antirusting paint coating is characterized in that, comprises the steps:
(1) takes by weighing following component according to mass parts: 40 parts of water soluble acrylic resins, 18 parts of Sodium Citrates, 14 parts of zinc chloride, 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride 9,13 parts in barium sulfate, 8 parts of red lead, 12 parts of pimelinketone; Evenly mix, obtain the composition of raw materials mixture, add deionized water in the composition of raw materials mixture, use agitator to stir, agitator speed is 20 rev/mins, and stirring at normal temperature 30 minutes obtains the partially mixed solution of raw material;
(2) adding mass parts in the above-mentioned raw materials partially aqueous solution is 13 parts of Natvosols, volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol, adjusting rotating speed is 150 rev/mins, stirring at normal temperature 60 minutes, regulating the ph value simultaneously is 7.5, obtains the crude product mixed solution;
(3) above-mentioned crude product mixed solution normal temperature is ground to no particle, obtains anti-corrosive antirusting paint.
1.2 measure total volatile organic compound (TVOC) of anti-corrosive antirusting paint and the content of free formaldehyde
1.2.1 preparation reference standard mixing solutions:
Diethylene glycol monobutyl ether
Butyl carbitol acetate
Butanols
Butyl acrylate
The 2-ethylhexyl acrylate
Vinylbenzene
Vinyl acetate
Above-mentioned reference material will wait quality to take by weighing, and every kind claims 1 g, accurately really to 0.001 mg, places the airtight bottle of barrier film, with PH be 5 citrate buffer solution 1L as solvent, obtain the reference standard mixing solutions.
1.2.2 Gas chromatography detects
Be benchmark with the reference standard mixing solutions, with the anti-corrosive antirusting paint 1:1000 dilution of embodiment 1 preparation, carry out stratographic analysis.
1.2.3 measurement result
1.3 measure the antiseptic and rustproof effect of described coating
Embodiment 2
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 41 parts of water soluble acrylic resins, 19 parts of Sodium Citrates, 14 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 13 parts in barium sulfate, 6 parts of red lead, 11 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 3
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 42 parts of water soluble acrylic resins, 20 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 15 parts in barium sulfate, 9 parts of red lead, 12 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 4
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 42 parts of water soluble acrylic resins, 20 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 6 parts in barium sulfate, 9 parts of red lead, 12 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 5
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 42 parts of water soluble acrylic resins, 20 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 9 parts in barium sulfate, 7 parts of red lead, 12 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 6
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 43 parts of water soluble acrylic resins, 19 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 9 parts in barium sulfate, 8 parts of red lead, 12 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 7
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 42 parts of water soluble acrylic resins, 20 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 12 parts in barium sulfate, 8 parts of red lead, 11 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
Embodiment 8
A kind of anti-corrosive antirusting paint is partly filled a prescription composed of the following components in its raw material of weight part: 42 parts of water soluble acrylic resins, 20 parts of Sodium Citrates, 15 parts of zinc chloride, 10 parts in 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride, 14 parts in barium sulfate, 8 parts of red lead, 11 parts of pimelinketone; Described coating also comprises: mass parts is 13 parts derivatived cellulose, and volume ratio is 13 parts in the mixture of the silicone oil of 5:1 and phosphoric acid ester, and volume ratio is 8 parts in the mixture of the volatile oil extracted from eucalyptus' leaves or twigs of 5:3 and tea-polyphenol.
The above; only be to preferred embodiment of the present invention; be not that the present invention is done other forms of restriction; any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent embodiment of equal variation; every disengaging the present invention program content; according to any simple modification that technical spirit of the present invention is done above embodiment, equivalent variations and remodeling all drop in protection scope of the present invention.
Claims (4)
1. anti-corrosive antirusting paint, it is characterized in that, partly fill a prescription composed of the following components in its raw material of weight part: water soluble acrylic resin 40-42 part, Sodium Citrate 18-20 part, zinc chloride 12-15 part, 1,900 ten thousand orders ~ 2,000 ten thousand purpose aluminum chloride 9-10 parts, barium sulfate 6-15 part, red lead 3-9 part, pimelinketone 10-12 part; Described coating also comprises by dispersion agent, lubricant, the auxiliary material part that biological preservative is formed; The TVOC value of described anti-corrosive antirusting paint is 0 g/l., and burst size of methanal is 0 g/l.
2. anti-corrosive antirusting paint according to claim 1, described dispersion agent is derivatived cellulose.
3. anti-corrosive antirusting paint according to claim 1, described lubricant is the mixture of silicone oil and phosphoric acid ester, the volume ratio of described silicone oil and phosphoric acid ester is 5:1.
4. anti-corrosive antirusting paint according to claim 1, described biological preservative is selected from the mixture into volatile oil extracted from eucalyptus' leaves or twigs and tea-polyphenol, and the mixed volume of described volatile oil extracted from eucalyptus' leaves or twigs and tea-polyphenol is than being 5:3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102124451A CN103232774A (en) | 2013-05-31 | 2013-05-31 | Corrosion-resisting and rust-resisting paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102124451A CN103232774A (en) | 2013-05-31 | 2013-05-31 | Corrosion-resisting and rust-resisting paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103232774A true CN103232774A (en) | 2013-08-07 |
Family
ID=48880847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102124451A Pending CN103232774A (en) | 2013-05-31 | 2013-05-31 | Corrosion-resisting and rust-resisting paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103232774A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313597A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Water-based antirust agent containing green tea extracts and preparation method of water-based antirust agent |
| CN104761964A (en) * | 2015-03-04 | 2015-07-08 | 浙江万佳热电器科技有限公司 | Preparation technology for electrothermal film heating pipe insulation protection material |
| ITUA20162167A1 (en) * | 2016-03-31 | 2017-10-01 | Bio Eco Active S R L | Manufactured product comprising an antioxidant agent and a bacteriostatic action agent and related production process. |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3112449A1 (en) * | 1980-04-03 | 1982-02-25 | Deutsche Itt Industries Gmbh, 7800 Freiburg | "GLASS COMPOSITION, METHOD FOR PRODUCING AND USE AS ANTI-CORROSION COATING OF METAL SURFACES" |
| CN1382755A (en) * | 2001-04-25 | 2002-12-04 | 湖南华菱管线股份有限公司涟钢事业部 | Anticorrosion paint and its preparing process |
| CN101186767A (en) * | 2007-08-29 | 2008-05-28 | 重庆丰博科技发展有限公司 | Slow release type biological anti-fouling paint |
| CN103085526A (en) * | 2011-11-03 | 2013-05-08 | 中国科学院化学研究所 | Printing plate material for ink-jet printing direct-to-plate and preparation method of printing plate material |
| CN103102725A (en) * | 2013-03-19 | 2013-05-15 | 郭漫笳 | Coating containing tea dust and tea polyphenol and preparation method of coating |
-
2013
- 2013-05-31 CN CN2013102124451A patent/CN103232774A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3112449A1 (en) * | 1980-04-03 | 1982-02-25 | Deutsche Itt Industries Gmbh, 7800 Freiburg | "GLASS COMPOSITION, METHOD FOR PRODUCING AND USE AS ANTI-CORROSION COATING OF METAL SURFACES" |
| CN1382755A (en) * | 2001-04-25 | 2002-12-04 | 湖南华菱管线股份有限公司涟钢事业部 | Anticorrosion paint and its preparing process |
| CN101186767A (en) * | 2007-08-29 | 2008-05-28 | 重庆丰博科技发展有限公司 | Slow release type biological anti-fouling paint |
| CN103085526A (en) * | 2011-11-03 | 2013-05-08 | 中国科学院化学研究所 | Printing plate material for ink-jet printing direct-to-plate and preparation method of printing plate material |
| CN103102725A (en) * | 2013-03-19 | 2013-05-15 | 郭漫笳 | Coating containing tea dust and tea polyphenol and preparation method of coating |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313597A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Water-based antirust agent containing green tea extracts and preparation method of water-based antirust agent |
| CN104761964A (en) * | 2015-03-04 | 2015-07-08 | 浙江万佳热电器科技有限公司 | Preparation technology for electrothermal film heating pipe insulation protection material |
| CN104761964B (en) * | 2015-03-04 | 2016-11-30 | 浙江万佳热电器科技有限公司 | A kind of preparation technology of heating tube with electric heating film isolation protective material |
| ITUA20162167A1 (en) * | 2016-03-31 | 2017-10-01 | Bio Eco Active S R L | Manufactured product comprising an antioxidant agent and a bacteriostatic action agent and related production process. |
| WO2017168357A1 (en) * | 2016-03-31 | 2017-10-05 | Bio Eco Active S.R.L. | Article comprising an antioxidizing agent and a bacteriostatic agent and a production process thereof |
| KR20180132738A (en) * | 2016-03-31 | 2018-12-12 | 바이오 에코 액티브 에스.알.엘. | Articles containing antioxidants and bacteriostats and processes for their production |
| US11178874B2 (en) | 2016-03-31 | 2021-11-23 | Benvic Sas | Articles comprising antioxidizing agents and bacteriostatic agents, and production processes thereof |
| KR102391639B1 (en) | 2016-03-31 | 2022-04-27 | 벤빅 에스에이에스 | Articles comprising antioxidants and bacteriostatic agents and processes for their manufacture |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104140732B (en) | A kind of water paint of high salt fog high durable and preparation method thereof | |
| CN101429402A (en) | Watersoluble metal self-drying antirusting paint | |
| CN103013337B (en) | A kind of metal protection coating and hot-dip galvanized metal material and hot-dip aluminizing zinc metallic substance | |
| CN102093799A (en) | Water-borne metal self-drying antirusting paint | |
| CN102277059A (en) | Novel stone paint | |
| CN106634377B (en) | A kind of aqueous metallic finishe and preparation method thereof suitable for common aluminium powder | |
| CN101260275A (en) | Water woodenware paint and preparation method thereof | |
| CN102746768A (en) | Water-borne colorful glass paint and preparation method and application thereof | |
| CN106995650A (en) | A kind of showcase aqueous finish paint | |
| CN103232774A (en) | Corrosion-resisting and rust-resisting paint | |
| CN109439168A (en) | A kind of water high light pool two-component polyurethane aluminium paint and preparation method thereof | |
| CN106752555A (en) | Formaldehydeless green inner wall paint of a kind of net taste and preparation method thereof | |
| CN104119708A (en) | Inorganic zinc-rich anticorrosive paint | |
| CN103232775B (en) | A kind of water soluble anti-corrosion paint and preparation method thereof | |
| CN103232776A (en) | Water-soluble environment-friendly anticorrosive coating and preparation method thereof | |
| CN102676009A (en) | Anionic ecological multicolour paint and preparation method thereof | |
| CN111205710B (en) | Quick-drying type water-based color modifier and preparation method thereof | |
| CN103242726B (en) | Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint that mildew-resistant is fungi-proofing and preparation method thereof | |
| CN103265861B (en) | A kind of Water-soluble low-bubble environment-friendlyantiseptic antiseptic coating and preparation method thereof | |
| CN101148552A (en) | Micro VOC anion environmental protection inner wall paint | |
| CN103242729A (en) | Anti-mosquito water-soluble environmental-friendly nanometer activated carbon wall paint and preparation method thereof | |
| CN102295851A (en) | Alcohol-soluble inorganic zinc silicate anti-corrosive coating curing agent without chloride ions | |
| CN103360841B (en) | A kind of metal protection coating and uses thereof and hot-dip metal plated material | |
| CN108531007A (en) | A kind of anticorrosive aqueous turn fire prevention priming paint and preparation method thereof that becomes rusty | |
| CN103265859B (en) | A kind of high light transmittance coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130807 |