CN104559515A - 一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法 - Google Patents

一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法 Download PDF

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CN104559515A
CN104559515A CN201410790093.2A CN201410790093A CN104559515A CN 104559515 A CN104559515 A CN 104559515A CN 201410790093 A CN201410790093 A CN 201410790093A CN 104559515 A CN104559515 A CN 104559515A
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vinyl acetate
protective film
acetate resin
coating
vinyl chloride
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杨瑞
张鹏飞
原玲
曹文健
房昺
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • C—CHEMISTRY; METALLURGY
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
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    • C09D7/63—Additives non-macromolecular organic
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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Abstract

本发明涉及一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法，所述涂料的组分及质量份数比为：氯醋树脂50～70份，增塑剂20～30份，触变剂1～5份，填料1～5份，颜料0～1份，制备该涂料的方法是首先按组分配比称取原料，将氯醋树脂、增塑剂、填料、颜料依次加入搅拌釜中搅拌，搅拌均匀后，加入触变剂，再次搅拌均匀，最后通过三辊研磨机分散均匀后出料。该涂料的优点是：1.非溶剂型，安全环保；2.施工工艺性能好；3.该涂料在加热后才会成膜，保存方便。

Description

一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法
技术领域
本发明涉及一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法，属于涂料及制备技术领域。
背景技术
可剥离保护膜涂料是一种涂覆于基材表面，用于隔绝侵蚀介质，从而防止基材划伤、腐蚀、磨损及污染等的材料，在完成保护后可方便的从被保护表面剥离。目前市面上销售的可剥离保护膜涂料多为溶剂型体系，在施工过程中污染严重，对工人的健康造成较大的影响。另外，由于溶剂的挥发，溶剂型可剥离保护膜涂料需要密封保存，与空气接触后容易成膜，给施工带来不便。
发明内容
本发明正是针对上述现有产品的不足而设计提供了一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法，其目的是提供一种非溶剂型、施工工艺性能好的可剥离保护膜涂料及其制备方法，该涂料在加热后才会成膜，保存方便。
本发明的目的是通过以下技术方案来实现的：
本发明技术方案提供了一种临时保护用非溶剂型可剥离保护膜涂料，其特征在于：所述涂料的组分及质量份数比为：
其中：
所述氯醋树脂的聚合度为800～2000，醋酸乙烯在氯醋树脂中的重量百分比为2％～20％；
所述氯醋树脂是由不同聚合度、不同醋酸乙烯含量的氯醋树脂混合而成；
所述增塑剂为邻苯二甲酸二辛脂、对苯二甲酸二辛酯、己二酸二辛脂、癸二酸二丁酯、癸二酸二辛酯、环氧大豆油或环氧亚麻子油中的一种或几种混合物；
所述触变剂为气相二氧化硅、沉淀二氧化硅、有机膨润土或高岭土中的一种或几种混合物；
所述的填料为碳酸钙、石英粉、硬脂酸钡或硬脂酸钙中的一种或几种混合物；
所述颜料为铁蓝、群青蓝或酞菁蓝。
本发明技术方案还提供了制备上述临时保护用非溶剂型可剥离保护膜涂料的方法，其特征在于：该方法首先按组分配比称取原料，将氯醋树脂、增塑剂、填料、颜料依次加入搅拌釜中搅拌，搅拌均匀后，加入触变剂，再次搅拌均匀，最后通过三辊研磨机分散均匀后出料。
本发明技术方案所述涂料的优点是：1.非溶剂型，安全环保；2.施工工艺性能好；3.该涂料在加热后才会成膜，保存方便。
具体实施方式
以下将结合实施例对本发明技术方案作进一步地详述：
表1为本发明技术方案所述临时保护用非溶剂型可剥离保护膜涂料的实施例的组分及配比，制备涂料的方法是首先按组分配比称取原料，将氯醋树脂、增塑剂、填料、颜料依次加入搅拌釜中搅拌，搅拌均匀后，加入触变剂，再次搅拌均匀，最后通过三辊研磨机分散均匀后出料。
表1中实施例1为无色近透明涂料配方；实施例2、3、4为蓝色涂料配方。表2为实施例2的涂料的性能测试结果。测试结果表明：该种涂料在触摸屏、电路板、玻璃、金属等表面均具有良好的可剥离性，加热后成膜，具有优异的工艺适应性，同时存储稳定，能满足临时保护的工艺要求。
表2涂料性能测试结果
检测项目 检测结果
颜色及外观 蓝色粘稠液体
粘度 30±1Pa·s
成膜条件 (140～150)℃×(10～15)min
可剥性 触摸屏、电路板、玻璃、金属等表面均能良好剥离

Claims (3)

1.一种临时保护用非溶剂型可剥离保护膜涂料，其特征在于：所述涂料的组分及质量份数比为：
其中：
所述氯醋树脂的聚合度为800～2000，醋酸乙烯在氯醋树脂中的重量百分比为2％～20％；
所述增塑剂为邻苯二甲酸二辛脂、对苯二甲酸二辛酯、己二酸二辛脂、癸二酸二丁酯、癸二酸二辛酯、环氧大豆油或环氧亚麻子油中的一种或几种混合物；
所述触变剂为气相二氧化硅、沉淀二氧化硅、有机膨润土或高岭土中的一种或几种混合物；
所述的填料为碳酸钙、石英粉、硬脂酸钡或硬脂酸钙中的一种或几种混合物；
所述颜料为铁蓝、群青蓝或酞菁蓝。
2.根据权利要求1所述的临时保护用非溶剂型可剥离保护膜涂料，其特征在于：所述氯醋树脂是由不同聚合度、不同醋酸乙烯含量的氯醋树脂混合而成。
3.一种制备权利要求1所述的临时保护用非溶剂型可剥离保护膜涂料的方法，其特征在于：该方法首先按组分配比称取原料，将氯醋树脂、增塑剂、填料、颜料依次加入搅拌釜中搅拌，搅拌均匀后，加入触变剂，再次搅拌均匀，最后通过三辊研磨机分散均匀后出料。
CN201410790093.2A 2014-12-17 2014-12-17 一种临时保护用非溶剂型可剥离保护膜涂料及其制备方法 Pending CN104559515A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108129925A (zh) * 2018-01-03 2018-06-08 厦门蓝科电子科技有限公司 一种热固型可剥蓝胶及其制备方法
CN113396193A (zh) * 2019-02-08 2021-09-14 Ppg工业俄亥俄公司 可剥离样本

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101096487A (zh) * 2006-06-30 2008-01-02 天津市振东涂料有限公司 金属表面暂时性保护用涂料制造方法
CN102219965A (zh) * 2011-05-20 2011-10-19 潍坊胜达科技股份有限公司 抗静电、阻燃及环境稳定的可剥离保护膜及其制备方法
CN102807785A (zh) * 2012-08-06 2012-12-05 武汉理工大学 一种非溶剂型耐高温可剥离保护油墨及其制备方法
CN102936469A (zh) * 2012-10-30 2013-02-20 武汉理工大学 一种热烘型耐迁移可剥离蓝胶及其制备方法
CN103031025A (zh) * 2013-01-06 2013-04-10 北京海斯迪克新材料有限公司 触摸屏临时保护用热固化非溶剂型可剥蓝胶及制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101096487A (zh) * 2006-06-30 2008-01-02 天津市振东涂料有限公司 金属表面暂时性保护用涂料制造方法
CN102219965A (zh) * 2011-05-20 2011-10-19 潍坊胜达科技股份有限公司 抗静电、阻燃及环境稳定的可剥离保护膜及其制备方法
CN102807785A (zh) * 2012-08-06 2012-12-05 武汉理工大学 一种非溶剂型耐高温可剥离保护油墨及其制备方法
CN102936469A (zh) * 2012-10-30 2013-02-20 武汉理工大学 一种热烘型耐迁移可剥离蓝胶及其制备方法
CN103031025A (zh) * 2013-01-06 2013-04-10 北京海斯迪克新材料有限公司 触摸屏临时保护用热固化非溶剂型可剥蓝胶及制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
卓昌明主编: "《塑料应用技术手册》", 31 May 2013, 机械工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108129925A (zh) * 2018-01-03 2018-06-08 厦门蓝科电子科技有限公司 一种热固型可剥蓝胶及其制备方法
CN113396193A (zh) * 2019-02-08 2021-09-14 Ppg工业俄亥俄公司 可剥离样本

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Application publication date: 20150429