CN104556205A - 一种利用电解锌废渣环保生产饲料级硫酸锌的工艺方法 - Google Patents
一种利用电解锌废渣环保生产饲料级硫酸锌的工艺方法 Download PDFInfo
- Publication number
- CN104556205A CN104556205A CN201410845627.7A CN201410845627A CN104556205A CN 104556205 A CN104556205 A CN 104556205A CN 201410845627 A CN201410845627 A CN 201410845627A CN 104556205 A CN104556205 A CN 104556205A
- Authority
- CN
- China
- Prior art keywords
- zinc
- solution
- content
- zinc sulfate
- waste residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 83
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 62
- 229960001763 zinc sulfate Drugs 0.000 title claims abstract description 52
- 229910000368 zinc sulfate Inorganic materials 0.000 title claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000002893 slag Substances 0.000 title abstract 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 title abstract 3
- 238000000034 method Methods 0.000 claims abstract description 55
- 239000012535 impurity Substances 0.000 claims abstract description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 claims abstract description 32
- 239000002184 metal Substances 0.000 claims abstract description 32
- 238000003756 stirring Methods 0.000 claims abstract description 30
- 239000000706 filtrate Substances 0.000 claims abstract description 29
- 238000001914 filtration Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000047 product Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 229910052742 iron Inorganic materials 0.000 claims abstract description 19
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 13
- 239000011575 calcium Substances 0.000 claims abstract description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- 239000001301 oxygen Substances 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 8
- RNZCSKGULNFAMC-UHFFFAOYSA-L zinc;hydrogen sulfate;hydroxide Chemical compound O.[Zn+2].[O-]S([O-])(=O)=O RNZCSKGULNFAMC-UHFFFAOYSA-L 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 5
- 239000004571 lime Substances 0.000 claims abstract description 5
- RZLVQBNCHSJZPX-UHFFFAOYSA-L zinc sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[O-]S([O-])(=O)=O RZLVQBNCHSJZPX-UHFFFAOYSA-L 0.000 claims description 73
- 239000002699 waste material Substances 0.000 claims description 45
- 238000006243 chemical reaction Methods 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 27
- 239000013078 crystal Substances 0.000 claims description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- 230000007613 environmental effect Effects 0.000 claims description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 12
- 238000003672 processing method Methods 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 11
- 230000032683 aging Effects 0.000 claims description 11
- 238000002425 crystallisation Methods 0.000 claims description 11
- 238000009423 ventilation Methods 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 10
- 239000001117 sulphuric acid Substances 0.000 claims description 9
- 235000011149 sulphuric acid Nutrition 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 229910052785 arsenic Inorganic materials 0.000 claims description 8
- -1 iron ion Chemical class 0.000 claims description 8
- 239000003352 sequestering agent Substances 0.000 claims description 8
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- MZNYADCLSDCSHV-UHFFFAOYSA-N sulfuric acid;zinc;hydrate Chemical compound O.[Zn].OS(O)(=O)=O MZNYADCLSDCSHV-UHFFFAOYSA-N 0.000 claims description 7
- 241000143687 Cantua buxifolia Species 0.000 claims description 6
- 230000008025 crystallization Effects 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 239000000700 radioactive tracer Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012452 mother liquor Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 125000003473 lipid group Chemical group 0.000 claims description 2
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 10
- 125000004122 cyclic group Chemical group 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000005862 Whey Substances 0.000 abstract 1
- 102000007544 Whey Proteins Human genes 0.000 abstract 1
- 108010046377 Whey Proteins Proteins 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 150000004688 heptahydrates Chemical class 0.000 abstract 1
- 239000013049 sediment Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 5
- 229910052745 lead Inorganic materials 0.000 description 4
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010563 solid-state fermentation Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/06—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201410845627.7A CN104556205B (zh) | 2014-12-31 | 2014-12-31 | 一种利用电解锌废渣环保生产饲料级硫酸锌的工艺方法 |
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CN201410845627.7A CN104556205B (zh) | 2014-12-31 | 2014-12-31 | 一种利用电解锌废渣环保生产饲料级硫酸锌的工艺方法 |
Publications (2)
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CN104556205A true CN104556205A (zh) | 2015-04-29 |
CN104556205B CN104556205B (zh) | 2016-03-16 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109133152A (zh) * | 2017-06-13 | 2019-01-04 | 荆门市格林美新材料有限公司 | 一种高纯一水硫酸锌的制备方法 |
CN110668488A (zh) * | 2019-11-27 | 2020-01-10 | 衡阳旭光锌锗科技有限公司 | 一种一水硫酸锌的生产方法 |
CN110668489A (zh) * | 2019-11-27 | 2020-01-10 | 衡阳旭光锌锗科技有限公司 | 一种从含锌废渣制备一水硫酸锌的方法 |
CN112374530A (zh) * | 2020-12-23 | 2021-02-19 | 郑州瑞普生物工程有限公司 | 一种高品质一水硫酸锌的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4156711A (en) * | 1975-06-19 | 1979-05-29 | Societe Des Mines Et Fonderies De Zinc De La Vieille Montagne, S.A. | Process for the removal of impurities contained in a zinc and cadmium sulfate solution |
CN101665265A (zh) * | 2009-09-17 | 2010-03-10 | 常宁市沿江锌业有限责任公司 | 一种利用高砷氧化锌和钢铁厂锌灰生产硫酸锌的方法 |
CN103359775A (zh) * | 2013-07-16 | 2013-10-23 | 杭州富阳新兴实业有限公司 | 一种含锌废料浸出液除铁的方法 |
CN104129811A (zh) * | 2014-08-14 | 2014-11-05 | 天津市新欣化工厂 | 一种制备硫酸锌的工艺 |
-
2014
- 2014-12-31 CN CN201410845627.7A patent/CN104556205B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4156711A (en) * | 1975-06-19 | 1979-05-29 | Societe Des Mines Et Fonderies De Zinc De La Vieille Montagne, S.A. | Process for the removal of impurities contained in a zinc and cadmium sulfate solution |
CN101665265A (zh) * | 2009-09-17 | 2010-03-10 | 常宁市沿江锌业有限责任公司 | 一种利用高砷氧化锌和钢铁厂锌灰生产硫酸锌的方法 |
CN103359775A (zh) * | 2013-07-16 | 2013-10-23 | 杭州富阳新兴实业有限公司 | 一种含锌废料浸出液除铁的方法 |
CN104129811A (zh) * | 2014-08-14 | 2014-11-05 | 天津市新欣化工厂 | 一种制备硫酸锌的工艺 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109133152A (zh) * | 2017-06-13 | 2019-01-04 | 荆门市格林美新材料有限公司 | 一种高纯一水硫酸锌的制备方法 |
CN109133152B (zh) * | 2017-06-13 | 2021-02-09 | 荆门市格林美新材料有限公司 | 一种高纯一水硫酸锌的制备方法 |
CN110668488A (zh) * | 2019-11-27 | 2020-01-10 | 衡阳旭光锌锗科技有限公司 | 一种一水硫酸锌的生产方法 |
CN110668489A (zh) * | 2019-11-27 | 2020-01-10 | 衡阳旭光锌锗科技有限公司 | 一种从含锌废渣制备一水硫酸锌的方法 |
CN112374530A (zh) * | 2020-12-23 | 2021-02-19 | 郑州瑞普生物工程有限公司 | 一种高品质一水硫酸锌的制备方法 |
Also Published As
Publication number | Publication date |
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CN104556205B (zh) | 2016-03-16 |
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Address after: 401220 Chongqing City longevity district peach blossom Avenue Apart Hotel Central 4 17-7 Patentee after: Yuan Futang Address before: 435100 Jinqiao Industrial Park, Daye City, Huangshi, Hubei Patentee before: Yuan Futang |
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Effective date of registration: 20180911 Address after: 225300 Pearl River Road, Yongan Town, Taizhou, Jiangsu Province, 108 Patentee after: Chen Deyan Address before: 401220 Chongqing Changshou District Peach Blossom Avenue Apart Hotel Central 4 17-7 Patentee before: Yuan Futang |
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Address after: Xikang Road, Gulou District of Nanjing city of Jiangsu Province, No. 1 210000 Patentee after: Chen Deyan Address before: 225300 No. 108 Mingzhu Avenue, Yonganzhou Town, Gaogang District, Taizhou City, Jiangsu Province Patentee before: Chen Deyan |
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Effective date of registration: 20200324 Address after: No.11, Chemical Road, songmu Economic Development Zone, shigu District, Hengyang City, Hunan Province Patentee after: HUNAN XINKESI BIOTECHNOLOGY Co.,Ltd. Address before: Xikang Road, Gulou District of Nanjing city of Jiangsu Province, No. 1 210000 Patentee before: Chen Deyan |
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