CN104552557B - Glass fiber reinforced cement surface retarded adhesive material preparation method - Google Patents
Glass fiber reinforced cement surface retarded adhesive material preparation method Download PDFInfo
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- CN104552557B CN104552557B CN201510023772.1A CN201510023772A CN104552557B CN 104552557 B CN104552557 B CN 104552557B CN 201510023772 A CN201510023772 A CN 201510023772A CN 104552557 B CN104552557 B CN 104552557B
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- adhesive material
- retarded adhesive
- glass fiber
- fiber reinforced
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/08—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/463—Organic solvents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5037—Clay, Kaolin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of compositionss that can make cement products surface slow setting, glass fiber reinforced cement surface retarded adhesive material preparation method and application technique, the present invention is applied to concrete, mortar and other hydratable cement material slow setting applications, is particularly suited for the undisguised material decoration of GRC decorated articles.By being sprayed or being brushed the die surface in GRC products, after waiting its demoulding, its surface is directly rinsed with water and reach undisguised material surface decoration effect.
Description
Technical field
The present invention relates to a kind of cement-based material surface retarded adhesive material, more particularly to glass fiber reinforced cement product
Surface retarded adhesive material, it is adaptable to concrete, mortar and other hydratable cement material slow setting applications, is particularly suited for GRC dresses
The undisguised material decoration of decorations product.
Background technology
At present, after GRC exposed on surface material decorative effect face processing technique is all GRC product strippings, using concentrated hydrochloric acid strong acid
Property there is acid-base neutralization reaction with GRC products cement alkalescence, surface layer about 0.2 millimeter of cement slurry is washed away to realize.This
The shortcoming for planting processing mode is the life because hydrochloric acid is the chemical materialss of highly corrosive and high volatility, to environment in production process
Product personnel easily cause harm.
Cement retardative material can extend hydrated cementitious and harden a kind of material of setting time, when retarded adhesive material is in cement
When amount in slurry reaches certain value, cement material just loses the performance of hardening solidification.So according to GRC product producing process
Feature is in its mould surface spraying or brushes one layer of retarded adhesive material, contact die surface cement layer is significantly prolonged setting time
Long, demoulding back layer slurry is still uncured and cement concrete of not in contact with retarded adhesive material has cured, and is rinsed with water, can
So that wash cement slurry to be washed out, the decorative cover effect for exposing aggregate is reached, can be realized in theory.
10213750 A patented invention patent names of CN：Based on the concrete surface retarders of ester, U.S.'s Grace is public
Department's application, is mainly sprayed at concrete and cement mortar surface, mainly with the material of oils as solvent, with saccharide, common fat
The organic esters set retarding active functional material of class, but it is used for GRC surface acidity Shortcomings.Mainly have：1. surface slow setting is imitated
Rate is not high, must rinse at the appointed time after the demoulding, flushing that time length cement just solidifies not surface layer cement, large area
Engineer applied difficulty is larger.2. plant and animal oil when die surface pollutes Datong District to die surface to product surface effect
There is pollution.3. the uniform undisguised combination with decorative surfaces of slow setting of thin layer can not be obtained.4. surface with complex structure especially inclined surface with
And very thick surface is corroded and the inadequate situation of depth above below occurring during vertical surface.5. filler is uniformly dispersed, stable
Performance is bad, and operation difficulty is big.
The content of the invention
The characteristics of present invention is directed to GRC ornament materials and the deficiency of existing surface slow setting technology, prepare one kind in GRC moulds
Skin layer thickness can reach the Novel clock of the suitable GRC die surfaces construction of 0.1-0.5mm homogeneous corrosion cement-based articles
The preparation method and application technique of face retarded adhesive material.
The technical solution used in the present invention is：
The technique for applying of glass fiber reinforced cement surface retarded adhesive material, step are as follows：
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint 50-
150g/m2；
（3）10-30 minutes are dried under natural environment, routinely technique productions GRC decorated articles；
（4）The demoulding after solidification 20-28h, then uniformly rinses architectural surface with hydraulic giant；
（5）GRC decorated articles are undisguisedly expected after maintenance；
The preparation method of glass fiber reinforced cement surface retarded adhesive material, step are as follows：
（1）Under conditions of room temperature closing, binding agent is dissolved in a solvent by way of stirring, treat thoroughly dissolving
Afterwards, filter and go the removal of impurity, obtain solution 1；
（2）Dispersant is added slowly under agitation in solution 1 so as to which thoroughly dissolving is uniformly dispersed, and obtains solution
2；
（3）Set retarding active material is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, is obtained
Solution 3；
（4）Thickening agent is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Filler is added in solution 4 under conditions of stirring, first low rate mixing 10-20min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
Described binding agent is selected but is not limited to Colophonium, PVA aqueous solutions, polyurethane, paste, waterglass, carboxymethyl cellulose
One kind in plain sodium；Described solvent includes easy volatile solvent or the one kind in water preparation；Described easy volatile solvent is selected but not
It is limited to one or more in methanol, ethanol, propanol, pentane, hexane, heptane, octane.
Described dispersant is fatty alcohol-polyoxyethylene ether, octyl phenyl polyoxyethylene ether, fatty alcohol-polyoxyethylene ether sulfur
One or more in sour sodium.
Described thickening agent is selected but is not limited to methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl first
One or more in base cellulose, triethanolamine, polyacrylamide, amino alcohol solvay-type titanate esters.
The one kind in white carbon, calcining metakaolin, superfine titanic oxide, silicon powder is selected but be not limited to described filler
Or it is several.
Described set retarding active material includes the one kind in saccharide and oils.
One kind that described saccharide is selected but is not limited in sucrose, maltose, glucose, Lactose.
One kind that described oils are selected but are not limited in vegetable oil, alkyl fat, phosphate ester, preferably phosphoric acid ester.It is described
Phosphate ester but one kind for being not limited in methyl orthophosphoric acid, laurel alcohol ether phosphate, polyoxy ethers ester, preferred polyoxy ethers ester.
Beneficial effect:
1st, the surface retarders prepared by the present invention uniformly can be constructed in GRC surfaces, and corrosion GRC case depths are
0.1-0.5mm, is effectively accomplished GRC exposed on surface material decorative effects.
2nd, the preferred polyoxy ethers ester of set retarding active material of the present invention, the phosphate radical of this material are imitated with the complexation of cement admixture
Efficient deferred action should be reached with the strongly hydrophilic energy collective effect of ether, meanwhile, by adjusting long alkyl chains control surface
Slow setting depth.
Description of the drawings
Below in conjunction with accompanying drawing, the invention will be further described.
Fig. 1 rushes design sketch for GRC surface applications retarded adhesive material Jing water.
Specific embodiment：
Case study on implementation 1
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, Colophonium is dissolved by way of stirring in methyl alcohol, after thoroughly dissolving,
The removal of impurity is gone in filtration, obtains solution 1；
（2）Fatty alcohol-polyoxyethylene ether is added slowly under agitation in solution 1 so as to which thoroughly dissolving dispersion is equal
It is even, obtain solution 2；
（3）Methyl orthophosphoric acid is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, is obtained solution
3；
（4）Methylcellulose is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）White carbon is added in solution 4 under conditions of stirring, first low rate mixing 10min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
50g/m2。
（3）It is dried 10 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 20h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 2
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, PVA aqueous solutions are dissolved in ethanol by way of stirring, treat thoroughly molten
Xie Hou, filtration go the removal of impurity, obtain solution 1；
（2）Octyl phenyl polyoxyethylene ether is added slowly under agitation in solution 1 so as to thoroughly dissolving dispersion
Uniformly, obtain solution 2；
（3）Laurel alcohol ether phosphate is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved,
Obtain solution 3；
（4）Hydroxymethyl cellulose is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Calcining metakaolin is added in solution 4 under conditions of stirring, first low rate mixing 20min, then quickly
Stirring 30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
150g/m2。
（3）It is dried 30 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 28h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 3
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, polyurethane is dissolved in propanol by way of stirring, treats thoroughly dissolving
Afterwards, filter and go the removal of impurity, obtain solution 1；
（2）Polyoxyethylenated alcohol sodium sulfate is added slowly under agitation in solution 1 so as to thoroughly dissolve
It is uniformly dispersed, obtains solution 2；
（3）Polyoxy ethers ester is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, obtains molten
Liquid 3；
（4）Hydroxyethyl cellulose is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Superfine titanic oxide is added in solution 4 under conditions of stirring, first low rate mixing 15min, then quickly
Stirring 30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
100g/m2。
（3）It is dried 20 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 24h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 4
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, paste is dissolved in water by way of stirring, after thoroughly dissolving, mistake
The removal of impurity is filtered off, solution 1 is obtained；
（2）Fatty alcohol-polyoxyethylene ether is added slowly under agitation in solution 1 so as to which thoroughly dissolving dispersion is equal
It is even, obtain solution 2；
（3）Sucrose is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, solution 3 is obtained；
（4）Hydroxypropyl methyl cellulose is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Silicon powder is added in solution 4 under conditions of stirring, first low rate mixing 13min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
80g/m2。
（3）It is dried 13 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 22h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 5
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, waterglass is dissolved in water by way of stirring, after thoroughly dissolving,
The removal of impurity is gone in filtration, obtains solution 1；
（2）Octyl phenyl polyoxyethylene ether is added slowly under agitation in solution 1 so as to thoroughly dissolving dispersion
Uniformly, obtain solution 2；
（3）Maltose is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, solution 3 is obtained；
（4）Triethanolamine is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）White carbon is added in solution 4 under conditions of stirring, first low rate mixing 16min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
70g/m2。
（3）It is dried 17 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 26h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 6
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, sodium carboxymethyl cellulose is dissolved in water by way of stirring, is treated thoroughly
After dissolving, the removal of impurity is gone in filtration, obtains solution 1；
（2）Polyoxyethylenated alcohol sodium sulfate is added slowly under agitation in solution 1 so as to thoroughly dissolve
It is uniformly dispersed, obtains solution 2；
（3）Glucose is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, solution 3 is obtained；
（4）Methylcellulose is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Filler is added in solution 4 under conditions of stirring, first low rate mixing 14min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
110g/m2。
（3）It is dried 17 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 25h, then uniformly rinses architectural surface with hydraulic giant.
（5）GRC decorated articles are undisguisedly expected after maintenance.
Case study on implementation 7
The preparation of surface retarded adhesive material
（1）Under conditions of room temperature closing, Colophonium is dissolved in pentane by way of stirring, after thoroughly dissolving,
The removal of impurity is gone in filtration, obtains solution 1；
（2）Fatty alcohol-polyoxyethylene ether is added slowly under agitation in solution 1 so as to which thoroughly dissolving dispersion is equal
It is even, obtain solution 2；
（3）Vegetable oil is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, solution 3 is obtained；
（4）Polyacrylamide is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Calcining metakaolin is added in solution 4 under conditions of stirring, first low rate mixing 16min, then quickly
Stirring 30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
120g/m2。
（3）It is dried 19 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 26h, then uniformly rinses architectural surface with hydraulic giant.
Case study on implementation 8
（1）Under conditions of room temperature closing, PVA aqueous solutions are dissolved in hexane by way of stirring, treat thoroughly molten
Xie Hou, filtration go the removal of impurity, obtain solution 1；
（2）Octyl phenyl polyoxyethylene ether is added slowly under agitation in solution 1 so as to thoroughly dissolving dispersion
Uniformly, obtain solution 2；
（3）Alkyl fat is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, solution 3 is obtained；
（4）Amino alcohol solvay-type titanate esters are slowly added in solution 3 under conditions of stirring, thoroughly disperse to obtain solution
4；
（5）Superfine titanic oxide is added in solution 4 under conditions of stirring, first low rate mixing 16min, then quickly
Stirring 30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
The application of surface retarded adhesive material
（1）Ensure that die surface is dried pollution-free；
（2）The surface coagulation material for preparing is sprayed twice using cross spraying process in die surface, a spray paint
100g/m2。
（3）It is dried 16 minutes under natural environment, routinely technique productions GRC decorated articles.
（4）The demoulding after solidification 24h, then uniformly rinses architectural surface with hydraulic giant.
Claims (8)
1. the preparation method of glass fiber reinforced cement surface retarded adhesive material, it is characterised in that step is as follows：
（1）Under conditions of room temperature closing, binding agent is dissolved by way of stirring in a solvent, after thoroughly dissolving, mistake
The removal of impurity is filtered off, solution 1 is obtained；
（2）Dispersant is added slowly under agitation in solution 1 so as to which thoroughly dissolving is uniformly dispersed, and obtains solution 2；
（3）Set retarding active material is slowly added in solution 2 under conditions of stirring, dispersion is thoroughly uniformly dissolved, is obtained solution
3；
（4）Thickening agent is slowly added in solution 3 under conditions of stirring, thoroughly disperses to obtain solution 4；
（5）Filler is added in solution 4 under conditions of stirring, first low rate mixing 10-20min, it is then quick to stir
30min, till making the dispersion in the solution of uniform filling, prepares surface retarded adhesive material.
2. the preparation method of glass fiber reinforced cement surface according to claim 1 retarded adhesive material, it is characterised in that：Institute
The binding agent stated is from the one kind in Colophonium, PVA aqueous solutions, polyurethane, paste, waterglass, sodium carboxymethyl cellulose；Described
Solvent includes easy volatile solvent or the one kind in water preparation；Described easy volatile solvent from methanol, ethanol, propanol, pentane, oneself
One or more in alkane, heptane, octane.
3. the preparation method of glass fiber reinforced cement surface according to claim 1 retarded adhesive material, it is characterised in that：Institute
The dispersant stated is fatty alcohol-polyoxyethylene ether, octyl phenyl polyoxyethylene ether, in polyoxyethylenated alcohol sodium sulfate one
Plant or several.
4. the preparation method of glass fiber reinforced cement surface according to claim 1 retarded adhesive material, it is characterised in that：Described
Thickening agent from methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, triethanolamine, poly- third
One or more in acrylamide, amino alcohol solvay-type titanate esters.
5. the preparation method of glass fiber reinforced cement surface according to claim 1 retarded adhesive material, it is characterised in that：Described
Filler is from one or more in white carbon, calcining metakaolin, superfine titanic oxide, silicon powder.
6. the preparation method of glass fiber reinforced cement surface according to claim 1 retarded adhesive material, it is characterised in that：Described
Set retarding active material includes the one kind in saccharide and oils.
7. the preparation method of glass fiber reinforced cement surface according to claim 6 retarded adhesive material, it is characterised in that：Institute
The saccharide stated is from the one kind in sucrose, maltose, glucose, Lactose.
8. the preparation method of glass fiber reinforced cement surface according to claim 6 retarded adhesive material, it is characterised in that：Oil
Lipid is from the one kind in vegetable oil, alkyl fat, phosphate ester；Described phosphate ester from methyl orthophosphoric acid, laurel alcohol ether phosphate,
One kind in polyoxy ethers ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510023772.1A CN104552557B (en) | 2015-01-19 | 2015-01-19 | Glass fiber reinforced cement surface retarded adhesive material preparation method |
Applications Claiming Priority (1)
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|---|---|---|---|
| CN201510023772.1A CN104552557B (en) | 2015-01-19 | 2015-01-19 | Glass fiber reinforced cement surface retarded adhesive material preparation method |
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| CN104552557A CN104552557A (en) | 2015-04-29 |
| CN104552557B true CN104552557B (en) | 2017-04-05 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2552446B (en) * | 2016-03-24 | 2020-11-25 | Waring Stephen | Method for forming a coated building element and mould therefor |
| CN111848215B (en) * | 2020-07-29 | 2022-11-04 | 浙江大东吴建筑科技有限公司 | Negative corrosion inhibitor capable of adjusting washing depth of exposed aggregate concrete and application thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5161140A (en) * | 1974-10-22 | 1976-05-27 | Obayashi Constr Co Ltd | Konkuriitono somenshiagekoho |
| EP1887053B1 (en) * | 2006-07-06 | 2012-09-05 | W.R. Grace & Co.-Conn. | Method for retarding the setting of mortar and concrete surfaces |
| FR2935140B1 (en) * | 2008-08-21 | 2012-06-01 | W R Grace Co Conin | ESTER-BASED SURFACE TAMPER RETARDANTS |
| CN101580354B (en) * | 2009-06-12 | 2012-10-24 | 福建科之杰新材料有限公司 | Polycarboxylic retarding high-performance water reducing agent for preparing concrete of middle and low strength grade |
| CN103420687B (en) * | 2013-08-07 | 2014-12-10 | 中建商品混凝土成都有限公司 | Surface cleaning agent dedicated to exposed pervious concrete and preparation and application methods thereof |
| CN103449755B (en) * | 2013-09-11 | 2015-01-21 | 北京中景橙石建筑科技有限公司 | Concrete sustained-release agent and preparation method thereof |
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2015
- 2015-01-19 CN CN201510023772.1A patent/CN104552557B/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 混凝土界面处理方法——缓凝水冲法;于光镇;《中国水运》;20100131;第10卷(第1期);第192-193页 * |
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