CN103482946B - Neutral mosaic adhesive - Google Patents
Neutral mosaic adhesive Download PDFInfo
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- CN103482946B CN103482946B CN201310414327.9A CN201310414327A CN103482946B CN 103482946 B CN103482946 B CN 103482946B CN 201310414327 A CN201310414327 A CN 201310414327A CN 103482946 B CN103482946 B CN 103482946B
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Abstract
The invention relates to a neutral mosaic adhesive which is obtained by preparing plaster selected and used as a cementing material, quartz sand, water-retaining agents, emulsion powder with redispersibility, retarder and water-reducing agents according to a recipe. The neutral mosaic adhesive is neutral after hydration, so that the problems of oxidizing and blackening of glass mosaics and returning of alkali due to the strong alkalinity of cement hydration products when traditional cement or a cement-based adhesive is used for sticking the glass mosaics are solved. Meanwhile, as the plaster and the quartz sand with the whiteness higher than that of the white cement are adopted, the effect of improving the whiteness can be achieved, and the better decoration effect is obtained. The neutral mosaic adhesive is high in adhesive strength, prevents the hollowing and falling phenomena, and is suitable for sticking tiles and the mosaics, and particularly suitable for sticking the glass mosaics indoors.
Description
Technical field
The present invention relates to a kind of tackiness agent, particularly a kind of Neutral mosaic adhesive, belong to the matrix material technical field in building trade.
Background technology
Mosaic has another name called mosaic tile, and be a kind of building decoration material that can be spliced into various pattern of sheet, be widely used in house ornamentation toilet metope, ground, the positions such as swimming pool, mosaic exquisiteness is small and exquisite, and pattern is changeable, has multiple combination mode, personalized pure.The production of mosaic normally one piece of block is processed mosaic material paste on base material, become the finished product of, the existing material be applied on mosaic mainly contains pottery, stone material, glass (comprising hot melt glass and crystal glass), metal, timber, shell, corium, resin etc., flourish along with mosaic in recent years, the mosaic product of various material emerges in an endless stream, and applied environment is also more and more extensive.Glass Mosaic is the maximum mosaic of current usage quantity.
The tackiness agent that mosaic mosaic tile adopts the notched scraper of 3mm*3mm or 4mm*4mm specification to be stirred adding water when paving is criticized and is scraped on basal plane, be carded to dentate stripe again, being rubbed by mosaic is pressed on tackiness agent, after solidification, selects suitable spackling to carry out joint filling process.The paving of traditional glass Mosaic is generally adopt cement or cement-based adhesive, and cement can produce calcium hydroxide in hydration process, and hydrated product is strong basicity.For the glass Mosaic of goldleaf, minute surface, plating, cold spray one class, because it is without high-temperature fusion, be linked by glue between the color layers of mosaic material and glass coating, once run into acid and alkali substance be easily oxidized blackening, thus lose decorative effect.Therefore, when using the tackiness agent paving glass Mosaic of cement or cement based, the strong base substance that hydrated cementitious produces acts on glass Mosaic, not only can affect decorative effect, also can affect the glass Mosaic life-span.
The whiteness of the tackiness agent usually made with the gelling material of common white cement is not high, therefore, when adopting this type of tackiness agent to paste bottoming, cannot set off out the beautiful color of glass Mosaic and moulding.
Adopt the gypsum material of high whiteness and preferred quartz sand in formula, adhesive material whiteness is high, and the mosaic after stickup not only keeps the beautiful true qualities of mosaic, and high whiteness also shows the top grade taste of mosaic.Someone proposes to adopt neutral glass glue to carry out the stickup of glass Mosaic, but in actual applications, the most normal produced problem of glass cement is used to be that (1) easily blackening is mouldy, even use waterproof glass glue, mildew-resistant glass cement can not avoid the generation of problems completely, therefore there is the place of water or immersion then should not construct for a long time; (2) glass cement wants the surface of bonding base material must be clean, can not have other dirt settlings (such as dust etc.), otherwise will there will be phenomenon that is loosely bonding or that come off after glass cement solidification; (3) bonding force of neutral glass glue is more weak, easily causes obscission.
The air-setting inorganic coagulation material of gypsum to be a kind of with calcium sulfate be main component, gypsum is of many uses in material of construction, gypsum also has report as the application of one of adhesive component, application documents as publication number CN 1141266A disclose a kind of decoration special cement, this kind of decoration special cement forms by weight ratio with white cement clinker, calcite or dry powder, dihydrate gypsum, talcum powder, is particularly useful for sticking glass, mosaic, Wall or floor tile, marble etc.This decoration special cement is still the tackiness agent belonging to cement based, dihydrate gypsum Main Function in its component plays delayed coagulation, therefore the deficiency existing for existing cement-based adhesive sticking glass mosaic is still likely there is when the paving of the paving for mosaic, particularly glass Mosaic.
There is not at present a kind of tackiness agent can well solve the aforesaid problem such as cause glass Mosaic oxidized owing to using conventional cement or cement-based adhesive, have no the report of the neutral gum stick of the special gypsum base of glass Mosaic yet.
Summary of the invention
The object of the present invention is to provide a kind of gypsum base Neutral mosaic adhesive being specifically designed to glass Mosaic, this Neutral mosaic adhesive selects gypsum as gelling material, be equipped with quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer prepares by formula, be neutral after this tackiness agent aquation, conventional cement or cement-based adhesive can be solved when sticking glass mosaic due to the oxidized blackening of glass Mosaic that the strong basicity of hydrolysis product of cement causes, the problem of the accumulation of salt in the surface soil, simultaneously owing to adopting the gypsum that whiteness is higher than white cement, quartz sand, raising whiteness can also be reached, obtain bright background color, improve the object of mosaic decorative effect, it is high that this Neutral mosaic adhesive also has cohesive strength, there is not hollowing, the phenomenon come off.
In order to solve the problem, the technical solution adopted in the present invention is as follows: a kind of Neutral mosaic adhesive, it is a kind of neutral gum stick of gypsum base, be made up of gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, in formula, each component concentration is in the kg number of adhesive products per ton containing this component, as follows:
Gypsum 480-800
Quartz sand 180-500
Water-holding agent 0.5-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 0.5-5,
Described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum, and whiteness is 85-95 degree; Described quartz sand particle size is 60-200 order, and whiteness is 85-90 degree; Hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose of described water-holding agent to be viscosity be 2500-75000mPas; Described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester; Stating retardant is one or both in Trisodium Citrate, Sunmorl N 60S; Described water reducer is one or both in poly carboxylic acid series water reducer, aminosulfonate-based superplasticizer.
Preferred ingredient proportioning is as follows, and each component concentration is in the kg number of adhesive products per ton containing this component:
Gypsum 500-700
Quartz sand 280-480
Water-holding agent 1.5-4
Redispersible latex powder 12-26
Retardant 1.2-4.2
Water reducer 0.8-4.
Water reducer of the present invention is one or both in poly carboxylic acid series water reducer, aminosulfonate-based superplasticizer, preferred polycarboxylate high performance water-reducing agent or aminosulfonate-based superplasticizer.
Neutral mosaic adhesive of the present invention adopts following methods preparation: first weigh gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer according to proportion speed, hand operated mixing mixing in advance, put into the cement mortar mixer of the planetary cement mortar mixer of JC/T681-2005 or other applicable models again, stirring at low speed, stir 10-20 minute, tackiness agent powder can be obtained until mix.
The present invention is as follows relative to the beneficial effect of prior art:
(1) the present invention be directed to the technical problem that glass Mosaic adopts cement or cement-based adhesive to exist, gypsum is selected to substitute cement as major gelled material: gypsum main component is calcium sulfate, it is a kind of air-setting inorganic coagulation material of neutrality, main raw using gypsum as glass Mosaic tackiness agent, when applying, tackiness agent pH value is 7, in neutral, therefore, adopt the tackiness agent of this neutrality to paste mosaic, there will not be the alkaline matter after similar conventional cement aquation to cause mosaic to be oxidized the problem such as blackening, the accumulation of salt in the surface soil;
(2) gypsum is a kind of white powder material, whiteness scope is at 85-95 degree, higher than general white cement whiteness 75-85 degree, the present invention's formula is main volume with gypsum, preferably adopt whiteness scope at the gypsum of 85-95 degree, adopt particle diameter 60-200 order simultaneously, whiteness is the quartz sand of 85-90 degree, selected gypsum and its whiteness of quartz sand are all higher than traditional, for the white cement of tackiness agent, can make by the present invention fill a prescription preparation tackiness agent there is high whiteness, during stickup for mosaic, decorative effect is good, especially at glass Mosaic, metal mosaic etc. this type of when will embody the construction of mosaic material of its beautiful decorative effect, background color is needed to become clear, adopt mosaic adhesive of the present invention can reach the object setting off the color of mosaic material own, obtain more excellent decorative effect,
(3) traditional sticking glass mosaic material is cement or sand-cement slurry, it is the use that arbitrarily adds water at the construction field (site) during construction, the mosaic of fritter can be caused to occur situations such as boning loosely, come off, and Neutral mosaic adhesive of the present invention is formed by meticulous configuration, adopt the quartz sand that selected high-quality whiteness is high, in conjunction with water-holding agent, retardant and water reducer, the cohesive strength of material, operable time and set time can be improved, be used for pasting after mosaic, the phenomenon such as do not occur hollowing, come off.
Neutral mosaic adhesive of the present invention is suitable for the stickup of ceramic tile, mosaic, is particularly useful for the stickup of glass Mosaic in indoor.Basic construction requirement during construction, construction process are as follows:
(1) all basal planes structurally must be firm, dry, clean and without movement, oils, grease, paraffin and other fouling productss; Paint basal plane must expose more than at least 75% clean basal plane;
(2) preparing Neutral mosaic adhesive powder according to formula of the present invention and preparation method, add the clear water accounting for powder quality 30%-35%, by electric blender, tackiness agent and water being stirred well to evenly without luming paste;
(3) after the tackiness agent after stirring being left standstill 5-10 minute, then stir 1-2 minute a little, can use;
(4) to be criticized by tackiness agent rubber cement with suitable notched scraper and scrape on working face, coating evenly;
(5) rub pressure mosaic, guarantee that mosaic and tackiness agent have and better paste and hollowing does not occur under mosaic;
(6) the surperficial adhesive material stayed of mosaic is wiped with sponge or wet cloth;
(7) after Neutral mosaic adhesive pastes 2 days, can arrange joint filling, the concrete time appropriately adjusts depending on weather, execution conditions difference.
Embodiment
Be described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, do not limit the scope of the invention.
embodiment 1by following formula preparation Neutral mosaic adhesive of the present invention:
(1) weigh llowing group of materials by proportion speed: the dehydrated gyp-500kg of whiteness 95, particle diameter is 180 orders, whiteness 85
Quartz sand 480 kg, viscosity is Vltra tears 1.5 kg of 2500mPas, ethylene-vinyl acetate copolymer 14.5 kg, Trisodium Citrate 2.5kg, high performance water reducing agent of polyocarboxy acid 1.5 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer of JC/T681-2005, stirring at low speed, stir 15 minutes, until mix.
Performance Indexs measure is carried out to the tackiness agent powder of above-mentioned preparation, as shown in the table:
Sequence number | Interventions Requested | Measure unit | Assay |
1 | Outward appearance | / | Homogeneous, dry powder, without caking |
2 | PH value | / | 7.3 |
3 | Operable time | h | 2 |
4 | Presetting period | min | 110 |
5 | Final setting time | min | 330 |
6 | Stretching adhesive strength | MPa | 0.58 |
7 | Open assembly time, 20min stretching adhesive strength | MPa | 0.54 |
embodiment 2adopt following formula preparation Neutral mosaic adhesive of the present invention:
(1) llowing group of materials is weighed by proportion speed: semi-hydrated gypsum 780 kg of whiteness 85, particle diameter are quartz sand 280 kg of 120 orders, whiteness 85, viscosity is hydroxyethyl ether cellulose 4 kg of 5000mPas, copolymer in cinnamic acrylic ester 12 kg, Trisodium Citrate 2 kg, aminosulfonate-based superplasticizer 2kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into cement mortar mixer, stirring at low speed, stir 10 minutes, until mix.
embodiment 3adopt following formula preparation Neutral mosaic adhesive of the present invention:
(1) llowing group of materials is weighed by proportion speed: dehydrated gyp-650 kg of whiteness 95, particle diameter is quartz sand 321 kg of 200 orders, whiteness 88, viscosity is Vltra tears 1 kg of 75000mPas, ethylene-vinyl acetate copolymer 26 kg, Sunmorl N 60S 1.2 kg, high performance water reducing agent of polyocarboxy acid 0.8 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer of JC/T681-2005, stirring at low speed, stir 18 minutes, until mix.
embodiment 4adopt following formula preparation Neutral mosaic adhesive of the present invention:
(1) llowing group of materials is weighed by proportion speed: dihydrate gypsum 800 kg of whiteness 85, particle diameter is quartz sand 180 kg of 60 orders, whiteness 90, viscosity is hydroxyethyl ether cellulose 2 kg of 50000mPas, copolymer in cinnamic acrylic ester 14.4 kg, Sunmorl N 60S 1.8kg, aminosulfonate-based superplasticizer 1.8 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer of JC/T681-2005, stirring at low speed, stir 20 minutes, until mix.
embodiment 5adopt following formula preparation Neutral mosaic adhesive of the present invention:
(1) llowing group of materials is weighed by proportion speed: semi-hydrated gypsum 160 kg of whiteness 88, the dehydrated gyp-320kg of whiteness 90, particle diameter is quartz sand 500 kg of 160 orders, whiteness 85, viscosity is Vltra tears 5 kg of 5000mPas, copolymer in cinnamic acrylic ester 6.8 kg, Trisodium Citrate 3 kg, Sunmorl N 60S 1.2 kg, high performance water reducing agent of polyocarboxy acid 4 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into cement mortar mixer, stirring at low speed, stir 14 minutes, until mix.
Claims (2)
1. a Neutral mosaic adhesive, it is characterized in that: the neutral gum stick being a kind of gypsum base, be made up of gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, in formula, each component concentration is in the kg number of adhesive products per ton containing this component, as follows:
Gypsum 480-800
Quartz sand 180-500
Water-holding agent 0.5-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 0.5-5;
Described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum, and its whiteness is 85-95 degree; Described quartz sand particle size is 60-200 order, and whiteness is 85-90 degree; Hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose of described water-holding agent to be viscosity be 2500-75000mPas; Described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester; Described retardant is one or both in Trisodium Citrate, Sunmorl N 60S; Described water reducer is one or both in poly carboxylic acid series water reducer, amino water reducer.
2. Neutral mosaic adhesive according to claim 1, it is characterized in that: the neutral gum stick being a kind of gypsum base, be made up of gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, in formula, each component concentration is in the kg number of adhesive products per ton containing this component, as follows:
Gypsum 500-700
Quartz sand 280-480
Water-holding agent 1.5-4
Redispersible latex powder 12-26
Retardant 1.2-4.2
Water reducer 0.8-4.
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CN201310414327.9A CN103482946B (en) | 2013-09-12 | 2013-09-12 | Neutral mosaic adhesive |
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CN201310414327.9A CN103482946B (en) | 2013-09-12 | 2013-09-12 | Neutral mosaic adhesive |
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CN103482946B true CN103482946B (en) | 2015-04-22 |
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CN104072076A (en) * | 2014-06-30 | 2014-10-01 | 孙红芳 | Surface layer grinding gypsum powder |
CN104086148B (en) * | 2014-06-30 | 2016-05-18 | 孙红芳 | Bottom layer brushing gypsum powder |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1955242A (en) * | 2005-10-19 | 2007-05-02 | 辽宁石油化工大学 | Dry powder color ceramic tile adhesive |
CN101172795A (en) * | 2007-10-30 | 2008-05-07 | 南京一夫建材实业有限公司 | Alpha type high-strength gypsum cementing agent |
CN102838337A (en) * | 2012-09-04 | 2012-12-26 | 同济大学 | Desulfurized gypsum based functional mortar for coating and preparation method thereof |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1955242A (en) * | 2005-10-19 | 2007-05-02 | 辽宁石油化工大学 | Dry powder color ceramic tile adhesive |
CN101172795A (en) * | 2007-10-30 | 2008-05-07 | 南京一夫建材实业有限公司 | Alpha type high-strength gypsum cementing agent |
CN102838337A (en) * | 2012-09-04 | 2012-12-26 | 同济大学 | Desulfurized gypsum based functional mortar for coating and preparation method thereof |
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