CN104530857A - Long-acting termite-control automatic spray paint and preparation method thereof - Google Patents
Long-acting termite-control automatic spray paint and preparation method thereof Download PDFInfo
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- CN104530857A CN104530857A CN201410720409.0A CN201410720409A CN104530857A CN 104530857 A CN104530857 A CN 104530857A CN 201410720409 A CN201410720409 A CN 201410720409A CN 104530857 A CN104530857 A CN 104530857A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/136—Phenols containing halogens
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a long-acting termite-control automatic spray paint and a preparation method thereof. The spray paint comprises a component A and a component B. The component A is composed of modified acrylic resin, binary biocide emulsifiable concentrate, dimethyl carbonate, 200# solvent oil, butyl acetate, talc powder, a colorant, and a dispersing agent. The component B is dimethyl ether. The long-acting termite-control automatic spray paint provided by the invention is prepared from the raw materials of benzene-free film-forming substance, diluting agent, propellant, and high-efficiency and low-toxicity biocide. With the spray paint, a termite-prevention application technology is simplified. The spray paint is safe to human and livestock, and is environment-friendly, such that the spray paint is an effective termite-control green product. The product is suitable for building external wall and ground spray. With the spray paint, termites can be directly killed and repelled, such that buildings and furniture can be effectively protected from termite damages. The product is also suitable for termite control of outdoor and garden shed frames and lumber.
Description
Technical field
The present invention relates to the preparation method of the white ant auto spray painting of a kind of long-acting control, belong to skin, ground mulching biocide coating composition field.
Background technology
Current chemicals control is the major measure of white ant prevention and cure.Along with the enhancing of mankind's environmental consciousness and the signature of " Convention of Stockholm about persistence organic pollutant (POPs) ", the inorganic insecticide used for a long time and organochlorine insecticide are eliminated just gradually, and the white ant studying and combating personnel of countries in the world are finding the environmentally friendly and green Prevention Technique of effective white ant.
In traditional control the medicament kind commonly used mainly belong to inorganic insecticide and the large class of organochlorine insecticide two.Inorganic insecticide was once the principal item of preventing and treating white ant in the world, comprising there being the strong stomach poison such as boric acid, borax, ARSENIC TRI OXIDE 98, utilized white ant trophallaxis habit can be mixed with various attractant insecticide.The shortcoming of inorganic insecticide and organic chlorinate chemicals is apparent, and high poison, high residue and three causing toxicityly can not adapt to the requirement of people to environment.The U.S. starts to prohibit the use Niran and mirex 1976 and 1987 respectively.
Organic phosphates medicament main representative is Chlorpyrifos 94, is that Dow Chemical company developed and the broad spectrum insecticide developed in nineteen sixty-five, and Chlorpyrifos 94 dropped into the white ant control market of the U.S. in 1980.By 1985, Chlorpyrifos 94 was own through reaching 61.4% in the occupation rate of American market, within 1988, is increased to 80.3%.It has tag efficiently, stomach toxicity and fumigation action, insecticidal spectrum is wide, the longevity of residure is long, alternative mirex, the comparatively ideal medicament of Niran, but consider that Chlorpyrifos 94 is to " all Americans; the particularly potential impact of children's health ", United States Government has stopped or being limited in the use in school, hospital, New Dwelling.
Pyrethroid medicament is rising year by year in the occupation rate in white ant control agent market.Pyrethroid vinegar class medicament dialogue ant has good repellent effect, and to people and Mammals low toxicity, is a class white ant prevention medicament that kind is maximum in the world at present.Even larger market ratio is all occupied in the whole world in the U.S. with the white ant control agent that the chrysanthemum ester classes such as Permanone (permethrin), Cypermethrin (cypermethrin), fenvalerate (fenvalerate), bifenthrin (bifenthrin) are effective constituent.
Chemicals barrier is by the predetermined portion of killing white ant chemicals treatment buildings longer for long-lasting, ensures the white ant preventive effect in the specified time, and this method is used for the white ant prevention of buildings.Advantage is that preventive effect is obvious if medicine uses appropriate.Shortcoming is that this kind of prevention medicament majority adopts dimethylbenzene emulsion, pulvis to use, harmful chemical is brought in environment, easy generation transport property harm, and operation enforcement need be carried out by white ant control professional and technical personnel, significantly inconvenient and limitation is brought for small area, local household termile-proof.
Summary of the invention
For deficiency existing in prior art, the object of the present invention is to provide auto spray painting of the white ant of a kind of long-acting control and preparation method thereof.
The technical solution used in the present invention is:
A kind of binary biocide missible oil, the component primarily of following mass parts forms: Permanone 10-13 part, Avrmectin 1-3 part, sepiolite 26-36 part, methylcarbonate (DMC) 40-50 part, L-548 tensio-active agent 1-3 part.
Permanone, Avrmectin are as synergy biocide, and rationally preferred blending ratio can make medicament produce synergistic function, is obviously better than the summation effect of single component drug, thus embodies the synergistic function of binary matching component.
Sepiolite as long-acting sustained-release agent, can make binary biocide be encapsulated in be slowly discharged into sprayed surface constantly, thus reach long-acting stable termile-proof invasion effect.
DMC(methylcarbonate) as solvent, dissolved dilution Permanone and Avrmectin in the present invention, makes Permanone and Avrmectin be evenly distributed in the solution, easily carries out the activity encapsulation of sepiolite.
L-548(tensio-active agent) as reducing surface tension wetting agent, Avrmectin and Permanone can be allowed in the present invention to advance uniformly smoothly in the deep layer microtubule of sepiolite in encapsulation process, realize good Continuous slow release effect.
The white ant auto spray painting of a kind of long-acting control, is characterized in that, comprise component A and B component, wherein:
Described component A forms primarily of the component of following weight part: acrylic resin modified 120-130 part, binary biocide missible oil 10-15 part, DMC 180-190 part, 200# solvent oil 30-40 part, BAC 20-30 part, talcum powder 45-50 part, mill base 35-40 part, dispersion agent 1.0-2.0 part;
Described B component is dme.
The mass ratio of B component and component A is 1:0.50-0.55.
Acrylic resin modified as filmogen, have that fullness ratio is good, good corrosion resistance, outdoor exposure good weatherability, film not easily decompose or turn yellow, the feature of use temperature wide ranges.Can make the unrestricted flow of binary biocide missible oil on the one hand, the binary biocide carried on the other hand can accurately stick in target piece.
Binary biocide missible oil in the present invention as killing, a kind of composition of the white ant of repellent, in the air-dry solidification process of film of ejection, the active submarine afrodite having encapsulated binary biocide can adjust position, surface after film forming forms good opacifying power, make that medicine is easier to be uniformly distributed in film coated surface, play effect of drugs.
200# solvent oil, BAC(N-BUTYL ACETATE) coordinate DMC as solvent, serve as the effect of diluting modification acrylic resin and binary biocide missible oil in the present invention, make whole mixture can under current system state evenly, the film of ejection just more fine uniform.
DME(dme in the present invention) as the whole propellent that sprays paint, be the gas colourless, there is slight ether fragrance under normal temperature and pressure, there is inertia, not easily autoxidation under normal temperature, non-corrosiveness, non-carcinogenesis.And in formula, have the dual function of solvent and propelling agent concurrently, content propellent and coating when spraying can be sprayed consistent, when propellent liquefies, coating being fully atomized.
The preparation method of the white ant auto spray painting of described long-acting control, comprises the steps:
(1) Permanone and Avrmectin are encapsulated in the microtubule of sepiolite, obtain binary biocide missible oil, concrete operations are: drop in reactor by Permanone, Avrmectin, DMC, L-548, after stirring, get dry sepiolite slowly to drop in reactor, continue to stir 10-30 min;
(2) acrylic resin modified and DMC mixing and stirring are extremely dissolved as resin mother liquor completely;
(3) in resin mother liquor, add dispersion agent, talcum powder and mill base after high speed dispersion 30-50min, then add binary biocide missible oil, 200# solvent, BAC, stir, obtain work in-process, it is 30-60S that middle control detects viscosity;
(4) carried out by work in-process filtering impurity and macrobead thing, after sub-packing pot, capping is filled with DME.
The invention has the beneficial effects as follows:
Long-acting control of the present invention white ant auto spray painting adopts the film forming matter, thinner, propellent and the high-efficiency low-toxicity biocide that do not contain benzene to be that starting material are formulated, realize the application technique easy of termile-proof, to person poultry safety, environmentally friendly, belong to effective white ant green control product.This product is applicable to exterior wall, the earth's surface spraying of buildings, and directly can kill with repellent white ant, available protecting buildings, household be not by the infringement of white ant.Meanwhile, this product is also applicable to outdoor, gardens scaffolding structure, and the termile-proof of timber.
Accompanying drawing explanation
Fig. 1 is long-acting control white ant auto spray painting spraying sample graph.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated, but be not limited thereto.
embodiment 1
The preparation (to allocate 90kg missible oil) of missible oil: will
sepioliteconstant temperature drying 4-18 hour in 120-380 DEG C of loft drier, is completely down to room temperature, for subsequent use; Permanone, Avrmectin, DMC, L-548 being taken sequentially respectively 13kg, 1.1kg, 44.2kg, 1.7kg drops in reactor, 30min is stirred at 60 revs/min of rotating speeds, treat that two kinds of former medicines are uniformly dissolved completely, dry Activated Sepiolite 30kg will be taken slowly drop in reactor, stop stirring after continuing to stir 15min, missible oil is distributed into 1.0kg/ bottle, de-bubble 10-40min in ultrasonic vibrator, makes binary biocide missible oil.
The preparation (to allocate 470kg coating) of coating: by acrylic resin modified 123 kg, DMC 188 kg drop in reactor, mixing speed 200-300 rev/min of stirring and dissolving evenly to clear solution, obtained resin mother liquor; Dispersion agent, talcum powder and mill base is added in above-mentioned resin mother liquor, quantity is respectively 1.8kg, 48kg, 36.2kg, high speed dispersion 30-50min is stirred through 1000 revs/min of rotating speeds, to fineness≤35um, then adjust rotating speed at 200-300 rev/min, drop into binary biocide missible oil, 200# solvent oil and the BAC in formula, quantity is respectively 12kg, 36kg, 25kg in reactor, stir 20-30min, makes coating work in-process, and it is 30-60S that middle control detects viscosity.
Filling: coating work in-process to be crossed with 325 mesh filter screens and filters various impurity and macrobead thing, adopt automatic filling machine to press 155g and load in 400ml aerosol container, put into mixed steel ball, insertion operated pneumatic valve encapsulates; Finally, the amount by weight 1:0.50-0.55 fills into DME, gets product.
embodiment 2
The preparation (to allocate 90kg missible oil) of missible oil: by sepiolite constant temperature drying 4-10 hour in 120-380 DEG C of loft drier, is completely down to room temperature, for subsequent use; Permanone, Avrmectin, DMC, L-548 being taken sequentially respectively 13kg, 1.1kg, 46.2kg, 1.7kg drops in reactor, 30min is stirred at 60 revs/min of rotating speeds, treat that two kinds of former medicines are uniformly dissolved completely, dry Activated Sepiolite 28kg will be taken slowly drop in reactor, stop stirring after continuing to stir 15min, missible oil is distributed into 1.0kg/ bottle, de-bubble 10-40min in ultrasonic vibrator, makes binary biocide missible oil.
The preparation (to allocate 470kg coating) of coating: acrylic resin modified 120kg, DMC188kg are dropped in reactor, mixing speed evenly to clear solution, obtains resin mother liquor 200-300 rev/min of stirring and dissolving; Dispersion agent, talcum powder and mill base is added in above-mentioned resin mother liquor, quantity is respectively 1.8kg, 50kg, 37.2kg, high speed dispersion 30-50min is stirred through 1000 revs/min of rotating speeds, sand milling, to fineness≤35um, then adjusts rotating speed at 200-300 rev/min, drops into binary biocide missible oil, 200# solvent oil and the BAC in formula, quantity is respectively 12kg, 36kg, 25kg in reactor, stir 30min, makes coating work in-process, and it is 30-60S that middle control detects viscosity.
Filling: coating work in-process to be crossed with 325 mesh filter screens and filters various impurity and macrobead thing, adopt automatic filling machine to press 155g and load in 400ml aerosol container, put into mixed steel ball, insertion operated pneumatic valve encapsulates; Finally, by weight: the amount of 1:0.50-0.55 fills into DME, gets product.
embodiment 3
The preparation (to allocate 90kg missible oil) of missible oil: by sepiolite constant temperature drying 4-18 hour in 120-280 DEG C of loft drier, is completely down to room temperature, for subsequent use; Permanone, Avrmectin, DMC, L-548 being taken sequentially respectively 13kg, 1.1kg, 42.2kg, 1.7kg drops in reactor, 30min is stirred at 60 revs/min of rotating speeds, treat that two kinds of former medicines are uniformly dissolved completely, dry Activated Sepiolite 32kg will be taken slowly drop in reactor, stop stirring after continuing to stir 15min, missible oil is distributed into 1.0kg/ bottle, de-bubble 60-80min in ultrasonic vibrator, makes binary biocide missible oil.
The preparation (to allocate 470kg coating) of coating: acrylic resin modified 123kg, DMC 188kg is dropped in reactor, mixing speed evenly to clear solution, obtains resin mother liquor 200-300 rev/min of stirring and dissolving; Dispersion agent, talcum powder and mill base is added in above-mentioned resin mother liquor, quantity is respectively 1.8kg, 48kg, 36.2kg, high speed dispersion 60-70min is stirred through 1000-1200 rev/min of rotating speed, to fineness≤35um, then adjust rotating speed at 200-300 rev/min, drop into binary biocide missible oil, 200# solvent oil and the BAC in formula, quantity is respectively 12kg, 36kg, 25kg in reactor, stir 20min, makes coating work in-process, and it is 30-60S that middle control detects viscosity.
Filling: coating work in-process to be crossed with 325 mesh filter screens and filters various impurity and macrobead thing, adopt automatic filling machine to press 155g and load in 400ml aerosol container, put into mixed steel ball, insertion operated pneumatic valve encapsulates; Finally, the amount by weight 1:0.50-0.55 fills into DME, gets product.
product the key technical indexes:
1, the binary biocide in coating work in-process of the present invention closes the following standard-required of symbol.
2, auto spray painting of the present invention meets " People's Republic of China's packaging industry standard-aerosol paint " (standard No. BB/T 0047-2007) standard-required.
Long-acting control of the present invention white ant auto spray painting adopts the film forming matter, thinner, propellent and the high-efficiency low-toxicity biocide that do not contain benzene to be that starting material are formulated, realize the application technique easy of termile-proof, to person poultry safety, environmentally friendly, belong to effective white ant green control product.This product is applicable to exterior wall, the earth's surface spraying of buildings, and directly can kill with repellent white ant, available protecting buildings, household be not by the infringement of white ant.Meanwhile, this product is also applicable to outdoor, gardens scaffolding structure, and the termile-proof of timber.
Above embodiment is only introduces preferred case of the present invention, to those skilled in the art, not deviating from any apparent changes and improvements of carrying out in the scope of spirit of the present invention, all should be regarded as a part of the present invention.
Claims (6)
1. a binary biocide missible oil, is characterized in that, the component primarily of following mass parts forms: Permanone 10-13 part, Avrmectin 1-3 part, sepiolite 26-36 part, DMC 40-50 part, L-548 tensio-active agent 1-3 part.
2. the white ant auto spray painting of long-acting control, is characterized in that, comprise component A and B component, wherein:
Described component A is mainly composed of the following components: acrylic resin modified, binary biocide missible oil, DMC, 200# solvent oil, BAC, talcum powder, mill base, dispersion agent, and described binary biocide missible oil as claimed in claim 1;
Described B component is dme.
3. the white ant auto spray painting of long-acting control according to claim 2, it is characterized in that, described component A forms primarily of the component of following weight part: acrylic resin modified 120-130 part, binary biocide missible oil 10-15 part, DMC 180-190 part, 200# solvent oil 30-40 part, BAC 20-30 part, talcum powder 45-50 part, mill base 35-40 part, dispersion agent 1.0-2.0 part.
4. the white ant auto spray painting of the long-acting control according to Claims 2 or 3, is characterized in that, the mass ratio of B component and component A is 1:0.50-0.55.
5. the preparation method of the white ant auto spray painting of long-acting control described in any one of claim 2-4, comprises the steps:
(1) Permanone and Avrmectin are encapsulated in the microtubule of sepiolite, obtain binary biocide missible oil;
(2) acrylic resin modified and DMC mixing and stirring are extremely dissolved as resin mother liquor completely;
(3) in resin mother liquor, add dispersion agent, talcum powder and mill base after high speed dispersion 30-50min, then add binary biocide missible oil, 200# solvent, BAC, stir, obtain work in-process, it is 30-60S that middle control detects viscosity;
(4) carried out by work in-process filtering impurity and macrobead thing, after sub-packing pot, capping is filled with DME.
6. preparation method according to claim 5, it is characterized in that, the concrete operations of step (1) are: drop in reactor, after stirring by Permanone, Avrmectin, DMC, L-548, get dry sepiolite slowly to drop in reactor, continue to stir 10-30 min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410720409.0A CN104530857A (en) | 2014-12-01 | 2014-12-01 | Long-acting termite-control automatic spray paint and preparation method thereof |
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| CN201410720409.0A CN104530857A (en) | 2014-12-01 | 2014-12-01 | Long-acting termite-control automatic spray paint and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318066A (en) * | 2015-06-24 | 2017-01-11 | 广东自由能实业科技有限公司 | Aerosol type insecticide water-based wall paint and preparation method thereof |
| CN106700742A (en) * | 2015-11-14 | 2017-05-24 | 中山市大田汽车护理用品有限公司 | Strippable fluorescent automatic spray paint used for automobile hubs, and preparation method thereof |
| AU2016200561B2 (en) * | 2016-01-29 | 2018-11-08 | Scientific Pest Management (Australia/Pacific) Pty Ltd | Termiticide Composition |
-
2014
- 2014-12-01 CN CN201410720409.0A patent/CN104530857A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318066A (en) * | 2015-06-24 | 2017-01-11 | 广东自由能实业科技有限公司 | Aerosol type insecticide water-based wall paint and preparation method thereof |
| CN106700742A (en) * | 2015-11-14 | 2017-05-24 | 中山市大田汽车护理用品有限公司 | Strippable fluorescent automatic spray paint used for automobile hubs, and preparation method thereof |
| CN106700742B (en) * | 2015-11-14 | 2019-05-21 | 中山市大田汽车护理用品有限公司 | A kind of automotive hub peelable fluorescence auto spray painting and preparation method thereof |
| AU2016200561B2 (en) * | 2016-01-29 | 2018-11-08 | Scientific Pest Management (Australia/Pacific) Pty Ltd | Termiticide Composition |
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