CN104519997B - 将氧合物转化成烯烃的催化剂和方法 - Google Patents

将氧合物转化成烯烃的催化剂和方法 Download PDF

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CN104519997B
CN104519997B CN201380042043.XA CN201380042043A CN104519997B CN 104519997 B CN104519997 B CN 104519997B CN 201380042043 A CN201380042043 A CN 201380042043A CN 104519997 B CN104519997 B CN 104519997B
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mfi
mel
zeolites
zeolite
phosphorus
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CN104519997A (zh
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K·斯潘霍夫
F·C·帕特卡斯
K·巴伊
M·加布
E·施瓦布
M·黑塞
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380042043.XA 2012-06-29 2013-06-26 将氧合物转化成烯烃的催化剂和方法 Active CN104519997B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12174288.6 2012-06-29
EP12174288 2012-06-29
PCT/EP2013/063434 WO2014001410A2 (de) 2012-06-29 2013-06-26 Katalysator und verfahren für die umwandlung von oxygenaten zu olefinen

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Publication Number Publication Date
CN104519997A CN104519997A (zh) 2015-04-15
CN104519997B true CN104519997B (zh) 2017-07-28

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EP (1) EP2866933B1 (enExample)
JP (1) JP6433892B2 (enExample)
CN (1) CN104519997B (enExample)
AU (1) AU2013283347B2 (enExample)
BR (1) BR112014031391B1 (enExample)
CA (1) CA2877560C (enExample)
MX (1) MX2014015734A (enExample)
RU (1) RU2015102198A (enExample)
WO (1) WO2014001410A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
JP6466325B2 (ja) * 2012-06-29 2019-02-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ オキシジェネートからオレフィンへの転化のための触媒コーティングおよび方法
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
JP6521979B2 (ja) * 2013-12-20 2019-05-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 含酸素化合物をオレフィンに変換するための触媒および方法
JP6617709B2 (ja) * 2014-09-30 2019-12-11 東亞合成株式会社 アクリル酸系重合体水溶液及びその製造方法
CN116408134A (zh) * 2021-12-30 2023-07-11 卓悦环保新材料（上海）有限公司 一种抗破碎的甲醇制丙烯催化剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4504690A (en) * 1982-03-18 1985-03-12 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
CN101036893A (zh) * 2007-04-24 2007-09-19 中国石油化工集团公司 一种催化裂化催化剂
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
DE2830787B2 (de) 1978-07-13 1981-02-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von stickstoffhaltigen kirstallinen Metallsilikaten mit Zeolithstniktur
DE3006471A1 (de) 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
US4548914A (en) * 1983-08-26 1985-10-22 Mobil Oil Corporation Zeolite catalysts of improved activity and para-selectivity
DD238733A1 (de) 1984-12-29 1986-09-03 Leuna Werke Veb Herstellung selektiver olefinkatalysatoren
EP0229952A3 (en) * 1985-12-30 1988-05-11 Mobil Oil Corporation A process for making light olefins from alcohols and ethers
EP2143700A1 (en) * 2008-06-25 2010-01-13 Total Petrochemicals Research Feluy Process to make olefins from oxygenates
DE102011013909A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine
DE102011013911A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Verbessertes Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine
DE102011013908A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
CA2843793A1 (en) * 2011-08-03 2013-02-07 Total Research & Technology Feluy Method for making a catalyst comprising a phosphorus modified zeolite and use of said zeolite

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4504690A (en) * 1982-03-18 1985-03-12 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
CN101036893A (zh) * 2007-04-24 2007-09-19 中国石油化工集团公司 一种催化裂化催化剂
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

Also Published As

Publication number Publication date
BR112014031391A2 (pt) 2017-06-27
CN104519997A (zh) 2015-04-15
RU2015102198A (ru) 2016-08-20
AU2013283347B2 (en) 2017-06-22
BR112014031391B1 (pt) 2020-12-08
CA2877560A1 (en) 2014-01-03
JP6433892B2 (ja) 2018-12-05
CA2877560C (en) 2020-07-21
WO2014001410A3 (de) 2014-03-06
EP2866933A2 (de) 2015-05-06
JP2015526280A (ja) 2015-09-10
MX2014015734A (es) 2016-01-12
AU2013283347A1 (en) 2015-01-22
EP2866933B1 (de) 2018-08-22
WO2014001410A2 (de) 2014-01-03

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