CN104513065A - Antifouling liquid and artificial stone processing method adopting the antifouling liquid - Google Patents
Antifouling liquid and artificial stone processing method adopting the antifouling liquid Download PDFInfo
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- CN104513065A CN104513065A CN201310594128.0A CN201310594128A CN104513065A CN 104513065 A CN104513065 A CN 104513065A CN 201310594128 A CN201310594128 A CN 201310594128A CN 104513065 A CN104513065 A CN 104513065A
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- artificial stone
- dirtying liquid
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- dirtying
- antifouling liquid
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Abstract
The invention discloses an antifouling liquid including the following components by weight: 35-50% of nano SiO2, 0.1-1.0% of a rare earth polishing material, 0.2-3.0% of super nano TiO2, 0.5-1.0% of a thickening agent, 0.1-0.2% of a brightener, 0.2-1.2% of a temperature resistant additive and balance of water. The super nano scale refers to average particle size of less than 10 nm, and the rare earth polishing material is ceria based polishing powder or zirconium based polishing powder. Compared with the prior art, when the surface of the stone is coated with the antifouling liquid, the antifouling liquid can quickly penetrate into a base material to plug fine pores and fine cracks, at the same time, a layer of functional protective film is formed on the substrate surface, and the infiltration of various stains can be effectively prevented, so that the stone surface is clear and bright. The invention also provides an artificial stone processing method adopting the antifouling liquid for artificial stone.
Description
Technical field
The present invention relates to coating or the dip treating technical field of artificial stone-like material, particularly relate to a kind of artificial stone-like material's anti-dirtying liquid and using method thereof.
Background technology
Artificial stone-like material is mainly used between cabinet panel and bathroom because of advantages such as its solid colour, attractive in appearance, firm, easy to clean and Seamless linkages, but because this sheet material is made by specific technique by resin and packing material and dispersing auxiliary etc., there is many pores, pore and hair line in its surface and inside, although through polishing grinding, (glossiness is on the low side not for the brightness of palette face, about about 45 °), not too antifouling and antifouling lasting, this is the deficiency of current artificial stone-like material.
For this defect of artificial stone-like material, current most of producer adopts silane fluorine carbon stain control agent to do antifouling process, but the anti-fouling effect of silane fluorine carbon stain control agent is unsatisfactory, and not only light enhancing effect is poor, sometimes even also have impact on surface gloss.
In the concrete use procedure of concrete stain control agent, currently used technique mainly comprises following flow process: first adopt wax-polishing machine to the waxing of artificial stone-like material surface, to accomplish fluently after wax drop stain control agent on artificial stone-like material again, and all throw process, finally, the artificial stone-like material all thrown is carried out overlay film, packs.
Summary of the invention
One object of the present invention is to provide a kind of tasteless, nontoxic, non-volatile, artificial stone-like material's anti-dirtying liquid that light enhancing effect is good.
Another object of the present invention is to provide a kind of artificial stone-like material's treatment process adopting above-mentioned anti-dirtying liquid.
For reaching above object, the present invention adopts following technical scheme.
A kind of anti-dirtying liquid, is characterized in that, comprise by weight percentage:
The Nano-meter SiO_2 of 35 ~ 50%
2,
The rare-earth polishing material of 0.1 ~ 1.0%,
The super nano level TiO of 0.2 ~ 3.0%
2,
The thickening material of 0.5 ~ 1.0%,
The brightening agent of 0.1 ~ 0.2%,
The heatproof auxiliary agent of 0.2 ~ 1.2%, all the other are water;
Wherein, described rare-earth polishing material is cerium based relief polishing powder or zirconium based relief polishing powder, and described super nano level refers to that the median size of particle is less than 10 nanometers.
As with improvement, described thickening material is propylene glycol alginate, guar gum, xanthan gum, gum arabic, one or more in carrageenin.
As with improvement, described brightening agent comprises: benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate and water.
As with improvement, described heatproof auxiliary agent is polyether glycol.
A kind of artificial stone-like material's treatment process, is characterized in that, it adopts as the artificial stone-like material's anti-dirtying liquid in claim 1-4 as described in any one.
As with improvement, described artificial stone-like material's treatment process, comprising:
Dedusting, the dust in removing artificial stone-like material's plate face;
Grinding, first adopts dropwise adding pipeline, anti-dirtying liquid is added drop-wise to artificial stone-like material surface, then adopt 6 ~ 12 groups of grinding head for polishing to carry out continuously grinding, in process of lapping, do not exert pressure in addition and only by bistrique pressure itself rubbing down, grinding temperature is no more than 45 DEG C;
Remove residue, remove the residue of artificial stone-like material surface, side;
Overlay film, at artificial stone-like material's outer cladding layer protecting film;
Packaging shipment.
As with improvement, rubbing down speed is 1 m/min-1.5 ms/min, to make anti-dirtying liquid fully infiltrate artificial stone-like material, is beneficial to and fills pin hole, crackle and pore.
As with improvement, in process of lapping, anti-dirtying liquid divide A, B two groups with the use of; The concentration of A group anti-dirtying liquid is higher than the concentration of B group anti-dirtying liquid.
As with improvement, every two groups of bistriques are reinforced once; Concrete grinding steps is: after being first ground to reinforced 3-4 time with A group anti-dirtying liquid, then terminates after being ground to reinforced 2-3 time with B group anti-dirtying liquid.Wherein, the A group anti-dirtying liquid of high density is conducive to the pin hole on filling artificial stone-like material surface, crackle and pore, and the B group anti-dirtying liquid that concentration is slightly low is conducive to percdation, organically combines with stone material body, thus strengthening filling effect.
Compared with prior art, when a kind of anti-dirtying liquid provided by the invention is coated with and grinds on stone surface, the inner shutoff pore of base material and hair line can be infiltrated rapidly, form one deck functional protection film at substrate surface, the effective infiltration stoping various stain.Meanwhile, owing to containing brightening agent in anti-dirtying liquid, effectively artificial stone-like material's surface brightness is improved; Test by experiment, after using anti-dirtying liquid provided by the invention, artificial stone-like material's surface gloss increases to more than 85 ° by about traditional 45 °.
Artificial stone-like material's treatment process of the above-mentioned anti-dirtying liquid of employing provided by the invention, utilize continuously grinding mode, and grind under the effect of grinding head pressure itself, an anti-dirtying liquid part is made to go deep into the solid pore of base material and the hair line of artificial stone-like material, another part forms one deck hardness with the high photo-protection layer of the densification that base material is consistent on surface, not only add lustre to but also antifouling.Meanwhile, owing to containing nano level SiO in anti-dirtying liquid
2with super nano level TiO
2, utilize the superfine of nano material and extremely excellent infiltration, electrostatic adhesion function, grind produce micro-electrostatic time, nanomaterial-filled artificial stone-like material's plate face pore that uniform adsorption is fine.In addition; under relative pressure, temperature and certain speed; excellent nano rare earth polishing function; anti-dirtying liquid is allowed to produce secondary compact crystal; electrostatic adhesion can make material be covered with plate surface uniformly after filling pore and pit; because certain expansion occurs volume; the crystal of infiltration in pore can sting tight base material; and form the extremely strong molecular linkage system of sticking power; all-in-one-piece dense protective layer is polymerized with plate surface biting the end of knot; under the grinding of polymer rare earth micro mist, produce high glossiness, thus reach the antifouling property that adds lustre in plate face.
Embodiment
Understand the essence of this creation for convenience of those of ordinary skill in the art better, below the specific embodiment of the present invention is described in detail.
Anti-dirtying liquid embodiment one
A kind of anti-dirtying liquid, is characterized in that, comprise by weight percentage: the Nano-meter SiO_2 of 35 ~ 50%
2, the rare-earth polishing material of 0.1 ~ 1.0%, the super nano level TiO of 0.2 ~ 3.0%
2, the thickening material of 0.5 ~ 1.0%, the brightening agent of 0.1 ~ 0.2%, the heatproof auxiliary agent of 0.2 ~ 1.2%, all the other are water.Here, described super nano level refers to that the median size of particle is less than 10 nanometers.
In the present embodiment, preferred Nano-meter SiO_2
2content be 40%; Preferred rare-earth polishing material is cerium rouge, and the content of rare-earth polishing material is 0.5%; Preferably super nano level TiO
2content be 2%; Preferred thickener is propylene glycol alginate, and amount of thickener is 0.8%; The excellent benzylideneacetone of preferred brightening agent, polyoxyethylene nonylphenol ether, Sodium Benzoate and water composition, the content of brightening agent is 0.1%; Preferred heatproof auxiliary agent is polyether glycol, helps warm agent content to be 1%.In other embodiments, described cerium oxide is substituted by other cerium based relief polishing powders or zirconium based relief polishing powder; Described thickening material is propylene glycol alginate, guar gum, xanthan gum, gum arabic, one or more in carrageenin; Be not limited to the present embodiment.
When a kind of anti-dirtying liquid that the present embodiment provides is coated with and grinds on stone surface; the inner shutoff pore of base material and hair line can be infiltrated rapidly, meanwhile, form one deck functional protection film at substrate surface; the infiltration of the various stain of effective prevention, makes stone surface limpid beautiful.
Anti-dirtying liquid embodiment two
A kind of anti-dirtying liquid, comprise by weight percentage: the nanosized SiO_2 of 35%, the rare-earth polishing material of 0.1%, the super nanosized TiO_2 of 0.2%, the thickening material of 0.5%, the brightening agent of 0.1%, the heatproof auxiliary agent of 0.2%, all the other are water.Wherein, described super nano level refers to that the median size of particle is less than 10 nanometers, described rare-earth polishing material is zirconium white polishing powder, described thickening material is gum arabic, described brightening agent is made up of benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate and water, and described heatproof auxiliary agent is polyether glycol.
Anti-dirtying liquid embodiment three
A kind of anti-dirtying liquid, comprise by weight percentage: the nanosized SiO_2 of 50%, the rare-earth polishing material of 1%, the super nanosized TiO_2 of 3%, the thickening material of 1%, the brightening agent of 0.2%, the heatproof auxiliary agent of 1.2%, all the other are water.Wherein, described super nano level refers to that the median size of particle is less than 10 nanometers, described rare-earth polishing material is zirconium white polishing powder, described thickening material is guar gum, described brightening agent is made up of benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate and water, and described heatproof auxiliary agent is polyether glycol.
Embodiment of the method
Adopt artificial stone-like material's treatment process of above-mentioned artificial stone-like material's anti-dirtying liquid, comprising:
Dedusting, the dust in removing artificial stone-like material's plate face;
Grinding, first adopts dropwise adding pipeline, anti-dirtying liquid is added drop-wise to artificial stone-like material surface, then adopt 6 ~ 12 groups of grinding head for polishing to carry out continuously grinding, in process of lapping, do not exert pressure in addition and only by bistrique pressure itself rubbing down, grinding temperature is no more than 45 DEG C;
Remove residue, remove the residue of artificial stone-like material surface, side;
Overlay film, at artificial stone-like material's outer cladding layer protecting film;
Packaging shipment.
Wherein, rubbing down speed is 1 m/min-1.5 ms/min, to make anti-dirtying liquid fully infiltrate artificial stone-like material, is beneficial to and fills pin hole, crackle and pore.
In process of lapping, anti-dirtying liquid divides A, B two groups with the use of the concentration of, preferred A group anti-dirtying liquid higher than the concentration of B group anti-dirtying liquid.The A group anti-dirtying liquid of high density is conducive to filling the pin hole on artificial stone-like material surface, crackle and pore, and the B group anti-dirtying liquid that concentration is slightly low is conducive to percdation, organically combines with stone material body, thus strengthens filling effect.In the present embodiment, preferred A group anti-dirtying liquid is obtained by above-mentioned anti-dirtying liquid embodiment one, and preferred B group anti-dirtying liquid is obtained by above-mentioned anti-dirtying liquid embodiment two.
During concrete grinding, every two groups of bistriques are reinforced once; Concrete grinding steps is: after being first ground to reinforced 3-4 time with A group anti-dirtying liquid, then terminates after being ground to reinforced 2-3 time with B group anti-dirtying liquid.
Artificial stone-like material's treatment process that the present embodiment provides, utilize continuously grinding mode, and grind under the effect of grinding head pressure itself, an anti-dirtying liquid part is made to go deep into the solid pore of base material and the hair line of artificial stone-like material, another part forms one deck hardness with the high photo-protection layer of the densification that base material is consistent on surface, not only add lustre to but also antifouling.Meanwhile, due in anti-dirtying liquid containing nano level SiO2 and super nanosized TiO_2, utilize the superfine of nano material and extremely excellent infiltration, electrostatic adhesion function, when grinding the micro-electrostatic of generation, nanomaterial-filled artificial stone-like material's plate face pore that uniform adsorption is fine.In addition; under relative pressure, temperature and certain speed; excellent nano rare earth polishing function; anti-dirtying liquid is allowed to produce secondary compact crystal; electrostatic adhesion can make material be covered with plate surface uniformly after filling pore and pit; because certain expansion occurs volume; the crystal of infiltration in pore can sting tight base material; and form the extremely strong molecular linkage system of sticking power; all-in-one-piece dense protective layer is polymerized with plate surface biting the end of knot; under the grinding of polymer rare earth micro mist, produce high glossiness, thus reach the antifouling property that adds lustre in plate face.
Above embodiment has been described in detail essence of the present invention, but can not limit protection scope of the present invention with this.Apparently, under the enlightenment of essence of the present invention, the art those of ordinary skill also can carry out many improvement and modification, it should be noted that these improve and modify and all drops within claims of the present invention.
Claims (9)
1. an anti-dirtying liquid, is characterized in that, comprises by weight percentage:
The Nano-meter SiO_2 of 35 ~ 50%
2,
The rare-earth polishing material of 0.1 ~ 1.0%,
The super nano level TiO of 0.2 ~ 3.0%
2,
The thickening material of 0.5 ~ 1.0%,
The brightening agent of 0.1 ~ 0.2%,
The heatproof auxiliary agent of 0.2 ~ 1.2%, all the other are water;
Wherein, described rare-earth polishing material is cerium based relief polishing powder or zirconium based relief polishing powder, and described super nano level refers to that the median size of particle is less than 10 nanometers.
2. anti-dirtying liquid according to claim 1, is characterized in that, described thickening material is propylene glycol alginate, guar gum, xanthan gum, gum arabic, one or more in carrageenin.
3. anti-dirtying liquid according to claim 1, is characterized in that, described brightening agent comprises: benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate and water.
4. anti-dirtying liquid according to claim 1, is characterized in that, described heatproof auxiliary agent is polyether glycol.
5. artificial stone-like material's treatment process, is characterized in that, it adopts as the artificial stone-like material's anti-dirtying liquid in claim 1-4 as described in any one.
6. artificial stone-like material's treatment process according to claim 5, is characterized in that, comprising:
Dedusting, the dust in removing artificial stone-like material's plate face;
Grinding, first adopts dropwise adding pipeline, anti-dirtying liquid is added drop-wise to artificial stone-like material surface, then adopt 6 ~ 12 groups of grinding head for polishing to carry out continuously grinding, in process of lapping, do not exert pressure in addition and only by the slow rubbing down of bistrique pressure itself, grinding temperature is no more than 45 DEG C;
Remove residue, remove the residue of artificial stone-like material surface, side;
Overlay film, at artificial stone-like material's outer cladding layer protecting film;
Packaging shipment.
7. artificial stone-like material's treatment process according to claim 6, is characterized in that, rubbing down speed is 1 m/min-1.5 ms/min, to make anti-dirtying liquid fully infiltrate artificial stone-like material, is beneficial to and fills pin hole, crackle and pore.
8. artificial stone-like material's treatment process according to claim 6, is characterized in that, in process of lapping, anti-dirtying liquid divide A, B two groups with the use of; The concentration of A group anti-dirtying liquid is higher than the concentration of B group anti-dirtying liquid.
9. artificial stone-like material's treatment process according to claim 8, is characterized in that, every two groups of bistriques are reinforced once; Concrete grinding steps is: after being first ground to reinforced 3-4 time with A group anti-dirtying liquid, then terminates after being ground to reinforced 2-3 time with B group anti-dirtying liquid.
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| CN201310594128.0A CN104513065B (en) | 2013-09-29 | 2013-11-22 | Antifouling liquid and artificial stone processing method adopting the antifouling liquid |
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Cited By (4)
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| CN105081911A (en) * | 2015-06-19 | 2015-11-25 | 苏州金螳螂园林绿化景观有限公司 | Method for keeping cleanness of stone material laid on red land |
| CN106747663A (en) * | 2016-11-17 | 2017-05-31 | 绥阳县华夏陶瓷有限责任公司 | A kind of manufacture craft of antiseepage dirt ceramic tile |
| CN107739217A (en) * | 2017-09-30 | 2018-02-27 | 佛山欧神诺陶瓷股份有限公司 | A kind of preparation method of the polishing class Ceramic Tiles with wet antiskid function |
| CN113211193A (en) * | 2021-04-02 | 2021-08-06 | 广东意新家居有限责任公司 | Cleaning method of inorganic artificial stone |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105081911A (en) * | 2015-06-19 | 2015-11-25 | 苏州金螳螂园林绿化景观有限公司 | Method for keeping cleanness of stone material laid on red land |
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| CN107739217A (en) * | 2017-09-30 | 2018-02-27 | 佛山欧神诺陶瓷股份有限公司 | A kind of preparation method of the polishing class Ceramic Tiles with wet antiskid function |
| CN107739217B (en) * | 2017-09-30 | 2020-06-16 | 佛山欧神诺陶瓷有限公司 | Preparation method of polished ceramic tile with wet anti-slip function |
| CN113211193A (en) * | 2021-04-02 | 2021-08-06 | 广东意新家居有限责任公司 | Cleaning method of inorganic artificial stone |
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| CN104513065B (en) | 2017-01-25 |
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