CN105385356A - Polishing liquid, preparation method and application - Google Patents
Polishing liquid, preparation method and application Download PDFInfo
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- CN105385356A CN105385356A CN201510663022.0A CN201510663022A CN105385356A CN 105385356 A CN105385356 A CN 105385356A CN 201510663022 A CN201510663022 A CN 201510663022A CN 105385356 A CN105385356 A CN 105385356A
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- Prior art keywords
- polishing fluid
- polishing
- marble
- wood
- palm wax
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- 238000005498 polishing Methods 0.000 title claims abstract description 78
- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 57
- 239000004203 carnauba wax Substances 0.000 claims abstract description 39
- 239000012188 paraffin wax Substances 0.000 claims abstract description 25
- 239000004579 marble Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000007822 coupling agent Substances 0.000 claims abstract description 22
- 239000002023 wood Substances 0.000 claims abstract description 22
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 20
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 239000012530 fluid Substances 0.000 claims description 61
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 57
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 29
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 235000011187 glycerol Nutrition 0.000 claims description 19
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 17
- 239000004593 Epoxy Substances 0.000 claims description 16
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 16
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 14
- 229940039790 sodium oxalate Drugs 0.000 claims description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 229940070337 ammonium silicofluoride Drugs 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 150000003891 oxalate salts Chemical class 0.000 claims description 7
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical group [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- -1 fluosilicate Chemical compound 0.000 abstract description 3
- 238000011282 treatment Methods 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000005282 brightening Methods 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 235000006408 oxalic acid Nutrition 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 3
- 238000004018 waxing Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000007494 plate polishing Methods 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)
Abstract
The present invention belongs to the technical field of marble or wood-based panel surface brightening and protection treatments, in particular relating to polishing liquid, a preparation method and an application. The polishing liquid comprises a pH modifier, soluble oxalate, a lubricant, fluosilicate, nano titanium dioxide, nano silicon dioxide, a coupling agent, a palm wax emulsion and/or a paraffin emulsion and water. By applying the polishing liquid provided by the present invention to a marble or wood-based panel surface, under a series of physical and chemical actions, a thick layer of dense bright glassy substances can be generated on the surface; the bright glassy substances are hard, wear-resistant and weather-resistant, so that the 'water'-like bright mirror effect on a floor surface is achieved; and a surface scratch can be easily repaired. When the marble or wood-based panel surface is treated by the polishing liquid, the polishing liquid is only required to be poured onto the marble or wood-based panel, and is spread by a polishing pad. Polishing steel wire cotton is not needed; production efficiency is improved; cost is saved; and polishing brightness is improved.
Description
Technical field
The invention belongs to marble or add lustre in wood-based plate surface, the technical field of protective treatment, particularly a kind of polishing fluid, preparation method and application.
Background technology
At present, the material surface such as marble or wood-based plate bright treatment method is generally in material surface waxing or uses polishing fluid to carry out surface treatment.But after material surface waxing, waxing layer not rub resistance, easily comes off, and material surface effect is also bright not.And Problems existing is when adopting polishing fluid to process the material surface such as marble or wood-based plate: (1) needs mat and steel wool to use simultaneously, polishing fluid just can be made to spread over material surface, and in use, polishing cotton needs often to change, not only waste material, and production rate is slow.(2) although do not need steel wool for indivedual import resene product, the dry solidification time of more than 24 hours is needed, ability polishing, this wastes the production time greatly, and resin material cost is very high, the time has grown the easy xanthochromia of formed film, difficult reparation after scratch.
Summary of the invention
The deficiency that the present invention exists to overcome prior art, provides a kind of time saving and energy saving and do not need polished steel silk flosssilk wadding just can well by the polishing fluid of the material surface such as marble or wood-based plate polishing.
Be specially: a kind of polishing fluid, calculate this polishing fluid by mass percentage and comprise following component:
PH adjusting agent: 0.02-1.27%;
Soluble oxalate salt: 0.2%-2%;
Lubricant: 2.3%-3.8%;
Silicofluoride: 10%-15%;
Nano titanium oxide: 2%-5%;
Nano silicon: 1%-5%;
Coupling agent: 0.1%-0.5%;
Palm wax emulsion and/or paraffin wax emulsions: 3.9%-11.8%;
Surplus is water.
Wherein, palm wax emulsion can adopt the palm wax emulsion that market is bought, such as, brand is the palm wax emulsion of holy nation, the palm wax emulsion of Laiyang Sheng Bang organosilicon Science and Technology Ltd. etc., can certainly adopt the palm wax emulsion disclosed in prior art prepared by method.Such as adopt palm wax emulsion prepared by the material such as sorbitan fatty acid ester (sapn) and polyoxyethylene sorbitan fatty acid ester (tween) series of surfactants.
Paraffin wax emulsions also can adopt the paraffin wax emulsions that market is bought, such as: Ao Da Chemical Co., Ltd. produces paraffin wax emulsions etc.Equally, paraffin wax emulsions also can adopt the paraffin wax emulsions disclosed in prior art prepared by method.
As further improvement, the solid content of described palm wax emulsion and/or paraffin wax emulsions is 15-30%.In palm wax emulsion, the mass ratio of palm wax and emulsifying agent is 85:15; In paraffin wax emulsions, the mass ratio of paraffin and emulsifying agent is 90:10.
As further improvement, described lubricant is the mixture of ethylene glycol and glycerine, and in polishing fluid, the massfraction of ethylene glycol is 0.3%-0.8%, and the massfraction of glycerine is 2%-3%; Described Soluble oxalate salt is potassium oxalate and/or sodium oxalate.
As further improvement, described pH adjusting agent is HOOCCOOH, H
3pO
4, H
2sO
4, one or several in HCl.Wherein, oxalic acid, phosphoric acid not only can regulate pH, can also with calcium carbonate reaction oxalic calcium, the calcium phosphate on marble or wood-based plate surface, improve the brightness on surface.In addition, add phosphoric acid and also there is lubrication, more lubricate when making polishing fluid be coated onto marble or wood-based plate surperficial, be more prone to cast aside.It should be noted that, in pH adjusting agent, the mass percent of various acid refers to the mass percent of the pure acid not containing water.
As further improvement, described silicofluoride is one or several in magnesium silicofluoride, zine fluosilicate, ammonium silicofluoride.Magnesium silicofluoride, zine fluosilicate and ammonium silicofluoride can be combined together with other materials and be applied to marble or wood-based plate surface, improve surface brightness.In raising luminance brightness, zine fluosilicate is than magnesium silicofluoride or ammonium silicofluoride better effects if.Separately exist, the polishing fluid adopting oxalic acid to prepare as pH adjusting agent, when placing more than 1 year, has a little precipitation, although do not affect use, can affect attractive in appearance, adds ammonium silicofluoride when placing for a long time, can reduce or avoid the generation of this situation.
As further improvement, described coupling agent is γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
Present invention also offers the preparation method of above-mentioned polishing fluid, specifically comprise the following steps:
A) pH adjusting agent is added to the water the formation aqueous solution;
B) Soluble oxalate salt, lubricant are added in step liquid a), stir;
C) silicofluoride, nano titanium oxide, nano silicon, coupling agent are added step b) in the liquid of gained, stir;
D) palm wax emulsion and/or paraffin wax emulsions are added step c) liquid in stir, such as stir one hour.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
As further improvement, described step a) in the pH of the aqueous solution be 0.5-2; Described steps d) in palm wax emulsion or paraffin wax emulsions solid content be 15-30%, and the rarer stirring of emulsion concentration is easier.In palm wax emulsion, the mass ratio of palm wax and emulsifying agent is 85:15, and in paraffin wax emulsions, the mass ratio of paraffin and emulsifying agent is 90:10.
Present invention also offers the application method of above-mentioned polishing fluid, its embody rule method is: polishing fluid be poured on marble or on wood-based plate, with polishing pad, polishing fluid cast aside.
Compared with prior art, the invention has the beneficial effects as follows:
(1) polishing fluid of the present invention is applied to marble or wood-based plate surface, can at the glassy bright material of a thick layer of densification of Surface Creation under a series of materialization effect, this glassy bright material is hard, wear-resisting weather-proof is good, make floor surface form the bright mirror surface effect of " Wang Shui ", very easily repair after surface tear.Significantly be better than like product in the world.Marble or wood-based plate surface brightness through testing polishing fluid process of the present invention can reach about 110 degree, and brightness effect is very good.
(2) polishing fluid of the present invention is when processing marble or wood-based plate surface, only needs polishing fluid to be poured on marble or wood-based plate, is cast aside by polishing fluid with polishing pad.Without the need to using polished steel silk flosssilk wadding, improve production efficiency, providing cost savings, improve polishing brightness.
(3) polishing fluid preparation method of the present invention is simple, and raw material sources are extensive, with low cost.
Embodiment
In polishing fluid of the present invention:
1) impurity of floor surface can be cleaned out by the pH adjusting agent in polishing fluid;
2) the Soluble oxalate salt in polishing fluid or oxalic acid can with the calcium carbonate reaction oxalic calcium crystal of marble or wood-based plate upper surface, make floor surface brighter, more wear-resisting, harder.
3) calcium carbonate reaction of the fluorion in silicofluoride and marble or wood-based plate upper surface generates Calcium Fluoride (Fluorspan), makes floor surface harder.
4) hydrophilic group of coupling agent contacts with silicate, nano silicon, nano titanium oxide, and oleophilic group contacts with palm wax and/or paraffin, mat cast aside heat effect under be combined into smooth film, make floor surface very bright.Wherein, silicate obtains by after silicofluoride and calcium carbonate reaction.
5) glycerine and ethylene glycol make the surface of marble or wood-based plate more lubricate, and are more prone to cast aside.
Its embodiment is as follows:
Embodiment 1
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
H
2SO
4：0.8％；
Sodium oxalate: 0.2%;
Ethylene glycol: 0.3%;
Glycerine: 2%;
Zine fluosilicate: 10%;
Nano titanium oxide: 2%;
Nano silicon: 1%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.1%;
Solid content is the palm wax emulsion of 30%: 3.9%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) sulfuric acid is added to the water the formation aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) zine fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% palm wax emulsion add step c) liquid in stir.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 2
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
H
3PO
4：0.5％；
Sodium oxalate: 2%;
Ethylene glycol: 0.8%;
Glycerine: 3%;
Magnesium silicofluoride: 15%;
Nano titanium oxide: 5%;
Nano silicon: 5%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.5%;
Solid content is the palm wax emulsion of 30%: 11.8%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) phosphoric acid is added to the water the formation aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) magnesium silicofluoride, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% palm wax emulsion add step c) liquid in stir.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 3
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
Oxalic acid: 0.5%;
Sodium oxalate: 0.2%;
Ethylene glycol: 0.3%;
Glycerine: 2%;
Ammonium silicofluoride: 10%;
Nano titanium oxide: 2%;
Nano silicon: 1%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.1%;
Solid content is the palm wax emulsion of 30%: 3.9%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) oxalic acid is added to the water the formation aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) ammonium silicofluoride, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) the palm wax emulsion with the solid content after emulsifier being 30% is added step c) liquid in stir.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 4
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
H
2SO
4：0.3％；
Sodium oxalate: 1%;
Ethylene glycol: 0.5%;
Glycerine: 2.5%;
Zine fluosilicate: 12%;
Nano titanium oxide: 3%;
Nano silicon: 3%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.4%;
Solid content is the palm wax emulsion of 30%: 7.8%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) sulfuric acid is added to the water the formation aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) zine fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% palm wax emulsion add step c) liquid in stir.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 5
Except H
2sO
4massfraction is beyond 0.1%, and all the other are identical with embodiment 4.
Embodiment 6
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
H
3PO
4：0.6％；
Sodium oxalate: 0.8%;
Ethylene glycol: 0.4%;
Glycerine: 2.2%;
Magnesium silicofluoride: 11%;
Nano titanium oxide: 4%;
Nano silicon: 2%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.2%;
Solid content is the palm wax emulsion of 30%: 5.9%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) phosphoric acid is added water and form the aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) magnesium silicofluoride, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% palm wax emulsion add step c) liquid in stir.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 7
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
H
2SO
4：1.27％；
Sodium oxalate: 0.2%;
Ethylene glycol: 0.3%;
Glycerine: 2%;
Zine fluosilicate: 10%;
Nano titanium oxide: 2%;
Nano silicon: 1%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.1%;
Solid content is the palm wax emulsion of 30%: 3.9%;
Surplus is water.
The concrete preparation method of this polishing fluid is:
A) sulfuric acid is added to the water the formation aqueous solution;
B) sodium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) zine fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% palm wax emulsion add step c) liquid in stir one hour.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 8
A kind of polishing fluid, this polishing fluid comprises following component by mass percentage:
HCl：0.02％；
Potassium oxalate: 2%;
Ethylene glycol: 0.8%;
Glycerine: 3%;
Magnesium silicofluoride: 15%;
Nano titanium oxide: 5%;
Nano silicon: 5%;
Coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.5%;
Solid content is 30% paraffin wax emulsions: 11.7%;
Surplus is water.
This polishing fluid concrete preparation method be:
A) hydrochloric acid is added to the water the formation aqueous solution;
B) potassium oxalate, ethylene glycol and glycerine are added in step aqueous solution a), stir;
C) magnesium silicofluoride, nano titanium oxide, nano silicon, coupling agent γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane are added step b) in the liquid of gained, stir;
D) by solid content be 30% paraffin wax emulsions add step c) liquid in stir one hour.
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
Embodiment 9
Except being changed to except the paraffin wax emulsions of 30% by the palm wax emulsion of 30%, all the other are identical with embodiment 4.
Embodiment 10
Except the palm wax emulsion of 30% being changed to the paraffin wax emulsions of 30% and the palm wax emulsion of 30% is except 1:1 with mass ratio, all the other are identical with embodiment 3.
Embodiment 11
Except being changed to except the paraffin wax emulsions of 15% by the palm wax emulsion of 30%, all the other are identical with embodiment 4.
Embodiment 12
Except the palm wax emulsion palm wax emulsion of 30% being changed to 15%, all the other are identical with embodiment 4.
It should be noted that, the massfraction of the total various acid of embodiment, refer to the massfraction of acid not containing water, and in preparation method, the acid such as the sulfuric acid added or hydrochloric acid, what add is solution containing water.
The application of embodiment 1-12 in marble and wood-based plate
1, polishing fluid is poured on marble, casts aside with polishing pad.The luminance brightness recording embodiment 1,2,3,4,5,6,7,8,9,10,11,12 with vancometer is 105,110,105,106,102,105,95,97,95,99,95,99.
2, polishing fluid is poured on wood-based plate, casts aside with polishing pad.The luminance brightness recording embodiment 1,2,3,4,5,6,7,8,9,10,11,12 with vancometer is 106,109,108,106,102,106,96,95,97,100,95,100.
Only as described above, be only the preferred embodiment of the present invention, when can not limit the scope of the invention process with this, namely generally according to equivalence change simple done by the content described in the claims in the present invention and description of the invention and modification, be all still covered by the claims of the invention.In addition, summary part and title are only used to the use of auxiliary patent document search, are not used for the interest field of restriction the present invention.
Claims (10)
1. a polishing fluid, is characterized in that, calculates this polishing fluid by mass percentage and comprises following component:
PH adjusting agent: 0.02-1.27%;
Soluble oxalate salt: 0.2%-2%;
Lubricant: 2.3%-3.8%;
Silicofluoride: 10%-15%;
Nano titanium oxide: 2%-5%;
Nano silicon: 1%-5%;
Coupling agent: 0.1%-0.5%;
Palm wax emulsion and/or paraffin wax emulsions: 3.9%-11.8%;
Surplus is water.
2. polishing fluid as claimed in claim 1, it is characterized in that, the solid content of described palm wax emulsion and/or paraffin wax emulsions is 15-30%.
3. polishing fluid as claimed in claim 1, it is characterized in that, in described palm wax emulsion, the mass ratio of palm wax and emulsifying agent is 85:15; In paraffin wax emulsions, the mass ratio of paraffin and emulsifying agent is 90:10.
4. polishing fluid as claimed in claim 1, it is characterized in that, described lubricant is the mixture of ethylene glycol and glycerine, and in polishing fluid, the massfraction of ethylene glycol is 0.3%-0.8%, and the massfraction of glycerine is 2%-3%; Described Soluble oxalate salt is potassium oxalate and/or sodium oxalate.
5. polishing fluid as claimed in claim 1, it is characterized in that, described pH adjusting agent is HOOCCOOH, H
3pO
4, H
2sO
4, one or several in HCl.
6. polishing fluid as claimed in claim 1, is characterized in that, described silicofluoride is one or several in magnesium silicofluoride, zine fluosilicate, ammonium silicofluoride.
7. polishing fluid as claimed in claim 1, it is characterized in that, described coupling agent is γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
8. the preparation method of the polishing fluid as described in any one of claim 1-7, is characterized in that, comprises the following steps:
A) pH adjusting agent is added to the water the formation aqueous solution;
B) Soluble oxalate salt, lubricant are added in step aqueous solution a), stir;
C) silicofluoride, nano titanium oxide, nano silicon, coupling agent are added step b) in the liquid of gained, stir;
D) palm wax emulsion and/or paraffin wax emulsions are added step c) liquid in stir;
Wherein, described step a), b), c) and d) is carried out at normal temperatures.
9. the preparation method of polishing fluid as claimed in claim 8, is characterized in that, described step a) in the pH of the aqueous solution be 0.5-2.
10. the application of the polishing fluid as described in any one of claim 1-7 in marble or rostone, its embody rule method is: be poured on by polishing fluid on marble or wood-based plate, with polishing pad, polishing fluid cast aside.
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| CN106905857A (en) * | 2017-02-24 | 2017-06-30 | 青岛海之星生物科技有限公司 | A kind of high-durability floor wax and preparation method thereof |
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| CN115466530B (en) * | 2022-09-30 | 2023-10-27 | 武汉工程大学 | Modified silicon dioxide crystal face agent and preparation method and application thereof |
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