CN104492340A - Emulsified composition - Google Patents

Emulsified composition Download PDF

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Publication number
CN104492340A
CN104492340A CN201410709288.XA CN201410709288A CN104492340A CN 104492340 A CN104492340 A CN 104492340A CN 201410709288 A CN201410709288 A CN 201410709288A CN 104492340 A CN104492340 A CN 104492340A
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China
Prior art keywords
glycolipid
fatty acid
ester
polyalcohol
acid ester
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CN201410709288.XA
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CN104492340B (en
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张志伟
张玲
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SHANGHAI JINRUI INDUSTRIAL Co Ltd
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SHANGHAI JINRUI INDUSTRIAL Co Ltd
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  • Colloid Chemistry (AREA)

Abstract

The invention relates to an emulsified composition. The emulsified composition is a mixture of glycolipid or glycolipid salt and fatty acid ester, phospholipid and sterol of polyalcohol at the part weight ratio of 1:10 to 10:1. The emulsified composition provided by the invention can be dissolved in an oil phase. When the emulsified composition contains an aqueous solution, oil can be added and stirred into the mixed solution to prepare a good water-in-oil emulsifier. The prepared emulsifier can be applied to a variety of industries of medicine, food, cosmetic, paint and petroleum.

Description

A kind of emulsion composition
Technical field
The present invention relates to a kind of emulsion composition.
Background technology
In the past few decades, Surfactant Industry achieves and develops fast, and the surfactant of multiple function admirable is developed, and is applied to the industry-by-industries such as cosmetics, medicine, food, agricultural chemicals, oil, coating.But in recent years, the security of surfactant and problem of environmental pollution are subject to increasing attention.Especially cationic surfactant, anion surfactant, amphoteric surfactant, non-ionic surface active agent etc. containing polyvinyl chloride are as emulsifying agent, and its security performance is troubling.So the nontoxicity using biological method to obtain, the Surface Active Substance be easily biodegradable start to cause people more to pay close attention to.But, adopt the Surface Active Substance of single variety to be difficult to the emulsifying agent obtaining excellent effect and stable performance.
Summary of the invention
The object of this invention is to provide a kind of novel emulsion composition as emulsifying agent, solve the problem of security and the environmental pollution brought in use procedure, improve the problem of emulsifying agent that single Surface Active Substance is difficult to be formed excellent effect, stable performance, meet the target of development environmental type product.
Technical scheme of the present invention is as follows:
A kind of emulsification composition, includes glycolipid or glycolipid salt, the fatty acid ester of polyalcohol, phosphatide, sterol mixing, and the ratio of quality and the number of copies of the fatty acid ester of glycolipid or glycolipid salt and polyalcohol, phosphatide, sterol is 1:10 ~ 10:1.
Described glycolipid comprises the aliphatic acid of α-side chain, the aliphatic acid of beta-hydroxy, aliphatic acid, different aliphatic acid, hydroxy fatty acid, glutamic acid and its mixture, and the carbon number on described glycolipid fat chain is 1 ~ 18.
Described glycolipid is sucrose monofatty acid ester, mannose monoesters, marine alga sugar ester, sophorolipid, rhamnolipid, gossypose monoesters and its mixture, and described glycolipid acquisition methods comprises extracting method and biological method from animal, plant.
The fatty acid ester of described polyalcohol comprises fatty acid glycerine fat, fatty acid propylene glycol ester, fatty acid loss water sorbit ester, aliphatic acid glucose ester, the aliphatic acid ester of xylitol, fatty acid cane sugar ester, cithrol, polyglyceryl fatty acid ester and its mixture, the fatty acid ester of described polyalcohol, its acquisition methods comprises artificial synthesis and biological method.
Described phosphatide comprises phosphatide and derivative thereof.
Described sterol comprises phytosterol, cholesterol.
The fatty acid ester of described polyalcohol, phosphatide and sterol, can separately or two kinds and more than, with described glycolipid or glycolipid salt used in combination.
Ultra-violet absorber, anticorrisive agent, antioxidant, dyestuff, pigment, essence, monohydric alcohol, polyalcohol, fatty alcohol, aliphatic acid, native paraffin, hydrogenated animal oil, hydrogenated vegetable oil is also comprised, water-soluble high-molecular substance, aluminium-magnesium silicate, cellulose in described constituent.
Described glycolipid salt needs in glycolipid, add NaOH, KOH, Ca (OH) 2, CsOH, or lysine, glutamic acid, MEA, di-methylcarbinol amine, triethanolamine, or inorganic acid, organic acid, and its mixture, wherein, the process added is before being emulsification or after emulsification.
When having the aqueous solution to exist in described emulsion composition, oil content can be joined in this mixed solution, under uniform stirring, obtain good oil-water emulsifiers.
The emulsifying agent adopting technique scheme to obtain can apply to many industries such as cosmetics, medicine, food, agricultural chemicals, oil, coating.
Compared with the prior art, beneficial effect of the present invention is as follows:
1. adopt Surface Active Substance as emulsifying agent, the safety problem that emulsifying agent in use causes can be solved, and Surface Active Substance is easily biodegradable, so the problem of environmental pollution brought thus can be avoided.
2. in the present invention, by regulating the proportioning in emulsification composition between component, mixing appropriate additive and can improve the problem that emulsifying agent result of use is not good, character is unstable.
3. in the present invention, glycolipid or its salt added aqueous phase by the combination of this kind of emulsifying agent than single to obtain emulsifying product size droplet diameter little, be evenly distributed, outward appearance is fine and smooth.
Accompanying drawing explanation
Fig. 1 is the size droplet diameter surveyed under microscope software with ordinary optical microscope in embodiment 1 moisturizing honey;
Fig. 2 is for fill a prescription identical with embodiment 1, but do not adopt the present invention to combine emulsifying manner, namely sucrose monolaurate adds aqueous phase, and single hard fatty acids glyceride and soybean lecithin add the size droplet diameter that oil phase emulsification gained face cream ordinary optical microscope is surveyed under microscope software.
Fig. 3 is the size droplet diameter that in embodiment 2, face cream ordinary optical microscope is surveyed under microscope software;
Fig. 4 is for fill a prescription identical with embodiment 2, but do not adopt the present invention to combine emulsifying manner, namely rhamnolipid adds aqueous phase, and fatty acid loss water sorbit ester and soybean lecithin add the size droplet diameter that oil phase emulsification gained face cream ordinary optical microscope is surveyed under microscope software.
Detailed description of the invention
See accompanying drawing, below in conjunction with embodiment, the present invention is further described, but the present invention is not limited in the content of these embodiments.Unless stated otherwise, the portion rate in embodiment is ratio of quality and the number of copies.
Embodiment 1: a kind of moisturizing honey, it comprises glycolipid or glycolipid salt, fatty acid ester, phosphatide or derivatives thereof, sterol at least containing a kind of polyalcohol, grease and other additives.
Embodiment 2: a kind of face cream, it comprises glycolipid or glycolipid salt, fatty acid ester, phosphatide or derivatives thereof, sterol at least containing a kind of polyalcohol, grease and other additives.
According to above-mentioned formula, required emulsification composition can be prepared in conventional manner.Preparation process is as follows: by one or both in the fatty acid ester of glycolipid or its salt and polyalcohol, phosphatide and sterol and more than, be dissolved in oil phase in formula after mixing, reach and clarify completely; Again aqueous phase is added oil phase or oil phase adds emulsification in aqueous phase.

Claims (8)

1. an emulsification composition, is characterized in that: include glycolipid or glycolipid salt, the fatty acid ester of polyalcohol, phosphatide, sterol mixing, and the ratio of quality and the number of copies of the fatty acid ester of glycolipid or glycolipid salt and polyalcohol, phosphatide, sterol is 1:10 ~ 10:1.
2. a kind of emulsification composition as claimed in claim 1, it is characterized in that: described glycolipid comprises the aliphatic acid of α-side chain, the aliphatic acid of beta-hydroxy, aliphatic acid, different aliphatic acid, hydroxy fatty acid, glutamic acid and its mixture, and the carbon number on described glycolipid fat chain is 1 ~ 18.
3. a kind of emulsification composition as claimed in claim 1, it is characterized in that: described glycolipid is sucrose monofatty acid ester, mannose monoesters, marine alga sugar ester, sophorolipid, rhamnolipid, gossypose monoesters and its mixture, and described glycolipid acquisition methods comprises extracting method and biological method from animal, plant.
4. a kind of emulsification composition as claimed in claim 1, it is characterized in that: the fatty acid ester of described polyalcohol comprises fatty acid glycerine fat, fatty acid propylene glycol ester, fatty acid loss water sorbit ester, aliphatic acid glucose ester, the aliphatic acid ester of xylitol, fatty acid cane sugar ester, cithrol, polyglyceryl fatty acid ester and its mixture, the fatty acid ester of described polyalcohol, its acquisition methods comprises artificial synthesis and biological method.
5. a kind of emulsification composition as claimed in claim 1, is characterized in that: described phosphatide comprises phosphatide and derivative thereof.
6. a kind of emulsification composition as claimed in claim 1, is characterized in that: described sterol comprises phytosterol, cholesterol.
7. a kind of emulsion composition as claimed in claim 1, is characterized in that: the fatty acid ester of described polyalcohol, phosphatide and sterol, can separately or two kinds and more than, with described glycolipid or glycolipid salt used in combination.
8. a kind of emulsion composition as claimed in claim 1, it is characterized in that: also comprise ultra-violet absorber, anticorrisive agent, antioxidant, dyestuff, pigment, essence, monohydric alcohol, polyalcohol, fatty alcohol, aliphatic acid, native paraffin, hydrogenated animal oil, hydrogenated vegetable oil in described constituent, water-soluble high-molecular substance, aluminium-magnesium silicate, cellulose.
CN201410709288.XA 2014-11-28 2014-11-28 Emulsified composition Active CN104492340B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105090747A (en) * 2015-08-14 2015-11-25 中国石油化工股份有限公司 Rhamnolipid containing matched type aquo-complex polymerization inhibitor
CN105179939A (en) * 2015-08-14 2015-12-23 中国石油化工股份有限公司 Application of compound hydrate anti-polymeric agent containing rhamnolipid
CN107406594A (en) * 2015-12-17 2017-11-28 株式会社Lg化学 Thermoplastic polymer, its preparation method and the thermoplastic polymer composition comprising the thermoplastic polymer
CN107625667A (en) * 2017-09-13 2018-01-26 西安瑞捷生物科技有限公司 A kind of basic aqua containing rhamnolipid and preparation method thereof and application
CN107737340A (en) * 2017-11-30 2018-02-27 合肥工业大学 A kind of application of pharmaceutic adjuvant sophorolipid in field of medicaments
CN107912491A (en) * 2017-12-13 2018-04-17 上海早苗食品有限公司 A kind of emulsifying agent and its deep process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5753241A (en) * 1995-02-27 1998-05-19 L'oreal Transparent nanoemulsion less than 100 NM based on fluid non-ionic amphiphilic lipids and use in cosmetic or in dermopharmaceuticals
CA2278766A1 (en) * 1997-02-07 1998-08-13 Henkel Kommanditgesellschaft Auf Aktien Skin care product
CN102488638A (en) * 2011-12-16 2012-06-13 江南大学 Cosmetic with no or less emulsifier and preservative

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5753241A (en) * 1995-02-27 1998-05-19 L'oreal Transparent nanoemulsion less than 100 NM based on fluid non-ionic amphiphilic lipids and use in cosmetic or in dermopharmaceuticals
CA2278766A1 (en) * 1997-02-07 1998-08-13 Henkel Kommanditgesellschaft Auf Aktien Skin care product
CN102488638A (en) * 2011-12-16 2012-06-13 江南大学 Cosmetic with no or less emulsifier and preservative

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105090747A (en) * 2015-08-14 2015-11-25 中国石油化工股份有限公司 Rhamnolipid containing matched type aquo-complex polymerization inhibitor
CN105179939A (en) * 2015-08-14 2015-12-23 中国石油化工股份有限公司 Application of compound hydrate anti-polymeric agent containing rhamnolipid
CN105179939B (en) * 2015-08-14 2017-11-21 中国石油化工股份有限公司青岛安全工程研究院 A kind of application of the hydrate anticoagulant of Compositional type containing rhamnolipid
CN107406594A (en) * 2015-12-17 2017-11-28 株式会社Lg化学 Thermoplastic polymer, its preparation method and the thermoplastic polymer composition comprising the thermoplastic polymer
US10508168B2 (en) 2015-12-17 2019-12-17 Lg Chem, Ltd. Thermoplastic polymer, method of preparing thermoplastic polymer, and thermoplastic polymer composition including thermoplastic polymer
CN107406594B (en) * 2015-12-17 2020-01-14 株式会社Lg化学 Thermoplastic polymer, method for preparing the same, and thermoplastic polymer composition comprising the same
CN107625667A (en) * 2017-09-13 2018-01-26 西安瑞捷生物科技有限公司 A kind of basic aqua containing rhamnolipid and preparation method thereof and application
CN107737340A (en) * 2017-11-30 2018-02-27 合肥工业大学 A kind of application of pharmaceutic adjuvant sophorolipid in field of medicaments
CN107912491A (en) * 2017-12-13 2018-04-17 上海早苗食品有限公司 A kind of emulsifying agent and its deep process
CN107912491B (en) * 2017-12-13 2021-04-27 上海早苗食品有限公司 Emulsifier and deep processing technology thereof

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