CN104458994A - 丙烯酸树脂的分析方法 - Google Patents
丙烯酸树脂的分析方法 Download PDFInfo
- Publication number
- CN104458994A CN104458994A CN201410773573.8A CN201410773573A CN104458994A CN 104458994 A CN104458994 A CN 104458994A CN 201410773573 A CN201410773573 A CN 201410773573A CN 104458994 A CN104458994 A CN 104458994A
- Authority
- CN
- China
- Prior art keywords
- acryl resin
- cracking
- monomer
- temperature
- fragment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 14
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 14
- 238000004458 analytical method Methods 0.000 title abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 64
- 238000005336 cracking Methods 0.000 claims description 73
- 239000011347 resin Substances 0.000 claims description 63
- 229920005989 resin Polymers 0.000 claims description 63
- -1 acryl Chemical group 0.000 claims description 60
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 45
- 239000012634 fragment Substances 0.000 claims description 30
- 238000003776 cleavage reaction Methods 0.000 claims description 24
- 230000007017 scission Effects 0.000 claims description 24
- 238000000631 analytical pyrolysis Methods 0.000 claims description 22
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 8
- 125000003158 alcohol group Chemical group 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 4
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 4
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 4
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000005311 nuclear magnetism Effects 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 21
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 18
- 150000002500 ions Chemical class 0.000 description 17
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 12
- 230000010354 integration Effects 0.000 description 10
- 238000005143 pyrolysis gas chromatography mass spectroscopy Methods 0.000 description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000004793 Polystyrene Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410773573.8A CN104458994B (zh) | 2014-12-16 | 2014-12-16 | 丙烯酸树脂的分析方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410773573.8A CN104458994B (zh) | 2014-12-16 | 2014-12-16 | 丙烯酸树脂的分析方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104458994A true CN104458994A (zh) | 2015-03-25 |
CN104458994B CN104458994B (zh) | 2016-01-27 |
Family
ID=52905385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410773573.8A Active CN104458994B (zh) | 2014-12-16 | 2014-12-16 | 丙烯酸树脂的分析方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104458994B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109270175A (zh) * | 2018-08-17 | 2019-01-25 | 安徽佳通乘用子午线轮胎有限公司 | 一种硫化橡胶中树脂的分析鉴定方法 |
CN111044657A (zh) * | 2019-12-16 | 2020-04-21 | 上海微谱化工技术服务有限公司 | 溶剂型丙烯酸树脂中功能单体的检测方法 |
US11579126B2 (en) | 2017-09-13 | 2023-02-14 | Lg Chem, Ltd. | Quantitative analysis method for monomer of photoresist binder |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226902A (zh) * | 1996-07-29 | 1999-08-25 | 伊希有限公司 | 将聚合物裂解为其单体的方法 |
CN1594268A (zh) * | 2004-06-17 | 2005-03-16 | 温州师范学院 | Pet的微波解聚方法 |
-
2014
- 2014-12-16 CN CN201410773573.8A patent/CN104458994B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226902A (zh) * | 1996-07-29 | 1999-08-25 | 伊希有限公司 | 将聚合物裂解为其单体的方法 |
CN1594268A (zh) * | 2004-06-17 | 2005-03-16 | 温州师范学院 | Pet的微波解聚方法 |
Non-Patent Citations (9)
Title |
---|
LAURA OSETE-CORTINA 等: "Characterization of acrylic resins used for restoration of artworks by pyrolysis-silylation-gas chromatography/mass spectrometry with hexamethyldisilazane", 《JOURNAL OF CHROMATOGRAPHY A》 * |
RAQUEL RIAL-OTERO 等: "A Review of Synthetic Polymer Characterization by Pyrolysis–GC–MS", 《CHROMATOGRAPHIA》 * |
SHUNCONG MAO 等: "Compositional analysis of multicomponent acrylic resins by pyrolysis-capillary gas chromatography", 《JOURNAL OF ANALYTICAL AND APPLIED PYROYLSIS》 * |
刘娟吉 等: "裂解气相色谱一质谱分析丙烯酸树脂", 《分析测试学报》 * |
徐正炎 等: "甲基丙烯酸甲酯-甲基丙烯酸正丁酯均聚共混物和无规共聚物的裂解色谱定量分析", 《色谱》 * |
王晓叶 等: "酚醛树脂热解性能研究", 《武汉理工大学学报》 * |
颜文礼 等: "S、MMA、AN中二元共聚物与一均聚物共混的裂解色谱分析", 《色谱》 * |
颜文礼 等: "S-MMA-AN三元共聚物和三均聚物共混的裂解色谱分析", 《色谱》 * |
高毅飞 等: "丙烯酸乳液聚合物裂解色谱/质谱研究", 《涂料工业》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11579126B2 (en) | 2017-09-13 | 2023-02-14 | Lg Chem, Ltd. | Quantitative analysis method for monomer of photoresist binder |
CN109270175A (zh) * | 2018-08-17 | 2019-01-25 | 安徽佳通乘用子午线轮胎有限公司 | 一种硫化橡胶中树脂的分析鉴定方法 |
CN111044657A (zh) * | 2019-12-16 | 2020-04-21 | 上海微谱化工技术服务有限公司 | 溶剂型丙烯酸树脂中功能单体的检测方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104458994B (zh) | 2016-01-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104458994B (zh) | 丙烯酸树脂的分析方法 | |
Atkuri et al. | Mass cytometry: a highly multiplexed single-cell technology for advancing drug development | |
WO2018058073A3 (en) | Measurement of protein expression using reagents with barcoded oligonucleotide sequences | |
JP5002530B2 (ja) | 液体クロマトグラフの測定メソッド変換方法および液体クロマトグラフ装置 | |
Kaal et al. | Extending the molecular application range of gas chromatography | |
MX361481B (es) | Composiciones y metodos para procesamiento de muestras. | |
JP7140215B2 (ja) | メタクリル系樹脂、メタクリル系樹脂の製造方法、成形体及び自動車 | |
González-Martín et al. | A tool to assess analytical sample preparation procedures: Sample preparation metric of sustainability | |
Baggiani et al. | Molecularly imprinted polymers for corticosteroids: Analysis of binding selectivity | |
Czech et al. | Thermal stability of poly (2-ethylhexyl acrylates) used as plasticizers for medical application | |
JP2011122822A5 (zh) | ||
EP4328327A3 (en) | Reporter dye for isothermal nucleic acid amplification, isothermal-based dual functional oligonucleotide containing quencher, and method for nucleic acid amplification and measurement using same | |
Parıldar et al. | Characterization of tertiary amine and epoxy functional all-acrylic coating system | |
JP2018508793A5 (zh) | ||
Chamseddin et al. | Multifactorial design principles applied for the simultaneous separation of local anesthetics using chromatography modeling software | |
Brooijmans et al. | Acid monomer analysis in waterborne polymer systems by targeted labeling of carboxylic acid functionality, followed by pyrolysis–gas chromatography | |
Cappitelli | THM-GCMS and FTIR for the study of binding media in Yellow Islands by Jackson Pollock and Break Point by Fiona Banner | |
CN104950049B (zh) | 一种共聚酰胺热熔胶相对分子质量及分布的分析方法 | |
CN105582691A (zh) | 一种萃取剂及其应用和测定聚合物交联度的方法 | |
He et al. | Dual-role transcription factors stabilize intermediate expression levels | |
Germier et al. | Real-time chromatin dynamics at the single gene level during transcription activation | |
Pandohee et al. | Evaluation of new micro solid-phase extraction cartridges for on-column derivatisation reactions | |
CN105536294B (zh) | 一种有机基质毛细管整体柱及其制备方法 | |
López-Beceiro et al. | Thermal degradation kinetics of two acrylic-based copolymers | |
Yoo et al. | A candidate reference method for quantification of low concentrations of plasmid DNA by exhaustive counting of single DNA molecules in a flow stream |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 200438 room 110, No.2, Lane 139, Guowei Road, Yangpu District, Shanghai Patentee after: Shanghai microspectrum Testing Technology Group Co.,Ltd. Country or region after: China Address before: 200438 4, 10 building, 135 Guowei Road, Yangpu District, Shanghai. Patentee before: SHANGHAI MICROSPECTRUM CHEMICAL TECHNOLOGY SERVICE Co.,Ltd. Country or region before: China |
|
CP03 | Change of name, title or address | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240515 Address after: 448000 155-4-5 Refinery Road, Duodao District, Jingmen City, Hubei Province Patentee after: Li Ke Country or region after: China Address before: 200438 room 110, No.2, Lane 139, Guowei Road, Yangpu District, Shanghai Patentee before: Shanghai microspectrum Testing Technology Group Co.,Ltd. Country or region before: China |
|
TR01 | Transfer of patent right |