CN104452334B - A kind of natural dye Printing and preparation method thereof - Google Patents
A kind of natural dye Printing and preparation method thereof Download PDFInfo
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- CN104452334B CN104452334B CN201410608308.4A CN201410608308A CN104452334B CN 104452334 B CN104452334 B CN 104452334B CN 201410608308 A CN201410608308 A CN 201410608308A CN 104452334 B CN104452334 B CN 104452334B
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Abstract
The present invention provides a kind of natural dye Printing and preparation method thereof。This preparation method comprises the following steps: fabric is carried out pre-treatment, obtains the fabric through pre-treatment；Use the modified working solution of cation stamp to carry out cation stamp in presumptive area in the described fabric through pre-treatment to modifiy, 100-180 DEG C of decatize or bake 10s-15min, obtain through the modified fabric of cation stamp；Undertaken washing and pickling by the described fabric modified through cation stamp, immerse in natural dye aqueous solution, after room temperature bakes 10s-15min to 100 DEG C of water-bath 10min-48h, 100-120 DEG C decatize 30s-15min or 100-180 DEG C, carry out washing, excessively soft, sizing, obtain described natural dye Printing。Present invention also offers the natural dye Printing that above-mentioned preparation method obtains。The preparation method of the natural dye Printing of the present invention can solve the problem that the heavy metals exceeding standard existed when adopting conventional natural dye stamp, and feel is partially hard, the problems such as color fastness is not good, and stamp part colours is not deep。
Description
Technical field
The invention provides a kind of natural dye Printing and preparation method thereof, belong to technical field of textile printing。
Background technology
Natural dye refers to and obtains from plant, animal or mineral resources, without synthetic, seldom or not past the dyestuff of chemical process。Because it can regenerate, meeting the requirement of sustainable development and environmental protection, the Printing pattern attractability obtained through stamp by natural dye in addition is strong, changes numerous and diverse, belongs to a more high-end series products, extensively liked by people。But, natural dye Printing color fastness is poor, and stamp part colours is shallow, prints the reasons such as complexity and limits its development。
Conventional natural dye Printing, carries out stamp mainly by the method adding heavy metal mordant or interpolation resin。Carry out stamp above by the method adding heavy metal mordant or interpolation resin and there will be the problems such as heavy metals exceeding standard, feel are partially hard, color fastness is not good, color is not deep。
Summary of the invention
For solving above-mentioned technical problem, it is an object of the invention to provide a kind of natural dye Printing。This natural dye Printing has the features such as color fastness is good, stamp part colours is deeper。
The present invention also aims to the preparation method that above-mentioned natural dye Printing is provided。
For reaching above-mentioned purpose, the preparation method that the present invention provides a kind of natural dye Printing, wherein, the method comprises the following steps:
A, fabric is carried out pre-treatment, obtain the fabric through pre-treatment；
B, use the modified working solution of cation stamp to carry out cation stamp in presumptive area in the described fabric through pre-treatment to modifiy, 100-180 DEG C of decatize or bake 10s-15min, obtain through the modified fabric of cation stamp；
C, undertaken washing and pickling by the described fabric modified through cation stamp, immerse in natural dye aqueous solution, after room temperature bakes 10s-15min to 100 DEG C of water-bath 10min-48h, 100-120 DEG C decatize 30s-15min or 100-180 DEG C, carry out washing, excessively soft, sizing, obtain described natural dye Printing。
Above-mentioned by modified for cation stamp working solution, the mode printed to through pre-treatment fabric presumptive area can carry out according to the conventional printing method of field of textiles employing, for instance ROTARY SCREAM PRINTING, PLATE SCREAM PRINTING；
" presumptive area " in the present invention refers to the position needing to carry out stamp on fabric；
Pre-treatment in order that the impurity removed on fabric, control to arrange fabric width and fabric weight, so as stamp, it can carry out according to the conventional pre-treating method that field of textiles adopts, such as, for pure-cotton woven fabric, its pretreatment process can include the pre-treatment steps such as desizing, kiering, bleaching, washing, dehydration, drying；For pure linen, real silk fabric, its pretreatment process can include the pre-treatment steps such as degumming, kiering, bleaching, washing, dehydration, drying；
Dehydration can carry out according to the conventional dehydration methods that field of textiles adopts, for instance for woven, dehydration is generally adopted the mode of squezzing and carries out；Pickling can carry out according to the conventional acid washing method that field of textiles adopts, for instance the aqueous acetic acid that concentration can be adopted to be 0.5g/L carries out pickling；The purpose of washing is to remove loose colour, can carry out according to the conventional water wash method that field of textiles adopts, and method for washing has a variety of combination, for instance can wash one time at about 70 DEG C, washes one time for about 50 DEG C, and room temperature is washed one time；Crossing and soft can cross soft method carry out according to the routine that field of textiles adopts, crossing soft dose can be usually used in soft dose of soft mistake in field of textiles, for instance organosilicon consistent lubricant；Sizing can carry out according to the conventional method for shaping that field of textiles adopts。
The room temperature of indication of the present invention meets the field of textiles usual definition to ambient temperature。
In the methods described above, it is preferable that the fabric of employing be cotton-containing fabrics, containing viscose fabric, containing wool fabric, containing silk fabrics or containing linen；It is highly preferred that the fabric adopted is pure cotton fabric, pure viscose fabric, pure woolen fabric, pure silk fabric or pure linen。
In the methods described above, it is preferable that the fabric of employing is knitted fabric, woven or non-woven fabrics。
In the methods described above, it is preferable that the form of the fabric of employing includes cloth, cut-parts or ready-made clothes。
In the methods described above, it is preferable that with the gross weight gauge of the modified working solution of cation stamp, the modified working solution of the cation stamp of employing includes 0.1-20wt% cation modifier, 0.1-20wt% alkaline agent, 1-20wt% thickening agent, and surplus is water。
In the methods described above, preferably, the cation modifier adopted includes quaternary ammonium compound, it is more preferably 2, the combination of one or more in the chloro-2-hydroxypropyl triethyl ammonium chloride of 3-epoxypropyltrimethylchloride chloride, 2,3-Epoxypropyl triethyl ammonium chlorides, 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, 3-, double reaction active base cation modifier, double reaction active base dication base cation modifier。Above-mentioned double reaction active base cation modifier is that (denomination of invention is a kind of double reaction active base cation modifier and preparation method thereof and application to patent CN104086512A, application number is 201410270387.2, the applying date is on 06 17th, 2014) disclosed in cation modifier, double reaction active base dication base cation modifier is that (denomination of invention is double reaction active base dication base cation modifier and preparation method thereof and application to patent CN104086511A, application number is 201410270386.8, the applying date is on 06 17th, 2014) disclosed in cation modifier, it is introduced in full herein by reference as。
In the modified working solution of cation stamp, alkaline agent can adopt field of textiles to be usually used in the alkaline agent of stamp, for instance sodium hydroxide, sodium silicate, sodium carbonate etc., it is preferred to sodium hydroxide；Thickening agent can adopt field of textiles to be usually used in the thickening agent of stamp, for instance sodium alginate and/or synthetic slurry；Preferably, described synthetic slurry includes the combination of one or more in esters of acrylic acid synthetic slurry, cellulose derivative class synthetic slurry, polyurethanes synthetic slurry, starch based synthetic slurry and starch derivatives class synthetic slurry；Above-mentioned thickening agent is preferably sodium alginate。
In the methods described above, preferably, the natural dye adopted is anionic water-soluble natural dyestuff, above-mentioned anionic water-soluble natural dyestuff can adopt field of textiles to be usually used in the water-soluble natural dyestuff with anionic charge of dyeing, it is highly preferred that above-mentioned anionic water-soluble natural dyestuff includes chlorophyll natural dye, alkermes natural dye, natural dye sorghum red, green tea natural dye, Pericarpium Granati natural dye, annatto natural dye or Gardenia Yellow natural dye etc.。
In the methods described above, it is preferable that the mode of the dyeing of employing includes exhaust dyeing, pad dyeing dyeing, foam dyeing or spray dyeing。
Present invention also offers the natural dye Printing that the preparation method of above-mentioned natural dye Printing obtains。
In the preparation method of the natural dye Printing of the present invention, presumptive area at the fabric after pre-treatment uses the modified working solution of cation stamp to carry out cation stamp and modifiies, then anion natural dye aqueous solution is used to dye in above-mentioned presumptive area, this anion natural dye can with the cationoid reaction in the modified working solution of the cation stamp in above-mentioned presumptive area so that it is can be combined with fabric better。Therefore, the natural dye Printing color fastness obtained is good for the preparation method of the present invention, and stamp part colours is relatively deep, and other non-printing area not easily staining, and material loss is less, and fabric is more soft。
The preparation method of the natural dye Printing of the present invention is without heavy metal mordant or resin, and therefore, this preparation method can successfully solve the heavy metals exceeding standard that tradition natural dye stamp process exists, the problems such as feel is partially hard。
Detailed description of the invention
In order to the technical characteristic of the present invention, purpose and beneficial effect are more clearly understood from, existing technical scheme is carried out described further below, but it is not intended that to the present invention can the restriction of practical range。
The pure-cotton woven fabric of embodiment 1 chlorophyll natural dye print NIKE letter
The preparation method present embodiments providing the pure-cotton woven fabric of a kind of chlorophyll natural dye print NIKE letter, the method comprises the following steps:
By the pure-cotton woven fabric after desizing, kiering, bleaching, through washing, dehydration, drying clot, obtain the pure-cotton woven fabric through pre-treatment。
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 7.5wt%2,3-epoxypropyltrimethylchloride chloride, 1wt%NaOH, 7wt% sodium alginate, and surplus is water。Above-mentioned pure-cotton woven fabric is needed the position of stamp, stamps cation-modified working solution by the mode of ROTARY SCREAM PRINTING, bake 150s at 130 DEG C subsequently, obtain the pure-cotton woven fabric modifiied through cation stamp；
By the above-mentioned pure-cotton woven fabric modified through cation stamp after 40 DEG C of 3 road is washed, cross 0.5g/L aqueous acetic acid pickling, with post-drying clot, again through the groove containing 50g/L chlorophyll natural dye aqueous solution prepared in advance, then by above-mentioned pure-cotton woven fabric 105 DEG C of decatizes 5 minutes, then wash 2 roads, 80 DEG C of washing 1 roads, 40 DEG C of washing 1 roads, last often regulation type through 40 DEG C, obtain the pure-cotton woven fabric of chlorophyll natural dye print NIKE letter。
The pure-cotton woven fabric heavy metal of the chlorophyll natural dye print NIKE letter that the present embodiment obtains does not exceed standard, and soft, color fastness is good, stamp part colours is deeper。
The stamp pure cotton knitting shirt of embodiment 2 alkermes natural dye print Esquel
The preparation method present embodiments providing the stamp pure cotton knitting shirt of a kind of alkermes natural dye print Esquel, the method comprises the following steps:
Pure cotton knitted fabric after kiering, bleaching, sizing is made sweater on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 5wt%2,3-Epoxypropyl triethyl ammonium chloride, 1wt%NaOH, 7wt% sodium alginate, and surplus is water。Need the position of stamp at above-mentioned pure cotton knitting shirt, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 150s at 140 DEG C, complete above-mentioned sweater is needed the cation stamp of the position of stamp to modifiy；
The modified sweater of cation stamp will be completed in garment dyeing cylinder after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse in the aqueous solution containing 2g/L alkermes natural dye prepared in advance again, process 60 minutes at 90 DEG C, 1 road, 40 DEG C of washing 2 roads are washed then through 80 DEG C, finally cross soft, dehydration, drying, obtain the stamp pure cotton knitting shirt of alkermes natural dye print Esquel。
The alkermes natural dye print Esquel stamp pure cotton knitting shirt that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
The pure-cotton woven fabric of embodiment 3 natural dye sorghum red print A&F letter
The preparation method present embodiments providing the pure-cotton woven fabric of a kind of natural dye sorghum red print A&F letter, the method comprises the following steps:
By the pure-cotton woven fabric after desizing, kiering, bleaching, through washing, dehydration, drying clot, obtain through pre-treatment the pure-cotton woven fabric after drying clot；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes chloro-2 hydroxypropyl-trimethyl ammonium chlorides of 7.5wt%3-, 1.5wt%NaOH, 8wt% sodium alginate, and surplus is water。Above-mentioned pure-cotton woven fabric is needed the position of stamp, stamps cation-modified working solution by the mode of ROTARY SCREAM PRINTING, 102 DEG C of decatizes 3 minutes, obtain through the modified pure-cotton woven fabric of cation stamp；
By the above-mentioned pure-cotton woven fabric modified through cation stamp in color jar after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse again prepare in advance containing in 3g/L natural dye sorghum red aqueous solution, process 60 minutes at 90 DEG C, then 1 road, 40 DEG C of washing 2 roads are washed through 80 DEG C, last conventional sizing, obtains the pure-cotton woven fabric of natural dye sorghum red print A&F letter。
The pure-cotton woven fabric of the natural dye sorghum red print A&F letter that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
Embodiment 4 green tea natural dye print Esquel stamp cotton textiles handkerchief
The preparation method present embodiments providing a kind of green tea natural dye print Esquel stamp cotton textiles handkerchief, the method comprises the following steps:
Woven after desizing, kiering, bleaching is made handkerchief on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 8wt%2,3-epoxypropyltrimethylchloride chloride, 1.5wt%NaOH, 8wt% sodium alginate, and surplus is water。Need the position of stamp at above-mentioned textile handkerchief, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 150s at 130 DEG C, complete to need the cation stamp of stamp position to modifiy on above-mentioned textile handkerchief；
The modified textile handkerchief of cation stamp will be completed in garment dyeing cylinder after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse again prepare in advance containing in 2g/L green tea natural dye aqueous solution, process 45 minutes at 95 DEG C, then 1 road, 40 DEG C of washing 2 roads are washed through 70 DEG C, add 2g/L organosilicon consistent lubricant, last dewatered drying, obtain green tea natural dye print Esquel stamp cotton textiles handkerchief。
The print Esquel green tea natural dye bandanna that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
Embodiment 5 alkermes natural dye print Esquel stamp real silk silk scarf
The preparation method present embodiments providing a kind of alkermes natural dye print Esquel stamp real silk silk scarf, the method comprises the following steps:
Real silk fabric after degumming, kiering, bleaching is made silk scarf on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 8wt%2,3-epoxypropyltrimethylchloride chloride, 1.5wt%NaOH, 12wt% sodium alginate, and surplus is water。Need the position of stamp at above-mentioned real silk silk scarf, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 150s at 130 DEG C, complete above-mentioned real silk silk scarf is needed the cation stamp of stamp position to modifiy；
The modified real silk silk scarf of cation stamp will be completed in garment dyeing cylinder after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse in alkermes natural dye aqueous solution containing 2g/L (pH=8.5) prepared in advance again, process 45 minutes at 90 DEG C, after 70 DEG C are washed 1 road, 40 DEG C of washing 2 roads, add 2g/L organosilicon consistent lubricant, last dewatered drying, obtain alkermes natural dye print Esquel stamp real silk silk scarf。
The alkermes natural dye print Esquel stamp real silk silk scarf that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
Embodiment 6 chlorophyll natural dye print Esquel stamp pure fiber crops handkerchief
The preparation method present embodiments providing a kind of chlorophyll natural dye print Esquel stamp pure fiber crops handkerchief, the method comprises the following steps:
Pure linen after degumming, kiering, bleaching is made handkerchief on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes chloro-2 hydroxypropyl-trimethyl ammonium chlorides of 8wt%3-, 2wt%NaOH, 12wt% sodium alginate, and surplus is water。Need the position of stamp at above-mentioned pure fiber crops handkerchief, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 130s at 130 DEG C, complete to need the cation stamp of stamp position to modifiy on above-mentioned pure fiber crops handkerchief；
The modified pure fiber crops handkerchief of cation stamp is completed in garment dyeing cylinder after 3 40 DEG C of washings by above-mentioned, cross 0.5g/L aqueous acetic acid pickling, immerse again prepare in advance containing in 2g/L chlorophyll natural dye aqueous solution, process 45 minutes at 95 DEG C, then after 70 DEG C are washed 1 road, 40 DEG C of washing 2 roads, add 2g/L organosilicon consistent lubricant, last dewatered drying, obtain chlorophyll natural dye print Esquel stamp pure fiber crops handkerchief。
The chlorophyll natural dye print Esquel stamp pure fiber crops handkerchief heavy metal that the present embodiment obtains does not exceed standard, and soft, color fastness is good, and stamp part colours is deeper。
Embodiment 7 alkermes natural dye print Esquel printed cotton/tencel woven shirt
The preparation method present embodiments providing a kind of alkermes natural dye print Esquel printed cotton/tencel woven shirt, the method comprises the following steps:
Cotton after desizing, kiering, bleaching, sizing/tencel woven thing is made tatting shirt cut-parts on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes the chloro-2 hydroxypropyl triethyl ammonium chlorides of 3wt%3-, 0.5wt%NaOH, 7wt% sodium alginate, and surplus is water。Need the position of stamp in above-mentioned cotton/tencel woven shirt cut-parts, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 150s at 140 DEG C, complete above-mentioned cotton/tencel woven shirt is needed the cation stamp of stamp position to modifiy；
Modified cotton/tencel woven shirt the cut-parts of cation stamp will be completed in garment dyeing cylinder after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse again prepare in advance containing in 1g/L alkermes natural dye aqueous solution, process 60 minutes at 90 DEG C, then 1 road, 40 DEG C of washing 2 roads are washed through 80 DEG C, finally, excessively soft, dehydration, drying, obtain alkermes natural dye print Esquel printed cotton/tencel woven shirt。
Alkermes natural dye print Esquel printed cotton/tencel woven shirt that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
The pure viscose glue looped fabric of embodiment 8 natural dye sorghum red print Esquel letter
The preparation method present embodiments providing the pure viscose glue looped fabric of a kind of natural dye sorghum red print Esquel letter, the method comprises the following steps:
By the pure viscose glue looped fabric after kiering, bleaching, through washing, dehydration, sizing, clot, obtain the pure viscose glue looped fabric through pre-treatment；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes chloro-2 hydroxypropyl-trimethyl ammonium chlorides of 10wt%3-, 1.5wt%NaOH, 12wt% sodium alginate, and surplus is water。Above-mentioned pure viscose glue looped fabric is needed the position of stamp, stamps cation-modified working solution by the mode of ROTARY SCREAM PRINTING, 102 DEG C of decatizes 2 minutes, obtain through the modified pure viscose glue looped fabric of cation stamp；
By the above-mentioned pure viscose glue looped fabric modified through cation stamp in color jar after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, immerse again prepare in advance containing in 3g/L natural dye sorghum red aqueous solution, process 60 minutes at 90 DEG C, then 1 roads are washed through 80 DEG C, 40 DEG C of washing 2 roads are peracid, excessively soft, last often regulation type, obtains the pure viscose glue looped fabric of natural dye sorghum red print Esquel letter。
The pure viscose glue looped fabric of the natural dye sorghum red print A&F letter that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
Embodiment 9 alkermes natural dye print A&F printed cotton/hair handkerchief
The preparation method present embodiments providing a kind of alkermes natural dye print A&F printed cotton/hair handkerchief, the method comprises the following steps:
Cotton/wool fabric after desizing, kiering, bleaching is made handkerchief on request；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 8wt%2,3-epoxypropyltrimethylchloride chloride, 1.5wt%NaOH, 12wt% sodium alginate, and surplus is water。Need the position of stamp at above-mentioned cotton/hair handkerchief, stamp cation-modified working solution by the mode of PLATE SCREAM PRINTING, bake 150s at 120 DEG C, complete above-mentioned cotton/hair handkerchief is needed the cation stamp of stamp position to modifiy；
Modified cotton/hair the handkerchief of cation stamp is completed in garment dyeing cylinder after 3 40 DEG C of washings by above-mentioned, cross 0.5g/L aqueous acetic acid pickling, immerse in alkermes natural dye aqueous solution containing 0.5g/L (pH=7.5) prepared in advance again, process 45 minutes at 95 DEG C, then wash 1 road through 70 DEG C, behind 40 DEG C of washing 2 roads, add 2g/L organosilicon consistent lubricant, last dewatered drying, obtains alkermes natural dye print A&F printed cotton/hair handkerchief。
Alkermes natural dye print A&F printed cotton/hair handkerchief that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
Cotton/viscose glue the woven fabric of embodiment 10 natural dye sorghum red print A&F letter
The preparation method present embodiments providing the cotton/viscose glue woven fabric of a kind of natural dye sorghum red print A&F letter, the method comprises the following steps:
By the cotton after desizing, kiering, bleaching/viscose glue woven, through washing, dehydration, drying clot, obtain the cotton through pre-treatment/viscose glue woven fabric；
Preparing cation-modified working solution, wherein, with the gross weight gauge of the modified working solution of cation stamp, this working solution includes 7.5wt%2,3-Epoxypropyl triethyl ammonium chloride, 1.5wt%NaOH, 8wt% sodium alginate, and surplus is water。Above-mentioned cotton/viscose glue woven fabric is needed the position of stamp, stamps cation-modified working solution by the mode of ROTARY SCREAM PRINTING, 102 DEG C of decatizes 3 minutes, obtain through the modified cotton/viscose glue woven fabric of cation stamp；
By the cotton/viscose glue woven fabric modified through cation stamp obtained above in color jar after 3 40 DEG C of washings, cross 0.5g/L aqueous acetic acid pickling, 20g/L foaming agent is contained again by what prepare in advance, after the aqueous solution of 40g/L natural dye sorghum red is foamed by foaming machine, blowing ratio is 1:10, then pass through foam coating machine and be uniformly applied on above-mentioned cotton/viscose glue woven, 3 minutes are baked at 140 DEG C, then 2 roads are washed through 40 DEG C, 80 DEG C of washing 1 roads and 40 DEG C of washing 1 roads, last conventional sizing, obtain the cotton/viscose glue woven fabric of natural dye sorghum red print A&F letter。
Cotton/viscose glue the woven fabric of the natural dye sorghum red print A&F letter that the present embodiment obtains is without heavy metal, and soft, color fastness is good, and stamp part colours is deeper。
In embodiment 1-10, the test of content of beary metal carries out according to GB/T17593.2-2007, GB/T17593.3-2006, GB/T17593.4-2006, and the evaluation of content of beary metal carries out according to GB/T18885-2009。
Claims (10)
1. a preparation method for natural dye Printing, wherein, the method comprises the following steps:
A, fabric is carried out pre-treatment, obtain the fabric through pre-treatment；
B, use the modified working solution of cation stamp to carry out cation stamp in presumptive area in the described fabric through pre-treatment to modifiy, 100-180 DEG C of decatize or bake 10s-15min, obtain through the modified fabric of cation stamp；
C, undertaken washing and pickling by the described fabric modified through cation stamp, immerse in natural dye aqueous solution, room temperature to 100 DEG C of water-bath 10min-48h or by after washing and the fabric of pickling are by the groove containing natural dye aqueous solution in 100-120 DEG C of decatize 30s-15min or first foaming agent and natural dye aqueous solution are foamed by foaming machine, then pass through foam coating machine and foam is uniformly applied on the fabric of washing and pickling, then at 100-180 DEG C bake 10s-15min after, carry out washing, excessively soft, sizing, obtain described natural dye Printing；
With the gross weight gauge of the modified working solution of cation stamp, the modified working solution of described cation stamp includes 0.1-20wt% cation modifier, 0.1-20wt% alkaline agent, 1-20wt% thickening agent, and surplus is water；
Described cation modifier is 2, the combination of one or more in the chloro-2-hydroxypropyl triethyl ammonium chloride of 3-epoxypropyltrimethylchloride chloride, 2,3-Epoxypropyl triethyl ammonium chloride, 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, 3-, double reaction active base cation modifier, double reaction active base dication base cation modifier；
Described alkaline agent is sodium hydroxide, sodium silicate or sodium carbonate；
Described thickening agent is sodium alginate and/or synthetic slurry。
2. method according to claim 1, wherein, described fabric be cotton-containing fabrics, containing viscose fabric, containing wool fabric, containing silk fabrics or containing linen。
3. method according to claim 1 and 2, wherein, described fabric is pure cotton fabric, pure viscose fabric, pure woolen fabric, pure silk fabric or pure linen。
4. method according to claim 1 and 2, wherein, described fabric is knitted fabric, woven or non-woven fabrics。
5. method according to claim 3, wherein, described fabric is knitted fabric, woven or non-woven fabrics。
6. method according to claim 4, wherein, the form of described fabric is cloth, cut-parts or ready-made clothes。
7. method according to claim 5, wherein, the form of described fabric is cloth, cut-parts or ready-made clothes。
8. method according to claim 1, wherein, described synthetic slurry includes the combination of one or more in esters of acrylic acid synthetic slurry, cellulose derivative class synthetic slurry, polyurethanes synthetic slurry, starch based synthetic slurry and starch derivatives class synthetic slurry。
9. method according to claim 1, wherein, with the entire volume of described natural dye aqueous solution, the concentration of described natural dye is 0.01-100g/L；Described natural dye is anionic water-soluble natural dyestuff, and described anionic water-soluble natural dyestuff is chlorophyll natural dye, alkermes natural dye, natural dye sorghum red, green tea natural dye, Pericarpium Granati natural dye, annatto natural dye or Gardenia Yellow natural dye。
10. the natural dye Printing that the preparation method of the natural dye Printing described in any one of claim 1-9 obtains。
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Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL91282C (en) * | 1955-02-21 | |||
| JP3660891B2 (en) * | 2001-04-06 | 2005-06-15 | 宏樹 宮松 | Manufacturing method of antibacterial tea-dyed fiber products |
| CN101177542B (en) * | 2007-11-16 | 2010-06-09 | 浙江理工大学 | Method for preparing aspidium rhizoma natural dye |
| CN101187175B (en) * | 2007-12-05 | 2010-11-03 | 广东溢达纺织有限公司 | Natural dye dying method based on cotton fiber modification |
| CN101349020A (en) * | 2008-08-28 | 2009-01-21 | 大连工业大学 | Method for dyeing modified cellulose fiber fabric on rhubarb and curcuma longa dyes |
| CN101914305B (en) * | 2010-08-11 | 2013-08-14 | 常州大学 | Extraction of natural gromwell dye and application thereof |
| CN102226315A (en) * | 2011-04-20 | 2011-10-26 | 盐城纺织职业技术学院 | Method for dyeing cellulose fiber fabric by using suaeda salsa natural dye |
| CN103790041A (en) * | 2013-11-11 | 2014-05-14 | 山东岱银纺织集团股份有限公司 | Method for dyeing short-process environment-friendly coating padding jean fabric |
| CN104088169B (en) * | 2014-07-10 | 2016-02-17 | 广东溢达纺织有限公司 | A kind of natural dye dying method of containing cellulose fiber fabric |
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