CN102787514B - Method for producing acid dye flat screen or rotary screen printing of protein fiber fabric and nylon fabric - Google Patents

Method for producing acid dye flat screen or rotary screen printing of protein fiber fabric and nylon fabric Download PDF

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Publication number
CN102787514B
CN102787514B CN201210262511.1A CN201210262511A CN102787514B CN 102787514 B CN102787514 B CN 102787514B CN 201210262511 A CN201210262511 A CN 201210262511A CN 102787514 B CN102787514 B CN 102787514B
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fabric
nylon fabric
nylon
acid
acid dyes
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CN102787514A (en
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蒋志平
秦杰峰
傅卫红
栾金鑫
张志伟
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Zhejiang Yide New Material Co., Ltd
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ZHEJIANG YIDE CHEMICAL CO Ltd
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Abstract

The invention relates to a method for producing the acid dye flat screen or rotary screen printing of a protein fiber fabric and a nylon fabric. The method specifically comprises the following steps of: a, preparing the acid agent solution with the use concentration of 20-30 grams/liters; b, padding the protein fiber fabric and the nylon fabric in the acid agent solution in padding equipment according to the specified padding time, mangle expression and speed, drying, and using the dried fabrics for subsequent acid dye flat screen or rotary screen printing in one day; c, preparing acid dye printing paste which is consistent with the large sample production, and not adding acidic materials into the paste; d, using a flat screen or rotary screen printing machine to print the acid dye printing paste on the protein fiber fabric and the nylon fabric with acid, drying, and using the dried fabrics for the subsequent steaming fixation in one day; e, feeding the printed protein fiber fabric and nylon fabric into a steamer for steaming fixation; and f, carrying out post-printing treatment on the fixed printed protein fiber fabric and nylon fabric. The production method provided in the invention is simple to operate, has good printing quality and less pollution.

Description

For protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method
Technical field
The present invention relates to a kind of for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method.
Background technology
Dyeing mainly adopts a phase method while using ACID DYES to carry out plain net or ROTARY SCREAM PRINTING production to protein fibre fabric, nylon fabric.
The application of ACID DYES to protein fibre fabric, nylon fabric one phase method plain net or ROTARY SCREAM PRINTING, has had the history of many decades.Owing to having added sour agent in print paste, the storage stability of this print paste is poor, can not store the long period; Again because the ACID DYES after ACID DYES plain net or ROTARY SCREAM PRINTING, vapour steaming colour fixing is to protein fibre fabric, especially the degree of fixation of nylon fabric is not high, generally only has 60-70%, remaining 30-40% ACID DYES enters in a large number in rinsing solution when washing, in water-washing process, loose colour is more, causes discharge of wastewater to exceed standard; These ACID DYES of not fallen by fixation even also can be stain the white ground of stamp protein fibre fabric, nylon fabric simultaneously, cause stamp protein fibre fabric, nylon fabric product to have quality problems.
As for ACID DYES, to protein fibre fabric, nylon fabric two-phase method plain net or ROTARY SCREAM PRINTING, the document of this respect or patent report are less generally speaking.
Summary of the invention
Provided by the present invention a kind of for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, simple to operate, printing quality is good, of reduced contamination.
The present invention takes following technical scheme for this reason: for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, concrete steps are as follows:
A. preparating acid agent solution, sour agent is the acid compound of ammonium sulfate, ammonium dihydrogen phosphate (ADP) and so on, its working concentration is 20-30 grams per liter.
B. protein fibre fabric, nylon fabric are padding and on equipment, are padding sour agent solution with dip time, pick-up rate (pick-up rate is between 60-100%), the speed of a motor vehicle (speed of a motor vehicle is between 10-40 m/min) of regulation, and dry (bake out temperature 80-100 ℃), after oven dry with acid protein fabric, nylon fabric must be in 1 day for ACID DYES plain net or the ROTARY SCREAM PRINTING in rear road.
C. preparation and full-page proof production ACID DYES print paste, do not add acidic materials in this mill base.
D. by plain net or rotary screen printing machines, ACID DYES print paste is printed to being with (speed of a motor vehicle is between 10-50 m/min) on acid protein fabric, nylon fabric, and dry, the stamp protein fibre fabric after oven dry, nylon fabric must be in 1 day for the vapour steaming colour fixing in rear road.
E. stamp protein fibre fabric, nylon fabric enter rapid steamer vapour steaming colour fixing (steam temperature between 110-120 ℃, decatize humidity between 80-90%, steaming time is between 15-40 minute).
F. the operation such as the stamp protein fibre fabric after fixation, nylon fabric is through cold wash, acidic color fixing agent fixation or soda ash is washed, cold wash, oven dry is carried out stamp post processing.
First the present invention innovates adjustment from printing technology flow process, protein fibre fabric, nylon fabric one phase method plain net or ROTARY SCREAM PRINTING are changed to ACID DYES into ACID DYES to protein fibre fabric, nylon fabric two-phase method plain net or ROTARY SCREAM PRINTING, the printing technology flow process adopting is: protein fibre fabric, nylon fabric first roll acid, oven dry, rear plain net or ROTARY SCREAM PRINTING, oven dry, vapour steaming colour fixing again, stamp post processing.Protein fibre fabric, nylon fabric two-phase method plain net or ROTARY SCREAM PRINTING process conditions are studied simultaneously, thereby have determined protein fibre fabric, nylon fabric two-phase method plain net or ROTARY SCREAM PRINTING process conditions.
Beneficial effect of the present invention:
(1) this method is a kind of dyeing ACID DYES plain net or ROTARY SCREAM PRINTING new method, its core technology is that protein fibre fabric, nylon fabric first pad sour agent before ACID DYES direct printing, drying and processing, and then carry out stamp, dry, vapour steaming colour fixing, stamp post processing, thus protein fibre fabric, nylon fabric stamp before having avoided are dried, vapour steaming colour fixing, the existing scarce filling of stamp post processing.
(2) adopt this kind of ACID DYES stamp new method and new printing technology flow process, owing to not adding acidic materials in ACID DYES print paste, thereby improved the storage stability of this print paste, can store the long period.
(3) adopt this kind of ACID DYES stamp new method and new printing technology flow process, can improve widely ACID DYES after ACID DYES plain net or ROTARY SCREAM PRINTING, vapour steaming colour fixing to protein fibre fabric, especially the degree of fixation of nylon fabric, can be increased to 70-85%, only have 15-30% ACID DYES to enter in rinsing solution when washing, compared with present phase method plain net or a ROTARY SCREAM PRINTING, the ACID DYES amount entering in rinsing solution will reduce a lot, thereby can reduce discharge of wastewater; Simultaneously these ACID DYES of not fallen by fixation also reduce greatly to the white ground contamination of stamp protein fibre fabric, nylon fabric, thereby have improved the product quality of stamp protein fibre fabric, nylon fabric.
(4) adopt this kind of ACID DYES stamp new method and new printing technology flow process, process equipment is conventional equipment, takes conveniently.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.
Embodiment 1
Wool cloth ACID DYES plain net or ROTARY SCREAM PRINTING new process for producing
Produce material: pretreated wool cloth
Dye chemical drug product: ammonium sulfate, ACID DYES print paste (not adding acidic materials).
Production equipment: evenness calender, infrared drying machine, cylinder drying machine, plain net or rotary screen printing machines, rapid steamer, open washing car.
1. pad sour technique
1.1 sour agent leach mill solution prescriptions
Table-1 ACID DYES stamp acid agent leach mill solution prescription
Figure BDA0000193560151
1.2 pad sour technological process and condition
Pretreated wool cloth → evenness calender pads the sour wool cloth of sour agent solution (soaks rolls, pick-up rate 70%, 30 ms/min of the speed of a motor vehicle) → oven dry (90 ℃ of bake out temperatures) → be with
2. printing technology
Printing technology flow process and condition
Be with sour wool cloth → plain net or rotary screen printing machines stamp (30 ms/min of the speed of a motor vehicle) → oven dry → stamp wool cloth
3. Steaming
Stamp wool cloth after stamp wool cloth → rapid steamer vapour steaming colour fixing (115 ℃ of steam temperatures, decatize humidity 85%, steaming time 20 minutes) → fixation
4. aftertreatment technology
Aftertreatment technology flow process and condition
Stamp wool cloth → open washing car cold wash → oven dry (90 ℃ of bake out temperatures) → stamp wool cloth finished product after fixation
Embodiment 2
Cloth of real silk ACID DYES plain net or ROTARY SCREAM PRINTING new process for producing
Produce material: the cloth of real silk after coming unstuck
Dye chemical drug product: ammonium sulfate, ACID DYES print paste (not adding acidic materials), acid fixation liquid (2g/L acidic color fixing agent).
Production equipment: evenness calender, infrared drying machine, cylinder drying machine, plain net or rotary screen printing machines, rapid steamer, open washing car.
1. pad sour technique
1.1 sour agent leach mill solution prescriptions
Table-2 ACID DYES stamp special acid agent leach mill solution prescriptions
Figure BDA0000193560152
1.2 pad sour technological process and condition
Cloth of real silk → evenness calender after coming unstuck pads the sour cloth of real silk of sour agent solution (soaks rolls, pick-up rate 70%, 30 ms/min of the speed of a motor vehicle) → oven dry (90 ℃ of bake out temperatures) → be with
2. printing technology
Printing technology flow process and condition
Be with sour cloth of real silk → plain net or rotary screen printing machines stamp (30 ms/min of the speed of a motor vehicle) → oven dry → stamp cloth of real silk
3. Steaming
Stamp cloth of real silk after stamp cloth of real silk → rapid steamer vapour steaming colour fixing (115 ℃ of steam temperatures, decatize humidity 85%, steaming time 20 minutes) → fixation
4. aftertreatment technology
Aftertreatment technology flow process and condition
Stamp cloth of real silk → open washing car cold wash → open washing car acidic color fixing agent fixation (2g/L acidic color fixing agent, 50 ℃ of color fixing temperatures, 10 minutes fixation time) after fixation → oven dry (90 ℃ of bake out temperatures) → stamp cloth of real silk finished product
Embodiment 3
POLYAMIDE FABRIC ACID DYES plain net or ROTARY SCREAM PRINTING new process for producing
Produce material: the POLYAMIDE FABRIC after deoiling
Dye chemical drug product: ammonium sulfate, ACID DYES print paste (not adding acidic materials), soda ash liquid (2g/L soda ash).
Production equipment: evenness calender, infrared drying machine, cylinder drying machine, plain net or rotary screen printing machines, rapid steamer, open washing car.
1. pad sour technique
1.1 sour agent solution prescriptions
Table-3 ACID DYES stamp special acid agent solution prescriptions
Figure BDA0000193560153
1.2 pad sour technological process and condition
POLYAMIDE FABRIC → evenness calender after deoiling pads the sour POLYAMIDE FABRIC of sour agent solution (soaks rolls, pick-up rate 70%, 30 ms/min of the speed of a motor vehicle) → oven dry (90 ℃ of bake out temperatures) → be with
2. printing technology
Printing technology flow process and condition
Be with sour POLYAMIDE FABRIC → plain net or rotary screen printing machines stamp (30 ms/min of the speed of a motor vehicle) → oven dry → stamp POLYAMIDE FABRIC
3. Steaming
Stamp POLYAMIDE FABRIC after stamp POLYAMIDE FABRIC → rapid steamer vapour steaming colour fixing (115 ℃ of steam temperatures, decatize humidity 85%, steaming time 20 minutes) → fixation
4. aftertreatment technology
Aftertreatment technology flow process and condition
After fixation, stamp POLYAMIDE FABRIC → open washing car cold wash → open washing car soda ash liquid is washed (1g/L soda ash, alkali cleaning temperature 45 C, 10 minutes alkali cleaning time) → open washing car cold wash → oven dry (90 ℃ of bake out temperatures) → stamp POLYAMIDE FABRIC finished product
Should be understood that these embodiment are only not used in and limit the scope of the invention for the present invention is described.In addition should be understood that those skilled in the art can make various changes or modifications the present invention after having read the content of the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.

Claims (5)

1. for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, it is characterized in that concrete steps are as follows:
A. preparating acid agent solution, described sour agent is ammonium sulfate or ammonium dihydrogen phosphate (ADP), the working concentration of sour agent solution is 20-30 grams per liter;
B. protein fibre fabric, nylon fabric are padded to sour agent solution padding on equipment, and dry, after oven dry with acid protein fabric, nylon fabric ACID DYES plain net or the ROTARY SCREAM PRINTING for rear road in 1 day;
C. preparation and full-page proof production ACID DYES print paste, do not add acidic materials in this mill base;
D. by plain net or rotary screen printing machines, ACID DYES print paste is printed to being with on acid protein fabric, nylon fabric, and dries, the stamp protein fibre fabric after oven dry, nylon fabric in 1 day for the vapour steaming colour fixing in rear road;
E. stamp protein fibre fabric, nylon fabric enter rapid steamer vapour steaming colour fixing;
F. the stamp protein fibre fabric after fixation, nylon fabric carry out stamp post processing after cold wash, baking operation.
2. according to claim 1 for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, it is characterized in that the stamp protein fibre fabric after fixation in described f step, nylon fabric is through cold wash, acidic color fixing agent fixation or soda ash is washed, carry out stamp post processing after cold wash, baking operation again.
3. according to claim 2 for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, while it is characterized in that in step b, protein fibre fabric, nylon fabric pad sour agent solution on padding equipment, pick-up rate is that 60-100%, the speed of a motor vehicle are 10-40 m/min, padding the bake out temperature that pads sour agent solution on equipment, is 80-100 ℃.
4. according to claim 3 for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, it is characterized in that in steps d by plain net or rotary screen printing machines, by ACID DYES print paste print to the speed of a motor vehicle with on acid protein fabric, nylon fabric time be 10-50 m/min.
5. according to claim 4 for protein fibre fabric, nylon fabric ACID DYES plain net or ROTARY SCREAM PRINTING production method, it is characterized in that steam temperature curing in step e is 110-120 ℃, decatize humidity is 80-90%, and steaming time is 15-40 minute.
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CN103981738A (en) * 2014-04-23 2014-08-13 桐乡市濮院毛针织技术服务中心 Wool fabric printing technology
CN104140714A (en) * 2014-07-18 2014-11-12 浙江亿得化工有限公司 Novel acid ink and preparation method and direct printing technology of novel acid ink
CN104264512A (en) * 2014-09-24 2015-01-07 无锡市东北塘宏良染色厂 Printing method
CN105887516A (en) * 2014-12-29 2016-08-24 张大钊 Ultra-thin high-density nylon fabric dry anhydrous printing method
CN105735005B (en) * 2016-04-19 2018-03-09 苏州大学 A kind of nylon fabric printing method based on polyamide copolymer

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Address after: 312369 Hangzhou Bay Shangyu economic and Technological Development Zone, Zhejiang, Shaoxing

Patentee after: Zhejiang Yide New Material Co., Ltd

Address before: 312369, No. three, No. 9, Shangyu Industrial Park, Hangzhou Bay, Zhejiang, Shaoxing

Patentee before: ZHEJIANG YIDE CHEMICAL Co.,Ltd.

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