CN104437371A - 一种复合多孔活性炭烟气吸附剂及其制备方法 - Google Patents

一种复合多孔活性炭烟气吸附剂及其制备方法 Download PDF

Info

Publication number
CN104437371A
CN104437371A CN201410666656.7A CN201410666656A CN104437371A CN 104437371 A CN104437371 A CN 104437371A CN 201410666656 A CN201410666656 A CN 201410666656A CN 104437371 A CN104437371 A CN 104437371A
Authority
CN
China
Prior art keywords
parts
activated carbon
flue gas
adsorbent
hour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410666656.7A
Other languages
English (en)
Inventor
卢叶恒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI TOPTECHSCR ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
Original Assignee
ANHUI TOPTECHSCR ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI TOPTECHSCR ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd filed Critical ANHUI TOPTECHSCR ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
Priority to CN201410666656.7A priority Critical patent/CN104437371A/zh
Publication of CN104437371A publication Critical patent/CN104437371A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0207—Compounds of Sc, Y or Lanthanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0296—Nitrates of compounds other than those provided for in B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14—Diatomaceous earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
    • B01J2220/4825—Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

本发明公开了一种复合多孔活性炭烟气吸附剂，其特征在于，由下列重量份的原料制备制成：果壳活性炭98-105、硅藻土36-40、泡花碱2-3、松香2-3、VAE乳液2-3、聚乙烯醇2-3、脂肪醇聚氧乙烯醚硫酸钠1-2、柠檬酸钠1-2、石膏渣1-2、粉煤灰2.5-3.5、食用玉米淀粉4-5、硝酸镧2-3、玻璃纤维粉9-12、吸附助剂4-6、水适量；本发明配方合理，添加聚乙烯醇、食用玉米淀粉等粘性物质，增加活性炭的韧性以及强度，延长使用寿命；添加吸附助剂，具有特殊多孔性，延长气体与之接触时间，起到抑菌、净化空气的效果；本发明吸附性效率高，生产工艺简单，适合工业干法脱硫，汽车尾气脱硫，日常空气净化等。

Description

一种复合多孔活性炭烟气吸附剂及其制备方法
技术领域
本发明涉及一种脱硫活性炭及其制备方法，特别是一种复合多孔活性炭烟气吸附剂及其制备方法。
背景技术
随着社会的迅猛发展，环境污染也日趋严重，工业废气﹑汽车尾气等严重困扰着人类的生活。污水处理、造纸、石油加工、化肥制造、化学纤维制造以及一些化工原料制造行业中排放出大量的烟气，而烟气中含有硫化氢、二氧化硫及其他灰尘，不仅造成环境污染，也容易导致催化剂中毒失活，因此降低工业生产中硫的排放量成为当今世界工业生产中需要解决的几大难题之一。目前都脱除毒素经常用到吸附剂，主要有硅胶、活性纳米碳、活性炭、分子筛等，另外还有针对某种组分选择性吸附而研制的吸附材料。但是这些吸附剂大多吸附能力有限，需要针对不同的要求研究不同的吸附剂，发挥最好的作用。同时，寻找新的原料，以增强吸附效果，节约成本。
发明内容
本发明的目的是提供一种复合多孔活性炭烟气吸附剂及其制备方法。
为了实现本发明的目的，本发明通过以下方案实施：
一种复合多孔活性炭烟气吸附剂，由下列重量份的原料制备制成：果壳活性炭98-105、硅藻土36-40、泡花碱2-3、松香2-3、VAE乳液2-3、聚乙烯醇2-3、脂肪醇聚氧乙烯醚硫酸钠1-2、柠檬酸钠1-2、石膏渣1-2、粉煤灰2.5-3.5、食用玉米淀粉4-5、硝酸镧2-3、玻璃纤维粉9-12、吸附助剂4-6、水适量；
所述吸附助剂由以下重量份的原料制成：鹿沼土 1.5-2.5、硫酸铝1.5-2.5、碳酸钠2-3、高岭土12-14、纳米碳2-3、二氧化钛2-3、茶籽壳8-10、莲房13-15；制备方法是将茶籽壳、莲房在100℃-120℃条件下干燥1-1.5小时，粉碎成40-60目粉末，然后加入适量水与除鹿沼土之外的其余剩余成分搅拌均匀，形成泥状物，然后放入400℃-500℃的炭化炉中炭化2-3小时，取出冷却后粉碎成80-100目粉末，用50%-60%的醋酸溶液浸泡1.5-2小时，过滤，取滤渣加鹿沼土、1.5-2倍量的纯水研磨40-50分钟得浆料即可。
本发明所述一种复合多孔活性炭烟气吸附剂，由以下具体步骤制成：
（1）将果壳活性炭、硅藻土、玻璃纤维粉放入球磨机中球磨1.5-2.5小时，球磨后过150-200目筛，得到混合粉末待用；
（2）将泡花碱、聚乙烯醇、石膏渣、粉煤灰、食用玉米淀粉、硝酸镧中加入适量的水，不断搅拌制成浆料，然后加入除吸附助剂之外的其余剩余成分，加热至70℃-80℃，保温研磨2-2.5小时，得混合浆料待用；
（3）将混合粉末、混合浆料、吸附助剂相互搅拌均匀，然后浓缩干燥，送入造粒机中造粒即得。
本发明的有益效果是：本发明配方合理，添加聚乙烯醇、食用玉米淀粉等粘性物质，增加活性炭的韧性以及强度，延长使用寿命；添加吸附助剂，具有特殊多孔性，延长气体与之接触时间，起到抑菌、净化空气的效果；本发明吸附性效率高，生产工艺简单，适合工业干法脱硫，汽车尾气脱硫，日常空气净化等。
具体实施方案
下面通过具体实例对本发明进行详细说明。
一种复合多孔活性炭烟气吸附剂，由下列重量份（公斤）的原料制备制成：果壳活性炭98、硅藻土36、泡花碱2、松香2、VAE乳液2、聚乙烯醇2、脂肪醇聚氧乙烯醚硫酸钠1、柠檬酸钠1、石膏渣1、粉煤灰2.5、食用玉米淀粉4、硝酸镧2、玻璃纤维粉9、吸附助剂4、水适量；
所述吸附助剂由以下重量份（公斤）的原料制成：鹿沼土 1.5、硫酸铝1.5、碳酸钠2、高岭土12、纳米碳2、二氧化钛2、茶籽壳8、莲房13；制备方法是将茶籽壳、莲房在100℃-120℃条件下干燥1-1.5小时，粉碎成40-60目粉末，然后加入适量水与除鹿沼土之外的其余剩余成分搅拌均匀，形成泥状物，然后放入400℃-500℃的炭化炉中炭化2-3小时，取出冷却后粉碎成80-100目粉末，用50%-60%的醋酸溶液浸泡1.5-2小时，过滤，取滤渣加鹿沼土、1.5-2倍量的纯水研磨40-50分钟得浆料即可。
本发明所述一种复合多孔活性炭烟气吸附剂，由以下具体步骤制成：
（1）将果壳活性炭、硅藻土、玻璃纤维粉放入球磨机中球磨1.5-2.5小时，球磨后过150-200目筛，得到混合粉末待用；
（2）将泡花碱、聚乙烯醇、石膏渣、粉煤灰、食用玉米淀粉、硝酸镧中加入适量的水，不断搅拌制成浆料，然后加入除吸附助剂之外的其余剩余成分，加热至70℃-80℃，保温研磨2-2.5小时，得混合浆料待用；
（3）将混合粉末、混合浆料、吸附助剂相互搅拌均匀，然后浓缩干燥，送入造粒机中造粒即得。
本发明样品主要技术参数为：硫容(wt%)：≥22.5%，脱硫精度（ppm）：≤1；利用本发明样品进行废气处理，捕集微尘效率≥99％。

Claims (2)

1.一种复合多孔活性炭烟气吸附剂，其特征在于，由下列重量份的原料制备制成：果壳活性炭98-105、硅藻土36-40、泡花碱2-3、松香2-3、VAE乳液2-3、聚乙烯醇2-3、脂肪醇聚氧乙烯醚硫酸钠1-2、柠檬酸钠1-2、石膏渣1-2、粉煤灰2.5-3.5、食用玉米淀粉4-5、硝酸镧2-3、玻璃纤维粉9-12、吸附助剂4-6、水适量；
所述吸附助剂由以下重量份的原料制成：鹿沼土 1.5-2.5、硫酸铝1.5-2.5、碳酸钠2-3、高岭土12-14、纳米碳2-3、二氧化钛2-3、茶籽壳8-10、莲房13-15；制备方法是将茶籽壳、莲房在100℃-120℃条件下干燥1-1.5小时，粉碎成40-60目粉末，然后加入适量水与除鹿沼土之外的其余剩余成分搅拌均匀，形成泥状物，然后放入400℃-500℃的炭化炉中炭化2-3小时，取出冷却后粉碎成80-100目粉末，用50%-60%的醋酸溶液浸泡1.5-2小时，过滤，取滤渣加鹿沼土、1.5-2倍量的纯水研磨40-50分钟得浆料即可。
2.根据权利要求1所述一种复合多孔活性炭烟气吸附剂，其特征在于，由以下具体步骤制成：
（1）将果壳活性炭、硅藻土、玻璃纤维粉放入球磨机中球磨1.5-2.5小时，球磨后过150-200目筛，得到混合粉末待用；
（2）将泡花碱、聚乙烯醇、石膏渣、粉煤灰、食用玉米淀粉、硝酸镧中加入适量的水，不断搅拌制成浆料，然后加入除吸附助剂之外的其余剩余成分，加热至70℃-80℃，保温研磨2-2.5小时，得混合浆料待用；
（3）将混合粉末、混合浆料、吸附助剂相互搅拌均匀，然后浓缩干燥，送入造粒机中造粒即得。
CN201410666656.7A 2014-11-20 2014-11-20 一种复合多孔活性炭烟气吸附剂及其制备方法 Pending CN104437371A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410666656.7A CN104437371A (zh) 2014-11-20 2014-11-20 一种复合多孔活性炭烟气吸附剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410666656.7A CN104437371A (zh) 2014-11-20 2014-11-20 一种复合多孔活性炭烟气吸附剂及其制备方法

Publications (1)

Publication Number Publication Date
CN104437371A true CN104437371A (zh) 2015-03-25

Family

ID=52884581

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410666656.7A Pending CN104437371A (zh) 2014-11-20 2014-11-20 一种复合多孔活性炭烟气吸附剂及其制备方法

Country Status (1)

Country Link
CN (1) CN104437371A (zh)

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104841363A (zh) * 2015-04-22 2015-08-19 马鞍山市顺达环保设备有限公司 一种矿热炉用吸附剂及其制备方法
CN104905409A (zh) * 2015-06-05 2015-09-16 滁州卷烟材料厂 一种止咳化痰保健香烟过滤嘴复合吸附剂及其制备方法
CN104921301A (zh) * 2015-06-05 2015-09-23 滁州卷烟材料厂 一种柿子皮香烟过滤嘴复合吸附剂及其制备方法
CN104921299A (zh) * 2015-06-05 2015-09-23 滁州卷烟材料厂 一种香蕉皮香烟过滤嘴复合吸附剂及其制备方法
CN104957769A (zh) * 2015-06-05 2015-10-07 滁州卷烟材料厂 一种清肺保健香烟过滤嘴复合吸附剂及其制备方法
CN104957768A (zh) * 2015-06-05 2015-10-07 滁州卷烟材料厂 一种促进睡眠保健香烟过滤嘴复合吸附剂及其制备方法
CN104984727A (zh) * 2015-07-06 2015-10-21 安徽成方新材料科技有限公司 一种快速吸附增强的沥青树脂复合基球形活性炭及其制备方法
CN105011367A (zh) * 2015-06-05 2015-11-04 滁州卷烟材料厂 一种清热降火香烟过滤嘴复合吸附剂及其制备方法
CN105011366A (zh) * 2015-06-05 2015-11-04 滁州卷烟材料厂 一种缓解疲劳保健香烟过滤嘴复合吸附剂及其制备方法
CN105148874A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种复合多孔烟气吸附剂
CN105148864A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种粉煤灰基重金属吸附剂
CN105148873A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种除尘除烟吸附剂
CN105148841A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种耐高温的汞吸附剂
CN105148865A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种气体吸附剂
CN105148863A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种汞吸附剂
CN105148840A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种粉煤灰烟气脱汞吸附剂
CN105148862A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种储存时间长不易失效的吸附剂
CN105195104A (zh) * 2015-09-01 2015-12-30 安徽省含山县天顺环保设备有限公司 一种能够净化汽车尾气的吸附剂
CN105854830A (zh) * 2016-06-16 2016-08-17 马鞍山市顺达环保设备有限公司 一种用于燃煤烟气的吸附剂
CN105921124A (zh) * 2016-06-16 2016-09-07 马鞍山市顺达环保设备有限公司 一种吸附效率高的烟气吸附剂
CN106310979A (zh) * 2016-11-15 2017-01-11 毛敬英 一种用于治理挥发性有机物的过滤膜
CN106512701A (zh) * 2016-11-30 2017-03-22 长白朝鲜族自治县北疆硅藻土新材料科技有限公司 一种复合硅藻土空气净化剂及其制备方法
CN108993063A (zh) * 2018-06-29 2018-12-14 薛敏强 一种移动式医用气溶胶高效吸附装置
CN109012602A (zh) * 2018-09-30 2018-12-18 江苏斯沃得环保科技有限公司 一种椰壳活性炭的制备方法
CN110496598A (zh) * 2019-07-04 2019-11-26 宁夏宝塔化工中心实验室(有限公司) 一种用于含焦油烟气处理的吸附剂及其使用方法
CN110975865A (zh) * 2019-12-20 2020-04-10 绍兴蓝竹新材料科技有限公司 高导光率高吸附性能净化空气用光催化复合剂的制备方法
CN111514866A (zh) * 2020-05-15 2020-08-11 湖南宇洁活性炭环保科技有限公司 一种溶剂回收高效木质活性炭及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060054023A1 (en) * 2004-09-03 2006-03-16 Raetz James A Air-permeable filtration media, methods of manufacture and methods of use
US20080047902A1 (en) * 2006-08-28 2008-02-28 Basf Catalysts Llc Media for the removal of heavy metals and volatile byproducts from drinking water
US8263525B1 (en) * 2009-05-27 2012-09-11 Nei Corporation Nanoparticle sorbent for efficient mercury remediation from contaminated water
CN103566922A (zh) * 2013-09-26 2014-02-12 蚌埠华纺滤材有限公司 一种稀土改性活性炭催化材料及其制备方法
CN103736368A (zh) * 2013-12-12 2014-04-23 芜湖中路实业有限责任公司 一种活性炭基烟气脱硫剂及其制备方法
CN103736268A (zh) * 2014-01-08 2014-04-23 太仓市车中宝休闲用品有限公司 铝挤型便携摆脚式旱冰鞋

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060054023A1 (en) * 2004-09-03 2006-03-16 Raetz James A Air-permeable filtration media, methods of manufacture and methods of use
US20080047902A1 (en) * 2006-08-28 2008-02-28 Basf Catalysts Llc Media for the removal of heavy metals and volatile byproducts from drinking water
US8263525B1 (en) * 2009-05-27 2012-09-11 Nei Corporation Nanoparticle sorbent for efficient mercury remediation from contaminated water
CN103566922A (zh) * 2013-09-26 2014-02-12 蚌埠华纺滤材有限公司 一种稀土改性活性炭催化材料及其制备方法
CN103736368A (zh) * 2013-12-12 2014-04-23 芜湖中路实业有限责任公司 一种活性炭基烟气脱硫剂及其制备方法
CN103736268A (zh) * 2014-01-08 2014-04-23 太仓市车中宝休闲用品有限公司 铝挤型便携摆脚式旱冰鞋

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
吴京淼: "《服装洗涤化料与应用》", 31 August 2009 *
沈春林: "《化学建材原材料手册》", 31 August 2008 *
郝近大: "《中国中药材及原植（动）物彩色图谱》", 28 February 2014 *

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104841363A (zh) * 2015-04-22 2015-08-19 马鞍山市顺达环保设备有限公司 一种矿热炉用吸附剂及其制备方法
CN104905409A (zh) * 2015-06-05 2015-09-16 滁州卷烟材料厂 一种止咳化痰保健香烟过滤嘴复合吸附剂及其制备方法
CN104921301A (zh) * 2015-06-05 2015-09-23 滁州卷烟材料厂 一种柿子皮香烟过滤嘴复合吸附剂及其制备方法
CN104921299A (zh) * 2015-06-05 2015-09-23 滁州卷烟材料厂 一种香蕉皮香烟过滤嘴复合吸附剂及其制备方法
CN104957769A (zh) * 2015-06-05 2015-10-07 滁州卷烟材料厂 一种清肺保健香烟过滤嘴复合吸附剂及其制备方法
CN104957768A (zh) * 2015-06-05 2015-10-07 滁州卷烟材料厂 一种促进睡眠保健香烟过滤嘴复合吸附剂及其制备方法
CN105011367A (zh) * 2015-06-05 2015-11-04 滁州卷烟材料厂 一种清热降火香烟过滤嘴复合吸附剂及其制备方法
CN105011366A (zh) * 2015-06-05 2015-11-04 滁州卷烟材料厂 一种缓解疲劳保健香烟过滤嘴复合吸附剂及其制备方法
CN104984727A (zh) * 2015-07-06 2015-10-21 安徽成方新材料科技有限公司 一种快速吸附增强的沥青树脂复合基球形活性炭及其制备方法
CN105148863A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种汞吸附剂
CN105148864A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种粉煤灰基重金属吸附剂
CN105148873A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种除尘除烟吸附剂
CN105148841A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种耐高温的汞吸附剂
CN105148865A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种气体吸附剂
CN105148874A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种复合多孔烟气吸附剂
CN105148840A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种粉煤灰烟气脱汞吸附剂
CN105148862A (zh) * 2015-09-01 2015-12-16 安徽省含山县天顺环保设备有限公司 一种储存时间长不易失效的吸附剂
CN105195104A (zh) * 2015-09-01 2015-12-30 安徽省含山县天顺环保设备有限公司 一种能够净化汽车尾气的吸附剂
CN105854830A (zh) * 2016-06-16 2016-08-17 马鞍山市顺达环保设备有限公司 一种用于燃煤烟气的吸附剂
CN105921124A (zh) * 2016-06-16 2016-09-07 马鞍山市顺达环保设备有限公司 一种吸附效率高的烟气吸附剂
CN106310979A (zh) * 2016-11-15 2017-01-11 毛敬英 一种用于治理挥发性有机物的过滤膜
CN106512701A (zh) * 2016-11-30 2017-03-22 长白朝鲜族自治县北疆硅藻土新材料科技有限公司 一种复合硅藻土空气净化剂及其制备方法
CN108993063A (zh) * 2018-06-29 2018-12-14 薛敏强 一种移动式医用气溶胶高效吸附装置
CN109012602A (zh) * 2018-09-30 2018-12-18 江苏斯沃得环保科技有限公司 一种椰壳活性炭的制备方法
CN110496598A (zh) * 2019-07-04 2019-11-26 宁夏宝塔化工中心实验室(有限公司) 一种用于含焦油烟气处理的吸附剂及其使用方法
CN110975865A (zh) * 2019-12-20 2020-04-10 绍兴蓝竹新材料科技有限公司 高导光率高吸附性能净化空气用光催化复合剂的制备方法
CN110975865B (zh) * 2019-12-20 2022-09-02 绍兴蓝竹新材料科技有限公司 高导光率高吸附性能净化空气用光催化复合剂的制备方法
CN111514866A (zh) * 2020-05-15 2020-08-11 湖南宇洁活性炭环保科技有限公司 一种溶剂回收高效木质活性炭及其制备方法

Similar Documents

Publication Publication Date Title
CN104437371A (zh) 一种复合多孔活性炭烟气吸附剂及其制备方法
Wang et al. Adsorption of heavy metal onto biomass-derived activated carbon
Qu et al. Multi-component adsorption of Pb (II), Cd (II) and Ni (II) onto microwave-functionalized cellulose: Kinetics, isotherms, thermodynamics, mechanisms and application for electroplating wastewater purification
CN107213787A (zh) 一种脱硫剂及其制备方法
CN104289195B (zh) 一种孔隙发达成本低的活性炭硅藻土颗粒及其制备方法
CN104437366A (zh) 一种不易崩解的混合活性炭脱硫剂及其制备方法
CN104475050A (zh) 一种能够快速净化烟气的活性炭硅藻土颗粒及其制备方法
CN104475020A (zh) 一种吸附降解效果好的环保活性炭颗粒及其制备方法
CN104475051B (zh) 一种具有杀菌作用的混合脱硫除尘颗粒及其制备方法
CN104475015A (zh) 一种添加陶瓷纤维棉的活性炭硅藻土脱硫剂及其制备方法
CN104437432B (zh) 一种分散均匀的活性炭硅藻土空气净化颗粒及其制备方法
CN103691394A (zh) 一种碱性改性活性炭脱硫剂及其制备方法
CN100569638C (zh) 脱汞专用活性炭的制造方法及其产品
CN106861642A (zh) 一种具有高吸附能力的生物质基水凝胶的制备与应用
CN104307493A (zh) 一种用于脱硫除尘的结实耐用型活性炭硅藻土颗粒及其制备方法
CN101456612A (zh) 粉煤灰制备环境污染治理材料的清洁生产新工艺
Patel et al. Coal fly ash derived adsorbent for enhancing waste water treatment
CN114229852A (zh) 一种利用钢渣脱除烟气中so2协同提取硅胶的方法
CN104437399A (zh) 一种孔隙发达成本低的活性炭硅藻土颗粒及其制备方法
Qin et al. Role of minerals in mushroom residue on its adsorption capability to Cd (II) from aqueous solution
CN103495393A (zh) 一种富氧改性木炭吸附脱硫剂及其制备方法
CN104437420A (zh) 一种多金属硅藻土活性炭复合固体脱硫剂及其制备方法
KR101629910B1 (ko) 폐석탄재를 이용한 복합 탈취제 제조방법
CN110575812B (zh) 一种陶土/软锰矿高效除磷的环保吸附材料及制备方法
CN107344062A (zh) 一种脱硫剂、其制备方法及应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150325

RJ01 Rejection of invention patent application after publication