CN104428940B - 作为镁离子传递介质的硼氢化镁及其衍生物 - Google Patents

作为镁离子传递介质的硼氢化镁及其衍生物 Download PDF

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Publication number
CN104428940B
CN104428940B CN201380037003.6A CN201380037003A CN104428940B CN 104428940 B CN104428940 B CN 104428940B CN 201380037003 A CN201380037003 A CN 201380037003A CN 104428940 B CN104428940 B CN 104428940B
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magnesium
mgb
electrolyte
alkyl
solvent
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CN104428940A (zh
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R·F·莫塔迪
松井雅树
T·J·卡特
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Toyota Motor Corp
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Toyota Motor Engineering and Manufacturing North America Inc
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Priority claimed from US13/839,003 external-priority patent/US9318775B2/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C01B6/19—Preparation from other compounds of boron
    • C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0045—Room temperature molten salts comprising at least one organic ion
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Secondary Cells (AREA)
CN201380037003.6A 2012-08-02 2013-08-02 作为镁离子传递介质的硼氢化镁及其衍生物 Active CN104428940B (zh)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US201261678672P 2012-08-02 2012-08-02
US61/678,672 2012-08-02
US13/720,522 2012-12-19
US13/720,522 US9312566B2 (en) 2012-08-02 2012-12-19 Magnesium borohydride and its derivatives as magnesium ion transfer media
US13/839,003 2013-03-15
US13/839,003 US9318775B2 (en) 2012-08-02 2013-03-15 Magnesium borohydride and its derivatives as magnesium ion transfer media
US13/956,993 2013-08-01
US13/956,993 US20140038037A1 (en) 2012-08-02 2013-08-01 Magnesium borohydride and its derivatives as magnesium ion transfer media
PCT/US2013/053331 WO2014022729A1 (en) 2012-08-02 2013-08-02 Magnesium borohydride and its derivatives as magnesium ion transfer media

Publications (2)

Publication Number Publication Date
CN104428940A CN104428940A (zh) 2015-03-18
CN104428940B true CN104428940B (zh) 2017-07-28

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Country Status (6)

Country Link
US (1) US20140038037A1 (enExample)
EP (1) EP2880706A4 (enExample)
JP (1) JP6301924B2 (enExample)
KR (2) KR102109796B1 (enExample)
CN (1) CN104428940B (enExample)
WO (1) WO2014022729A1 (enExample)

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US9362593B2 (en) 2012-12-19 2016-06-07 Toyota Motor Engineering & Manufacturing North America, Inc. Borohydride solvo-ionic liquid family for magnesium battery
US9843080B2 (en) * 2014-04-11 2017-12-12 Alliance For Sustainable Energy, Llc Magnesium-based methods, systems, and devices
JP6287649B2 (ja) * 2014-07-08 2018-03-07 株式会社村田製作所 電解液及び電気化学デバイス
WO2016049309A1 (en) * 2014-09-25 2016-03-31 Virginia Commonwealth University Halogen-free electrolytes
CN104538669B (zh) * 2014-12-16 2017-11-10 上海交通大学 一种可充镁电池
US20160181662A1 (en) * 2014-12-23 2016-06-23 Toyota Motor Engineering & Manufacturing North America, Inc. Functionalized carboranyl magnesium electrolyte for magnesium battery
US9455473B1 (en) 2015-05-12 2016-09-27 Toyota Motor Engineering & Manufacturing North America, Inc. Ionic liquids for rechargeable magnesium battery
US9716289B1 (en) 2016-01-12 2017-07-25 Toyota Motor Engineering & Manufacturing North America, Inc. Solid-phase magnesium boranyl electrolytes for a magnesium battery
KR101864812B1 (ko) * 2016-02-15 2018-06-05 다이슨 테크놀러지 리미티드 마그네슘 염
US9997815B2 (en) * 2016-08-05 2018-06-12 Toyota Motor Engineering & Manufacturing North America, Inc. Non-aqueous magnesium-air battery
US10910672B2 (en) 2016-11-28 2021-02-02 Toyota Motor Engineering & Manufacturing North America, Inc. High concentration electrolyte for magnesium battery having carboranyl magnesium salt in mixed ether solvent
US10673095B2 (en) 2017-09-13 2020-06-02 Toyota Motor Engineering & Manufacturing North America, Inc. Electrochemical cells having ionic liquid-containing electrolytes
US10680280B2 (en) 2017-09-26 2020-06-09 Toyota Jidosha Kabushiki Kaisha 3D magnesium battery and method of making the same
CN108285130A (zh) * 2018-02-11 2018-07-17 庄英俊 一种硼氢化锂的制备方法及检测方法
CN110336079B (zh) * 2019-06-24 2020-11-10 清华大学 镁电池电解液、其制备方法以及镁电池
JP7384346B2 (ja) * 2019-11-05 2023-11-21 国立大学法人山口大学 マグネシウム二次電池用の絶縁抑制電解液及び絶縁抑制方法
CN111370759B (zh) * 2020-03-17 2023-03-17 清华大学 镁电池电解液及其制备方法和镁电池
CN115000513B (zh) * 2022-07-13 2025-06-10 广东省国研科技研究中心有限公司 一种宽电位窗口可充镁电池电解液及其制备方法
CN116154295B (zh) * 2023-04-04 2025-11-28 江西思远再生资源有限公司 一种用于镁电池的两性离子液体电解质

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US4139680A (en) * 1975-09-03 1979-02-13 P. R. Mallory & Co. Inc. Method for preventing dendritic growth in secondary cells
US4808282A (en) * 1987-01-05 1989-02-28 The Dow Chemical Company Alkaline earth metal compounds and alkali metal substances via electrochemical process
US4894302A (en) * 1985-06-14 1990-01-16 The Dow Chemical Company Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent

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US4397925A (en) * 1981-10-15 1983-08-09 Ray-O-Vac Corporation Alkaline battery with reducing agents in the electrolyte
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Also Published As

Publication number Publication date
KR20150040900A (ko) 2015-04-15
KR20190021498A (ko) 2019-03-05
WO2014022729A1 (en) 2014-02-06
KR102109796B1 (ko) 2020-05-12
EP2880706A1 (en) 2015-06-10
US20140038037A1 (en) 2014-02-06
JP6301924B2 (ja) 2018-03-28
EP2880706A4 (en) 2016-09-14
CN104428940A (zh) 2015-03-18
JP2015523703A (ja) 2015-08-13

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