CN104413513B - A kind of carbon dioxide hydrate is used for the application for preparing beverage - Google Patents
A kind of carbon dioxide hydrate is used for the application for preparing beverage Download PDFInfo
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- CN104413513B CN104413513B CN201310397768.2A CN201310397768A CN104413513B CN 104413513 B CN104413513 B CN 104413513B CN 201310397768 A CN201310397768 A CN 201310397768A CN 104413513 B CN104413513 B CN 104413513B
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- carbon dioxide
- dioxide hydrate
- beverage
- hydrate
- water
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/1522—Inorganic additives, e.g. minerals, trace elements; Chlorination or fluoridation of milk; Organic salts or complexes of metals other than natrium or kalium; Calcium enrichment of milk
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F5/00—Coffee; Coffee substitutes; Preparations thereof
- A23F5/24—Extraction of coffee; Coffee extracts; Making instant coffee
- A23F5/36—Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee
- A23F5/42—Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee using inorganic additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
- A23G9/325—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds containing inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C5/00—Other raw materials for the preparation of beer
- C12C5/02—Additives for beer
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Nutrition Science (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
It is used for the application for preparing beverage the invention discloses a kind of carbon dioxide hydrate, belongs to food technology field.Carbon dioxide hydrate particle is directly appended to obtain the beverage containing carbon dioxide hydrate in non-foamed beverage, makes it have the application that there is same mouthfeel with city's dealer's Carbonated drinks.The raw material of the invention is only water and carbon dioxide, and the carbon dioxide hydrate of nontoxic solid-state is formed in the environment of cryogenic high pressure.The carbon dioxide hydrate used in the present invention has the characteristic for accommodating ultra-large volume gas, and after storing three weeks in the household electric refrigerator environment of simulation, the carbon dioxide content in sample is still higher than city's dealer's Carbonated drinks.In view of carbon dioxide hydrate is easy to inexpensive large-scale production, there is broad mass market space using this technological development Novel beverage.
Description
Technical field
The invention belongs to the application of carbon dioxide hydrate and food technology field, and in particular to a kind of hydrated carbon dioxide
Thing is used for the application for preparing beverage.
Background technology
Carbon dioxide hydrate is a kind of more special envelope that water and carbon dioxide are formed under low temperature, condition of high voltage
Compound.In carbon dioxide hydrate, hydrone forms main body crystalline network by stronger hydrogen bond, in the hole in network
Full of carbon dioxide molecule (title guest molecule), and the degree that its hole is filled up then depends on temperature, pressure and the supercooling of system
Degree.Without stoichiometric relationship between main, guest molecule, and the active force between its molecule is Van der Waals force.At present to titanium dioxide
The study hotspot of Kohlenhydrate effect concentrates on stores and fixes carbon dioxide in seabed using hydrate, to slow down global temperature
Room effect.
The carbonic acid food now peddled in the market contains CO2The main body of food be liquid carbonic acid beverage.Soft drink also one
As refer to the non-alcoholic drink that there is refrigerant sense.Soft drink can be divided into sparkling beverage and non-foamed beverage again.Sparkling beverage
Representative have soda water, fruity carbonated drink etc.；The representative of non-foamed beverage has fruit and vegetable juice, coffee beverage, tea beverage etc..Consumer
For liking for soft drink, it is in the majority to have selectable multifarious country as China, but and America and Europe and Japan and other countries phase
Than the soft drink in China has certain gap in the change of mouthfeel and the innovation of product.
The history of the soda in China can trace back to traditional fruity carbonated drink.Because the amount for being wherein pressed into carbonic acid is big,
In order to pressure-resistant using vial and special lid.Now fast-selling cola and its similar products is in China after being introduced by the U.S.
Peddled in market, really rise and start from the eighties in last century, away from the present existing more than 40 years history.The raw material of soda remove
Mainly there are the carbohydrate of granulated sugar, opposite sexization liquid sugar etc and the acid as citric acid outside drinking water, spices is mainly with lemon
It is widely used based on lemon and sweet orange taste, is pressed into CO wherein2Final drink is made in gas.The gas pressure intensity of soda leads to
Often in 200~340KPa, pH value is between 2.7~3.6.And some non-foamed beverages and freezing point are then drunk without similar carbonic acid
The mouthfeel of material.If Hydrate Technology can be applied to make CO2It is present among these drinks, is tantamount to fill up non-foamed beverage outstanding
It is the blank of the mouthfeel improvement of freezing point, consumer is had more selections, brings food service industry revolutionary innovation.
The content of the invention
It is used for the application for preparing beverage it is an object of the invention to provide a kind of carbon dioxide hydrate, by non-foamed
Property be to add harmless carbon dioxide using Hydrate Technology in non-Carbonated drinks, there are itself and commercially available Carbonated drinks
Same mouthfeel.The technology brings the innovation of technology to non-foamed field of beverage.
The technical scheme is that：
A kind of carbon dioxide hydrate is used for the application for preparing beverage, carbon dioxide hydrate particle is directly appended to non-
Obtained in sparkling beverage, gained beverage has and the same mouthfeel of soda.The mode of addition is：By the carbon dioxide
After hydrate is added in non-foamed beverage, gained beverage is preserved under the conditions of normal pressure and (temperature) before drinking；Or will
The carbon dioxide hydrate is preserved, it is necessary to be added to non-hair when drinking under normal pressure and -15~-10 DEG C of temperature conditionss
In bubble property beverage.
The non-foamed beverage includes fruit juice, coffee, cold drink, beer or milk；The cold drink is ice cream..
The carbon dioxide hydrate grain diameter is 0.5~1.0cm, the carbon dioxide hydrate by carbon dioxide and
Water forms, and the mol ratio of carbon dioxide and water is 1：(5.75~6.25).
The preparation of the carbon dioxide hydrate particle comprises the following steps：
(1) water is placed in stainless steel closed container, the temperature control of water is 0~1 DEG C, prevents water-setting from build-uping ice；
(2) carbon dioxide is passed through stainless steel closed container, gas in container pressure is reached 2000MPa, simultaneously
Water in stirring container, accelerate the generation of carbon dioxide hydrate.
(3) because the generation of carbon dioxide hydrate causes the reduction of carbon dioxide in container, when pressure is less than in container
During 1400MPa, then being passed through carbon dioxide makes its pressure reach 2000MPa, repeats this operation until chamber pressure is without aobvious
Write and reduce.
(4) at low ambient temperatures (- 50~-60 DEG C) unlatching stainless steel closed container, take out carbon dioxide hydrate, will take
The carbon dioxide hydrate gone out pulverizes into a diameter of 0.5~1.0cm and obtains the carbon dioxide hydrate particle.
The design principle of the present invention is as follows：
The present invention is made nontoxic to human body under conditions of relative low temperature high pressure using water and carbon dioxide as raw material
Carbon dioxide hydrate particle, the reaction of water and carbon dioxide generation hydrate is physical reactions, and chemically non-reactive.Standard
Atmospheric pressure, under conditions of 0 DEG C, its can receiving volume than the carbon dioxide for 160 times, utilize carbon dioxide hydrate particle
It is this that there is the characteristics of very big gas inclusive, only a small amount of carbon dioxide hydrate need to be added to non-foamed drink
(non-Carbonated drinks) are particularly in cold drink, and the same mouthfeel of soda is bought to resell with city with regard to that can make it have.
Carbon dioxide hydrate is that a carbon dioxide molecule institute is included in the cage structure being made up of the hydrogen bond of hydrone
The crystallization of formation, its physical behavior are similar to ice.The Phase Equilibrium Temperature of normal atmosphere pressure is about -53 DEG C, and household electric refrigerator is cold
The pressure that balances each other for freezing -15~-10 DEG C in room is 600KPa, about 6 standard atmospheric pressures.Under this condition, carbon dioxide water
Compound is in unstable state thermodynamically, and the radial decomposition since surface, the ice formed after decomposition, which is wrapped in, not to be had
The hydrate surface of decomposition, it is continued to be decomposed to form suppression.Using this characteristic, the drink containing carbon dioxide hydrate can
To be preserved for a long time in the environment of household electric refrigerator.Even if the time of storage three weeks still has two higher than city's dealer's soda
Content of carbon oxide.
The advantage of the invention is that：
1st, it is global to increase wherein carbon dioxide content using carbon dioxide hydrate in drink first, improve mouth
Sense.Fundamentally drink industry can be reformed, meet a variety of needs of consumer.
2nd, carbon dioxide hydrate generation method is simple, is easy to large-scale low-cost to produce.Raw materials for production are nontoxic, clearly
Clean, cheap, production program is simple, is easy to go into operation on a large scale.
3rd, it is very convenient to be stored in household electric refrigerator, it is easy to use.
Even if the 4, not adding this product in drink, single commodity selling can be still used as, consumer can voluntarily drink
Added in product.
Brief description of the drawings
Fig. 1 is the outward appearance of carbon dioxide hydrate particulate samples.
Fig. 2 is the outward appearance of carbon dioxide hydrate particulate samples.
Fig. 3 is the mass fraction change that carbon dioxide hydrate particle preserves three weeks under household electric refrigerated conditions.
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
Embodiment 1
1st, the preparation of carbon dioxide hydrate particle：
(1) water is placed in stainless steel closed container, the temperature control of water is 0~1 DEG C, prevents water-setting from build-uping ice；
(2) carbon dioxide is passed through stainless steel closed container, gas in container pressure is reached 2000MPa, simultaneously
Water in stirring container, accelerate the generation of carbon dioxide hydrate.
(3) when pressure is less than 1400MPa in container, then being passed through carbon dioxide makes its pressure reach 2000MPa, weight
Multiple this operation is until chamber pressure is without being substantially reduced.
(4) stainless steel closed container is opened at -50 DEG C, carbon dioxide hydrate is taken out, by the carbon dioxide water of taking-up
Compound pulverizes into the carbon dioxide hydrate particle of four kinds of particle diameters respectively, and respectively 1. diameter is less than 2.8mm；2. diameter 2.8~
4.0mm；3. 5.6~8.0mm of diameter；4. diameter is more than 8mm, its outward appearance is similar to ice cube shape, as shown in Figure 1-2.
2nd, the preparation of the beverage containing carbon dioxide hydrate
By the carbon dioxide hydrate particle of four kinds of particle diameters of preparation be placed in refrigerator preserve (normal pressure, temperature be -15~-
10 DEG C) three weeks, time of preservation influences as shown in Figure 3 on the mass fraction of carbon dioxide hydrate particle.It can be seen by Fig. 3
Go out, the bigger easier preservation of carbon dioxide hydrate sample of particle diameter, contained carbon dioxide content is more in same time.
Embodiment 2
Example 1 prepare diameter 5.6~8.0mm carbon dioxide hydrate particles, cold drink (such as dairy ice cream and
Fruit juice ice cream) manufacture during add because it is in temperature below freezing all the time, even if hydrate is from surface
Decompose, the film that ice can be also formed on surface cover particle, continue to decompose so as to suppress carbon dioxide hydrate, eating
Used time still can keep good carbonic acid mouthfeel.
Embodiment 3
Diameter 5.6~8.0mm carbon dioxide hydrate particles prepared by embodiment 1 are chosen, in the manufacturing process of beer
It is added into, the beer containing carbon dioxide hydrate particle is made.Both it can meet that consumer wanted to alcohol and mouthfeel
Ask, again can in the form of subversive change like product single present situation.
Comparative example 1
Carbon dioxide hydrate particle is handled according to the preparation technology of presently commercially available canned soda, but due to titanium dioxide
Kohlenhydrate is not easy stabilization and preserved at normal temperatures and pressures, and general city dealer beverage is used for normal temperature preservation, and pressure is about in bottle/tank
300KPa, it is unfavorable for carbon dioxide hydrate preservation.The carbon dioxide hydrate being previously mentioned in the present invention can not so be added
Grain strengthens the mouthfeel of beverage, can only before consumption add, is drunk before it is fully decomposed.
Examples provided above is only the mode illustrated, is not considered as limiting the scope of the present invention, appoints
What technique according to the invention scheme and its inventive concept are subject to equivalent substitution or the method for change, should all cover the present invention's
Within protection domain.
Claims (4)
1. a kind of carbon dioxide hydrate is used for the application for preparing beverage, it is characterised in that：By particle diameter be 0.5~1.0cm two
Carbonoxide hydrate particle is directly appended in non-foamed beverage obtain the beverage containing carbon dioxide hydrate；Wherein：
Preserved after the carbon dioxide hydrate is added in non-foamed beverage under normal pressure and -15~-10 DEG C of temperature conditionss,
Holding time≤3 week, it is necessary to when drink；Or by the carbon dioxide hydrate under conditions of normal pressure and -15~-10 DEG C
Preserve, holding time≤3 week when drinking, it is necessary to be added in non-foamed beverage；The non-foamed beverage includes fruit
Juice, coffee, cold drink, beer or milk；The cold drink is ice cream.
2. carbon dioxide hydrate according to claim 1 is used for the application for preparing beverage, it is characterised in that：The dioxy
Change Kohlenhydrate to be made up of carbon dioxide and water, the mole ratio of carbon dioxide and water is 1：(5.75~6.25).
3. the application for being used to prepare beverage according to any described carbon dioxide hydrate of claim 1 or 2, it is characterised in that：
The carbon dioxide hydrate particle is prepared as follows：
(1) water is placed in stainless steel closed container, the temperature control of water is 0~1 DEG C；
(2) carbon dioxide is passed through stainless steel closed container, gas in container pressure is reached 2000MPa, stir simultaneously
Water in container, accelerate the generation of carbon dioxide hydrate；
(3) when pressure is less than 1400MPa in container, then being passed through carbon dioxide makes its pressure reach 2000MPa, and repeating should
Item is operated until pressure no longer reduces in container；
(4) stainless steel closed container is opened at low ambient temperatures, carbon dioxide hydrate is taken out, by the hydrated carbon dioxide of taking-up
Thing pulverizes to obtain the carbon dioxide hydrate particle.
4. carbon dioxide hydrate according to claim 3 is used for the application for preparing beverage, it is characterised in that：Step (4)
In, the low temperature environment refers to -50~-60 DEG C of temperature range.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310397768.2A CN104413513B (en) | 2013-09-03 | 2013-09-03 | A kind of carbon dioxide hydrate is used for the application for preparing beverage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310397768.2A CN104413513B (en) | 2013-09-03 | 2013-09-03 | A kind of carbon dioxide hydrate is used for the application for preparing beverage |
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| Publication Number | Publication Date |
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| CN104413513A CN104413513A (en) | 2015-03-18 |
| CN104413513B true CN104413513B (en) | 2018-02-27 |
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| CN201310397768.2A Active CN104413513B (en) | 2013-09-03 | 2013-09-03 | A kind of carbon dioxide hydrate is used for the application for preparing beverage |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112018009410B1 (en) | 2015-11-30 | 2022-09-20 | Unilever Ip Holdings B.V. | PROCESS FOR MANUFACTURING FROZEN GAS HYDRATES FOR USE IN A FROZEN CONFECTIONERY PRODUCT |
| JPWO2019124438A1 (en) * | 2017-12-22 | 2020-12-10 | キリンホールディングス株式会社 | Bubble-containing beverages using high-CO2 ice and methods for producing them |
| CN108669262A (en) * | 2018-03-26 | 2018-10-19 | 杨鸣杰 | A kind of tea beverage and preparation method thereof |
| CN109907203A (en) * | 2019-03-15 | 2019-06-21 | 常州大学 | A kind of method and apparatus for producing iced soda using hydrate |
| MX2021013827A (en) * | 2019-06-05 | 2021-12-10 | Nestle Sa | Instant coffee powder. |
-
2013
- 2013-09-03 CN CN201310397768.2A patent/CN104413513B/en active Active
Non-Patent Citations (3)
| Title |
|---|
| 二氧化碳水合物储气特性的实验研究;刘妮等;《环境工程学报》;20100331;第4卷(第3期);第621－623页 * |
| 全新饮料——"汽奶";作者不详;《兰州科技情报》;19960215;第25卷(第1期);第20页 * |
| 天然气水合物综合利用新技术;作者不详;《中国高校技术市场》;19971115;第15页 * |
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| CN104413513A (en) | 2015-03-18 |
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