CN104409569B - 三维网络结构石墨烯-银复合材料的绿色制备方法 - Google Patents
三维网络结构石墨烯-银复合材料的绿色制备方法 Download PDFInfo
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- CN104409569B CN104409569B CN201410667164.XA CN201410667164A CN104409569B CN 104409569 B CN104409569 B CN 104409569B CN 201410667164 A CN201410667164 A CN 201410667164A CN 104409569 B CN104409569 B CN 104409569B
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- graphene
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- 229910052709 silver Inorganic materials 0.000 title claims abstract description 74
- 239000004332 silver Substances 0.000 title claims abstract description 74
- 239000002131 composite material Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 111
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 105
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000010409 thin film Substances 0.000 claims abstract description 31
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 14
- 238000001069 Raman spectroscopy Methods 0.000 claims abstract description 13
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 13
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 11
- 239000001913 cellulose Substances 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- 235000000069 L-ascorbic acid Nutrition 0.000 abstract 1
- 239000002211 L-ascorbic acid Substances 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 239000010408 film Substances 0.000 description 22
- 239000001963 growth medium Substances 0.000 description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 8
- 241000233866 Fungi Species 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 235000011149 sulphuric acid Nutrition 0.000 description 6
- 239000001117 sulphuric acid Substances 0.000 description 6
- 241000191967 Staphylococcus aureus Species 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000012286 potassium permanganate Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 229910001626 barium chloride Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 235000010344 sodium nitrate Nutrition 0.000 description 4
- 239000004317 sodium nitrate Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000006142 Luria-Bertani Agar Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910021608 Silver(I) fluoride Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000008121 dextrose Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 229940071870 hydroiodic acid Drugs 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 229940043267 rhodamine b Drugs 0.000 description 2
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
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- 239000004677 Nylon Substances 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- VYXSBFYARXAAKO-WTKGSRSZSA-N chembl402140 Chemical compound Cl.C1=2C=C(C)C(NCC)=CC=2OC2=C\C(=N/CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-WTKGSRSZSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
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- 230000007812 deficiency Effects 0.000 description 1
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- 238000000502 dialysis Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
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- 239000000706 filtrate Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- -1 graphite alkenes Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
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CN201410667164.XA CN104409569B (zh) | 2014-11-20 | 2014-11-20 | 三维网络结构石墨烯-银复合材料的绿色制备方法 |
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CN201410667164.XA CN104409569B (zh) | 2014-11-20 | 2014-11-20 | 三维网络结构石墨烯-银复合材料的绿色制备方法 |
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CN104409569A CN104409569A (zh) | 2015-03-11 |
CN104409569B true CN104409569B (zh) | 2016-12-07 |
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CN105964303B (zh) * | 2016-05-13 | 2018-08-17 | 南阳师范学院 | 一种绿色合成大环化合物修饰石墨烯氧还原催化剂的制备方法 |
CN106084366A (zh) * | 2016-06-28 | 2016-11-09 | 苏州宽温电子科技有限公司 | 一种石墨烯复合材料及其制备方法 |
CN106939260A (zh) * | 2017-03-02 | 2017-07-11 | 湖北民族学院 | 一种石墨烯纳米银透明皂及其制备方法和用途 |
CN107331526B (zh) * | 2017-07-20 | 2021-05-11 | 齐鲁工业大学 | 一种可压缩石墨烯气凝胶及其超级电容器的制备方法、应用 |
CN111678908A (zh) * | 2020-06-17 | 2020-09-18 | 华中农业大学 | 石墨烯银sers复合衬底及其制备方法 |
CN112118708B (zh) * | 2020-09-10 | 2023-03-21 | 安徽工业大学 | 一种导热膜及其制备方法 |
Citations (5)
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CN102125056A (zh) * | 2011-01-10 | 2011-07-20 | 中国科学技术大学 | 一种银/石墨烯抗菌复合材料的制备方法 |
CN102136306A (zh) * | 2010-11-10 | 2011-07-27 | 西北师范大学 | Ag/石墨烯纳米导电复合材料及其制备方法 |
CN103073665A (zh) * | 2013-01-19 | 2013-05-01 | 华南理工大学 | 高强度、温度敏感的聚合物-氧化石墨烯复合水凝胶和导电石墨烯复合水凝胶及其制备方法 |
CN103334096A (zh) * | 2013-07-02 | 2013-10-02 | 江苏大学 | 一种制备纳米银-石墨烯复合薄膜的方法 |
CN103880000A (zh) * | 2014-03-07 | 2014-06-25 | 中南大学 | 一种超轻石墨烯粉体的制备方法 |
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WO2008048295A2 (en) * | 2005-11-18 | 2008-04-24 | Northwestern University | Stable dispersions of polymer-coated graphitic nanoplatelets |
US8263843B2 (en) * | 2009-11-06 | 2012-09-11 | The Boeing Company | Graphene nanoplatelet metal matrix |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN102136306A (zh) * | 2010-11-10 | 2011-07-27 | 西北师范大学 | Ag/石墨烯纳米导电复合材料及其制备方法 |
CN102125056A (zh) * | 2011-01-10 | 2011-07-20 | 中国科学技术大学 | 一种银/石墨烯抗菌复合材料的制备方法 |
CN103073665A (zh) * | 2013-01-19 | 2013-05-01 | 华南理工大学 | 高强度、温度敏感的聚合物-氧化石墨烯复合水凝胶和导电石墨烯复合水凝胶及其制备方法 |
CN103334096A (zh) * | 2013-07-02 | 2013-10-02 | 江苏大学 | 一种制备纳米银-石墨烯复合薄膜的方法 |
CN103880000A (zh) * | 2014-03-07 | 2014-06-25 | 中南大学 | 一种超轻石墨烯粉体的制备方法 |
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