CN104400170A - Aluminum alloy ultrasonic semi-solid coating brazing method - Google Patents

Aluminum alloy ultrasonic semi-solid coating brazing method Download PDF

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Publication number
CN104400170A
CN104400170A CN201410591200.9A CN201410591200A CN104400170A CN 104400170 A CN104400170 A CN 104400170A CN 201410591200 A CN201410591200 A CN 201410591200A CN 104400170 A CN104400170 A CN 104400170A
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CN
China
Prior art keywords
brazing
ultrasonic
aluminum alloy
alloy
solder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410591200.9A
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Chinese (zh)
Inventor
丁敏
于鑫业
邢文清
王文先
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Taiyuan University of Technology
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Taiyuan University of Technology
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Publication date
Application filed by Taiyuan University of Technology filed Critical Taiyuan University of Technology
Priority to CN201410591200.9A priority Critical patent/CN104400170A/en
Publication of CN104400170A publication Critical patent/CN104400170A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/20Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/06Soldering, e.g. brazing, or unsoldering making use of vibrations, e.g. supersonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/20Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • B23K1/206Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • B23K2103/10Aluminium or alloys thereof

Abstract

The invention provides an aluminum alloy ultrasonic semi-solid coating brazing method and belongs to the technical field of welding. The aluminum alloy ultrasonic semi-solid coating brazing method is characterized in that solder needed by the method is Sn-Pb-Zn-Ag-Cu solder, the chemical components of the solder comprise, by weight percentage, 90-92% of Sn-Pb eutectic alloy, 1.5-2% of Ag-Cu eutectic alloy, 6-10% of zinc element and the rest of Bi. The process comprises the following steps of polishing, cleaning, positioning, using a clamp to fix aluminum alloy, performing ultrasonic auxiliary plating, cooling and performing semi-cold pressing brazing. The minimum brazing joint cutting strength of the brazing method is 101MPa. The aluminum alloy ultrasonic semi-solid coating brazing method is particularly suitable for brazing of the large-area aluminum alloy, the technology is simple, and the brazing method can guarantee a good brazing manufacturability and a joint mechanical property and is a simple and practical low-temperature brazing technical scheme for aluminum with a good application prospect.

Description

A kind of aluminium alloy ultrasonic semisolid coating method for welding
Technical field
A kind of aluminium alloy of the present invention ultrasonic semisolid coating method for welding, belongs to welding technology field, is specifically related to the technical scheme of a kind of aluminium alloy ultrasonic semisolid coating soldering.
Background technology
Aluminium alloy has lightweight, good corrosion resistance and the characteristic such as heat-conductivity conducting is functional.More and more extensive in the application of the dual-use industrial circles such as Aeronautics and Astronautics, electronics, automobile, building materials.But because aluminum alloy surface easily generates compact oxidation layer, solder is difficult to wetting aluminum alloy surface, so the soldering of aluminium alloy is also confined on indivedual trades mark such as fine aluminium and 6063, the aluminium alloy that a large amount of intensity ranks is higher still cannot carry out soldering.On the other hand, due to product lightweight and demand attractive in appearance, the demand of aluminium alloy being carried out to soldering is more and more urgent, only the soldering of fine aluminium and the rank aluminium alloys such as 6063 can not meet structural strength, rigidity and technical requirement attractive in appearance, and therefore research and development are applicable to the welding method of aluminium alloy brazing is solve one of key technology that aluminium alloy element manufacture need solve.
Just current, aluminium alloy brazing method mainly contains following several, (1) braze welding, and braze welding utilizes more than 450 degree solder brazing aluminium alloys.This kind of method is because temperature is for a long time more than 450 degree, and aluminium alloy mother metal can soften.(2) solder method, braze welding utilizes less than 450 degree solder brazing aluminium alloys.This kind of method, because weld strength is lower, is not suitable for large-scale promotion.(3) laser assisted method for brazing, the method is on the basis of existing method for welding, assist laser thermal source, improves solder wetting, thus improves wetting effect, but the method apparatus expensive.(4) ultrasonic wave added method for brazing, the method is on the basis of existing method for welding, assist ultrasonic vibration, improves solder wetting, thus improves wetting effect.Whether directly contact with solder according to ultrasonic, the method has ultrasonic immersed solder method and ultrasonic wave added vibrating and soldering method.The bonding area of aluminium alloy is mainly determined by the volume of ultrasonic device, and the method mainly can not weld large-area aluminium alloy, and institute's bonding strength is not high, is generally about 30MPa.Therefore, researching and developing a kind of aluminium alloy brazing method with excellent manufacturability and joint mechanical property is Al and Alalloy connecting material field technical problem urgently to be resolved hurrily.
Through finding the literature search of prior art, " solder of LD31 aluminium alloy electric brush plating SnPb brazing filler metal alloy " that Zhao Zhenqing, Wang Chunqing, Du Miao and Yi Huang etc. deliver on " welding journal " the 7th phase in 2005, propose in this article to adopt in brush nickel barrier layer, LD31 surface, copper modified layer, the connection of LD31 aluminium alloy is converted into the connection of copper, directly soldering is carried out at the surface electrical brush plating SnPb solder of copper plate, this research achieves the low temperature solder of aluminium alloy, and the shearing strength of joint can reach 20MPa.Its deficiency is: needed to carry out twice electroplating technology before brazed aluminum alloy, technical process is more loaded down with trivial details." Joining of 6061 aluminium ultrasonic soldered of Sn – Pb – Zn alloys " that article dingmin delivers on " Materials Science and Technology ", this article proposes to adopt ultrasonic wave added immersed solder method welding aluminum alloy, and maximum intensity is 54.36MPa.Its deficiency is: need workpiece all to immerse, solder is comparatively wasted, and intensity is slightly low.Patent CN101284323B disclosed " titanium alloy and aluminium alloy or aluminum base compound material ultrasound precoating and soldering method ", aluminium alloy or aluminum base compound material ultrasound precoating and soldering method are proposed, technique is more complicated, and temperature is higher, need to polish to the solder layer that titanium alloy sheet and aluminium alloy or aluminum matrix composite plate apply respectively, solder layer thickness after polishing is evenly, smoothly, strict to pre-coated solder thickness requirement, and soldering Front-coating mirror needs cool to room temperature.
Summary of the invention
The object of a kind of aluminium alloy of the present invention ultrasonic semisolid coating method for welding technical scheme is: in order to solve manufacturability deficiency and problem demanding prompt solution in above-mentioned prior art, thus provide a kind of good brazing manufacturability and joint mechanical property of ensureing, simple and practical aluminium alloy ultrasonic semisolid coating soldering tech scheme.
A kind of aluminium alloy of the present invention ultrasonic semisolid coating method for welding, it is characterized in that a kind of good brazing manufacturability and joint mechanical property of ensureing, simple and practical aluminium alloy ultrasonic semisolid coating method for welding, its concrete process step is:
1) first polish to 6061 aluminium alloys that wish of the present invention will carry out soldering, then clean, expose metallic luster, its polishing time is: its scavenging period of 30-60s is: 30-60s;
2) adopt conventional clamp fixing through 1) positioning for 6061 aluminium alloys that will carry out soldering of processing;
3) be SnPb eutectic alloy 90 ~ 92%, AgCu eutectic alloy 1.5 ~ 2%, Zn element 6 ~ 10% by weight percentage by required chemical composition in atmosphere, surplus is the Sn-Pb-Zn-Ag-Cu brazing filler metal melts of Bi, and be warming up to 270-300 DEG C for subsequent use;
4) ultrasonic wave added plating: open ultrasonic, energy is 300-900W, simultaneously 2) the aluminum alloy surface plating 3 of locating) solder for subsequent use, its braze surface Plating times is 30-60S;
5) by 4) after aluminium alloy that plating is good is cooled to 180-210 DEG C, make it be semi-solid state, then under semisolid, apply pressure 0.1-0.5MPa, the time of exerting pressure is 10-15S, completes soldering.
A kind of aluminium alloy of the present invention ultrasonic semisolid coating method for welding, its advantage is: adopt the most I of the soldered fitting shear strength of method for welding of the present invention to reach 101MPa.Method for welding of the present invention is particularly suitable for the soldering of large area aluminium alloy, and technique is simple, and intensity is high, has a good application prospect.
Accompanying drawing explanation
Typical case's macroscopic view metallograph of joint prepared by Fig. 1 the inventive method
Detailed description of the invention
Elaborate to embodiments of the invention below, the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
The solder that the present invention adopts is Sn-Pb-Zn-Ag-Cu solder, and the chemical composition of this solder is SnPb eutectic alloy 90 ~ 92%, AgCu eutectic alloy 1.5 ~ 2%, Zn element 6 ~ 10% by weight percentage, and surplus is Bi.
The aluminium alloy adopted in the embodiment of the present invention is 6061 aluminium alloys.
Embodiment 1:
Aluminum alloy surface time to be brazed of polishing is 30s, and cleaning 30s, exposes metallic luster.In atmosphere brazing filler metal melts is warming up to 280 DEG C, open ultrasonic, energy is 600W, braze surface Plating times is 40S.After the aluminium alloy that plating is good is cooled to 200 DEG C, apply pressure 0.3MPa, the time of exerting pressure is 10S.
At room temperature carry out shear strength test by test, test result shear strength is 101MPa.
Embodiment 2:
Aluminum alloy surface time to be brazed of polishing is 45s, and cleaning 45s, exposes metallic luster.In atmosphere brazing filler metal melts is warming up to 270 DEG C, open ultrasonic, energy is 300W, braze surface Plating times is 30S.After the aluminium alloy that plating is good is cooled to 180 DEG C, apply pressure 0.1MPa, the time of exerting pressure is 10S.
At room temperature carry out shear strength test by test, test result shear strength is 105MPa.
Embodiment 3:
Aluminum alloy surface time to be brazed of polishing is 45s, and cleaning 60s, exposes metallic luster.In atmosphere brazing filler metal melts is warming up to 300 DEG C, open ultrasonic, energy is 900W, braze surface Plating times is 60S.After the aluminium alloy that plating is good is cooled to 210 DEG C, apply pressure 0.5MPa, the time of exerting pressure is 15S.
At room temperature carry out shear strength test by test, test result shear strength is 109MPa.

Claims (1)

1. an aluminium alloy ultrasonic semisolid coating method for welding, it is characterized in that a kind of good brazing manufacturability and joint mechanical property of ensureing, simple and practical aluminium low temperature brazing aluminium alloy ultrasonic semisolid coating method for welding, its concrete process step is:
1) first polish to 6061 aluminium alloys that wish of the present invention will carry out soldering, then clean, expose metallic luster, its polishing time is: its scavenging period of 30-60s is: 30-60s;
2) adopt conventional clamp fixing through 1) positioning for 6061 aluminium alloys that will carry out soldering of processing;
3) be SnPb eutectic alloy 90 ~ 92%, AgCu eutectic alloy 1.5 ~ 2%, Zn element 6 ~ 10% by weight percentage by required chemical composition in atmosphere, surplus is the Sn-Pb-Zn-Ag-Cu brazing filler metal melts of Bi, and be warming up to 270-300 DEG C for subsequent use;
4) ultrasonic wave added plating: open ultrasonic, energy is 300-900W, simultaneously 2) the aluminum alloy surface plating 3 of locating) solder for subsequent use, its braze surface Plating times is 30-60S;
5) by 4) after aluminium alloy that plating is good is cooled to 180-210 DEG C, make it be semi-solid state, then under semisolid, apply pressure 0.1-0.5MPa, the time of exerting pressure is 10-15S, completes soldering.
CN201410591200.9A 2014-10-29 2014-10-29 Aluminum alloy ultrasonic semi-solid coating brazing method Pending CN104400170A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105598541A (en) * 2016-02-23 2016-05-25 深圳市昌龙盛机电技术有限公司 Method for plating surfaces of Ni-Cr alloy wires with zinc at low temperature
CN105603159A (en) * 2016-01-21 2016-05-25 江苏科技大学 Ultrasonic-assisted surface engineering treatment device in furnace and ultrasonic-assisted surface engineering treatment method
CN105643040A (en) * 2016-03-23 2016-06-08 徐宏达 Brazing method for aluminum and aluminum alloy

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040016793A1 (en) * 2002-07-24 2004-01-29 Zhibo Zhao Method for direct application of flux to a brazing surface
CN101234446A (en) * 2008-03-06 2008-08-06 上海交通大学 Aluminum alloy low temperature brazing method based on ultrasonic coating
CN101284323A (en) * 2008-05-09 2008-10-15 哈尔滨工业大学 Titanium alloy and aluminum alloy or aluminum base compound material ultrasound precoating and soldering method
CN101474699A (en) * 2009-01-19 2009-07-08 哈尔滨工业大学 Ultrasonic soldering method of aluminum or aluminum alloy
CN102179588A (en) * 2011-04-29 2011-09-14 重庆理工大学 Method for coating brazing filler metal on surface of aluminum alloy and aluminum compound material by stirring at semi-solid state
CN102266994A (en) * 2011-07-20 2011-12-07 重庆理工大学 Heterogeneous semi-solid brazing method for aluminum alloy and magnesium alloy under assistance of external vibration energy
CN102699562A (en) * 2012-06-11 2012-10-03 太原理工大学 Aluminum low-temperature soft solder and manufacturing method thereof
CN103240924A (en) * 2013-04-17 2013-08-14 太原理工大学 Magnesium alloy honeycomb structure material and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040016793A1 (en) * 2002-07-24 2004-01-29 Zhibo Zhao Method for direct application of flux to a brazing surface
CN101234446A (en) * 2008-03-06 2008-08-06 上海交通大学 Aluminum alloy low temperature brazing method based on ultrasonic coating
CN101284323A (en) * 2008-05-09 2008-10-15 哈尔滨工业大学 Titanium alloy and aluminum alloy or aluminum base compound material ultrasound precoating and soldering method
CN101474699A (en) * 2009-01-19 2009-07-08 哈尔滨工业大学 Ultrasonic soldering method of aluminum or aluminum alloy
CN102179588A (en) * 2011-04-29 2011-09-14 重庆理工大学 Method for coating brazing filler metal on surface of aluminum alloy and aluminum compound material by stirring at semi-solid state
CN102266994A (en) * 2011-07-20 2011-12-07 重庆理工大学 Heterogeneous semi-solid brazing method for aluminum alloy and magnesium alloy under assistance of external vibration energy
CN102699562A (en) * 2012-06-11 2012-10-03 太原理工大学 Aluminum low-temperature soft solder and manufacturing method thereof
CN103240924A (en) * 2013-04-17 2013-08-14 太原理工大学 Magnesium alloy honeycomb structure material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105603159A (en) * 2016-01-21 2016-05-25 江苏科技大学 Ultrasonic-assisted surface engineering treatment device in furnace and ultrasonic-assisted surface engineering treatment method
CN105598541A (en) * 2016-02-23 2016-05-25 深圳市昌龙盛机电技术有限公司 Method for plating surfaces of Ni-Cr alloy wires with zinc at low temperature
CN105598541B (en) * 2016-02-23 2018-03-30 深圳市昌龙盛机电技术有限公司 A kind of tin plating method of Ni Cr B alloy wire surface low-temperatures
CN105643040A (en) * 2016-03-23 2016-06-08 徐宏达 Brazing method for aluminum and aluminum alloy

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Application publication date: 20150311