CN104387206B - A kind of preparation method of silico-calcium potassium magnesium soil conditioner - Google Patents

A kind of preparation method of silico-calcium potassium magnesium soil conditioner Download PDF

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Publication number
CN104387206B
CN104387206B CN201410605265.4A CN201410605265A CN104387206B CN 104387206 B CN104387206 B CN 104387206B CN 201410605265 A CN201410605265 A CN 201410605265A CN 104387206 B CN104387206 B CN 104387206B
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China
Prior art keywords
silico
soil conditioner
raw material
potassium
calcium
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Expired - Fee Related
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CN201410605265.4A
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CN104387206A (en
Inventor
王焱
张路军
杨永新
姚金海
李少云
王奎英
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HEBEI ZHONGRUI AGRICULTURAL SCIENCE AND TECHNOLOGY Co Ltd
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HEBEI ZHONGRUI AGRICULTURAL SCIENCE AND TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

A kind of preparation method of silico-calcium potassium magnesium soil conditioner, comprises the following steps:A, raw material prepare;B, grinding;C, calcining;D, water quenching;E, crushing;F, pelletize;G, drying.This preparation method produces silicon-calcium-potafertilizer fertilizer using potassium-bearing shale, therein potassium is not only taken full advantage of as potash fertilizer, also therein silicon oxide output excellent siliceous fertilizer is taken full advantage of, the limestone and dolomite output calcareous fertilisers and excellent soil conditioner that in production add also is made full use of, raw material used is fully used and is converted into fertilizer, and the acidifying of soil, alkalization, hardened after applying, is not resulted in, the marketing quality of crops and product quality are obviously improved, and nutritive value is higher.

Description

A kind of preparation method of silico-calcium potassium magnesium soil conditioner
Technical field
The present invention relates to a kind of preparation method of silico-calcium potassium magnesium soil conditioner.
Background technology
Plant is carried out in proportion to the absorption of nitrogen, phosphorus, potassium, and three mutually promotes, it is impossible to substituted mutually.Long-term with Come, due to the outstanding role played to higher yield of crops by chemical fertilizer, people are using applying important handss of the chemical fertilizer as higher yield of crops Section, and start a large amount of uses, the generation of the hardened and fertilizer damage of soil is thereby resulted in, various organic matters and trace element in soil A large amount of disappearances so that chemical fertilizer effect is gradually lowered.
103739341 A of patent CN discloses " a kind of production technology of silicon-calcium-potafertilizer fertilizer and equipment ", and its technical process is: Broken, grinding, calcined by rotary kiln, cooler are passed through with water-insoluble potassium ore deposit and limestone or dolomite as raw material, sequentially cold But, crush and grinding, obtain silicon-calcium-potafertilizer fertilizer;Wherein, in calcined by rotary kiln operation, burning zone temperature is 1150~1400 DEG C, material It is 20~60 minutes in kiln residence time, material is preheated before calcined by rotary kiln operation after powder-grinding process and divided Solution.
Although 103739341 A of patent CN is provided adopt with water-insoluble potassium ore deposit and limestone or dolomite as original Material prepares silicon-calcium-potafertilizer fertilizer, is utilized the shale of sand containing potassium, but the conversion ratio of effectively potassium is very low so that greatly Effectively potassium can not be converted and cause the wasting of resources.
Patent ZL92111690.X discloses " a kind of production method of potash-lime fertilizer ", and its technical process is:Potassium ore powder and Agstone or dolomite dusts by weight 1:0.7~1:1.4 ratio is mixed evenly to prepare bulk, then is placed on annular kiln, tunnel cave Or calcine at 1150~1350 DEG C in down-draft kiln, sinter is size-reduced to form potash-lime fertilizer product or silicon-magnesium potash fertilizer product.
Calcined using tunnel cave more than the production of silicon-calcium-potafertilizer fertilizer at present, i.e., first potassium ore and limestone are crushed, by one After certainty ratio dispensing again through grinding, add water briquet, by being manually attached on kiln car, the kiln car for installing is advanced tunnel cave;Logical After crossing certain temperature retention time, the raw material of silico-calcium potassium are cooked, and after silicon-calcium-potafertilizer fertilizer is cooled, kiln discharge enters semifinished product warehouse;Again by semi-finished product The silicon-calcium-potafertilizer fertilizer of briquetting carries out broken and grinding, you can obtains finished product fertilizer and enters feed bin, entering back into packer carries out finished product packing Warehouse-in.This method complex operation, needs man-handling of materials to waste time and energy, although effectively potassium conversion ratio increases, but calcining Uneven, have a strong impact on yield and quality.
Content of the invention
The present invention is solution defect of the prior art, there is provided a kind of preparation method of silico-calcium potassium magnesium soil conditioner, Effect that aggregate balancing adjusts nutrient distribution is played, and there is improved soil performance, improve soil alkali, strengthen crop tolerance to salt The effect of property, does not result in the loss of soil compaction and nutritional labeling.
The present invention is to realize that the technical scheme that its purpose is adopted is:
A kind of preparation method of silico-calcium potassium magnesium soil conditioner, comprises the following steps:
A, raw material prepare:
By weight, including potassium-bearing shale 60%-70%, limestone 15%-20%, dolomite 15%-20%;
B, grinding:
The raw material ball mill grinding that will prepare in step A, is ground to 200 mesh;
C, calcining:
The raw material that step B is ground to 200 mesh is placed in rotary kiln, is calcined at 1160-1240 DEG C, obtained ripe Material, controls calcination time for 40-50min during calcining, calcining pressure is 1 atmospheric pressure;
D, water quenching:
The grog obtained after step C is calcined carries out water quenching by conveyer belt transmission immediately, obtains solid product, during water quenching Temperature is adopted for 20 DEG C of Water spray, hydraulic pressure is 1.5 atmospheric pressure, the transfer rate of conveyer belt is controlled in 60-80cm/s;
E, crushing:
The solid product that step D is obtained is crushed to 300 mesh by pulverizer, obtains powder;
F, pelletize:
The powder that step E is obtained obtains graininess silico-calcium potassium magnesia earth tune by carrying out pelletize to roller Squeezinggranulator Reason agent;
G, drying:
The graininess silico-calcium potassium magnesium soil conditioner that step F is obtained is placed in rotating drum type drying machine is dried, and is obtained Silico-calcium potassium magnesium soil conditioner, drying time are 10min, and drying temperature is 200-300 DEG C.
In step A, raw material prepares, by weight, including potassium-bearing shale 60%, limestone 20%, dolomite 20%.
In step A, raw material prepares, by weight, including potassium-bearing shale 65%, limestone 17.5%, dolomite 17.5%.
In step A, raw material prepares, by weight, including potassium-bearing shale 70%, limestone 15%, dolomite 15%.
The invention has the beneficial effects as follows:A kind of preparation method of silico-calcium potassium magnesium soil conditioner, simple to operation, grind it High-temperature calcination being carried out directly afterwards, not preheated, directly allow raw material to enter high-temperature region, the Hubeiwan for contributing to raw material quickly divides Solution, improves the conversion ratio of silicon potassium magnesium.And prior art can reduce the heat consumption of production line in preheating principle, but can make simultaneously Raw material thermostability is improved, and Hubeiwan decomposes does not have drastically heat resolve abundant and quick, and therefore, necessary production line heat consumption is Need, this is related to the quality and performance of final products.
This preparation method carries out water quenching after firing, strictly must control to spray the transfer rate with conveyer belt during water quenching, Contribute to the activity transformation for increasing effective silicon, potassium, improve conversion ratio and the utilization rate of effective silicon and effective potassium.
This preparation method produces silicon-calcium-potafertilizer fertilizer using potassium-bearing shale, not only takes full advantage of potassium therein as potash fertilizer, The excellent siliceous fertilizer of silicon oxide output therein is taken full advantage of, also makes full use of the limestone added in production and dolomite to produce Calcareous fertilisers and excellent soil conditioner are gone out, raw material used is fully used and is converted into fertilizer.
Using silico-calcium potassium magnesium soil conditioner obtained in this preparation method, water solublity is determined up to 21% through test, pH value 9- 10, alkalescence, with nontoxic, odorless, non-corrosiveness, does not lump, not hardened soil, and fertilizer efficiency persistently, is not evaporated, do not oozed down, no The characteristic being easy to run off.In agricultural production, it is of great benefit to improving Soil structure, increasing the effective nutritional labeling of soil after administration, The acidifying of soil, alkalization, hardened is not resulted in after use, as the fertile raw material itself is nutritious, fertilizer efficiency permanent, to soil The inhibition of nutritional deficiency disease is clearly.
The silico-calcium potassium magnesium soil conditioner prepared using this preparation method is also had the effect that:
(1) outer except effective silicon element is improved to crop, also contain in raw material substantial amounts of calcium, potassium and phosphorus, magnesium, zinc, molybdenum, manganese, Micro-nutrient composition in ferrum, boron etc., can improve the comprehensive nutrient of crop and comprehensive fertilizer efficiency effect.
(2) pollen of crops vigor can be strengthened:Test shows that silico-calcium potassium applied in good time by the melon and fruit in florescence, such as Fructus Lycopersici esculenti Magnesium soil conditioner effectively improves their setting ratio, and improves flavor quality, and sugar content improves 2 sugarinesses.
(3) quality of agricultural product can effectively be improved so as to excellent in color.Commodity value is improved not only, is conducive to Healthy health care, meanwhile, there are the benefits such as increase product storage tolerance, resistance to transport.
(4) can be with improved soil:It is both fertilizer supply crop nutrition content, again can be as soil conditioner, with improvement Soil function, improves soil alkali, strengthens salt tolerance of crop, promotes the decomposition and conversion of soil with organic matter, and suppresses soil Earth pathogen transmission etc..Meanwhile, it makes the surface of crops form silicified cell, can accordingly mitigate pest and disease damage, the pollution of crops The invasion and attack such as noxious substance, pesticide are polluted.
Specific embodiment
The present invention is solution defect of the prior art, there is provided a kind of preparation method of silico-calcium potassium magnesium soil conditioner, Effect that aggregate balancing adjusts nutrient distribution is played, and there is improved soil performance, improve soil alkali, strengthen crop tolerance to salt Property effect, do not result in the loss of soil compaction and nutritional labeling, the present invention made further with reference to specific embodiment Explanation.
Embodiment 1
A, raw material prepare:
By weight, including potassium-bearing shale 60%, limestone 20%, dolomite 20%;
B, grinding:
The raw material ball mill grinding that will prepare in step A, is ground to 200 mesh;
C, calcining:
The raw material that step B is ground to 200 mesh is placed in rotary kiln, is calcined at 1200 DEG C, obtain grog, calcined When control calcination time for 45min, calcining pressure is 1 atmospheric pressure;
D, water quenching:
The grog obtained after step C is calcined carries out water quenching by conveyer belt transmission immediately, obtains solid product, during water quenching Using 20 DEG C of Water spray, hydraulic pressure is 1.5 atmospheric pressure, and the transfer rate control of conveyer belt is in 60-80cm/s;
E, crushing:
The solid intermediate product that step D is obtained is crushed to 300 mesh by pulverizer, obtains powder;
F, pelletize:
The powder that step E is obtained obtains graininess silico-calcium potassium magnesia earth tune by carrying out pelletize to roller Squeezinggranulator Reason agent;
G, drying:
The graininess silico-calcium potassium magnesium soil conditioner that step F is obtained is placed in rotating drum type drying machine is dried, and is obtained Silico-calcium potassium magnesium soil conditioner, drying time are 10min, and drying temperature is 200-300 DEG C.
Embodiment 2
In step A, raw material prepares as different from Example 1, by weight, including potassium-bearing shale 65%, limestone 17.5%, dolomite 17.5%.In step C calcining heat be 1160 DEG C, calcination time be 50min.
Embodiment 3
In step A, raw material prepares as different from Example 1, by weight, including potassium-bearing shale 70%, limestone 15%, dolomite 15%.In step C calcining heat be 1240 DEG C, calcination time be 40min.
The product analyses and application effect of the present invention are shown in Table 1- tables 4:
Potassium in 1 potassium-bearing shale of table is converted into the conversion ratio of effective potassium
Potassium in 2 potassium-bearing shale of table is converted into the conversion ratio comparing result of effective potassium
By Tables 1 and 2 can be apparent show, the potassium in technical scheme potassium-bearing shale is converted into effectively The high conversion rate of potassium, can reach more than 98.6%, and the conversion ratio of potassium is obviously improved, hence it is evident that higher than prior art.
Impact effect of 3 present invention of table to Fructus Lycopersici esculenti
Impact effect of 4 present invention of table to Fructus Vitis viniferae
By table 3 and table 4, we easily can obtain, silico-calcium potassium magnesia earth obtained in the preparation method of the present invention Conditioner is obviously improved to the quality of crops, and nutritive value is higher, can be seen that result number from the application effect to Fructus Lycopersici esculenti Increase, i.e., fruiting rate is obviously improved, every mu of average product may be up to 8134.1kg, at least increase production than applying prior art 17.16%;The Soluble adhesion molecule of Fructus Vitis viniferae, sugar/acid are all higher than the application effect of prior art, and the system for applying the present invention is described Obtained in Preparation Method, silico-calcium potassium magnesium soil conditioner improves the quality of grape fruit, and every mu of average product may be up to 5966kg, at least increases production 8.57% than applying prior art.

Claims (4)

1. a kind of preparation method of silico-calcium potassium magnesium soil conditioner, it is characterised in that:Comprise the following steps:
A, raw material prepare:
By weight, including potassium-bearing shale 60%-70%, limestone 15%-20%, dolomite 15%-20%;
B, grinding:
The raw material ball mill grinding that will prepare in step A, is ground to 200 mesh;
C, calcining:
The raw material that step B is ground to 200 mesh is placed in rotary kiln, is calcined at 1160-1240 DEG C, is obtained grog, forged Calcination time is controlled during burning for 40-50min, and calcining pressure is 1 atmospheric pressure;
D, water quenching:
The grog obtained after step C is calcined carries out water quenching by conveyer belt transmission immediately, obtains solid product, adopts during water quenching Temperature is 20 DEG C of Water spray, and hydraulic pressure is 1.5 atmospheric pressure, and the transfer rate control of conveyer belt is in 60-80cm/s;
E, crushing:
The solid product that step D is obtained is crushed to 300 mesh by pulverizer, obtains powder;
F, pelletize:
The powder that step E is obtained obtains graininess silico-calcium potassium magnesium soil conditioner by carrying out pelletize to roller Squeezinggranulator;
G, drying:
The graininess silico-calcium potassium magnesium soil conditioner that step F is obtained is placed in rotating drum type drying machine is dried, and obtains silico-calcium Potassium magnesium soil conditioner, drying time are 10min, and drying temperature is 200-300 DEG C.
2. the preparation method of a kind of silico-calcium potassium magnesium soil conditioner according to claim 1, it is characterised in that:In step A Raw material prepares, by weight, including potassium-bearing shale 60%, limestone 20%, dolomite 20%.
3. the preparation method of a kind of silico-calcium potassium magnesium soil conditioner according to claim 1, it is characterised in that:In step A Raw material prepares, by weight, including potassium-bearing shale 65%, limestone 17.5%, dolomite 17.5%.
4. the preparation method of a kind of silico-calcium potassium magnesium soil conditioner according to claim 1, it is characterised in that:In step A Raw material prepares, by weight, including potassium-bearing shale 70%, limestone 15%, dolomite 15%.
CN201410605265.4A 2014-10-31 2014-10-31 A kind of preparation method of silico-calcium potassium magnesium soil conditioner Expired - Fee Related CN104387206B (en)

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CN106365899B (en) * 2016-08-27 2019-08-06 中南民族大学 A kind of method that industrial residue prepares siliceous fertilizer
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CN107586228A (en) * 2017-10-18 2018-01-16 山西富邦肥业有限公司 A kind of method for producing the acidic soil conditioner rich in silico-calcium magnesium-potassium nutritional ingredient
CN108314578A (en) * 2018-02-28 2018-07-24 河北百禾丰化肥有限公司 One kind is rich in silico-calcium potassium magnesium biological organic type soil conditioner and preparation method thereof
CN108558506A (en) * 2018-05-17 2018-09-21 中材鼎原生态肥业有限公司 A kind of preparation method for producing potassium calcium silicon magnesium fertilizer calcining fluxing agent
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CN113150787A (en) * 2021-03-24 2021-07-23 河南农业大学 Silicon-calcium-magnesium fertilizer soil conditioner and preparation method and application thereof
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CN115745686A (en) * 2022-11-08 2023-03-07 方城县华裕肥料有限公司 Special fertilizer for improving quality and increasing yield of tobacco leaves
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