CN1042634C - 含羟基和/或巯基基团的膦酰基羧酸的氟化羧酸酯类及其制备方法和用途 - Google Patents
含羟基和/或巯基基团的膦酰基羧酸的氟化羧酸酯类及其制备方法和用途 Download PDFInfo
- Publication number
- CN1042634C CN1042634C CN94100611A CN94100611A CN1042634C CN 1042634 C CN1042634 C CN 1042634C CN 94100611 A CN94100611 A CN 94100611A CN 94100611 A CN94100611 A CN 94100611A CN 1042634 C CN1042634 C CN 1042634C
- Authority
- CN
- China
- Prior art keywords
- phosphono
- group
- carbon atom
- ester
- straight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title claims abstract description 31
- 150000001733 carboxylic acid esters Chemical class 0.000 title claims abstract description 24
- 125000003396 thiol group Chemical group [H]S* 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 7
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- MEUIIHOXOWVKNP-UHFFFAOYSA-N phosphanylformic acid Chemical class OC(P)=O MEUIIHOXOWVKNP-UHFFFAOYSA-N 0.000 title abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical class OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 claims description 15
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 230000032050 esterification Effects 0.000 claims description 6
- 238000005886 esterification reaction Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- -1 synthon Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 125000001118 alkylidene group Chemical group 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 239000010985 leather Substances 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 12
- 239000000126 substance Substances 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- 238000001308 synthesis method Methods 0.000 claims 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 150000001721 carbon Chemical group 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 10
- 238000013019 agitation Methods 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical group [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 6
- 239000004519 grease Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000024287 Areas Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
- D06M13/29—Phosphonic or phosphonous acids or derivatives thereof containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4300800.3 | 1993-01-14 | ||
| DE4300800A DE4300800C2 (de) | 1993-01-14 | 1993-01-14 | Hydroxy- und/oder mercaptogruppenhaltige fluorierte Carbonsäureester von Phosphono- und Phosphinocarbonsäuren, ein Verfahren zu ihrer Herstellung sowie deren Verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1096788A CN1096788A (zh) | 1994-12-28 |
| CN1042634C true CN1042634C (zh) | 1999-03-24 |
Family
ID=6478182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94100611A Expired - Fee Related CN1042634C (zh) | 1993-01-14 | 1994-01-14 | 含羟基和/或巯基基团的膦酰基羧酸的氟化羧酸酯类及其制备方法和用途 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5424474A (OSRAM) |
| EP (1) | EP0606831B1 (OSRAM) |
| JP (1) | JP3310439B2 (OSRAM) |
| KR (1) | KR940018390A (OSRAM) |
| CN (1) | CN1042634C (OSRAM) |
| CA (1) | CA2113239A1 (OSRAM) |
| DE (2) | DE4300800C2 (OSRAM) |
| ES (1) | ES2133422T3 (OSRAM) |
| TW (1) | TW271447B (OSRAM) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6646088B2 (en) | 2000-08-16 | 2003-11-11 | 3M Innovative Properties Company | Urethane-based stain-release coatings |
| DE10101190A1 (de) * | 2001-01-12 | 2002-08-01 | Clariant Gmbh | Verwendung einer Pulver-Zusammensetzung zur Hydrophobierung von Baustoffmassen |
| US6803109B2 (en) | 2001-03-09 | 2004-10-12 | 3M Innovative Properties Company | Water-and oil-repellency imparting urethane oligomers comprising perfluoroalkyl moieties |
| US6753380B2 (en) | 2001-03-09 | 2004-06-22 | 3M Innovative Properties Company | Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties |
| US6890360B2 (en) | 2001-12-17 | 2005-05-10 | 3M Innovative Properties Company | Fluorochemical urethane composition for treatment of fibrous substrates |
| US20040147188A1 (en) * | 2003-01-28 | 2004-07-29 | 3M Innovative Properties Company | Fluorochemical urethane composition for treatment of fibrous substrates |
| US20070014927A1 (en) * | 2005-07-15 | 2007-01-18 | Buckanin Richard S | Fluorochemical urethane composition for treatment of fibrous substrates |
| US7459186B2 (en) | 2005-08-05 | 2008-12-02 | Wacker Chemical Corporation | Masonry sealing compositions comprising semi-crystalline ethylene-vinyl acetate polymer emulsions |
| EP2155830A1 (en) * | 2007-05-23 | 2010-02-24 | 3M Innovative Properties Company | Aqueous compositions of fluorinated surfactants and methods of using the same |
| US8476385B2 (en) * | 2007-06-06 | 2013-07-02 | 3M Innovative Properties Company | Fluorinated ether compositions and methods of using the same |
| JP2010530014A (ja) | 2007-06-06 | 2010-09-02 | スリーエム イノベイティブ プロパティズ カンパニー | フッ素化組成物及びそれから製造される表面処理 |
| WO2008154421A1 (en) | 2007-06-08 | 2008-12-18 | 3M Innovative Properties Company | Blends of fluoroalkyl-containing ester oligomers with polydicarbodiimide(s) |
| US20080306238A1 (en) * | 2007-06-08 | 2008-12-11 | 3M Innovative Properties Company | Water- and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties |
| JP2011528659A (ja) * | 2008-07-18 | 2011-11-24 | スリーエム イノベイティブ プロパティズ カンパニー | フッ素化エーテル化合物及びその使用方法 |
| US20110232530A1 (en) * | 2008-11-25 | 2011-09-29 | Dams Rudolf J | Fluorinated ether urethanes and methods of using the same |
| WO2010080473A1 (en) | 2008-12-18 | 2010-07-15 | 3M Innovative Properties Company | Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions |
| US9057012B2 (en) | 2008-12-18 | 2015-06-16 | 3M Innovative Properties Company | Method of contacting hydrocarbon-bearing formations with fluorinated phosphate and phosphonate compositions |
| CN117004122A (zh) * | 2023-09-04 | 2023-11-07 | 吴江市拓研电子材料有限公司 | 一种耐高温耐油铁氟龙扎带及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2424243A1 (de) * | 1974-05-18 | 1975-11-27 | Bayer Ag | Perfluoralkansulfonamidoalkanphosphonsaeure- bzw. -phosphinsaeurederivate |
| DE2439281A1 (de) * | 1974-08-16 | 1976-02-26 | Henkel & Cie Gmbh | Beta-trifluormethyl-beta-phosphonobuttersaeure und derivate |
| US4824886A (en) * | 1986-02-22 | 1989-04-25 | Bayer Aktiengesellschaft | 2-phosphono-butane-1,2,4,-tricarboxylic acid emulsifier derivatives |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4293441A (en) | 1979-03-12 | 1981-10-06 | Minnesota Mining And Manufacturing Company | Corrosion inhibiting heat transfer liquid |
| US4602092A (en) * | 1983-09-19 | 1986-07-22 | E. R. Squibb & Sons, Inc. | Method for making phosphinic acid intermediates |
-
1993
- 1993-01-14 DE DE4300800A patent/DE4300800C2/de not_active Expired - Fee Related
- 1993-12-17 TW TW082110701A patent/TW271447B/zh active
- 1993-12-23 US US08/172,274 patent/US5424474A/en not_active Expired - Fee Related
-
1994
- 1994-01-03 EP EP94100003A patent/EP0606831B1/de not_active Expired - Lifetime
- 1994-01-03 DE DE59408219T patent/DE59408219D1/de not_active Expired - Fee Related
- 1994-01-03 ES ES94100003T patent/ES2133422T3/es not_active Expired - Lifetime
- 1994-01-10 JP JP01205594A patent/JP3310439B2/ja not_active Expired - Fee Related
- 1994-01-11 CA CA002113239A patent/CA2113239A1/en not_active Abandoned
- 1994-01-13 KR KR1019940000456A patent/KR940018390A/ko not_active Ceased
- 1994-01-14 CN CN94100611A patent/CN1042634C/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2424243A1 (de) * | 1974-05-18 | 1975-11-27 | Bayer Ag | Perfluoralkansulfonamidoalkanphosphonsaeure- bzw. -phosphinsaeurederivate |
| DE2439281A1 (de) * | 1974-08-16 | 1976-02-26 | Henkel & Cie Gmbh | Beta-trifluormethyl-beta-phosphonobuttersaeure und derivate |
| US4824886A (en) * | 1986-02-22 | 1989-04-25 | Bayer Aktiengesellschaft | 2-phosphono-butane-1,2,4,-tricarboxylic acid emulsifier derivatives |
Also Published As
| Publication number | Publication date |
|---|---|
| TW271447B (OSRAM) | 1996-03-01 |
| JP3310439B2 (ja) | 2002-08-05 |
| KR940018390A (ko) | 1994-08-16 |
| EP0606831B1 (de) | 1999-05-12 |
| US5424474A (en) | 1995-06-13 |
| EP0606831A1 (de) | 1994-07-20 |
| CN1096788A (zh) | 1994-12-28 |
| DE4300800C2 (de) | 1996-09-19 |
| DE59408219D1 (de) | 1999-06-17 |
| JPH06279469A (ja) | 1994-10-04 |
| ES2133422T3 (es) | 1999-09-16 |
| CA2113239A1 (en) | 1994-07-15 |
| DE4300800A1 (de) | 1994-07-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |