CN104247041A - 氟掺杂氧化锡(IV)SnO2：F在制备光伏板上的加热层中的应用以及该光伏板 - Google Patents
氟掺杂氧化锡(IV)SnO2：F在制备光伏板上的加热层中的应用以及该光伏板 Download PDFInfo
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- CN104247041A CN104247041A CN201380009344.2A CN201380009344A CN104247041A CN 104247041 A CN104247041 A CN 104247041A CN 201380009344 A CN201380009344 A CN 201380009344A CN 104247041 A CN104247041 A CN 104247041A
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- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 238000010438 heat treatment Methods 0.000 title claims abstract description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052731 fluorine Inorganic materials 0.000 title abstract 4
- 239000011737 fluorine Substances 0.000 title abstract 4
- 229920006254 polymer film Polymers 0.000 claims abstract description 9
- 229910001887 tin oxide Inorganic materials 0.000 claims description 19
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 15
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 4
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S30/00—Structural details of PV modules other than those related to light conversion
- H02S30/10—Frame structures
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
- H02S40/10—Cleaning arrangements
- H02S40/12—Means for removing snow
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Photovoltaic Devices (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Laminated Bodies (AREA)
- Surface Heating Bodies (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
本发明包括氟掺杂氧化锡(IV)SnO2：F(FTO)在制备光伏板上的加热层中的应用。本发明还包括一种光伏板，其特征在于，所述光伏板的前部(1)覆盖有氟掺杂氧化锡(IV)SnO2：F的导电层(2)，所述导电层上沉积有电极(3)。当与电源连接时，所述导电层(2)变为加热层。在优选的实施方案中，在所述导电层上施加透明聚合物膜(4)，所述透明聚合物膜与氟掺杂氧化锡(IV)SnO2：F的导电层(2)和光伏电池(5)不可分割地且永久地粘接在一起。
Description
本发明的主题包括氟掺杂氧化锡(IV)SnO2：F在制备光伏板的加热层中的应用，以及该光伏板。本发明应用在电磁辐射(优选太阳能)转换成电能的过程中。
氟掺杂氧化锡(IV)SnO2：F在汽车玻璃除霜上的应用在现有技术中是已知的。
除此之外，具有叠层结构的光伏板是已知的。将太阳能转换为电能的光伏电池是它们最重要的部件。单个电池是一个在其结构中具有p-n结的半导体。所述光伏板是用各种类型的半导体材料制备的。根据它们的类型，该板分类为单晶硅(c-Si)、多晶硅(m-Si)以及由非晶硅(α-Si、α-Si：H)、铜铟硒(CIS)或铜铟镓硒(CIGS)和碲化镉(CdTe)的薄层技术制备的板。光伏板的前部由保护光伏电池的玻璃制成，同时整个结构封闭在一个框架中，所述框架是一个能够使板固定在支撑结构上的结构性部件。
如果不安装在垂直面上，在温度接近或低于零摄氏度的降水期间，所有已知的光伏板容易被霜或雪覆盖。在板表面的一部分被例如雪、霜等遮蔽的情况下，会导致严重的性能损失，并且整个光伏设备的整体效率会降低。这个问题发生在冬天、在下雪天和低于零摄氏度的温度下。光伏板的已知的除雪和除冰系统是通过由安装在该板下的电阻丝或具有液体介质的系统(安装在该板下的管道系统)制成的加热垫提供加热。由于它们的性质，加热垫不能直接放置在需要除冰或除霜的位置里(例如前部)，而是位于该板之下。这导致在从垫到板前部的路径上产生不希望的热损失。
从日本专利JP2002021265还已知一种用于供应电能的太阳能电池。该太阳能电池设置有用于融化雪的加热部件。然而，该加热部件仅设置在太阳能电池的一部分上，这阻碍了太阳能电池的整个表面均匀受热。
本发明包括氟掺杂氧化锡(IV)SnO2：F在光伏板上用于接收加热层的应用。
本发明还包括一种光伏板，其包括一个前部和一个其中具有一个或多个光伏电池的框架，其特征在于，其前部覆盖有氟掺杂氧化锡(IV)SnO2：F的导电层，所述导电层上沉积有电极。由于氟掺杂氧化锡(IV)SnO2：F的导电层的电阻合适，当与电压源连接时，其成为加热层。
在优选的实施方案中，所述光伏板的特征在于其前部由玻璃制成。
在推荐的实施方案中，所述光伏板的特征在于在前部内侧覆盖有氟掺杂氧化锡(IV)SnO2：F的导电层。
在另一个实施方案中，所述光伏板的特征在于，在氟掺杂氧化锡(IV)SnO2：F的导电层和光伏电池之间施加一层透明聚合物膜。有利地，该层透明聚合物膜是乙烯-乙酸乙烯酯(EVA)膜或聚乙烯醇缩丁醛(PVB)膜。
在另一个实施方案中，所述光伏板的特征在于透明聚合物膜层与氟掺杂氧化锡(IV)SnO2：F的导电层和/或光伏电池不可分割地粘接在一起。
在另一个推荐的实施方案中，所述光伏板的特征在于电极位于相对侧的边缘，这使得温度均匀分布。
本发明的优点是达到工作温度所需的时间短，以及在光伏板表面上的温度分布均匀。此外，其提供了在光伏板的除霜、除冰和除雪期间降低热损失的解决办法。
附图中显示了根据本发明所述的技术方案，其中图1显示了光伏板的截面图，图2显示了氟掺杂氧化锡(IV)SnO2：F的导电层、以及光伏板加热电路的部件。
在所示的实施方案中，所述光伏板包括框架(图中未示出)和由平面玻璃板制成的前部1。在前部1上施加有氟掺杂氧化锡(IV)SnO2：F的导电层2的薄膜。例如采用透明聚合物膜4，在≤200℃的温度下采用层叠工艺，由此将经涂覆的前部1与光伏电池5不可分割地且永久地粘接在一起。所述透明聚合物膜4是例如乙烯-乙酸乙烯酯(EVA)膜或聚乙烯醇缩丁醛(PVB)膜。该操作的结果是，作为电加热部件的氟掺杂氧化锡(IV)SnO2：F的导电层2与光伏电池5电隔离。在氟掺杂氧化锡(IV)SnO2：F的导电层2上，沉积有由导电材料制成的电极3，优选彼此相对。电极3与电源线6连接。
本发明的操作如下：将电源线6与DC或AC电源(例如10-250V的电压值)连接。由于施加了电压，电流流过氟掺杂氧化锡(IV)SnO2：F的导电层2，并且在这个层的电阻上产生热。所产生的热穿过前部1到达霜、冰或雪的层，使之融化以暴露光伏电池5。
Claims (9)
1.氟掺杂氧化锡(IV)SnO2：F在光伏板上接收加热层的应用。
2.一种光伏板，包括前部(1)和在其中包括至少一个光伏电池(5)的框架，其特征在于，所述前部(1)覆盖有氟掺杂氧化锡(IV)SnO2：F的导电层(2)，所述导电层上沉积有电极(3)，使得当所述电极(3)与电压源相连时，所述导电层(2)成为一个加热层。
3.根据权利要求2所述的板，其特征在于，所述前部(1)由玻璃制成。
4.根据权利要求2或3所述的板，其特征在于，所述前部(1)在其内侧覆盖有氟掺杂氧化锡(IV)SnO2：F的导电层(2)。
5.根据权利要求4所述的板，其特征在于，在氟掺杂氧化锡(IV)SnO2：F的导电层(2)和光伏电池(5)之间施加一层透明聚合物膜(4)。
6.根据权利要求5所述的板，其特征在于，该层透明聚合物膜(4)与氟掺杂氧化锡(IV)SnO2：F的导电层(2)和/或光伏电池(5)不可分割地粘接在一起。
7.根据权利要求5或6所述的板，其特征在于，该层透明聚合物膜(4)是乙烯-乙酸乙烯酯(EVA)膜。
8.根据权利要求5或6所述的板，其特征在于，该层透明聚合物膜(4)是聚乙烯醇缩丁醛(PVB)膜。
9.根据权利要求2至8中任一个所述的板，其特征在于，所述电极(3)位于板的相对侧的边缘。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12460005.7A EP2629337B1 (en) | 2012-02-16 | 2012-02-16 | Application of fluorine doped tin (IV) oxide SnO2:F for making a heating layer on a photovoltaic panel, and the photovoltaic panel |
| EP12460005.7 | 2012-02-16 | ||
| PCT/PL2013/000017 WO2013122489A1 (en) | 2012-02-16 | 2013-02-14 | Application of fluorine doped tin (iv) oxide sno2:f for making a heating layer on a photovoltaic panel, and the photovoltaic panel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104247041A true CN104247041A (zh) | 2014-12-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380009344.2A Pending CN104247041A (zh) | 2012-02-16 | 2013-02-14 | 氟掺杂氧化锡(IV)SnO2：F在制备光伏板上的加热层中的应用以及该光伏板 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20150020869A1 (zh) |
| EP (1) | EP2629337B1 (zh) |
| JP (1) | JP2015525050A (zh) |
| KR (1) | KR20140135950A (zh) |
| CN (1) | CN104247041A (zh) |
| AU (1) | AU2013220980A1 (zh) |
| CA (1) | CA2863027A1 (zh) |
| IN (1) | IN2014MN01232A (zh) |
| PL (1) | PL2629337T3 (zh) |
| RU (1) | RU2014126235A (zh) |
| SG (1) | SG11201403595RA (zh) |
| WO (1) | WO2013122489A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109546957A (zh) * | 2018-12-29 | 2019-03-29 | 常州华美光电新材料有限公司 | 一种用于光伏组件的加热玻璃 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10505240B1 (en) | 2018-10-25 | 2019-12-10 | Sunlight Aerospace Inc. | Methods and apparatus for thermal energy management in electric vehicles |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080289680A1 (en) * | 2007-05-21 | 2008-11-27 | Macfarlane Alexander T | Photovoltaic module with improved heat transfer and recovery potential |
| US20110056924A1 (en) * | 2009-09-10 | 2011-03-10 | Benjamin Park Townsend | Solar defrost panels |
| CN202013894U (zh) * | 2011-01-11 | 2011-10-19 | 上海勒卡彭建筑信息咨询有限公司 | 低反射融雪抗污太阳能晶体硅电池组件构件 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3521993B2 (ja) * | 1995-03-20 | 2004-04-26 | ミサワホーム株式会社 | 太陽電池付屋根 |
| JP3418781B2 (ja) * | 1997-10-31 | 2003-06-23 | 幸作 板鼻 | 融雪屋根材及び融雪屋根構造 |
| US6291763B1 (en) * | 1999-04-06 | 2001-09-18 | Fuji Photo Film Co., Ltd. | Photoelectric conversion device and photo cell |
| JP2002021265A (ja) * | 2000-07-04 | 2002-01-23 | Nissin Electric Co Ltd | 融雪装置 |
| JP2007311635A (ja) * | 2006-05-19 | 2007-11-29 | Ecomode:Kk | 融雪型太陽電池モジュール |
| US20100236608A1 (en) * | 2009-03-20 | 2010-09-23 | Ball Jasper T | Photovoltaic module with heater |
-
2012
- 2012-02-16 PL PL12460005T patent/PL2629337T3/pl unknown
- 2012-02-16 EP EP12460005.7A patent/EP2629337B1/en active Active
-
2013
- 2013-02-14 IN IN1232MUN2014 patent/IN2014MN01232A/en unknown
- 2013-02-14 AU AU2013220980A patent/AU2013220980A1/en not_active Abandoned
- 2013-02-14 JP JP2014557595A patent/JP2015525050A/ja active Pending
- 2013-02-14 WO PCT/PL2013/000017 patent/WO2013122489A1/en active Application Filing
- 2013-02-14 KR KR1020147022244A patent/KR20140135950A/ko not_active Application Discontinuation
- 2013-02-14 RU RU2014126235A patent/RU2014126235A/ru not_active Application Discontinuation
- 2013-02-14 CN CN201380009344.2A patent/CN104247041A/zh active Pending
- 2013-02-14 US US14/373,061 patent/US20150020869A1/en not_active Abandoned
- 2013-02-14 SG SG11201403595RA patent/SG11201403595RA/en unknown
- 2013-02-14 CA CA2863027A patent/CA2863027A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080289680A1 (en) * | 2007-05-21 | 2008-11-27 | Macfarlane Alexander T | Photovoltaic module with improved heat transfer and recovery potential |
| US20110056924A1 (en) * | 2009-09-10 | 2011-03-10 | Benjamin Park Townsend | Solar defrost panels |
| CN202013894U (zh) * | 2011-01-11 | 2011-10-19 | 上海勒卡彭建筑信息咨询有限公司 | 低反射融雪抗污太阳能晶体硅电池组件构件 |
Non-Patent Citations (1)
| Title |
|---|
| PETER GERHARDINGER: ""Coated Glass for Transparent Heating Elements"", 《NASA TECH BRIEFS》, 1 November 2008 (2008-11-01), pages 1 - 2 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109546957A (zh) * | 2018-12-29 | 2019-03-29 | 常州华美光电新材料有限公司 | 一种用于光伏组件的加热玻璃 |
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201403595RA (en) | 2014-08-28 |
| EP2629337A1 (en) | 2013-08-21 |
| KR20140135950A (ko) | 2014-11-27 |
| RU2014126235A (ru) | 2016-01-27 |
| EP2629337B1 (en) | 2016-10-19 |
| JP2015525050A (ja) | 2015-08-27 |
| PL2629337T3 (pl) | 2017-02-28 |
| WO2013122489A8 (en) | 2014-03-13 |
| IN2014MN01232A (zh) | 2015-07-03 |
| CA2863027A1 (en) | 2013-08-22 |
| US20150020869A1 (en) | 2015-01-22 |
| AU2013220980A1 (en) | 2014-06-26 |
| WO2013122489A1 (en) | 2013-08-22 |
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