CN104212400A - Water-based ABS(acrylonitrile butadiene styrene) glue for transfer printing and preparation method thereof - Google Patents
Water-based ABS(acrylonitrile butadiene styrene) glue for transfer printing and preparation method thereof Download PDFInfo
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- CN104212400A CN104212400A CN201310220065.2A CN201310220065A CN104212400A CN 104212400 A CN104212400 A CN 104212400A CN 201310220065 A CN201310220065 A CN 201310220065A CN 104212400 A CN104212400 A CN 104212400A
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Abstract
The invention relates to water-based ABS (acrylonitrile butadiene styrene) glue for transfer printing and a preparation method thereof; the water-based ABS (acrylonitrile butadiene styrene) glue comprises the following components by weight: 20-60 parts of self emulsifying polyurethane water dispersion, 0-40 parts of acrylic emulsion, 40-80 parts of deionized water, 0-10 parts of a wetting dispersing agent, 0-5 parts of a leveling agent and 0-3 parts of a defoaming agent; the raw materials are prepared according to the formula, then are stirred and mixed evenly then under normal temperature and pressure for coating a transfer printing substrate. Compared with the prior art, the production process of the water-based ABS (acrylonitrile butadiene styrene) glue completely does not use an organic solvent, and has advantages of simple operation and low cost and the like.
Description
Technical field
The present invention relates to a kind of preparation method of transfer printing glue, especially relate to a kind of transfer printing water base ABS glue and preparation method thereof.
Background technology
Hot transfer printing is a newer typography, it is made up of carrier of undertaking the printing of (being generally PET biaxially oriented polyester film), release layer, ink layer, gum layer, then through certain pressure, temperature, ink layer is stripped down from carrier of undertaking the printing of by thermoprinting machine, by the bonding effect of glue ink layer is attached to securely and is transferred on base material.This technology is widely used in the industry such as packaging, decoration of daily necessities, building materials etc.And according to being transferred the difference of substrate material, need different glue.The most glue of current thermal-transfer line industry is all solvent-borne type, wherein volatile organic content accounts for 60-90%, the organic solvent of such tackiness agent contained by coating process is through heating, volatilization, not only ambient air is polluted, affect the healthy of operator, and the dissolvent residual in heat transfer film also can affect the quality of product, today that environmentally safe requirement is more and more higher in the whole world, solvent based product more and more restricts production and the application of heat transfer film.Research and develop no-solvent type heat transfer film for this reason and become a kind of development trend.
Summary of the invention
Object of the present invention be exactly in order to overcome above-mentioned prior art exist defect and provide one in process of production completely not with an organic solvent, transfer printing water base ABS glue and preparation method thereof that production process is simple to operate and with low cost.
Object of the present invention can be achieved through the following technical solutions:
The water base ABS glue of a kind of transfer printing, comprises following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20-60;
ACRYLIC EMULSION 0-40;
Deionized water 40-80;
Wetting dispersing agent 0-10;
Flow agent 0-5;
Defoamer 0-3;
Wherein, be 0 when ACRYLIC EMULSION, wetting dispersing agent, flow agent and defoamer are different.
Described self-emulsifying polyurethane aqueous dispersion is anionic polyurethane aqueous dispersions or nonionic polyurethane aqueous dispersions, and solid content is 30-70wt%.
Described self-emulsifying polyurethane aqueous dispersion is commercially available XP2557, XP2558, XP2606, U54 or 565 type polyurethane emulsions.
Described ACRYLIC EMULSION is polyacrylate resin emulsion or polymethacrylate resin emulsion, is selected from commercially available NeoCryl BT-9 type or NeoCryl BT-67 type ACRYLIC EMULSION.
Described wetting dispersing agent is water-soluble wetting dispersing agent, is selected from commercially available DISPERBYK-181 type, 193 types, SILOK7110 type or 7117 type wetting dispersing agents.
Described flow agent is aqueous solution systems flow agent, is selected from commercially available BYK-341 type, BYK-352 type or BYK-381 type flow agent.
Described defoamer is aqueous solution systems defoamer, is selected from commercially available BYK-028, BYK-094, BYK-1730 type defoamer.
The preparation method of water base ABS glue comprises the following steps in transfer printing:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20-60, ACRYLIC EMULSION 0-40, deionized water 40-80, wetting dispersing agent 0-10, flow agent 0-5, defoamer 0-3;
(2) in reactor, add self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, wetting dispersing agent, flow agent, defoamer by formula, then at normal temperatures and pressures, be uniformly mixed and namely can be coated with use in transfer substrate.
Stirring velocity controls at 50-2000rpm, and churning time controls at 5-60min.
Compared with prior art, the present invention does not need to use any organic solvent, and preparation is simple, operational safety, only needs simple container, without the need to heating, through mechanical stirring, comprises following advantage:
(1) the glue good stability prepared, long-term placement can not sex change, and the application adopts the aqueous polyurethane emulsion of self-crosslinking, self-emulsifying and the aqueous acrylic emulsion of self-crosslinking, and its resin stability is excellent, the glue good stability of preparation, long-term placement also can not sex change;
(2) glue dries prepared is good, good leveling property, and be easy to intaglio plate coating, the resin that the application selects is small molecules type, bonding force is strong, good leveling property, and the water base flow agent of appropriate interpolation, make coating planarization good, be easy to dry feature, be easy to intaglio plate coating;
(3) glue performance prepared is excellent, and the polyaminoester emulsion that the application selects and ACRYLIC EMULSION all have more excellent bonding force to various engineering plastics such as the materials such as ABS, PMMA, PC, AS, applied widely;
(4) do not need to use any organic solvent, product environmental protection, the application take water as thinner, completely without any need for organic solvent, the volatilization of coating process organic solvent-free and discharge, the heat transfer film organic solvent-free of production remains, production safety, environmental friendliness.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
In batching kettle, add 30 parts of polyaminoester emulsions, 565 type polyurethane emulsions can be selected; 65 parts of deionized waters; 3 parts of wetting dispersing agents, can select BYK polyamino acid and alkanol amine type wetting dispersing agent; 1 part of flow agent, can select BYK-307 organic silicon modified by polyether type leveling auxiliary agent; 1 part of defoamer, can select the water base defoamer of BYK-028 type.Then start stirrer, rotating speed is 1000 revs/min, stirs 30 minutes.
Embodiment 2
In batching kettle, add 20 parts of polyaminoester emulsions, can be XP2606 type polyurethane emulsion; 20 parts of Emulsion acrylic resins can be NeoCryl BT-9 types; 55 deionized waters; 3 parts of wetting dispersing agents, can select HX-5880 type nonionogenic tenside; 1 part of flow agent, can select HX-3300 polyacrylate flow agent; 1 part of defoamer, can select HX-5042 polysiloxane type defoamer.Then start stirrer, rotating speed is 1500 revs/min, stirs 25 minutes.
Embodiment 3
In batching kettle, add 15 parts of polyaminoester emulsions, can be U54 type polyurethane emulsion, and 10 parts of Emulsion acrylic resins can be NeoCryl BT-67 types, 70 parts of deionized waters; 3 parts of wetting dispersing agents, can select TEGO655 type; 1 part of flow agent, can select TEGO3030 type; 1 part of defoamer, can select TEGO904W type.Then start stirrer, rotating speed is 2000 revs/min, stirs 15 minutes.
Embodiment 4
The preparation method of water base ABS glue comprises the following steps in transfer printing:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20, ACRYLIC EMULSION 40, deionized water 40, flow agent 5, defoamer 3, wherein, the self-emulsifying polyurethane aqueous dispersion solid content used is 70wt%, commercially available XP2558 type polyurethane emulsion is selected in the present embodiment, flow agent selects BYK-341 type aqueous solution systems flow agent, and defoamer is from commercially available BYK-028 type aqueous solution systems defoamer;
(2) in reactor, self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, flow agent, defoamer is added by formula, then at normal temperatures and pressures, control stirring velocity is 50rpm, stirs 60min and makes it mix, namely can be coated with use in transfer substrate.
Embodiment 5
The preparation method of water base ABS glue comprises the following steps in transfer printing:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 40, ACRYLIC EMULSION 20, deionized water 60, wetting dispersing agent 5, defoamer 2, wherein, the self-emulsifying polyurethane aqueous dispersion used is commercially available XP2606 type polyurethane emulsion, solid content 50wt%, ACRYLIC EMULSION is commercially available NeoCryl BT-9 type emulsion, wetting dispersing agent is the commercially available water-soluble wetting dispersing agent of DISPERBYK-181 type, and defoamer is commercially available BYK-094 type aqueous solution systems defoamer;
(2) in reactor, self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, wetting dispersing agent, defoamer is added by formula, then at normal temperatures and pressures, control stirring velocity is 200rpm, stirring 30min makes it mix, and evenly namely can be coated with use in transfer substrate.
Embodiment 6
The preparation method of water base ABS glue comprises the following steps in transfer printing:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 50, ACRYLIC EMULSION 30, deionized water 60, wetting dispersing agent 10, flow agent 5, wherein, self-emulsifying polyurethane aqueous dispersion is commercially available U54 type polyurethane emulsion, solid content is 30wt%, ACRYLIC EMULSION is NeoCryl BT-67 type emulsion, wetting dispersing agent is the commercially available water-soluble wetting dispersing agent of SILOK7110 type, and flow agent is the commercially available water-soluble flow agent of BYK-381 type;
(2) in reactor, self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, wetting dispersing agent, flow agent is added by formula, then at normal temperatures and pressures, control stirring velocity is 1000rpm, stirring 15min makes it mix, and namely can be coated with use in transfer substrate.
Embodiment 7
The preparation method of water base ABS glue comprises the following steps in transfer printing:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20, ACRYLIC EMULSION 40, deionized water 80, wetting dispersing agent 10, flow agent 5, defoamer 3, the self-emulsifying urethane solid content used is 30wt%, what the present embodiment was selected is 565 commercially available type polyurethane emulsions, ACRYLIC EMULSION is commercially available NeoCryl BT-9 type emulsion, wetting dispersing agent is the water-soluble wetting dispersing agent of 7117 type, flow agent is commercially available BYK-341 type aqueous solution systems flow agent, and defoamer is commercially available BYK-094 type aqueous solution systems defoamer;
(2) in reactor, self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, wetting dispersing agent, flow agent, defoamer is added by formula, then at normal temperatures and pressures, control stirring velocity is 2000rpm, stirring 5min makes it mix, and is uniformly mixed and namely can be coated with use in transfer substrate.
The water base ABS glue standby in order to top legal system carries out intaglio plate coating, roller netting twine is 175 orders/inch, coating machine speed is 45m/min, heat transfer film thermoprint ABS material workpiece after coating, thermoprinting machine temperature is 220 DEG C, rubber tire moderate pressure, and rubber tire linear velocity is 80cm/min, workpiece after transfer printing 3M detects adhesive tape test glue sticking power, comes off without ink layer.
Claims (9)
1. the water base ABS glue of transfer printing, is characterized in that, comprises following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20-60;
ACRYLIC EMULSION 0-40;
Deionized water 40-80;
Wetting dispersing agent 0-10;
Flow agent 0-5;
Defoamer 0-3;
Wherein, be 0 when ACRYLIC EMULSION, wetting dispersing agent, flow agent and defoamer are different.
2. the water base ABS glue of a kind of transfer printing according to claim 1, is characterized in that, described self-emulsifying polyurethane aqueous dispersion is anionic polyurethane aqueous dispersions or nonionic polyurethane aqueous dispersions, and solid content is 30-70wt%.
3. the water base ABS glue of a kind of transfer printing according to claim 1 and 2, is characterized in that, described self-emulsifying polyurethane aqueous dispersion is commercially available XP2557, XP2558, XP2606, U54 or 565 type polyurethane emulsions.
4. the water base ABS glue of a kind of transfer printing according to claim 1, it is characterized in that, described ACRYLIC EMULSION is polyacrylate resin emulsion or polymethacrylate resin emulsion, is selected from commercially available NeoCryl BT-9 type or NeoCryl BT-67 type ACRYLIC EMULSION.
5. the water base ABS glue of a kind of transfer printing according to claim 1, it is characterized in that, described wetting dispersing agent is water-soluble wetting dispersing agent, is selected from commercially available DISPERBYK-181 type, 193 types, SILOK7110 type or 7117 type wetting dispersing agents.
6. the water base ABS glue of a kind of transfer printing according to claim 1, it is characterized in that, described flow agent is aqueous solution systems flow agent, is selected from commercially available BYK-341 type, BYK-352 type or BYK-381 type flow agent.
7. the water base ABS glue of a kind of transfer printing according to claim 1, it is characterized in that, described defoamer is aqueous solution systems defoamer, is selected from commercially available BYK-028, BYK-094, BYK-1730 type defoamer.
8. the preparation method of water base ABS glue of the transfer printing according to any one of claim 1-7, it is characterized in that, the method comprises the following steps:
(1) get the raw materials ready according to following component and weight part content:
Self-emulsifying polyurethane aqueous dispersion 20-60, ACRYLIC EMULSION 0-40, deionized water 40-80, wetting dispersing agent 0-10, flow agent 0-5, defoamer 0-3;
(2) in reactor, add self-emulsifying polyurethane aqueous dispersion, ACRYLIC EMULSION, deionized water, wetting dispersing agent, flow agent, defoamer by formula, then at normal temperatures and pressures, be uniformly mixed and namely can be coated with use in transfer substrate.
9. a kind of transfer printing according to claim 8 preparation method of water base ABS glue, it is characterized in that, stirring velocity controls at 50-2000rpm, and churning time controls at 5-60min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310220065.2A CN104212400B (en) | 2013-06-04 | 2013-06-04 | A kind of transfer water base ABS glue and preparation method thereof |
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| CN201310220065.2A CN104212400B (en) | 2013-06-04 | 2013-06-04 | A kind of transfer water base ABS glue and preparation method thereof |
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| CN104212400B CN104212400B (en) | 2016-11-23 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105985747A (en) * | 2015-01-28 | 2016-10-05 | 浙江恒丰包装有限公司 | Transparent back glue used for double-face color development hot stamping foil |
| CN106924965A (en) * | 2017-03-15 | 2017-07-07 | 江苏奥光智慧信息科技有限公司 | Wooden jigsaw puzzle and its production technology |
| CN108546530A (en) * | 2018-03-30 | 2018-09-18 | 广东星宇耐力新材料股份有限公司 | Aqueous adhesive and preparation method thereof |
| CN108949059A (en) * | 2018-07-23 | 2018-12-07 | 福建省张氏新材料科技有限公司 | A kind of heat transfer flock dusted paper and its production technology |
| CN109517566A (en) * | 2018-11-19 | 2019-03-26 | 香洋新材料（江苏）有限公司 | A kind of aqueous thermal transfer PP adhesive and preparation method thereof |
| CN109837043A (en) * | 2019-02-28 | 2019-06-04 | 广东星宇耐力新材料股份有限公司 | A kind of noncrystalline plastic packing box water base paste box glue and preparation method thereof |
| CN112552856A (en) * | 2020-12-09 | 2021-03-26 | 清远慧谷新材料技术有限公司 | Aqueous hot melt adhesive |
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| JPS59217779A (en) * | 1983-05-26 | 1984-12-07 | Showa Highpolymer Co Ltd | Adhesive composition of aqueous contact type |
| US20060148970A1 (en) * | 2003-09-26 | 2006-07-06 | Kazuo Kuba | Water base dispersion of polyurethane resin, and water base adhesive and water base primer coating agent containing the same |
| CN1888001A (en) * | 2006-06-30 | 2007-01-03 | 中山大学 | Dry composite water-thined adhesive in soft package and its prepn |
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2013
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| JPS59217779A (en) * | 1983-05-26 | 1984-12-07 | Showa Highpolymer Co Ltd | Adhesive composition of aqueous contact type |
| US20060148970A1 (en) * | 2003-09-26 | 2006-07-06 | Kazuo Kuba | Water base dispersion of polyurethane resin, and water base adhesive and water base primer coating agent containing the same |
| CN1888001A (en) * | 2006-06-30 | 2007-01-03 | 中山大学 | Dry composite water-thined adhesive in soft package and its prepn |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105985747A (en) * | 2015-01-28 | 2016-10-05 | 浙江恒丰包装有限公司 | Transparent back glue used for double-face color development hot stamping foil |
| CN106924965A (en) * | 2017-03-15 | 2017-07-07 | 江苏奥光智慧信息科技有限公司 | Wooden jigsaw puzzle and its production technology |
| CN108546530A (en) * | 2018-03-30 | 2018-09-18 | 广东星宇耐力新材料股份有限公司 | Aqueous adhesive and preparation method thereof |
| CN108546530B (en) * | 2018-03-30 | 2020-05-12 | 广东星宇耐力新材料股份有限公司 | Water-based adhesive and preparation method thereof |
| CN108949059A (en) * | 2018-07-23 | 2018-12-07 | 福建省张氏新材料科技有限公司 | A kind of heat transfer flock dusted paper and its production technology |
| CN109517566A (en) * | 2018-11-19 | 2019-03-26 | 香洋新材料（江苏）有限公司 | A kind of aqueous thermal transfer PP adhesive and preparation method thereof |
| CN109837043A (en) * | 2019-02-28 | 2019-06-04 | 广东星宇耐力新材料股份有限公司 | A kind of noncrystalline plastic packing box water base paste box glue and preparation method thereof |
| CN112552856A (en) * | 2020-12-09 | 2021-03-26 | 清远慧谷新材料技术有限公司 | Aqueous hot melt adhesive |
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| CN104212400B (en) | 2016-11-23 |
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Effective date of registration: 20211215 Address after: 201807 zone B, floor 1, building 3, No. 599, Xingxian Road, Jiading Industrial Zone, Jiading District, Shanghai Patentee after: Shanghai Huagong Aimar New Material Co.,Ltd. Address before: 201807 No. 599, Xingxian Road, North District, Jiading Industrial Zone, Shanghai Patentee before: RESPLENDENT (SHANGHAI) SPECIAL DECAL CO.,LTD. |
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