CN104292972B - A kind of metal base high-performance and low-cost UV-curable water-borne ink - Google Patents
A kind of metal base high-performance and low-cost UV-curable water-borne ink Download PDFInfo
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- CN104292972B CN104292972B CN201410584937.8A CN201410584937A CN104292972B CN 104292972 B CN104292972 B CN 104292972B CN 201410584937 A CN201410584937 A CN 201410584937A CN 104292972 B CN104292972 B CN 104292972B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to technical field of ink, particularly relate to a kind of metal base high-performance and low-cost UV-curable water-borne ink.Described a kind of metal base high-performance and low-cost UV-curable water-borne ink is counted by weight, is prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 50 ~ 60 parts；Pigment: 1 ~ 2 part；Photoepolymerizationinitiater initiater: 2 ~ 5 parts；Reactive diluent: 10 ~ 20 parts；Defoamer: 1 ~ 5 part；Aqueous solvent: 100 ~ 120 parts.Present invention employs ultraviolet light radical cation and mix curing system, occur radical UV curing reaction and cation photocuring to react in same system simultaneously, at aspects such as light-initiated, Volume Changes is complementary, property regulation, there is preferable cooperative effect.The present invention has solvent resistance and the adhesive force of excellence, and overall performance is superior, low cost, it is adaptable to all kinds of construction substrate.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of metal base high-performance and low-cost UV-curable water-borne ink.
Background technology
UV-curing technology is since coming out, because it has the feature of 5E, i.e. efficiently (Efficient), applicable wide (Enabling), economical (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, UV-curing technology has been widely used in by people and has lived closely bound up field, beautifies object and the effect of protection object to play.
Ultraviolet light radically curing system, ultraviolet light Cationic curing systems and ultraviolet light free radical-cationic hybrid curing system can be divided into according to the different UV-curing technologies of initiator system.It is fast that radical UV curing system has curing rate, and performance such as can easily be accommodated at the advantage, but there is problems such as shrinking serious, oxygen inhibition, adhesive ability difference.Cationic curing systems development is later, it has, and volume contraction is little, adhesive force is strong, wear-resisting, hardness advantages of higher, but it also has that curing rate is slow, oligomer and reactive diluent kind few, price is high, cured product performance is difficult to the shortcomings such as regulation, thus limits its actual application.Therefore from ultraviolet light free radical-cationic hybrid curing system, can maximize favourable factors and minimize unfavourable ones the most theoretically, the advantage giving full play to free radical and Cationic curing systems, widen the range of photocuring system.
Summary of the invention
The present invention is directed to above-mentioned background technology, it is provided that a kind of metal base high-performance and low-cost UV-curable water-borne ink.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
A kind of metal base high-performance and low-cost UV-curable water-borne ink, it is characterised in that: count by weight, be prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 50 ~ 60 parts；Pigment: 1 ~ 2 part；Photoepolymerizationinitiater initiater: 2 ~ 5 parts；Reactive diluent: 10 ~ 20 parts；Defoamer: 1 ~ 5 part；Aqueous solvent: 100 ~ 120 parts；
The preparation method that described bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer comprises the following steps: by bisphenol A epoxide resin and p methoxy phenol, isobornyl acrylate mix and blend, it is heated to 80 ~ 90 DEG C, it is slowly added to acrylic acid, stirs 1 ~ 2h, to obtain final product.
Further, described a kind of metal base high-performance and low-cost UV-curable water-borne ink is counted by weight, is prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 55 parts；Pigment: 1.5 parts；Photoepolymerizationinitiater initiater: 4 parts；Reactive diluent: 15 parts；Defoamer: 3 parts；Aqueous solvent: 100 parts.
Further, described reactive diluent is hydroxy-ethyl acrylate or hydroxyethyl methacrylate.
Further, described Photoepolymerizationinitiater initiater is benzoin methyl ether, benzoin ethyl ether or said mixture.
Further, described defoamer is polysiloxanes silicones.
Further, described aqueous solvent is ethanol and water mixed solvent.
Present invention also offers the preparation method of above-mentioned a kind of metal base high-performance and low-cost UV-curable water-borne ink, comprise the following steps: bisphenol A epoxide resin list isobornyl acrylate is mixed prepolymer, reactive diluent, pigment, defoamer, aqueous solvent mix and blend, it is heated to 40 ~ 50 DEG C, maintain 2 ~ 3h, add Photoepolymerizationinitiater initiater, stirring 0.5 ~ 1h, to obtain final product.
The invention provides a kind of metal base high-performance and low-cost UV-curable water-borne ink, have the beneficial effect that:
One metal base high-performance and low-cost UV-curable water-borne ink of the present invention, have employed ultraviolet light free radical-cationic hybrid curing system, occur radical UV curing reaction and cation photocuring to react in same system simultaneously, at aspects such as light-initiated, Volume Changes is complementary, property regulation, there is preferable cooperative effect.The present invention has solvent resistance and the adhesive force of excellence, and overall performance is superior, low cost, it is adaptable to all kinds of construction substrate.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of metal base high-performance and low-cost UV-curable water-borne ink is counted by weight, is prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 55 parts；Pigment: 1.5 parts；Benzoin methyl ether: 4 parts；Hydroxy-ethyl acrylate: 15 parts；Polysiloxanes silicones: 3 parts；Ethanol and water mixed solvent: 100 parts.
The preparation method that described bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer comprises the following steps: by bisphenol A epoxide resin and p methoxy phenol, isobornyl acrylate mix and blend, is heated to 80 DEG C, is slowly added to acrylic acid, stirs 1h, to obtain final product.
Bisphenol A epoxide resin list isobornyl acrylate is mixed prepolymer, hydroxy-ethyl acrylate, pigment, polysiloxanes silicones, ethanol and water mixed solvent mix and blend, is heated to 40 DEG C, maintain 2h, add benzoin methyl ether, stir 0.5h, to obtain final product.
Embodiment 2:
Described a kind of metal base high-performance and low-cost UV-curable water-borne ink is counted by weight, is prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 52 parts；Pigment: 1 part；Benzoin ethyl ether: 3 parts；Hydroxyethyl methacrylate: 14 parts；Polysiloxanes silicones: 2 parts；Ethanol and water mixed solvent: 120 parts.
The preparation method that described bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer comprises the following steps: by bisphenol A epoxide resin and p methoxy phenol, isobornyl acrylate mix and blend, is heated to 90 DEG C, is slowly added to acrylic acid, stirs 2h, to obtain final product.
Bisphenol A epoxide resin list isobornyl acrylate is mixed prepolymer, hydroxyethyl methacrylate, pigment, polysiloxanes silicones, ethanol and water mixed solvent mix and blend, is heated to 50 DEG C, maintain 3h, add benzoin ethyl ether, stir 1h, to obtain final product.
Claims (3)
1. a metal base high-performance and low-cost UV-curable water-borne ink, it is characterised in that: count by weight, be prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 50 ~ 60 parts；Pigment: 1 ~ 2 part；Photoepolymerizationinitiater initiater: 2 ~ 5 parts；Reactive diluent: 10 ~ 20 parts；Defoamer: 1 ~ 5 part；Aqueous solvent: 100 ~ 120 parts；
The preparation method that described bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer comprises the following steps: by bisphenol A epoxide resin and p methoxy phenol, isobornyl acrylate mix and blend, it is heated to 80 ~ 90 DEG C, it is slowly added to acrylic acid, stirs 1 ~ 2h, to obtain final product；
Described reactive diluent is hydroxy-ethyl acrylate or hydroxyethyl methacrylate；
Described Photoepolymerizationinitiater initiater is benzoin methyl ether, benzoin ethyl ether or said mixture；
Described defoamer is polysiloxanes silicones；
Described aqueous solvent is ethanol and water mixed solvent.
A kind of metal base high-performance and low-cost UV-curable water-borne ink the most according to claim 1, it is characterized in that: described a kind of metal base high-performance and low-cost UV-curable water-borne ink is counted by weight, is prepared from the following materials: bisphenol A epoxide resin list isobornyl acrylate mixes prepolymer: 55 parts；Pigment: 1.5 parts；Photoepolymerizationinitiater initiater: 4 parts；Reactive diluent: 15 parts；Defoamer: 3 parts；Aqueous solvent: 100 parts.
A kind of metal base high-performance and low-cost UV-curable water-borne ink the most according to claim 1, it is characterized in that: the preparation method of described a kind of metal base high-performance and low-cost UV-curable water-borne ink, comprise the following steps: bisphenol A epoxide resin list isobornyl acrylate is mixed prepolymer, reactive diluent, pigment, defoamer, aqueous solvent mix and blend, it is heated to 40 ~ 50 DEG C, maintain 2 ~ 3h, add Photoepolymerizationinitiater initiater, stir 0.5 ~ 1h, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410584937.8A CN104292972B (en) | 2014-10-28 | 2014-10-28 | A kind of metal base high-performance and low-cost UV-curable water-borne ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584937.8A CN104292972B (en) | 2014-10-28 | 2014-10-28 | A kind of metal base high-performance and low-cost UV-curable water-borne ink |
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| CN104292972A CN104292972A (en) | 2015-01-21 |
| CN104292972B true CN104292972B (en) | 2016-08-24 |
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| CN201410584937.8A Active CN104292972B (en) | 2014-10-28 | 2014-10-28 | A kind of metal base high-performance and low-cost UV-curable water-borne ink |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3774360B1 (en) * | 2018-03-27 | 2024-01-10 | Sun Chemical Corporation | Uv-curable compositions comprising cleavage type photoinitiators |
| CN110144140B (en) * | 2019-06-23 | 2021-10-26 | 珠海君奥新材料科技有限公司 | Mixed photocuring ink-jet ink composition suitable for LED photocuring and mixer |
| CN111205733A (en) * | 2020-02-28 | 2020-05-29 | 上海超彩油墨有限公司 | Cationic/free radical dual-curing UV gloss oil for tin printing ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007929A (en) * | 2006-01-26 | 2007-08-01 | 深圳清华大学研究院 | Free radical- cation type ultraviolet photo-curing cementing agent and its preparation method |
| CN101857776A (en) * | 2010-06-11 | 2010-10-13 | 上海拓引数码技术有限公司 | UV-curable adhesive composition for compact discs |
| CN103042824A (en) * | 2011-10-14 | 2013-04-17 | 武汉海蓝生物技术有限公司 | Low viscosity solder resist ink and printing method thereof |
| CN103725243A (en) * | 2013-12-27 | 2014-04-16 | 山东禹王实业有限公司 | Anaerobic adhesive for surface bonding of inert metal |
-
2014
- 2014-10-28 CN CN201410584937.8A patent/CN104292972B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007929A (en) * | 2006-01-26 | 2007-08-01 | 深圳清华大学研究院 | Free radical- cation type ultraviolet photo-curing cementing agent and its preparation method |
| CN101857776A (en) * | 2010-06-11 | 2010-10-13 | 上海拓引数码技术有限公司 | UV-curable adhesive composition for compact discs |
| CN103042824A (en) * | 2011-10-14 | 2013-04-17 | 武汉海蓝生物技术有限公司 | Low viscosity solder resist ink and printing method thereof |
| CN103725243A (en) * | 2013-12-27 | 2014-04-16 | 山东禹王实业有限公司 | Anaerobic adhesive for surface bonding of inert metal |
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| CN104292972A (en) | 2015-01-21 |
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Inventor after: Yu Shufeng Inventor after: Chen Siyuan Inventor before: Xi Xiaoshan Inventor before: Wang Jun Inventor before: Huang Bo |
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Effective date of registration: 20170411 Address after: 511458 Guangzhou Province, Nansha District City, the town of Tai Gang long road, No. 100 (plant C-2), layer three, Patentee after: Guangzhou Shanmu new Mstar Technology Ltd Address before: 610000 Sichuan city of Chengdu province high tech Zone Shiyang Industrial Park Patentee before: Chengdu Nashuo Technology Co., Ltd. |
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