CN103045035A - High-temperature resistant aluminum powder paint - Google Patents
High-temperature resistant aluminum powder paint Download PDFInfo
- Publication number
- CN103045035A CN103045035A CN2012105736402A CN201210573640A CN103045035A CN 103045035 A CN103045035 A CN 103045035A CN 2012105736402 A CN2012105736402 A CN 2012105736402A CN 201210573640 A CN201210573640 A CN 201210573640A CN 103045035 A CN103045035 A CN 103045035A
- Authority
- CN
- China
- Prior art keywords
- agent
- powder paint
- temperature resistant
- aluminium
- high temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 30
- -1 Aluminium-silver Chemical compound 0.000 claims description 21
- 239000002002 slurry Substances 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229920002050 silicone resin Polymers 0.000 claims description 15
- 239000004411 aluminium Substances 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 229920002301 cellulose acetate Polymers 0.000 claims description 7
- 239000002318 adhesion promoter Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000006224 matting agent Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical compound OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920006221 acetate fiber Polymers 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses high-temperature resistant aluminum powder paint. Modified organic silicon resin, hydroxyl acrylic acid and acetate fiber are adopted as resin base materials; and aluminum powder, auxiliary agent and solvent are added. The aluminum powder paint has the better binding force with a metal substrate, can resist the high temperature of 400-450 DEG C for a long time, stably paints films, resists the chemical corrosion, and has excellent construction performance.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of high temperature resistant aluminium powder paint.
Background technology
Development along with China's modernization industry, the industry of using high temperature service and related facility is more and more, yet metallic substance is easy and airborne oxygen generation oxidizing reaction in hot environment, produces corrosion phenomena, thereby causes the structural breakage of metallic substance.
High temperature resistant aluminium powder paint is a kind of coating for the high temperature environment such as chemical industry operation and boiler and member, is used for newly-built thing maintenance, to prevent the corrosion and ageings such as iron and steel in workerization industry environment.
Summary of the invention
The purpose of this invention is to provide a kind of high temperature resistant aluminium powder paint.
Realize that technical scheme of the present invention is as follows:
A kind of high temperature resistant aluminium powder paint, mainly the material by following weight percent forms:
Organosilicon resin 25 ~ 30%
Hydroxylated acrylic resin 30 ~ 40%
Cellulose acetate 8 ~ 10%
Aluminium-silver slurry 6 ~ 10%
Aluminium-silver slurry directing agent 0.5 ~ 1.5%
Auxiliary agent 0.3 ~ 1.5%
Solvent 10 ~ 20%
Further, described silicone resin comprises poly-methyl silicon resin, poly-aryl silicone resin, epoxy modified silicone resin, polyimide modified silicone resin, phenol aldehyde modified silicone resin.
Further, described auxiliary agent comprises flow agent, anti-settling agent, adhesion promoter, wetting dispersing agent, matting agent, and the weight ratio between them is 1:2:3:0.1 ~ 0.5:0.2 ~ 0.6.
Further, described solvent comprises: N-BUTYL ACETATE, vinyl acetic monomer, dimethylbenzene, mass ratio are 5:3:2.
The preparation method of described high temperature resistant aluminium powder paint may further comprise the steps:
1) silicone resin, Hydroxylated acrylic resin, cellulose acetate, aluminium-silver slurry directing agent and the auxiliary agent of adding formula ratio in container A, the setting stirring velocity is 1200 ~ 1300rpm, stirs 15 ~ 20min, gets resin binder a.
2) aluminium-silver slurry, the solvent of adding formula ratio in container B, the setting stirring velocity is 450 ~ 500rpm, stirs 20 ~ 25min, gets aluminium-silver slurry material b.
3) setting the container A stirring velocity is 300 ~ 400rpm, and a is slowly joined among the b, continues to stir 30min to a and mixes with b.
The present invention has the following advantages and beneficial effect:
Can for a long time high temperature resistantly reach 400 ~ 450 ℃, good with the metal substrate bonding force, paint film is stable, and resistance to chemical attack also has excellent workability.
Embodiment
Describe technical scheme of the present invention in detail below in conjunction with embodiment, but protection domain is not so limited.
Embodiment 1
Entering mass percent in container A is 25% silicone resin, 40% Hydroxylated acrylic resin, 8% cellulose acetate, (auxiliary agent comprises 0.15% flow agent for 1.0% aluminium-silver slurry directing agent and 1.0% auxiliary agent, 0.32% anti-settling agent, 0.47% adhesion promoter, 0.02% wetting dispersing agent and 0.04% matting agent), the setting stirring velocity is 1300rpm, stirs 20min, gets resin binder a.
Add 10% aluminium-silver slurry, 15% solvent (solvent comprises 7.5% N-BUTYL ACETATE, 4.5% vinyl acetic monomer and 3.0% dimethylbenzene) of formula ratio in container B, the setting stirring velocity is 450 ~ 500rpm, stirs 25min, gets aluminium-silver slurry material b.
Setting the container A stirring velocity is 400rpm, and a is slowly joined among the b, continues to stir 30min to a and mixes with b.
Embodiment 2
Entering mass percent in container A is 28% silicone resin, 35% Hydroxylated acrylic resin, 10% cellulose acetate, (auxiliary agent comprises 0.15% flow agent for 1.0% aluminium-silver slurry directing agent and 1.0% auxiliary agent, 0.32% anti-settling agent, 0.47% adhesion promoter, 0.02% wetting dispersing agent and 0.04% matting agent), the setting stirring velocity is 1300rpm, stirs 20min, gets resin binder a.
Add 8% aluminium-silver slurry, 17% solvent (solvent comprises 8.5% N-BUTYL ACETATE, 5.1% vinyl acetic monomer and 3.4% dimethylbenzene) of formula ratio in container B, the setting stirring velocity is 450rpm, stirs 25min, gets aluminium-silver slurry material b.
Setting the container A stirring velocity is 400rpm, and a is slowly joined among the b, continues to stir 30min to a and mixes with b.
Embodiment 3
Entering mass percent in container A is 30% silicone resin, 40% Hydroxylated acrylic resin, 10% cellulose acetate, (auxiliary agent comprises 0.15% flow agent for 1.5% aluminium-silver slurry directing agent and 1.5% auxiliary agent, 0.32% anti-settling agent, 0.47% adhesion promoter, 0.02% wetting dispersing agent and 0.04% matting agent), the setting stirring velocity is 1300rpm, stirs 20min, gets resin binder a.
Add 10% aluminium-silver slurry, 6% solvent (solvent comprises 3% N-BUTYL ACETATE, 1.8% vinyl acetic monomer and 1.2% dimethylbenzene) of formula ratio in container B, the setting stirring velocity is 450rpm, stirs 25min, gets aluminium-silver slurry material b.
Setting the container A stirring velocity is 400rpm, and a is slowly joined among the b, continues to stir 30min to a and mixes with b.
Claims (5)
1. high temperature resistant aluminium powder paint is characterized in that: mainly the material by following weight percent forms:
Organosilicon resin 15 ~ 20%
Hydroxylated acrylic resin 30 ~ 40%
Cellulose acetate 8 ~ 10%
Aluminium-silver slurry 6 ~ 10%
Aluminium-silver slurry directing agent 0.5 ~ 1.5%
Auxiliary agent 0.3 ~ 1.5%
Solvent 10 ~ 20%.
2. high temperature resistant aluminium powder paint according to claim 1 is characterized in that: described silicone resin comprises poly-methyl silicon resin, poly-aryl silicone resin, epoxy modified silicone resin, polyimide modified silicone resin, phenol aldehyde modified silicone resin.
3. high temperature resistant aluminium powder paint according to claim 1, it is characterized in that: described auxiliary agent comprises flow agent, anti-settling agent, adhesion promoter, wetting dispersing agent, matting agent, the weight ratio between them is 1:2:3:0.1 ~ 0.5:0.2 ~ 0.6.
4. high temperature resistant aluminium powder paint according to claim 1, it is characterized in that: described solvent comprises: N-BUTYL ACETATE, vinyl acetic monomer, dimethylbenzene, mass ratio are 5:3:2.
5. the preparation method of high temperature resistant aluminium powder paint according to claim 1 is characterized in that: may further comprise the steps:
1) at silicone resin, Hydroxylated acrylic resin, cellulose acetate, aluminium-silver slurry directing agent and the auxiliary agent of container A adding formula ratio, the setting stirring velocity is 1200 ~ 1300rpm, stirs 15 ~ 20min, gets resin binder a;
2) aluminium-silver slurry, the solvent of adding formula ratio in container B, the setting stirring velocity is 450 ~ 500rpm, stirs 20 ~ 25min, gets aluminium-silver slurry material b;
3) setting the container A stirring velocity is 300 ~ 400rpm, and a is slowly joined among the b, continues to stir 30min to a and mixes with b.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210573640.2A CN103045035B (en) | 2012-12-26 | 2012-12-26 | High-temperature resistant aluminum powder paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210573640.2A CN103045035B (en) | 2012-12-26 | 2012-12-26 | High-temperature resistant aluminum powder paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103045035A true CN103045035A (en) | 2013-04-17 |
| CN103045035B CN103045035B (en) | 2014-12-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210573640.2A Active CN103045035B (en) | 2012-12-26 | 2012-12-26 | High-temperature resistant aluminum powder paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103045035B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275614A (en) * | 2013-05-30 | 2013-09-04 | 苏州艾特斯环保材料有限公司 | High-temperature-resistant anticorrosive coating containing polyimide modified organic silicon resin |
| CN104479546A (en) * | 2014-12-21 | 2015-04-01 | 劳启绪 | Preparation process of coating added with nanometer calcium carbonate powder |
| CN104479545A (en) * | 2014-12-21 | 2015-04-01 | 劳启绪 | Antibacterial coating |
| CN104497863A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Electrostatic shielding coating containing nano Ni powder |
| CN104497862A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Nanometer Co powder-doped modified coating |
| CN104497864A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Composite nanometer electrostatic screening coating and process thereof |
| CN104497865A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Nanometer ZnO powder-doped coating |
| CN104530964A (en) * | 2014-12-21 | 2015-04-22 | 劳启绪 | Preparation method of magnetic coating |
| CN105778687A (en) * | 2016-03-17 | 2016-07-20 | 国家电网公司 | Organosilicon-aluminum powder corrosion inhibitor preparation method, organosilicon-aluminum powder corrosion inhibitor and application of organosilicon-aluminum powder corrosion inhibitor |
| CN107201168A (en) * | 2017-07-19 | 2017-09-26 | 合肥铭佑高温技术有限公司 | A kind of high Wear-resistant, high-temperature resistant coating of adhesive force |
| CN107868569A (en) * | 2017-11-17 | 2018-04-03 | 湖南太子化工涂料有限公司 | A kind of metallic paint |
| CN108841029A (en) * | 2018-06-08 | 2018-11-20 | 凯鑫管道科技有限公司 | A kind of anticorrosive heatproof modification plastic and its preparation process |
| CN110537824A (en) * | 2018-05-28 | 2019-12-06 | 佛山市顺德区美的电热电器制造有限公司 | Inner pot suitable for electromagnetic heating, preparation method thereof and cooking utensil |
| CN113717637A (en) * | 2021-09-07 | 2021-11-30 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101737952A (en) * | 2010-01-29 | 2010-06-16 | 曾赞伦 | Manufacturing method of water tank of water heater |
| CN102492323A (en) * | 2011-11-30 | 2012-06-13 | 精碳伟业（北京）科技有限公司 | Ultra-thin steel structure fire-resistant coating material with multi-core structure |
-
2012
- 2012-12-26 CN CN201210573640.2A patent/CN103045035B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101737952A (en) * | 2010-01-29 | 2010-06-16 | 曾赞伦 | Manufacturing method of water tank of water heater |
| CN102492323A (en) * | 2011-11-30 | 2012-06-13 | 精碳伟业（北京）科技有限公司 | Ultra-thin steel structure fire-resistant coating material with multi-core structure |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275614A (en) * | 2013-05-30 | 2013-09-04 | 苏州艾特斯环保材料有限公司 | High-temperature-resistant anticorrosive coating containing polyimide modified organic silicon resin |
| CN103275614B (en) * | 2013-05-30 | 2015-08-05 | 苏州艾特斯环保材料有限公司 | A kind of fire-resistant anticorrosion paint containing polyimide modified silicone resin |
| CN104497862A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Nanometer Co powder-doped modified coating |
| CN104497863A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Electrostatic shielding coating containing nano Ni powder |
| CN104479545A (en) * | 2014-12-21 | 2015-04-01 | 劳启绪 | Antibacterial coating |
| CN104497864A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Composite nanometer electrostatic screening coating and process thereof |
| CN104497865A (en) * | 2014-12-21 | 2015-04-08 | 陈翠莲 | Nanometer ZnO powder-doped coating |
| CN104530964A (en) * | 2014-12-21 | 2015-04-22 | 劳启绪 | Preparation method of magnetic coating |
| CN104479546A (en) * | 2014-12-21 | 2015-04-01 | 劳启绪 | Preparation process of coating added with nanometer calcium carbonate powder |
| CN105778687A (en) * | 2016-03-17 | 2016-07-20 | 国家电网公司 | Organosilicon-aluminum powder corrosion inhibitor preparation method, organosilicon-aluminum powder corrosion inhibitor and application of organosilicon-aluminum powder corrosion inhibitor |
| CN105778687B (en) * | 2016-03-17 | 2018-05-15 | 国家电网公司 | The preparation method of organic aluminum silicon powder corrosion inhibiter, organic aluminum silicon powder corrosion inhibiter and its application |
| CN107201168A (en) * | 2017-07-19 | 2017-09-26 | 合肥铭佑高温技术有限公司 | A kind of high Wear-resistant, high-temperature resistant coating of adhesive force |
| CN107868569A (en) * | 2017-11-17 | 2018-04-03 | 湖南太子化工涂料有限公司 | A kind of metallic paint |
| CN110537824A (en) * | 2018-05-28 | 2019-12-06 | 佛山市顺德区美的电热电器制造有限公司 | Inner pot suitable for electromagnetic heating, preparation method thereof and cooking utensil |
| CN108841029A (en) * | 2018-06-08 | 2018-11-20 | 凯鑫管道科技有限公司 | A kind of anticorrosive heatproof modification plastic and its preparation process |
| CN108841029B (en) * | 2018-06-08 | 2021-01-19 | 凯鑫管道科技有限公司 | Corrosion-resistant heat-resistant modified plastic and preparation process thereof |
| CN113717637A (en) * | 2021-09-07 | 2021-11-30 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
| CN113717637B (en) * | 2021-09-07 | 2022-08-02 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103045035B (en) | 2014-12-10 |
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Inventor after: Wang Aiyuan Inventor before: Di Chuanwei Inventor before: Li Zhuangxian |
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Free format text: CORRECT: INVENTOR; FROM: ZHAI CHUANWEI LI ZHUANGXIAN TO: WANG AIYUAN |
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| C14 | Grant of patent or utility model | ||
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Address after: 266112 Chengyang District, Qingdao, Shandong Province, Wangjiazhuang Street Community Neighborhood Committee North 500 meters. Patentee after: Qingdao Kerui new environmental protection materials Group Co. Ltd. Address before: 266112 Chengyang District, Qingdao, Shandong Province, Wangjiazhuang Street Community Neighborhood Committee North 500 meters. Patentee before: Qingdao Creek New Environmental Materials Co., Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high temperature resistant aluminum paint Effective date of registration: 20201012 Granted publication date: 20141210 Pledgee: Qingdao Huiquan Private Capital Management Co., Ltd Pledgor: QINGDAO KERUI NEW ENVIRONMENTAL MATERIALS GROUP Co.,Ltd. Registration number: Y2020370010043 |